CRUISE REPORT HUDSON 95003 NEWFOUNDLAND BASIN WOCE CONTROL VOLUME AR13 19 APRIL 1995 - 17 MAY 1995 A. CRUISE NARRATIVE 1. Highlights a.WOCE Designation: Control Volume 4, Atlantic Repeat Hydrographic Section 13 b. Expedition Designation: Hudson 95003 c. Chief Scientist: R. Allyn Clarke Ocean Circulation Division Physical and Chemical Sciences Branch Department of Fisheries and Oceans Bedford Institute of Oceanography P.O. Box 1006 Dartmouth, NS, Canada B2Y 2A4 FAX 902 426 7827 Internet clarkea@mar.dfo-mpo.gc.ca d. Ship: CSS Hudson e. Ports of Call: April 19 BIO, Dartmouth, NS, Canada May 17 BIO, Dartmouth, NS, Canada f. Cruise Dates: April 19, 1995 to May 17, 1995 2. Cruise Summary Information a. Cruise Track A cruise track is included without time information in Figure 1*. The station positions are shown in Figure 2*. Some station numbers are indicated for clarity. The various types of stations are indicated. The WHP stations are all contained in the box defined by 38-47 (N and 38-50 (W. Test CTD stations and Scotian shelf monitoring stations were also occupied. This map also shows the locations of the North Atlantic Current Meter Mooring Array (ACM6) set from Oceanus in August 1993. Fig. 1* 95003 Cruise Track Fig. 2* 95003 Station Positions b. Total Number of Stations Occupied 88 full depth WHP small volume CTD stations with up to 23 rosette samples analyzed for CFC's, carbon tetrachloride, total carbonate, alkalinity, oxygen, salinity and nutrients. 88 full depth velocity profiles using a lowered Acoustic Doppler Current profiler attached to the CTD/rosette 8 full depth Scotian Shelf monitoring stations with up to 12 rosette samples analyzed for oxygen, salinity and nutrients. 3 test CTD stations with or without rosette sampling. 8 current meter mooring stations 3 aborted CTD casts c. Floats and Drifters deployed none d. Moorings deployed or recovered 8 current meter mooring stations; 6 moorings recovered, failed to recover two other moorings in the same array 3. List of Principal Investigators Name Affiliation Responsibility Allyn Clarke Physical and Chemical Sciences CTD, shipboard Bedford Institute of Oceanography ADCP, clarkea@mar.dfo-mpo.gc.ca current meter data Peter Jones Physical and Chemical Sciences chemical data Bedford Institute of Oceanography jonesp@mar.dfo-mpo.gc.ca Robert Pickart Physical Oceanography Department lowered ADCP Woods Hole Oceanographic Institution pickart@rsp.whoi.edu Randy Watts Graduate School of Oceanography current meter data University of Rhode Island South Ferry Road Narragansett, RI 02882 randy@drw.gso.uri.edu 4. Scientific Program and Methods a. Narrative This was primarily a hydrographic survey involving a series of full depth CTD/Tracer stations spaced at 20 nautical miles or less apart. The sections were selected to be either historical sections for which there were a number of earlier occupations or along TOPEX/POSEIDON ground paths. The sections enclosed three volumes of water; it was hoped that the section data and the boxes could be used to determine the splitting of the Gulf Stream, North Atlantic Current, Labrador Current and Deep Western Undercurrent within this topographically and dynamically complex region. Initial results have indicated that this goal is achievable. It was originally intended to split the southernmost box into two parts with a section crossing the Southeast Newfoundland ridge (normally at a location at which the shallowest depth crossing the ridge would have been about 4000 metres). This section has not been occupied on any of the three hydrographic surveys; the two previous surveys (18HU93039 and 18HU94030) and this one (18HU95003). During this cruise, an ADCP was added to the CTD/rosette package to provide a estimate of the full depth velocity profile at each CTD station. This data will be useful for the detection and definition of various subsurface currents such as the deep western boundary undercurrents. The mooring array (ACM6) was set from Oceanus in August 1993. The array was designed to measure the transport of the North Atlantic Current just downstream of the Southeast Newfoundland ridge. The array was also designed to measure the transport of the currents between the North Atlantic Current and the upper continental slope of the Grand Banks of Newfoundland, as well as the transport of the deep western boundary current found in this same region. 5. Major Problems and Goals Not Achieved Time lost due to poor weather and mooring recovery delays meant that there was not enough time to complete the fourth section across the North Atlantic Current. As an alternative, an additional section was surveyed to aid in defining the water masses and transports south of Flemish Cap. Insufficient time did not permit the section across the Southeast Newfoundland Ridge to be occupied. This will reduce our ability to separate what waters move from the Gulf Stream extension into the North Atlantic Current and what waters turn southward back into the Saragasso Sea. The loss of the main buoyancy packages and the flooding of two current meters will reduce the ability to accurately define the transport of the North Atlantic Current, particularly in the upper kilometre of the water column. Release failures also prevented the recovery of two of the eight moorings. Hopefully an attempt to recover these moorings can be made in June (18HU95011) using cable cutters or dragging. It is known that both moorings are in their original locations and are still upright. 6. Other Incidents of Note Early in the program, there were several failures of the ground connection between the CTD and the armour of the CTD cable and one failure of the slip rings on the winch. This delayed progress and also resulted in the lack of discrete samples on one CTD station. 7. List of Cruise Participants Name Responsibility Affiliation Larry Bellefontaine Watchkeeper BIO Gerry Boudreau Computers/watchkeeper BIO Rick Boyce Watchkeeper/moorings BIO Bruce Carson CTD tech./salts BIO Allyn Clarke Chief Scientist BIO Pierre Clement Nutrients/Oxygen BIO Paul d'Entremont Watchkeeper/moorings BIO Bob Gershey CFC/Alkalinity/Carbonate BDR Research Mike Hingston CFC/Alkalinity/Carbonate BDR Research Anthony Isenor Data Quality/watchkeeper BIO Peter Jones Assistant Scientist BIO Daniel Torres LADCP/Watchkeeper WHOI Igor Yashayaev Data Quality/watchkeeper Shirshov Frank Zemlyak CFC/Alkalinity/Carbonate BIO BIO Bedford Institute of Oceanography P.O. Box 1006 Dartmouth, NS, CANADA B2Y 2A4 BDR BDR Research Ltd. Box 652, Station 'M' Halifax, N.S., Canada, B3J 2T3 WHOI Woods Hole Oceanographic Institution Woods Hole, MA 02543, USA Shirshov P.P. Shirshov Institute of Oceanology Russian Academy of Sciences Krasikova, 23 Moscow, Russia B. UNDERWAY MEASUREMENTS 1. Navigation and Bathymetry Anthony W. Isenor The navigation system onboard CSS Hudson consisted of a Trimble Navigation Loran-GPS 10X decoder and a software package called AGCNAV. The decoder receives the satellite fixes and decoded the signals to obtain latitude, longitude and time. The decoder signals were approximately 1Hz. The navigation data was logged at one minute intervals on a personal computer (PC). This PC was running AGCNAV, a PC based display and way-point setting software package developed at the Atlantic Geoscience Centre at BIO. This software graphically displayed ship position, way-points, course, speed, etc. to the various science working areas. The echo sounder system used for collecting bathymetric data consisted of a Raytheon Line Scan Recorder, Model LSR 1811-1 connected to a hull mounted 12kHz transducer. The transducer beam width was 15 degrees. The sweep rate of the recorder was adjusted throughout the course of data collection to aid in identifying the bottom signal. The recorder was also linked to a clock, and thus could indicate five minute intervals on the sounder paper. The system was used to collect bathymetric soundings at five minute intervals while underway between stations throughout the cruise. In total, 4330 kilometres of deep sea bathymetric sounding data was collected. 2. Acoustic Doppler Current Profiler Murray Scotney The Hudson was equipped with a hull mounted RDI acoustic doppler current profiler. The transducer (serial number 177) had SC ADCP electronics (serial number 172) converted for ship board use. Using Transect software, ADCP logging was started on April 19 at 15:35 GMT in Halifax Harbour (Bedford Basin). The configuration of the equipment resulted in a bin length of eight metres and a total of 50 bins. The raw data were stored to disk and backed up every two days. Two days of logging created about 30MB of data. The data was also averaged in real-time over one minute intervals. ADCP logging was stopped on May 16 at 19:06 GMT. In total, 640 hours of Acoustic Doppler Current Profiler data was collected. 3. Thermosalinograph No instrument was used. 4. XBT and XCTD No probes were used. 5. Meteorological Observations Routine reporting of meteorological variables was carried out by the ship's crew. 6. Atmospheric Chemistry There was no atmospheric chemistry program. C. HYDROGRAPHIC MEASUREMENTS - DESCRIPTIONS, TECHNIQUES AND CALIBRATIONS 1. CTD Measurements Allyn Clarke, Anthony Isenor and Igor Yashayaev a. Description of the Equipment and Technique The CTD measurements were made with a standard SEABIRD model 9Plus CTD (serial number 09P 7356-0299, BIO System #4 or serial number 09P 9984-0370, BIO System #5) that was equipped with a model 3-02/F temperature sensor, a model 4-02/0 conductivity sensor, a paroscientific digiquartz model 410K-105 pressure sensor and a model 13-02 dissolved oxygen sensor. All but the pressure sensor were mounted in a duct through which a pump pulled sea water. Hence, the water flow past the actual sensors was independent of the lowering rate; this simplified the data processing considerably. The Seabird CTD was mounted vertically within a custom designed and built CTD/Rosette frame. This frame was square rather than round to better accommodate the restricted space of Hudson's winch room and winch room door. All the pressure cases as well as the sample bottles were mounted vertically to improve the package's stability as it descended through the water column. In the centre of the frame was a 10 inch diameter aluminium tube. The top end of this tube contained a General Oceanics Model 1015-24 bottle rosette unit. The bottom of this tube was designed to hold an RDI 150 khz Broadband ADCP in a shortened pressure case. On this cruise, the short pressure case RDI was not available; instead a full length RDI pressure case was clamped vertically down one side of the central tube. On the second side was clamped the pressure case for the Seabird CTD. The CTD sensors and pump were mounted on the third side. On the fourth side was clamped a rechargeable battery pack for the RDI and below it a General Oceanics model 6000 12 kHz pinger unit. BIO Rosette #3 (model 1015-24, serial number 1348) was used throughout the cruise. The rosette bottles were made by the Physical and Chemical Oceanographic Data Facility of the Scripps Institution of Oceanography. The bottles were mounted six to each side of the rosette frame. Each bottle collected 10 litres of water. b. Sampling Procedure and Data Processing Techniques The CTD was deployed with a lowering rate of 60 metres/min (40 metres/min in the upper 200 metres or deeper if the conditions were rough). It was recovered at a rate of 75 metres/min (60 metres/min when deeper than 4000 metres or when conditions were rough) The CTD data was recorded onto disk by a 486 computer using SEABIRD SEASOFT Version 4.205 software. A screen display of temperature, oxygen and salinity profiles vs pressure was used to determine the depths at which bottles were to be tripped on the upcast. The bottles were tripped using the enable and fire buttons on the SEABIRD deck unit. The SEASAVE software stored fifty scans at each bottle trip within a separate file. At the end of each station, the SEASAVE software was used to create one and two dbar processed data files, a one second processed data file, an IGOSS TESAC message and a processed rosette trip file. All the raw and processed data files associated with the station were then transferred to the ship's MicroVax computer for the purpose of archiving the data, allowing subsequent access to the data, and to enable the distribution of the data to various users on the vessel. The data processing used the following steps: DATCNV Converted the raw data to physical parameters. SPLIT Split the data into DOWN and UP cast. WILDEDIT For every block of 12 scans, flagged all scans whose pressure, temperature, conductivity and oxygen values differed from the mean by more than two standard deviations. Recomputed the mean and standard deviation from unflagged data then marked as bad all scans exceeding four standard deviations from these new values. FILTER Used a low pass filter to time match the pressure and conductivity parameters for salinity computation. Time constant used for conductivity was 0.045 seconds, for pressure 0.150 seconds. LOOPEDIT Marks as bad, all cycles on the down trace for which the vertical velocity of the CTD unit was less than 0.1 metres/sec. ALIGNCTD Aligned the temperature, conductivity and oxygen values relative to the pressure values accounting for the time delays in the system. Time offsets of 0.010 seconds for conductivity, 0.000 seconds for temperature and 3.000 seconds for oxygen were used. CELLTM A recursive filter used to remove the thermal mass effects from the conductivity data. Thermal anomaly amplitude and time constants of 0.0300 and 9.0000 were used. DERIVE Computed oxygen values. BINAVG Averaged the down cast into one or two dbar pressure bins. (Note: The procedure to produce the two dbar averages took about 5% of the total processing time). DERIVE Computed salinity, potential temperature and sigmatheta. c. Calibration Data A calibration summary is presented in Table C1. The three headings in the Table (Shipboard Processing, First Calibration and Second Calibration) represent sections in the text that follows. In the Oxygen row, the numerals I, II, and III represent procedures that were followed to determine the applied coefficients. The procedures are described in section (iv) Oxygen Calibration Procedure. The numerics in this table (e.g. 1 - 107) represent station numbers. Parameter 24 Hz Data 1 and 2 dbar data Shipboard First Second Processing Calibration Calibration Conductivity 1-6, 98-107 7-97(1) 7-97 Temperature 1-6, 98-107 7-97 Pressure 1-6, 98-107 7-97 Salinity 1-6(3) 7-97(4) 98-107(5) Oxygen 1 7-97(2) 2-6, 98-107(6) 2-107 7-75(7) 76-97(8) I, II => 7-97 I, III => 1-107 (1) : see Eqn 1 section ii (2) : see Eqn 2 section ii (3) : see Eqn 3 section iii (4) : see Eqn 4 section iii (5) : see Eqn 5 section iii (6) : see Eqn 6 section iii (7) : see Eqn 7 section iii (8) : see Eqn 8 section iii Table C1. CTD Calibration Summary. i. Shipboard Processing BIO SEABIRD CTD System #5 (Stations 1 to 6 and 98 to 107) Temperature Sensor (#031638) Coefficients used for Stations 1 to 6 and 98 to 107 Temperature = 1/{a + b[ln(Fo/F)] + c[ln^2[Fo/F] + d[ln^3(Fo/F)]} - 273.15 where ln indicates a natural logarithm, F is the frequency (Hz) a = 3.68096719 E-03 b = 6.02683750 E-04 c = 1.55348636 E-05 d = 2.30707462 E-06 Fo = 6034.530 slope = 1, offset = 0 (Seabird calibration dated July 6, 1994) System #5 Temperature Sensor (#031638) Calibration, 13-14 September, 1994, no pump Bath Temperature Seabird Temperature Temperature Residual °C °C Freq Temperature Hz m°C 30.0085 30.0064 11490.993 -2.1 30.0083 30.0059 11490.891 -2.4 25.0070 25.0053 10456.699 -1.7 25.0065 25.0048 10456.590 -1.7 20.0018 20.0010 9487.863 -0.8 20.0020 20.0011 9487.871 -0.9 15.0020 15.0019 8584.242 -0.1 15.0020 15.0018 8584.219 -0.2 9.9973 9.9984 7742.164 +1.1 9.9979 9.9985 7742.188 +0.6 4.9969 4.9979 6960.889 +1.0 4.9964 4.9973 6960.793 +0.9 -0.0065 -0.0043 6237.465 +2.2 -0.0070 -0.0051 6237.355 +1.9 -2.0091 -2.0068 5963.676 +2.3 -2.0090 -2.0068 5963.676 +2.2 System #5, Temperature Sensor (#031638) Calibration, 10-11 January, 1995, no pump Bath Temperature Seabird Temperature Temperature Residual °C °C Freq Temperature Hz m°C 30.0071 30.0022 11490.094 -4.9 30.0071 30.0020 11490.055 -5.1 25.0059 25.0017 10455.969 -4.2 25.0058 25.0016 10455.953 -4.2 20.0017 19.9981 9487.317 -3.6 20.0015 19.9979 9487.277 -3.6 14.9996 14.9973 8583.441 -2.3 14.9998 14.9973 8583.438 -2.5 9.9970 9.9954 7741.678 -1.6 9.9970 9.9955 7741.699 -1.5 4.9934 4.9915 6959.918 -1.9 4.9945 4.9932 6960.172 -1.3 -0.0120 -0.0128 6236.289 -0.8 -0.0122 -0.0132 6236.234 -1.0 -2.0134 -2.0136 5962.758 -0.2 -2.0133 -2.0135 5962.770 -0.2 System #5, Pressure Sensor (#50601) Coefficients used for Stations 1 to 6 and 98 to 107 Pressure = c (1 - To^2/T^2) (1 - d[1 - To^2/T^2]) where T is the pressure period c = c1 + c2 U + c3 U^2 d = d1 + d2 U To = T1 + T2 U + T3 U2 + T4 U^3 + T5 U^4 U is the temperature (°C) c1 = -4.274464E+04 psia c2 = 1.048032E+00 psia/°C c3 = 1.266000E-02 psia/°C^2 d1 = 4.087300E-02 d2 = 0 T1 = 3.009631E+01 µsec T2 = -6.293786E-05 µsec/°C T3 = 4.345040E-06 µsec/°C^2 T4 = 2.428830E-09 µsec/°C^3 T5 = 0 M = 1.145 E-02 B = -8.57985 slop = 1, offset = 0 (Seabird calibration, July 27, 1994) System #5, Pressure Sensor (#50601) Calibration, BIO, 20 September, 1994 Cylinder Mass Corrected Pressure Pressure Pressure Sensitivity Hysteresis Temp Load Pressure dbars Frequency Temp dbars dbars °C Kh dbars Hz °C 21.50 0 not -0.660 33231.281 21.35 -0.660 connected 21.50 0 connected -0.661 33231.265 21.44 -0.661 21.70 34 6800.008 6799.246 36835.238 21.52 -0.762 21.67 0 0.0 -0.705 33231.230 21.52 -0.705 -0.044 21.68 5 1000.050 999.570 33789.896 21.55 -0.480 21.70 10 2000.084 1999.522 34337.785 21.56 -0.562 21.72 15 3000.100 2999.689 34875.675 21.58 -0.411 21.74 20 4000.100 3999.464 35403.796 21.59 -0.636 21.75 25 5000.082 4999.386 35922.811 21.61 -0.696 21.77 30 6000.048 5999.109 36432.974 21.63 -0.939 21.80 34 6800.008 6799.173 36835.191 21.65 -0.835 -0.073 21.80 30 6000.048 5999.060 36432.947 21.66 -0.988 -0.049 21.80 25 5000.082 4999.266 35922.798 21.66 -0.816 -0.120 21.81 20 4000.100 3999.383 35403.740 21.67 -0.717 -0.081 21.83 15 3000.100 2999.438 34875.531 21.68 -0.662 -0.251 21.82 10 2000.084 1999.383 34337.680 21.69 -0.701 -0.139 21.85 5 1000.050 999.350 33789.733 21.71 -0.700 -0.187 21.85 0 0.0 -0.564 33231.281 21.74 -0.564 -0.141 21.85 0 disconnected -0.789 33231.141 21.83 -0.789 -0.129 System #5, Pressure Sensor (#50601) Calibration, BIO, 16 January, 1995 Cylinder Mass Corrected Pressure Pressure Pressure Sensitivity Hysteresis Temp Load Pressure dbars Frequency Temp dbars dbars °C Kh dbars Hz °C - 0 not -0.700 33231.215 21.66 -0.700 connected 0 - 0 connected 0 -0.633 33231.244 21.72 -0.633 21.05 34 6800.042 6799.270 36835.234 21.79 -0.772 21.02 0 0.0 -0.700 33231.199 21.77 -0.700 -0.067 21.03 5 1000.055 999.484 33789.797 21.79 -0.571 21.04 10 2000.094 1999.590 34337.764 21.80 -0.504 21.05 15 3000.115 2999.649 34875.633 21.81 -0.166 21.07 20 4000.120 3999.537 35403.809 21.82 -0.583 21.08 25 5000.107 4999.429 35922.820 21.84 -0.678 21.10 30 6000.078 5999.205 36433.012 21.85 -0.873 21.11 34 6800.042 6799.213 36835.203 21.87 -0.829 -0.057 21.12 30 6000.078 5999.137 36432.977 21.87 -0.941 -0.068 21.13 25 5000.107 4999.433 35922.820 21.88 -0.674 +0.004 21.14 20 4000.120 3999.486 35403.777 21.89 -0.634 -0.051 21.14 15 3000.115 2999.486 34875.539 21.89 -0.629 -0.163 21.15 10 2000.094 1999.395 34337.648 21.90 -0.699 -0.195 21.17 5 1000.055 999.408 33789.738 21.91 -0.647 -0.076 21.17 0 0.0 -0.706 33231.172 21.93 -0.706 -0.006 - 0 disconnected 0 -0.754 33231.141 21.96 -0.754 -0.054 - 0 20 minutes later -0.725 33231.113 22.27 -0.725 -0.025 System #5, Conductivity Sensor (#041375) Coefficients used for Stations 1 to 6 and 98 to 107 Conductivity = (aF^m + bF^2 + c + dT)/[10(1-9.57(10^-8)P)] where F is the conductivity frequency (Hz) P is pressure (dbars) T is the temperature ((C) m = 4.3 a = 1.18499540E-05 b = 5.13875405405E-01 c = -4.13341052E+02 d = 4.56046244E-05 Cpcor = -9.57 E-08 slope = 1, offset = 0 System #5, Conductivity Sensor (#041375), BIO calibration, 15 September, 1994 Bath Temp Bath Sal Inst Inst Inst Cond Inst Sal Residual T68 psu Temp Cond Freq psu Sal °C °C s/m Hz mpsu 1.7780 34.0935 1.7791 2.986140 8121.917 34.0890 -4.5 1.7829 34.0931 1.7837 2.986542 8122.397 34.0891 -4.0 10.4495 34.0559 10.4500 3.757474 8992.859 34.0498 -6.1 10.4382 34.0567 10.4386 3.756534 8991.850 34.0510 -5.7 17.4698 34.0508 17.4687 4.425574 9683.129 34.0456 -5.2 17.4737 34.0522 17.4730 4.426113 9683.665 34.0466 -5.6 System #5, Conductivity Sensor (#041375), BIO calibration, 12 January, 1995 Bath Temp Bath Sal Inst Inst Inst Cond Inst Sal Residual T68 psu Temp Cond Freq psu Sal °C °C s/m Hz mpsu 1.9366 34.2203 1.9355 3.009724 8149.949 34.2170 -3.3 1.9095 34.2201 1.9083 3.007394 8147.184 34.2171 -3.0 10.1104 34.1524 10.1086 3.735330 8969.055 34.1466 -5.8 10.0882 34.1520 10.0864 3.733313 8966.883 34.1470 -5.0 17.7877 34.1600 17.7845 4.469218 9726.484 34.1551 -4.9 17.7748 34.1610 17.7716 4.468103 9725.379 34.1564 -4.6 System #5, Oxygen Sensor (#130266) Coefficients used for Station 1 Oxygen = {Soc <--> (oc + tau <--> doc/dt ) + Boc] <--->OXSAT(T,S) <---> e^{tcor <-->[T + wt <-->(To - T)] + pcor <-->P} where Soc = 2.1015 oc is the oxygen sensor current (µamps) oc = mV + b m = 2.4692e-7 V is the oxygen temperature sensor voltage signal b = -4.1977e-10 tau = 2.0 doc/dt is the time derivative of oc Boc = -0.0646 T is the water temperature (°C) S is salinity (psu) e is natural log base tcor = -0.033 wt = 0.670 To oxygen sensor internal temperature (°C) To = kV + c k = 8.8993 c = -7.0715 pcor = 1.5e-4 P is the pressure (psia) System #5, Oxygen Sensor (#130284) Coefficients used for Stations 2 to 6 and 98 to 107 Oxygen = {Soc <--> (oc + tau <--> doc/dt ) + Boc] <--->OXSAT(T,S) <---> e^{tcor <-->[T + wt <-->(To - T)] + pcor <-->P} where Soc = 2.5328 oc is the oxygen sensor current (µamps) oc = mV + b m = 2.4528e-7 V is the oxygen temperature sensor voltage signal b = -3.9245e-9 tau = 2.0 doc/dt is the time derivative of oc Boc = -0.0322 OXSAT is the oxygen saturation value T is the water temperature (°C) S is salinity (psu) e is natural log base tcor = -0.033 wt = 0.670 To oxygen sensor internal temperature (°C) To = kV + c k = 8.9625 c = -6.9161 pcor = 1.5e-4 P is the pressure (psia) BIO Seabird CTD System #4 (Stations 7 to 97) System #4, Temperature Sensor (#031422) Coefficients used for Stations 7 to 97 Temperature = 1/{a + b[ln(Fo/F)] + c[ln^2[Fo/F] + d[ln^3(Fo/F)]} - 273.15 where ln indicates a natural logarithm F is the temperature frequency (Hz) a = 3.68096068 E-03 b = 5.98528033 E-04 c = 1.47933699 E-05 d = 2.18572143 E-06 Fo = 6142.890 slope = 1, offset = 0 (Seabird calibration 30 March, 1993) System #4, Temperature Sensor (#031422) Calibration, 5 May, 1993, no pump Bath Temperature Seabird Temperature Freq Residual °C Temperature Hz Temperature °C m°C 30.0094 30.0072 11745.723 -2.2 30.0091 30.0066 11745.582 -2.5 30.0094 30.0071 11745.703 -2.3 30.0096 30.0071 11745.703 -2.4 25.0082 25.0057 10682.410 -2.5 25.0081 25.0057 10682.410 -2.4 25.0082 25.0057 10682.410 -2.5 25.0081 25.0054 10682.336 -2.7 20.0036 20.0013 9686.863 -2.3 20.0033 20.0010 9686.812 -2.3 20.0035 20.0012 9686.848 -2.3 20.0035 20.0010 9686.836 -2.5 15.0046 15.0022 8758.813 -2.4 15.0044 15.0020 8758.781 -2.4 15.0041 15.0018 8758.743 -2.3 15.0041 15.0020 8758.781 -2.1 10.0029 10.0012 7894.793 -1.7 10.0030 10.0012 7894.793 -1.8 10.0038 10.0017 7894.875 -2.1 10.0039 10.0019 7894.902 -2.0 5.0057 5.0041 7093.652 -1.6 5.0060 5.0043 7093.676 -1.7 5.0068 5.0051 7093.813 -1.7 5.0060 5.0046 7093.739 -1.4 0.0085 0.0081 6352.609 -0.4 0.0085 0.0082 6352.629 -0.3 0.0049 0.0036 6351.972 -1.3 0.0056 0.0044 6352.098 -1.2 -1.9912 -1.9918 6072.230 -0.6 -1.9922 -1.9927 6072.145 -0.5 System #4, Temperature Sensor (#031422) Calibration, 6- 8 February, 1995, no pump Bath Temperature Seabird Temperature Freq Residual °C Temperature Hz Temperature °C m°C 30.0084 30.0039 11745.004 -4.5 30.0074 30.0030 11744.797 -4.4 25.0071 25.0033 10681.914 -3.8 25.0069 25.0031 10681.859 -3.8 20.0001 19.9971 9686.063 -3.0 20.0001 19.9973 9686.105 -2.8 14.9998 14.9974 8757.953 -2.4 15.0000 14.9976 8757.984 -2.4 9.9953 9.9936 7893.527 -1.7 9.9956 9.9940 7893.594 -1.6 4.9913 4.9906 7091.570 -0.7 4.9912 4.9900 7091.473 -1.2 -0.0133 -0.0136 6249.523 -0.3 -0.0128 -0.0131 6249.598 -0.3 -2.0151 -2.0148 6069.098 +0.3 -2.0153 -2.0146 6069.125 +0.7 System #4, Pressure Sensor (#53355) Coefficients used for Stations 7 to 97 Pressure = c (1 - To^2/T^2) (1 - d[1 - To^2/T^2]) where T is the pressure period ((sec) c = c1 + c2 U + c3 U^2 d = d1 + d2 U To = T1 + T2 U + T3 U^2 + T4 U^3 + T5 U^4 U is the temperature (°C) c1 = -42902.43 psia c2 = 5.13724 E-01 psia/°C c3 = 1.33407 E-02 psia/°C^2 d1 = 0.040395 d2 = 0.0 T1 = 29.93058 µsec T2 = -8.85537 E-05 µsec/°C T3 = 3.59773 E-06 µsec/°C^2 T4 = 5.58385 E-09 µsec/°C^3 T5 = 0.0 M = 1.146 E-02 B = -8.11354 slope = 1, offset = 0 (Seabird calibration dated 2 February, 1993) System #4, Pressure Sensor (#53355) Calibration, BIO, 5 May, 1993 Cylinder Mass Corrected Pressure Pressure Pressure Sensitivity Hysteresis Temp Load Pressure dbars Frequency Temp dbars dbars °C Kh dbars Hz °C 0 disconnected -0.731 33416.126 - -0.731 0 0.10 -0.594 33416.165 - -0.694 21.3 34 6800.108 6799.332 37027.258 - -0.776 21.3 0 0.10 -0.415 33416.149 - -0.515 +0.179 21.3 5 1000.150 999.522 33975.570 - -0.628 21.3 10 2000.184 1999.510 34524.473 - -0.674 21.3 15 3000.200 2999.312 35063.238 - -0.888 21.3 20 4000.200 3999.544 35592.664 - -0.656 21.4 25 5000.182 4999.472 36112.789 - -0.710 21.4 30 6000.148 5999.483 36624.219 24.70 -0.665 21.4 34 6800.108 6799.335 37027.242 24.75 -0.773 21.4 30 6000.148 5999.577 36624.264 24.80 -0.571 +0.094 21.5 25 5000.182 4999.628 36112.863 24.81 -0.554 +0.156 21.5 20 4000.200 3999.736 35592.754 24.85 -0.464 +0.192 21.5 15 3000.200 2999.540 35063.344 24.87 -0.660 +0.228 21.5 10 2000.184 1999.725 34524.566 24.89 -0.459 +0.215 21.5 5 1000.150 999.497 33975.522 24.92 -0.653 -0.025 21.5 0 0.10 -0.416 33416.104 24.95 -0.516 -0.001 0 disconnected -0.552 33416.012 25.10 -0.552 +0.179 2.5 hrs 0 disconnected -0.637 33416.100 23.69 -0.637 +0.094 later System #4, Pressure Sensor (#53355) Calibration, BIO, 1 February, 1995 Cylinder Mass Corrected Pressure Pressure Pressure Sensitivity Hysteresis Temp Load Pressure dbars Frequency Temp dbars dbars °C Kh dbars Hz °C - 0 not connected 0 -0.393 33416.336 21.74 -0.393 - 0 connected 0 -0.305 33416.383 21.77 -0.305 21.3 34 6800.042 6799.707 37027.379 21.82 -0.335 21.3 0 0.0 -0.231 33416.422 21.81 -0.231 +0.074 21.3 5 1000.055 999.480 33975.680 21.83 -0.575 21.3 10 2000.094 1999.700 34524.676 21.84 -0.394 21.3 15 3000.115 2999.580 35063.449 21.85 -0.535 21.3 20 4000.120 3999.679 35592.770 21.88 -0.441 21.4 25 5000.107 4999.708 36112.914 21.89 -0.399 21.4 30 6000.078 5999.790 36624.348 21.91 -0.288 21.4 34 6800.042 6799.693 37027.371 21.92 -0.349 21.4 30 6000.078 5999.853 36624.379 21.93 -0.225 +0.063 21.4 25 5000.107 4999.893 36113.008 21.95 -0.214 +0.185 21.4 20 4000.120 3999.923 35592.895 21.96 -0.197 +0.244 21.4 15 3000.115 2999.766 35063.543 21.97 -0.349 +0.186 21.4 10 2000.094 1999.766 34524.703 21.98 -0.328 +0.066 21.4 5 1000.055 999.559 33975.711 21.99 -0.496 +0.079 21.4 0 0.0 - 0.220 33416.410 22.01 -0.220 +0.011 - 0 disconnected 0 -0.300 33416.363 22.04 -0.300 +0.093 - 0 20 minutes -0.279 33416.336 22.48 -0.279 +0.114 later System #4, Conductivity Sensor (#041124) Coefficients used for Stations 7 to 97 Conductivity = (aF^m + bF^2 + c + dT)/[10(1-9.57(10^-8)P)] where F is the conductivity frequency (Hz) P is the pressure (dbars) T is the temperature (°C) m = 4.2 a = 1.35924955 E-05 b = 4.87959496 E-01 c = -4.19483432 E+00 d = -1.04684736 E-04 Cpcor = -957 E-08 slope = 1, offset = 0 (Seabird Calibration, 2 April, 1993) System #4, Conductivity Sensor (#041124), BIO calibration, 5 May, 1993 Bath Temp Bath Sal Inst Inst Inst Cond Inst Sal Residual T68 psu Temp Cond Freq psu Sal °C °C s/m Hz mpsu 0.1267 35.0423 0.1277 2.917687 8257.891 35.0411 -1.2 0.1240 35.0424 0.1251 2.917472 8257.625 35.0412 -1.2 0.1215 35.0424 0.1227 2.917263 8257.367 35.0412 -1.2 4.3346 35.0210 4.3355 3.286899 8701.239 35.0176 -3.4 4.3409 35.0210 4.3419 3.287479 8701.918 35.0177 -3.3 7.7561 35.0356 7.7584 3.601437 9061.598 35.0317 -3.9 7.7523 35.0352 7.7529 3.600926 9061.024 35.0318 -3.4 7.7456 35.0352 7.7459 3.600312 9060.344 35.0321 -3.1 10.6795 35.0226 10.6796 3.875049 9363.619 35.0183 -4.3 10.6639 35.0226 10.6642 3.873605 9362.052 35.0185 -4.1 13.4486 35.0389 13.4484 4.143345 9650.443 35.0349 -4.0 13.4452 35.0391 13.4451 4.143054 9650.136 35.0350 -4.1 13.4459 35.0391 13.4455 4.143132 9650.212 35.0354 -3.7 - 35.0228 19.4106 4.733862 10252.997 35.0192 -3.6 19.4216 35.0238 19.4204 4.734923 10254.047 35.0198 -4.0 19.4255 35.0238 19.4248 4.735397 10254.516 35.0200 -3.8 19.4285 35.0238 19.4278 4.735699 10254.815 35.0200 -3.8 System #4, Conductivity Sensor (#041124), BIO calibration, 9 - 10 February, 1995 Bath Temp Bath Sal Inst Inst Inst Cond Inst Sal Residual T68 psu Temp Cond Freq psu Sal °C °C s/m Hz mpsu 2.8866 33.4953 2.8863 3.032501 8398.320 33.4886 - 6.7 2.8588 33.4955 2.8569 3.030037 8395.332 33.4892 - 6.3 11.5195 34.4262 11.5169 3.894080 9384.266 34.4164 - 9.8 11.4847 34.4268 11.4823 3.890868 9380.785 34.4169 - 9.9 16.7196 34.4033 16.7165 4.391920 9908.648 34.3923 -11.0 16.7063 34.4044 16.7033 4.390761 9907.461 34.3935 -10.9 System #4, Oxygen Sensor (#130284) Coefficients used for Stations 7 to 97 Oxygen = [Soc <-->(oc + tau <--> doc/dt) + Boc] <-->OXYSAT(T,S) <-->e^{tcor <-->[T + wt <-->(To-T)] + pcor <-->P} where Soc = 2.5328 oc is the oxygen sensor current (µamps) oc = mV + b m = 2.4528e-7 V is the oxygen temperature sensor voltage signal b = -3.9245e-9 tau = 2.0 doc/dt is the time derivative of oc Boc = -0.0322 OXSAT is the oxygen saturation value T is the water temperature (°C) S is salinity (psu) e is natural log base tcor = -0.033 wt = 0.670 To oxygen sensor internal temperature (°C) To = kV + c k = 8.9625 c = -6.9161 pcor = 1.5e-4 P is the pressure (psia) ii. First Calibration The generated shipboard 1dbar downcast ODF data and the water sample data were used to determine calibrations (given below) for the System #4 CTD conductivity and oxygen data. These new calibrations were then applied to the raw 24 Hz data. The pressure, temperature and conductivity sensor coefficients given in section (i) for System #4 were applied, with the following changes: a) the conductivity slope and offset were changed according to Eqn. 1 below, b) Oxygen sensor coefficients were changed according to Eqn. 2 below. Conductivity Sensor (#041124) Coefficients used for Stations 7 to 97 Conductivity = 1.00039254 * Conductivity - 0.00054 Eqn. 1 Oxygen Sensor (#130284) Coefficients for System #4 (Stations 7 to 97) Oxygen = [Soc <-->(oc + tau <--> doc/dt) + Boc] <-->OXYSAT(T,S) <-->e^{tcor <-->[T + wt <-->(To-T)] + pcor <-->P} Eqn .2 where Soc = 3.679 oc is the oxygen sensor current (µamps) oc = mV + b m = 2.4528e-7 V is the oxygen temperature sensor voltage signal b = -3.9245e-9 tau = 2.0 doc/dt is the time derivative of oc Boc = -0.0696 OXSAT is the oxygen saturation value T is the water temperature (°C) S is salinity (psu) e is natural log base tcor = -0.033 wt = 0.670 To oxygen sensor internal temperature (°C) To = kV + c k = 8.9625 c = -6.9161 pcor = 1.70e-4 P is the pressure (psia) iii. Second Calibration The second calibration was applied to the 1 and 2 dbar dataset that resulted from the first calibration, section (ii). The second calibration is represented in Eqns. 3 - 8. Salinity Calibration for Station 1 to 6 Salinity(calibrated) = CTD Salinity(raw)+P0 + P1 <--> P(CTD) Eqn. 3 where P0 = 0.0033532 P1 = -6.78158E-07 P(CTD) is the CTD pressure in dbars Salinity Calibration for Station 7 to 97 Salinity(calibrated) = Salinity(raw)+P0 + P1 <--> P(CTD) + P2 <-->P^2(CTD) + P3 <-->P^3(CTD) + P4 <-->P^4(CTD) Eqn. 4 where P0 = 6.79984E-05 P1 = 2.17599E-06 P2 = -1.60105E-09 P3 = 3.4602E-13 P4 = -2.53291E-17 P(CTD) is the CTD pressure in dbars Salinity Calibration for Station 98 to 107 Salinity(calibrated) = Salinity(raw) + 0.0045 Eqn. 5 Oxygen calibration for Stations 2 to 6 and 98 to 107 (see section iv): Ox(ctd) = Ox(ctd) + o_ Ox(ctd) + t1 <-->T(CTD) + t2 <-->T^2(CTD) + a Eqn. 6 where a = 0.578 o = 0.296214 t1 = 0.0908199 t2 = -0.013218 Oxygen calibration for Stations 7 to 75 (see section iv): Ox(ctd) = Ox(ctd) + o_ Ox(ctd) + t1 <-->T(CTD) + t2 <-->T^2(CTD) + t3 <-->T^3(CTD) + p1 <-->P(CTD) + p2 <-->P^2(CTD) + a + Time_cor (Station number) Eqn. 7 where a = -0.3315964 o = 5.15001E-02 t = -1.8817E-02 t = -1.31562E-03 t = 1.44749E-04 p= -4.04006E-05 p= 9.03202E-09 Time_cor (Station number) - see Table C. 2 PCTD is the CTD pressure in dbars Oxygen calibration for Stations 76 to 97 (see section iv): Ox(ctd) = Ox(ctd) + o_ Ox(ctd) + t <-->T(CTD) + p1 <-->P(CTD) + p2 <-->P^2(CTD) + p3 <-->P^3(CTD) + p4 <-->P^4(CTD) + a Eqn. 8 where a = -1.913914 o = 0.184303 t = 0.162267 p1= 9.83471E-04 p2= -9.91903E-07 p3= 4.28312E-10 p4= -6.37949E-14 P(CTD) is the CTD pressure in dbars Table C.2 Station-to-station corrections. Station Correction Station Correction number (Time_cor) number (Time_cor) 7 0.2848143 42 0.0356818 8 0.1813909 43 0.04 9 0.0405818 44 0.04 10 0.11 45 0.0404813 11 0.1879071 46 0.1236333 12 0.11305 47 0.0064167 13 0.13994 48 0.01 14 0.0777733 49 0.03 15 0.0892929 50 0.05 16 0.1337333 51 0.0964111 17 0.1223 52 0.12847 18 0.0491714 53 0.056325 19 0.0699636 54 0.2120667 20 0.0081417 55 0.1764167 21 0.1265182 56 0.21886 22 0.0220546 57 0.2479417 23 -0.004567 58 0.2709636 24 0.0400077 59 0.2614 25 0.0425539 60 0.295 26 0.0189364 61 0.475 27 0.0440455 62 0.285 28 -0.017883 63 0.2352154 29 0.022882 64 0.2514615 30 0.039858 65 0.2502929 31 0.019646 66 0.2640154 32 -0.004789 67 0.2613273 33 -0.0143 68 0.26248 34 -0.007567 69 0.2750556 35 0 70 0.277625 36 0.005 71 0.3096555 37 0.01579 72 0.3310714 38 0.1192818 73 0.2840727 39 0.08 74 0.30094 40 0.07 75 0.28303 41 0.0534875 iv. Oxygen Calibration Procedure The calibration parameters for the CTD oxygen data (see equations 6, 7 and 8) were based on down trace CTD data and measurements of water sample oxygen concentration from bottles tripped on the uptrace. Although these datasets are inconsistent (to some degree) in time and spatial location, they were considered the only reliable source of information for calibration of CTD oxygen. The procedure for finding the calibrations to be applied to the downcast CTD oxygen was subdivided into three stages (both II and III are iterative procedures): I. Creating a calibration file, II. Computing non-linear 'hardware' coefficients, III. Computing corrections of time drift and residual effects of pressure, temperature and oxygen (secondary correction). I. Creating a Calibration File 1) The calibration file is used for finding and testing calibrations (set of coefficients) later applied to the CTD data, while computing CTD Oxygen. A base for this file consisted of discrete CTD readings of temperature, pressure, salinity, etc. averaged over three seconds at the depth and time of bottle tripping. The calibration file creation steps are outlined below; 2) Water sample salinity and oxygen concentration determined onboard were added to the calibration file; 3) For initial 'indirect' check of quality, the differences between water sample and calibrated CTD salinity were computed. If the absolute difference exceeded 0.004 the point (record) containing this data was considered unreliable and discarded from further analysis; 4) Next, a search and selection was performed for each record of the calibration file. The goal is to find a point in a downtrace profile in the same general water type. * data from a downtrace profile were restricted to a certain pressure (or/and) density (or/and) temperature (or/and) salinity vicinity of the uptrace point (the calibration file). This defines a group. Typical criteria (definition of vicinity): differences between uptrace and downtrace pressure 25 db, potential temperature 0.5K, salinity 0.02. [Note: For some upcast data points, no downcast point was found within the defined criteria. In these cases, the CTD oxygen in the SEA file is indicated with a null value of -9.0 and a quality flag of 9, not sampled.] * find a point in the group which is closest to the uptrace data point (from the calibration file) in multidimensional space, where dimensions are normalized (weighted or rescaled) pressure, potential temperature, salinity and density. Normalization for each axis was done according to expected variability within a water type. In ultimate cases only one or two dimensions were chosen. The found point was identified as being "closest" to the upcast CTD data point at the time of bottle trip. At this point, the downtrace CTD data has been added to the calibration file. 5) Next the dataset was split into sets based on distinct changes in the sensors behavior. The set represented quasi-steady periods of oxygen sensor behavior. This avoided extreme temporal drifts in any of the sets and allowed the use of the same non-linear coefficients for each set. II. Computing Non-linear 'Hardware' Coefficients 1) A nonlinear multiparametric least square technique was used to determine the oxygen sensor processing coefficients (soc, boc, tcor, and bcor) using oxygen(ws) vs. downcast temperature(ctd), salinity(ctd), pressure(ctd), oxygen current(ctd) and oxygen temperature(ctd) (where the ws/ctd subscripts represents water sample/CTD data). 2) Applying the results of step II.1, the oxygen(ctd) was derived. 3) Compute oxygen(ws) - oxygen(ctd). Statistics of the difference were computed and the records that produced outliers (no matter if the outliers were produced by oxygen(ws) or oxygen(ctd)) were marked or deleted from the calibration file. 4) Checking the oxygen(ws) - oxygen(ctd) distributions: * if the differences (oxygen(ws) - oxygen(ctd)) are randomly distributed versus all parameters (temperature, pressure, oxygen current, and oxygen temperature) and there are no evident outliers, proceed to stage III, * otherwise, using the cleaned calibration file (derived in stage I and cleaned according to II.3) repeat all the steps of stage II until the first part of the check II.4 is true (typically, it requires 10 to 15 iterations to clean the calibration file and determine the oxygen sensor processing coefficients soc, boc, tcor, and bcor). III. Computing corrections of time drift and residual effects of pressure, temperature and oxygen 1) Using the differences from II.4 (first iteration on this stage) or III.4 (second and higher iteration), compute the median oxygen(ws) - oxygen(ctd) for each station. The series of station-by-station medians represents the time drift of the sensor. 2) Subtract the individual station median (time drift, III.1) from the differences oxygen(ws) - oxygen(ctd) for that station, which must be taken from II.4. 3) Individually for pressure, temperature and then oxygen, use the set of stations (as defined in I.5) to compute a polynomial fit of the residuals from III.2 in pressure, temperature and oxygen. 4) Subtract the polynomial correction, derived in III.3, from the differences computed in II.4 (before subtraction of the time-drift). Check if there are any outliers. 5) Subtract the time drift (station median) from the results of III.4. * If these (new III.5) residuals don't depend on pressure, temperature, oxygen or time and their statistics is not improving with any sequential iteration (distribution getting tighter) advance to III.6. * Otherwise, use the results of step III.4 and repeat all the steps of stage III until the first bulleted part of III.5 is true. This iteration typically requires 7 to 14 repetitions. 6) Finalize calibration coefficients. v. CTD Quality Flagging The processed 2 dbar CTD was quality flagged by applying "bad" flags to the near-surface data. This data would have been collected before the system pump was activated, and thus does not represent a measurement from a properly operating system. This typically meant that the temperature, salinity and oxygen data above 10 dbars is flagged using WOCE flag "4". 2. Salinity Bruce Carson a. Description of Equipment and Technique Salinity samples were analyzed on one of two Guildline Autosal model 8400 salinometers. Samples were drawn in 150 ml medicine bottles. New caps, equipped with plastic liners, were placed on the sample bottles for each use. The salinometer cell was filled and rinsed three times with sample water before readings were recorded. Two readings of the salinometer were recorded for every sample and standardization. If the values were fluctuating, more readings were taken. b. Sampling Procedure and Data Processing Technique Salinity samples were drawn into medicine bottles after three rinses. The bottles were filled up to the shoulders and then capped with new caps with plastic liners. One conductivity file for the entire cruise was prepared. The file consisted of a sequential record number, the bath temperature, sample ID number, average conductivity ratio and a quality flag. A PC based program running under a commercial DBMS computed the salinity using the average conductivity ratio and the standard IAPSO formula. Any changes in the salinometer readings between successive standardizations was assumed to have occurred as a linear drift of the instrument. Thus, the program applied a correction to the ratios, which varied linearly with the samples analyzed. The salinity data was then placed in the water sample database. c. Laboratory and Sample Temperatures Full cases of samples were taken from the winch room to the GP lab where they were left for a period of at least 10 hours to equilibrate to laboratory temperature before being analyzed. The baths in these two salinometers were kept at 21°C and 24°C. The salinometer which was just above the current laboratory temperature would be the one that was used for any given run of samples. d. Replicate Analysis A duplicate salinity sample was drawn from one of the rosette bottles on every cast. In total, 82 duplicate samples were drawn for 82 sample id numbers. Seven of these sample id numbers (152952, 153208, 153686, 153831, 153832, 153833 and 154400) had at least one unacceptable sample value. All duplicate samples and their quality flags are given in Table C.3. Computed statistics on the absolute value of acceptable duplicate differences follow. Statistic Value Number of Duplicate Differences 75 Minimum 0 Maximum 0.0092 Mean 0.0007 Median 0.0006 Standard Deviation 0.0011 e. Standards Used The salinometer was standardized using IAPSO standard water, Batch P120, prepared on April 6, 1992. Standardization with a new ampoule was carried out at the beginning, middle and end of every 32 bottle case and at intermediate points during a case if instrument drift was suspected. Table C3 Replicate water sample salinity values. Sample ID Salinity WOCE QF Number -------- -------- ------- 152949 33.0339 2 152949 33.0337 2 152952 32.8931 2 152952 34.8676 4 152956 34.7786 2 152956 34.7788 2 152962 34.8739 2 152962 34.8751 2 152980 34.9245 2 152980 34.9247 2 153032 34.9039 2 153032 34.9041 2 153049 34.9014 2 153049 34.9013 2 153083 34.9363 2 153083 34.9369 2 153094 34.8793 2 153094 34.8800 2 153121 34.8929 2 153121 34.9022 2 153149 34.9442 2 153149 34.9451 2 153172 34.9448 2 153172 34.9460 2 153174 34.9608 2 153174 34.9610 2 153188 34.8833 2 153188 34.8837 2 153208 34.8680 2 153208 34.8749 3 153232 34.8723 2 153232 34.8722 2 153262 34.9417 2 153262 34.9419 2 153278 34.8755 2 153278 34.8757 2 153306 34.9148 2 153306 34.9157 2 153323 34.8747 2 153323 34.8755 2 153354 34.9342 2 153354 34.9346 2 153372 34.8972 2 153372 34.8976 2 153392 34.8822 2 153392 34.8824 2 153419 34.9117 2 153419 34.9119 2 153444 34.9134 2 153444 34.9136 2 153470 34.9273 2 153470 34.9263 2 153485 34.8949 2 153485 34.8953 2 153519 34.9595 2 153519 34.9601 2 153530 34.8900 2 153530 34.8908 2 153564 34.9319 2 153564 34.9327 2 153580 34.9092 2 153580 34.9088 2 153600 34.8924 2 153600 34.8908 2 153625 34.9038 2 153625 34.9039 2 153650 34.9144 2 153650 34.9149 2 153686 35.1460 2 153686 35.1460 3 153695 34.9078 2 153695 34.9067 2 153723 34.8846 2 153723 34.8862 2 153744 33.0321 2 153744 33.0322 2 153747 34.8614 2 153747 34.8620 2 153755 34.7606 2 153755 34.7616 2 153764 32.8646 2 153764 32.8634 2 153779 34.8900 2 153779 34.8899 2 153794 34.9209 2 153794 34.9211 2 153816 34.8535 2 153816 34.8541 2 153831 34.8939 3 153831 36.2645 4 153832 34.8984 3 153832 36.2808 4 153833 5 153833 34.9023 3 153836 34.9167 2 153836 34.9167 2 153857 34.9129 2 153857 34.9130 2 153884 34.9145 2 153884 34.9149 2 153902 34.8949 2 153902 34.8955 2 153927 34.9028 2 153927 34.9036 2 153946 34.8927 2 153946 34.8929 2 153970 34.8920 2 153970 34.8924 2 153993 34.8920 2 153993 34.8928 2 154024 34.9331 2 154024 34.9337 2 154044 34.9288 2 154044 34.9286 2 154069 34.9160 2 154069 34.9181 2 154085 34.8943 2 154085 34.8949 2 154109 34.8993 2 154109 34.8997 2 154131 34.8947 2 154131 34.8948 2 154171 34.9994 2 154171 35.0010 2 154177 34.8948 2 154177 34.8951 2 154202 34.9083 2 154202 34.9093 2 154223 34.8951 2 154223 34.8957 2 154246 34.8947 2 154246 34.8955 2 154275 34.9292 2 154275 34.9284 2 154308 34.8585 2 154308 34.8589 2 154322 34.9014 2 154322 34.9024 2 154337 34.9107 2 154337 34.9120 2 154356 34.0929 2 154356 34.0931 2 154359 34.4786 2 154359 34.4782 2 154363 34.1558 2 154363 34.1542 2 154374 33.8869 2 154374 33.8870 2 154400 5 154400 34.8736 2 154413 34.8186 2 154413 34.8186 2 154417 34.8758 2 154417 34.8776 2 154424 34.8535 2 154424 34.8545 2 154434 34.8677 2 154434 34.8669 2 154450 32.5194 2 154450 32.5202 2 154457 34.9317 2 154457 34.9329 2 154480 32.3407 2 154480 32.3399 2 3. Oxygen Pierre Clement a. Description of Equipment and Technique The oxygen samples were analyzed using an automated procedure developed by the Physical and Chemical Services Branch (PCS) of the Bedford Institute of Oceanography (BIO) from a manual titration system (Levy et al. 1977). The PCS procedure used a modified Winkler titration from Carritt and Carpenter (1966), using a whole bottle titration. In this method there was no starch indicator, and a wetting agent (Wetting Agent A, BDH) was introduced to reduce bubble formation. This automated titration system consisted of an IBM PC linked to a Brinkmann PC800 colorimeter and a Metrohm 665 Multi-Dosimat Automatic Titrator. A full description of the system and method can be found in Jones, et al. (1992). b. Sampling Procedure and Data Processing Technique The sampling bottles were 125ml Iodine flasks with custom ground stoppers (Levy et al. 1977). The flask volumes were determined gravimetrically. The matched flasks and stoppers were etched with identification numbers and entered into the Oxygen program database. For this cruise 10 litre rosette bottles were used to obtain the original sample. The oxygen subsamples were drawn, immediately following the drawing of the CFC subsamples, through the bottles spigot with a latex or silicone tube attached so as to introduce the water to the bottom of the flask. The flask and its stopper were thoroughly rinsed and filled to overflowing. The flow was allowed to continue until at least two to three flask volumes overflowed. The flask was then slowly retracted with continuous low flow to ensure that no air got trapped in the flask. The flask was then brought to the reagent station and one millilitre each of the Alkaline Iodide and Manganous Chloride Reagents were added and the stoppers carefully inserted, again ensuring that no air got into the flasks. The flasks were thoroughly shaken then carried to the lab for analysis. c. Replicate Analysis There were 1593 unique sample id numbers analyzed for dissolved oxygen, of which 1509 had one sample value, 83 had two sample values and 1 had three sample values. The replicate samples were taken from a water sample bottle at each station in order to monitor precision, which can be affected by flaws in sampling or titration. Statistics of the replicate differences follow. Only acceptable values were used in calculating the replicate differences. The calculated replicate statistics used the absolute value of the replicate differences. Of the 84 unique ids that had replicate samples, a replicate difference could not be calculated for seven of them. The sample id numbers were: 152952 , 153046, 153649, 153959, 153969, 154068 and 154176. The replicate difference could not be calculated for these sample id numbers because one or both of the sample values were unacceptable. In total, 157 acceptable sample values were used in calculating the 79 replicate differences. All of replicate sample values and their quality flags are listed in Table C.4 below. Number of replicate differences = (83 - 7) sample id numbers having one replicate * 1 possible difference + (1) sample id numbers having two replicates * 3 possible differences = 79 Median of [(absolute difference/sample mean concentration of all samples) * 100%] = 0.17 % Statistic Value (µmoles/kg) Minimum 0.0 Maximum 4.6 Mean 1.0 Median 0.4 Standard Deviation 1.2 Cumulative Frequency Oxygen Difference (µmoles/kg) 50 % less than or equal to 0.4 68 % less than or equal to 0.9 95 % less than or equal to 3.3 Table C4 Replicate water sample oxygen values in µmoles/kg. Sample ID Oxygen WOCE QF Number -------- ------ ------- 152949 353.4 2 152949 353.2 2 152952 284.8 4 152952 381.6 2 152960 276.7 2 152960 276.7 2 152990 266.1 2 152990 266.3 2 153002 274.8 2 153002 275.2 2 153027 275.4 2 153027 275.3 2 153046 266.6 3 153046 267.3 2 153082 265.7 2 153082 268.9 2 153093 256.1 2 153093 257.0 2 153129 268.0 2 153129 268.3 2 153139 256.9 2 153139 256.4 2 153166 263.9 2 153166 263.7 2 153195 265.9 2 153195 266.3 2 153209 256.9 2 153209 257.0 2 153231 256.9 2 153231 257.0 2 153269 209.5 2 153269 210.2 2 153277 255.2 2 153277 257.0 2 153312 270.8 2 153312 270.6 2 153329 266.4 2 153329 269.3 2 153361 265.5 2 153361 265.6 2 153370 263.6 2 153370 263.7 2 153393 263.6 2 153393 264.4 2 153422 265.3 2 153422 265.4 2 153457 184.6 2 153457 184.9 2 153463 273.5 2 153463 273.7 2 153503 199.9 2 153503 199.9 2 153510 273.7 2 153510 273.6 2 153531 268.0 2 153531 268.2 2 153573 233.1 2 153573 233.2 2 153589 250.1 2 153589 250.2 2 153599 265.5 2 153599 265.8 2 153637 224.1 2 153637 223.7 2 153649 273.4 2 153649 267.6 3 153681 241.9 2 153681 245.3 2 153681 246.6 2 153692 277.5 2 153692 279.8 2 153706 268.2 2 153706 268.6 2 153727 268.4 2 153727 268.2 2 153737 285.1 2 153737 286.5 2 153750 275.7 2 153750 276.9 2 153759 336.7 2 153759 336.9 2 153764 369.8 2 153764 370.2 2 153771 274.0 2 153771 273.3 2 153808 228.1 2 153808 229.8 2 153821 295.0 2 153821 295.4 2 153834 279.3 2 153834 280.2 2 153854 284.3 2 153854 285.6 2 153897 160.9 2 153897 161.1 2 153904 274.0 2 153904 274.3 2 153923 275.4 2 153923 274.8 2 153959 266.7 4 153959 266.9 4 153969 267.4 2 153969 269.5 3 153992 268.2 2 153992 268.6 2 154016 270.2 2 154016 270.4 2 154051 274.5 2 154051 274.5 2 154063 272.9 2 154063 276.2 2 154068 273.3 3 154068 279.1 3 154084 273.1 2 154084 273.5 2 154110 277.5 2 154110 275.3 2 154136 273.9 2 154136 274.1 2 154161 278.2 2 154161 278.3 2 154176 267.7 3 154176 269.4 2 154200 270.8 2 154200 271.4 2 154222 282.8 2 154222 282.3 2 154245 274.8 2 154245 273.4 2 154277 274.8 2 154277 276.9 2 154303 293.9 2 154303 298.4 2 154317 281.2 2 154317 281.6 2 154338 282.4 2 154338 283.1 2 154353 284.8 2 154353 284.5 2 154360 318.8 2 154360 320.1 2 154362 283.9 2 154362 285.8 2 154378 331.3 2 154378 333.7 2 154379 277.0 2 154379 278.0 2 154384 275.8 2 154384 275.3 2 154398 277.8 2 154398 277.6 2 154419 279.2 2 154419 281.1 2 154430 298.2 2 154430 298.6 2 154433 291.6 2 154433 295.5 2 154445 305.0 2 154445 309.3 2 154448 322.0 2 154448 324.4 2 154452 377.7 2 154452 376.9 2 154462 154.1 2 154462 157.0 2 154475 358.5 2 154475 358.8 2 154482 354.0 2 154482 353.8 2 4. Nutrients Pierre Clement a. Description of Equipment and Technique Nutrient concentrations were determined using a Technicon Autoanalyser II. The chemistries were standard Technicon (Silicate 186-72W, Phosphate 155-71W, Nitrate/Nitrite 158-71W) except for Phosphate which was modified by separating the Ascorbic Acid (4.0 gms/l) from the Mixed Reagent. This alteration was achieved by introducing the modified Mixed Reagent instead of water at the start of the sample stream at 0.23 ml/min and the Ascorbic Acid was pumped into the stream between the two mixing coils at 0.32 ml/min. b. Sampling Procedure and Data Processing Technique Duplicate nutrient subsamples were drawn into 30 ml HDPE (Nalge) wide mouth sample bottles from 10 litre Niskins. The bottles were 10% HCl washed, rinsed once with tap water, three times with Super-Q and oven dried at more than 100 Degrees F. A sample run included six Working Standards run at the beginning and end. Duplicate Check Standards were run every 16 samples followed by blanks as a Baseline Check. These Standards were made up in 33 ppt NaCl (VWR,Analar grade) as is the wash water. The Standards were tested against CSK Solution Standards (Sagami Chemical Center, Japan). Analog data was converted to digital, processed and statistics calculated by a Pascal 6.0 in house program (Logger) on a PC. Chart recordings, hard copy and disk copies of the data were kept for reference. c. Replicate Analysis A total of 3136 seawater samples were analyzed for silicate, phosphate and NO2+NO3. Included in these samples were a total of 1543 duplicate samples. Duplicate samples were drawn from each rosette bottle on every cast. Statistics relating to the precision of the sample values follow. All values are given in µmoles/kg. Only the samples that had acceptable duplicate values were included in the statistics. All duplicate values and their quality flags are given in Table C.5. Precision is a measure of the variability of individual measurements and in the following analysis two categories of precision were determined; field and analytical precision. Analytical precision is based on the pooled estimate of the standard deviation of the check standards over the course of a complete autoanalyzer run and is a measure of the greatest precision possible for a particular analysis. Field precision is based on the analysis of two or more water samples taken from a single Niskin sampling bottle and has an added component of variance due to subsampling, storage and natural sample variability. Both categories of precision were determined by computing the variance, sigma(i)^2 of each replicate set, where "i" is the index of the replicate set. In the case of analytical (field) precision, a replicate set consisted of all the check standards (duplicate samples). Given p replicate sets and n samples within any replicate set, the mean standard deviation, sigma was determined from *see equation in PDF file. The precision expressed in percent was based on the mean concentration, M, of the check standards (analytical precision) or water samples (field precision) and was given by *see equation in PDF file. The following table indicates the analytical and field precision obtained for this cruise. Statistic Silicate Phosphate NO2+NO3 Number of Samples 3136 3136 3136 Number of Duplicates 1543 1543 1543 Mean concentration 14.07 1.07 15.64 (µmoles/kg) Field Precision 0.24 0.03 0.42 (µmoles/kg) Field Precision (%) 1.70 3.00 2.70 Analytical Precision 0.38 0.05 0.23 (µmoles/kg) Analytical Precision 1.18 4.40 1.41 (%) Detection Limit 0.16 0.04 0.16 (µmoles/kg) The laboratory temperature during all analyses was between 21 and 23 °C. The conversion to mass units for the analytical precision and detection limits used a standard density of 1.02443 kg/litre corresponding to 33 ppt and 15°C. The conversion of individual sample values from volume to mass units used a potential density with a fixed temperature of 15°C. Duplicate samples were drawn from each rosette bottle for the determination of silicate, phosphate and nitrate concentrations. The nutrient detection limits noted in the above table were applied to the dataset. All values at or below the detection limits were set to zero. The following duplicate measurements (Table C.5) were used to compute the values given in the SEA file. All values that follow are in µmoles/kg. Table C5 Nutrient replicate water sample values in µmoles/kg. ID SiO4 PO4 NO2+NO3 WOCE QF ----- ----- ---- ------- ----------------- 152925 13.57 1.45 20.90 2 2 2 152925 13.53 1.45 21.06 2 2 2 152926 13.27 1.53 21.32 2 2 2 152926 13.36 1.49 21.58 2 2 2 152928 13.33 1.45 21.02 2 2 2 152928 13.52 1.47 21.02 2 2 2 152929 13.42 1.42 21.42 2 2 2 152929 13.62 1.46 21.24 2 2 2 152930 13.57 1.45 21.28 2 2 2 152930 13.45 1.43 21.54 2 2 2 152931 13.67 1.44 21.02 2 2 2 152931 13.80 1.46 21.34 2 2 2 152932 13.59 1.48 21.82 2 2 2 152932 13.76 1.45 21.68 2 2 2 152933 13.72 1.44 21.34 2 2 2 152933 13.82 1.46 21.32 2 2 2 152934 14.06 1.45 21.70 2 2 2 152934 13.93 1.41 21.22 2 2 2 152935 14.06 1.49 21.90 2 2 2 152935 13.86 1.46 22.10 2 2 2 152936 13.95 1.45 22.02 2 2 2 152936 14.31 1.43 21.46 2 2 2 152937 14.17 1.44 21.72 2 2 2 152937 14.27 1.45 21.94 2 2 2 152938 13.91 1.45 22.06 2 2 2 152938 14.00 1.46 21.92 2 2 2 152939 14.10 1.43 22.30 2 2 2 152939 14.19 1.44 21.64 2 2 2 152940 14.28 1.44 21.90 2 2 2 152940 14.28 1.44 22.18 2 2 2 152941 14.05 1.46 21.74 2 2 2 152941 14.34 1.44 22.24 2 2 2 152942 14.26 1.40 21.57 2 2 2 152942 14.10 1.43 21.99 2 2 2 152943 14.35 1.45 21.87 2 2 2 152943 14.28 1.42 21.85 2 2 2 152944 14.02 1.43 22.13 2 2 2 152944 14.11 1.41 22.35 2 2 2 152945 14.14 1.45 21.89 2 2 2 152945 14.30 1.41 21.79 2 2 2 152946 14.19 1.44 22.17 2 2 2 152946 14.20 1.44 22.25 2 2 2 152947 14.32 1.43 21.85 2 2 2 152947 14.32 1.46 21.73 2 2 2 152948 14.38 1.43 22.09 2 2 2 152948 14.15 1.42 22.07 2 2 2 152949 7.75 0.97 6.85 2 2 2 152949 7.92 0.89 6.96 2 2 2 152950 8.47 0.93 7.08 2 2 2 152950 8.67 0.87 7.06 2 2 2 152951 6.93 0.84 6.45 2 2 2 152951 6.93 0.88 6.51 2 2 2 152952 4.26 0.65 2.92 2 2 2 152952 4.37 0.63 2.98 2 2 2 152952 10.36 1.14 16.78 4 4 4 152952 10.50 1.09 16.94 4 4 4 152953 10.55 1.10 16.54 2 2 2 152953 10.82 1.12 16.73 2 2 2 152954 10.93 1.12 17.16 2 2 2 152954 10.93 1.14 17.03 2 2 2 152955 10.72 1.12 17.46 2 2 2 152955 10.83 1.12 17.26 2 2 2 152956 11.65 1.28 17.67 2 2 2 152956 11.72 1.19 18.01 2 2 2 152957 8.60 1.04 14.73 2 2 2 152957 8.66 1.06 14.79 2 2 2 152958 5.56 0.67 4.20 2 2 2 152958 5.56 0.70 4.18 2 2 2 152959 7.40 0.84 7.75 2 2 2 152959 7.50 0.86 7.91 2 2 2 152960 13.38 1.13 17.12 2 2 2 152960 13.41 1.13 16.77 2 2 2 152961 12.10 1.17 16.81 2 2 2 152961 12.20 1.16 16.77 2 2 2 152962 11.17 1.14 16.93 2 2 2 152962 11.07 1.16 16.97 2 2 2 152963 10.59 1.14 16.77 2 2 2 152963 10.76 1.14 16.29 2 2 2 152964 10.62 1.20 16.93 2 2 2 152964 10.86 1.12 16.64 2 2 2 152965 10.73 1.15 16.83 2 2 2 152965 10.80 1.14 16.85 2 2 2 152966 10.59 1.14 17.12 2 2 2 152966 10.52 1.15 17.28 2 2 2 152967 10.45 1.15 16.83 2 2 2 152967 10.28 1.14 16.99 2 2 2 152968 10.63 1.17 16.99 2 2 2 152968 10.76 1.17 17.10 2 2 2 152969 11.42 1.16 16.66 2 2 2 152969 11.56 1.18 16.56 2 2 2 152970 10.15 0.97 10.54 3 2 3 152970 10.91 1.04 12.68 3 2 3 152971 10.05 0.98 10.15 2 2 2 152971 10.15 0.98 10.13 2 2 2 152972 5.40 0.86 5.33 2 2 2 152972 5.36 0.82 5.33 2 2 2 152973 6.52 0.82 6.19 2 2 2 152973 6.52 0.90 6.02 2 2 2 152974 2.69 0.58 0.37 2 2 2 152974 2.62 0.54 0.41 2 2 2 152976 18.67 1.14 16.71 2 2 2 152976 18.32 1.18 16.37 2 2 2 152977 17.79 1.13 16.87 2 2 2 152977 18.07 1.13 16.93 2 2 2 152978 16.08 1.12 16.61 2 2 2 152978 16.11 1.11 16.45 2 2 2 152979 16.15 1.15 17.25 2 2 2 152979 16.25 1.16 17.23 2 2 2 152980 13.54 1.12 16.49 2 2 2 152980 13.61 1.12 16.53 2 2 2 152981 14.44 1.16 17.39 2 2 2 152981 14.20 1.25 17.19 2 2 2 152982 12.85 1.12 17.25 2 2 2 152982 12.96 1.13 17.17 2 2 2 152983 11.89 1.13 17.41 2 2 2 152983 11.92 1.12 17.29 2 2 2 152984 11.71 1.13 17.05 2 2 2 152984 11.92 1.14 17.19 2 2 2 152985 12.02 1.15 17.29 2 2 2 152985 11.71 1.13 17.42 2 2 2 152986 11.68 1.15 17.56 2 2 2 152986 11.71 1.15 17.60 2 2 2 152987 10.92 1.13 17.11 2 2 2 152987 10.92 1.14 17.07 2 2 2 152988 11.20 1.15 17.09 2 2 2 152988 11.20 1.16 17.25 2 2 2 152989 10.99 1.14 17.48 2 2 2 152989 11.03 1.24 17.19 2 2 2 152990 11.10 1.16 17.92 2 2 2 152990 11.13 1.14 17.96 2 2 2 152991 10.89 1.14 17.74 2 2 2 152991 10.89 1.14 17.92 2 2 2 152992 10.37 1.13 16.89 2 2 2 152992 10.31 1.14 17.17 2 2 2 152993 10.96 1.19 17.88 2 2 2 152993 10.99 1.16 18.09 2 2 2 152994 10.17 1.06 15.93 2 2 2 152994 10.21 1.08 15.91 2 2 2 152995 12.79 1.28 19.04 2 2 2 152995 12.86 1.30 19.00 2 2 2 152996 10.59 0.97 11.72 2 2 2 152996 10.49 0.99 11.62 2 2 2 152997 2.10 0.48 1.20 2 2 2 152997 2.17 0.47 1.31 2 2 2 152998 0.87 0.41 0.00 2 2 2 152998 0.93 0.39 0.00 2 2 2 152999 20.77 1.23 16.73 2 2 2 152999 21.26 1.14 17.22 2 2 2 153000 19.17 1.12 17.09 2 2 2 153000 18.71 1.10 16.55 2 2 2 153001 17.86 1.12 17.03 2 2 2 153001 17.34 1.12 16.84 2 2 2 153002 16.13 1.11 16.93 2 2 2 153002 16.23 1.10 16.64 2 2 2 153003 16.00 1.11 16.89 2 2 2 153003 16.00 1.13 17.50 2 2 2 153004 15.77 1.14 17.50 2 2 2 153004 15.93 1.14 17.69 2 2 2 153008 12.12 1.13 17.21 2 2 2 153008 12.54 1.13 17.38 2 2 2 153009 12.27 1.12 17.52 2 2 2 153009 12.17 1.26 17.20 2 2 2 153010 11.42 1.13 17.37 2 2 2 153010 11.48 1.09 17.12 2 2 2 153011 10.86 1.11 17.54 2 2 2 153011 10.77 1.10 17.29 2 2 2 153012 10.67 1.12 16.94 2 2 2 153012 10.63 1.12 17.07 2 2 2 153013 11.51 1.18 18.04 2 2 2 153013 11.61 1.23 18.19 2 2 2 153014 11.63 1.18 18.19 2 2 2 153014 11.83 1.18 17.83 2 2 2 153015 11.57 1.19 18.32 2 2 2 153015 11.73 1.18 18.62 2 2 2 153016 12.31 1.23 18.68 2 2 2 153016 12.34 1.23 18.77 2 2 2 153017 12.56 1.26 19.09 2 2 2 153017 12.50 1.40 19.26 2 2 2 153018 10.35 1.04 15.23 2 2 2 153018 10.48 1.02 15.15 2 2 2 153019 11.49 1.06 14.23 2 2 2 153019 11.55 1.07 13.74 2 2 2 153020 7.08 0.82 8.08 2 2 2 153020 7.28 0.79 8.10 2 2 2 153021 1.01 0.32 0.00 2 2 2 153021 0.94 0.37 0.00 2 2 2 153022 25.27 1.26 17.74 2 2 2 153022 25.56 1.18 18.26 2 2 2 153023 25.26 1.18 18.29 2 2 2 153023 25.39 1.17 17.63 2 2 2 153024 23.30 1.14 17.67 2 2 2 153024 23.37 1.16 18.01 2 2 2 153025 21.24 1.14 17.34 2 2 2 153025 21.57 1.28 16.96 2 2 2 153026 20.26 1.12 17.51 2 2 2 153026 20.55 1.14 17.31 2 2 2 153027 17.65 1.11 16.82 2 2 2 153027 17.38 1.11 17.06 2 2 2 153028 16.73 1.12 17.21 2 2 2 153028 16.54 1.11 17.30 2 2 2 153029 15.72 1.09 17.09 2 2 2 153029 15.91 1.13 17.49 2 2 2 153030 15.88 1.16 17.63 2 2 2 153030 16.04 1.13 17.40 2 2 2 153031 13.65 1.11 17.61 2 2 2 153031 13.69 1.10 17.36 2 2 2 153032 12.32 1.16 16.99 2 2 2 153032 12.48 1.11 17.12 2 2 2 153033 12.56 1.12 17.41 2 2 2 153033 12.37 1.26 17.32 2 2 2 153034 11.84 1.12 17.22 2 2 2 153034 12.17 1.10 17.05 2 2 2 153035 11.74 1.13 17.14 2 2 2 153035 11.91 1.16 17.08 2 2 2 153036 11.94 1.14 17.53 2 2 2 153036 12.03 1.16 17.93 2 2 2 153037 11.44 1.14 17.19 2 2 2 153037 11.51 1.15 17.83 2 2 2 153038 10.53 1.12 17.03 2 2 2 153038 10.59 1.14 17.28 2 2 2 153040 11.44 1.18 17.96 2 2 2 153040 11.70 1.20 17.63 2 2 2 153041 11.89 1.21 18.81 2 2 2 153041 11.79 1.23 18.69 2 2 2 153042 12.11 1.21 18.86 2 2 2 153042 12.27 1.36 18.47 2 2 2 153043 12.86 1.36 20.57 2 2 2 153043 12.99 1.35 20.37 2 2 2 153044 9.27 0.96 13.39 2 2 2 153044 9.36 1.05 13.46 2 2 2 153045 2.05 0.43 0.91 2 2 2 153045 2.15 0.57 0.98 2 2 2 153046 29.82 1.36 18.86 2 2 2 153046 30.77 1.26 18.82 2 2 2 153047 22.77 1.17 17.45 2 2 2 153047 23.19 1.18 17.17 2 2 2 153048 21.10 1.14 17.11 2 2 2 153048 21.62 1.16 17.38 2 2 2 153049 20.64 1.17 16.97 2 2 2 153049 20.35 1.16 17.29 2 2 2 153050 20.08 1.28 16.72 2 2 2 153050 20.21 1.14 16.91 2 2 2 153051 17.53 1.10 16.89 2 2 2 153051 17.75 1.13 17.13 2 2 2 153052 16.74 1.14 16.71 2 2 2 153052 17.10 1.14 16.83 2 2 2 153053 15.86 1.13 17.05 2 2 2 153053 16.05 1.15 17.22 2 2 2 153054 16.15 1.14 17.01 2 2 2 153054 15.82 1.15 17.35 2 2 2 153055 14.77 1.16 17.68 2 2 2 153055 14.90 1.16 17.44 2 2 2 153056 13.49 1.14 17.32 2 2 2 153056 13.56 1.12 17.09 2 2 2 153057 12.54 1.14 17.24 2 2 2 153057 12.71 1.16 16.95 2 2 2 153058 11.88 1.24 16.83 2 2 2 153058 11.91 1.16 17.06 2 2 2 153059 11.71 1.14 17.06 2 2 2 153059 11.71 1.16 16.81 2 2 2 153061 11.58 1.18 17.63 2 2 2 153061 11.42 1.17 17.74 2 2 2 153062 11.48 1.15 17.27 2 2 2 153062 11.15 1.16 17.69 2 2 2 153063 10.43 1.15 17.39 2 2 2 153063 10.46 1.15 16.74 2 2 2 153064 10.56 1.15 17.20 2 2 2 153064 10.72 1.16 17.52 2 2 2 153066 12.75 1.33 19.13 2 2 2 153066 12.84 1.30 18.58 2 2 2 153067 12.51 1.36 19.89 2 2 2 153067 12.48 1.36 19.89 2 2 2 153068 7.87 0.97 12.73 2 2 2 153068 7.90 1.01 12.79 2 2 2 153070 30.07 1.25 18.48 2 2 2 153070 30.91 1.32 18.63 2 2 2 153071 30.00 1.23 18.19 2 2 2 153071 30.14 1.27 18.14 2 2 2 153072 25.82 1.19 18.01 2 2 2 153072 25.53 1.18 17.67 2 2 2 153073 24.09 1.17 17.92 2 2 2 153073 24.02 1.18 17.68 2 2 2 153074 23.89 1.20 17.93 2 2 2 153074 23.92 1.28 17.72 2 2 2 153075 23.32 1.18 17.84 2 2 2 153075 23.39 1.18 17.82 2 2 2 153076 22.05 1.18 17.85 2 2 2 153076 22.05 1.17 17.76 2 2 2 153077 20.66 1.17 17.65 2 2 2 153077 20.66 1.19 17.99 2 2 2 153078 18.96 1.16 18.15 2 2 2 153078 18.93 1.21 18.15 2 2 2 153079 17.47 1.18 17.42 2 2 2 153079 17.53 1.24 17.54 2 2 2 153080 17.83 1.20 18.10 2 2 2 153080 17.80 1.18 17.84 2 2 2 153081 16.47 1.18 18.22 2 2 2 153081 16.27 1.18 18.19 2 2 2 153082 15.01 1.17 17.77 2 2 2 153082 15.01 1.19 17.81 2 2 2 153083 13.52 1.15 17.78 2 2 2 153083 13.52 1.23 17.71 2 2 2 153084 11.91 1.13 17.58 2 2 2 153084 11.97 1.14 17.53 2 2 2 153085 11.67 1.14 17.65 2 2 2 153085 11.67 1.14 17.67 2 2 2 153086 11.97 1.17 18.51 2 2 2 153086 11.94 1.21 18.46 2 2 2 153087 11.01 1.17 17.71 2 2 2 153087 11.14 1.16 17.91 2 2 2 153088 11.94 1.30 18.62 2 2 2 153088 12.07 1.21 18.54 2 2 2 153089 11.94 1.18 16.88 2 2 2 153089 11.94 1.25 17.16 2 2 2 153090 11.05 1.23 17.63 2 2 2 153090 10.95 1.23 17.35 2 2 2 153091 8.31 1.09 17.77 2 2 2 153091 8.67 1.10 17.63 2 2 2 153092 1.21 0.43 0.00 2 2 2 153092 1.24 0.39 0.27 2 2 2 153093 44.77 1.47 21.68 2 2 2 153093 45.00 1.51 21.88 2 2 2 153094 39.97 1.38 20.73 2 2 2 153094 40.07 1.43 20.88 2 2 2 153095 36.97 1.35 20.14 2 2 2 153095 37.20 1.35 20.29 2 2 2 153096 35.46 1.35 20.34 2 2 2 153096 35.23 1.31 20.19 2 2 2 153097 32.54 1.31 19.98 2 2 2 153097 31.94 1.34 19.73 2 2 2 153098 29.25 1.31 19.15 2 2 2 153098 29.35 1.31 19.19 2 2 2 153099 26.36 1.24 18.83 2 2 2 153099 28.35 1.33 18.96 2 2 2 153100 24.60 1.21 18.98 2 2 2 153100 24.67 1.20 19.09 2 2 2 153101 21.49 1.21 18.58 2 2 2 153101 21.56 1.28 18.60 2 2 2 153102 19.94 1.26 18.87 2 2 2 153102 19.44 1.20 19.10 2 2 2 153103 17.62 1.26 18.47 2 2 2 153103 17.65 1.29 18.31 2 2 2 153104 16.07 1.22 18.22 2 2 2 153104 16.30 1.26 18.34 2 2 2 153105 14.62 1.24 18.66 2 2 2 153105 14.66 1.14 18.45 2 2 2 153106 12.84 1.19 19.44 2 2 2 153106 12.94 1.18 19.26 2 2 2 153107 12.09 1.25 18.52 2 2 2 153107 12.35 1.16 20.14 2 2 2 153108 12.48 1.19 18.86 2 2 2 153108 12.48 1.18 18.93 2 2 2 153109 12.35 1.29 18.65 2 2 2 153109 12.25 1.19 18.71 2 2 2 153110 12.54 1.27 19.42 2 2 2 153110 12.61 1.32 19.46 2 2 2 153111 13.50 1.39 21.53 2 2 2 153111 13.59 1.44 21.63 2 2 2 153112 14.35 1.52 24.89 2 2 2 153112 15.14 1.51 24.81 2 2 2 153113 5.45 0.74 12.25 2 2 2 153113 5.45 0.82 12.13 2 2 2 153114 2.40 0.38 8.10 2 2 2 153114 2.50 0.34 6.24 2 2 2 153115 1.48 0.18 3.46 2 2 2 153115 1.51 0.18 3.51 2 2 2 153117 40.11 1.43 20.77 2 2 2 153117 40.70 1.40 20.88 2 2 2 153118 37.88 1.37 19.92 2 2 2 153118 37.85 1.36 20.21 2 2 2 153119 34.83 1.40 19.85 2 2 2 153119 34.96 1.35 19.80 2 2 2 153120 32.32 1.32 19.44 2 2 2 153120 32.38 1.28 19.54 2 2 2 153121 30.63 1.30 19.52 2 2 2 153121 30.66 1.28 19.44 2 2 2 153122 29.08 1.29 19.20 2 2 2 153122 28.45 1.29 18.90 2 2 2 153123 26.57 1.34 18.64 2 2 2 153123 26.60 1.30 18.73 2 2 2 153124 23.15 1.24 18.54 2 2 2 153124 23.21 1.25 18.68 2 2 2 153125 21.04 1.25 18.66 2 2 2 153125 21.17 1.25 18.45 2 2 2 153126 20.31 1.27 18.52 2 2 2 153126 20.61 1.27 18.73 2 2 2 153127 17.94 1.23 18.31 2 2 2 153127 18.14 1.28 18.37 2 2 2 153128 16.27 1.25 18.64 2 2 2 153128 16.37 1.25 18.31 2 2 2 153129 14.69 1.22 18.51 2 2 2 153129 14.69 1.21 18.40 2 2 2 153130 12.66 1.21 18.15 2 2 2 153130 12.79 1.21 17.96 2 2 2 153131 12.59 1.24 18.08 2 2 2 153131 12.63 1.25 18.35 2 2 2 153132 12.07 1.23 18.61 2 2 2 153132 12.14 1.23 18.57 2 2 2 153133 13.08 1.34 20.30 2 2 2 153133 13.12 1.35 20.59 2 2 2 153134 11.44 1.38 21.76 2 2 2 153134 11.34 1.38 21.51 2 2 2 153135 4.14 0.76 10.91 2 2 2 153135 4.17 0.73 11.05 2 2 2 153136 1.40 0.17 3.02 2 2 2 153136 1.43 0.19 2.95 2 2 2 153137 1.20 0.13 1.83 2 2 2 153137 1.26 0.13 1.84 2 2 2 153138 0.81 0.08 0.70 2 2 2 153138 0.64 0.08 0.70 2 2 2 153139 43.27 1.45 20.89 2 2 2 153139 43.05 1.52 20.86 2 2 2 153140 40.78 1.42 20.80 2 2 2 153140 40.97 1.52 21.07 2 2 2 153141 38.60 1.38 20.63 2 2 2 153141 39.03 1.39 20.75 2 2 2 153142 33.32 1.35 19.24 2 2 2 153142 34.34 1.32 19.52 2 2 2 153143 31.24 1.39 18.21 2 2 2 153143 31.40 1.28 18.43 2 2 2 153144 30.27 1.27 18.64 2 2 2 153144 30.14 1.35 18.38 2 2 2 153145 27.85 1.26 18.45 2 2 2 153145 28.04 1.25 18.53 2 2 2 153146 25.04 1.24 17.87 2 2 2 153146 24.95 1.23 17.94 2 2 2 153147 22.14 1.21 17.84 2 2 2 153147 22.04 1.22 17.43 2 2 2 153148 20.23 1.20 17.80 2 2 2 153148 20.39 1.20 17.85 2 2 2 153149 17.39 1.20 17.25 2 2 2 153149 17.68 1.19 17.39 2 2 2 153150 16.07 1.20 17.62 2 2 2 153150 16.20 1.20 17.76 2 2 2 153151 14.45 1.27 17.12 2 2 2 153151 14.90 1.20 17.27 2 2 2 153152 13.00 1.19 17.37 2 2 2 153152 13.00 1.17 17.48 2 2 2 153153 12.09 1.18 17.61 2 2 2 153153 12.09 1.17 17.66 2 2 2 153154 11.93 1.22 18.05 2 2 2 153154 12.09 1.23 18.02 2 2 2 153155 13.08 1.33 19.81 2 2 2 153155 13.12 1.34 19.64 2 2 2 153156 13.66 1.52 23.46 2 2 2 153156 13.63 1.51 23.54 2 2 2 153157 6.54 0.95 14.92 2 2 2 153157 6.57 0.91 15.08 2 2 2 153158 3.16 0.54 8.54 2 2 2 153158 3.16 0.51 8.58 2 2 2 153159 1.09 0.14 1.53 2 2 2 153159 1.10 0.16 1.55 2 2 2 153160 1.09 0.14 1.52 2 2 2 153160 1.09 0.16 1.50 2 2 2 153161 1.12 0.13 1.54 2 2 2 153161 1.12 0.13 1.52 2 2 2 153162 44.43 1.52 20.94 2 2 2 153162 44.14 1.45 20.42 2 2 2 153163 38.80 1.40 19.69 2 2 2 153163 38.70 1.40 19.71 2 2 2 153164 37.09 1.35 19.61 2 2 2 153164 37.28 1.36 19.65 2 2 2 153165 34.93 1.35 18.84 2 2 2 153165 35.44 1.33 19.36 2 2 2 153166 34.05 1.32 19.14 2 2 2 153166 34.09 1.34 18.93 2 2 2 153167 32.43 1.34 18.50 2 2 2 153167 32.66 1.40 18.74 2 2 2 153168 29.44 1.31 18.34 2 2 2 153168 29.28 1.31 18.24 2 2 2 153169 26.99 1.29 18.02 2 2 2 153169 27.12 1.28 18.23 2 2 2 153170 24.28 1.27 17.73 2 2 2 153170 24.61 1.27 18.25 2 2 2 153171 21.64 1.26 17.53 2 2 2 153171 21.77 1.27 17.44 2 2 2 153172 19.58 1.27 17.66 2 2 2 153172 19.74 1.24 17.94 2 2 2 153173 17.59 1.25 18.05 2 2 2 153173 17.65 1.26 17.85 2 2 2 153174 17.23 1.24 17.42 2 2 2 153174 17.26 1.25 17.48 2 2 2 153175 13.30 1.26 17.08 2 2 2 153175 13.23 1.18 16.92 2 2 2 153176 12.37 1.20 17.10 2 2 2 153176 12.43 1.20 17.49 2 2 2 153177 12.14 1.22 18.01 2 2 2 153177 12.23 1.24 18.19 2 2 2 153178 12.52 1.30 18.73 2 2 2 153178 12.55 1.29 18.95 2 2 2 153179 13.03 1.45 20.69 2 2 2 153179 13.06 1.44 20.81 2 2 2 153180 10.36 1.31 19.54 2 2 2 153180 10.39 1.29 19.58 2 2 2 153181 3.87 0.64 9.45 2 2 2 153181 3.87 0.59 9.63 2 2 2 153182 0.98 0.15 1.53 2 2 2 153182 1.01 0.12 1.59 2 2 2 153183 1.16 0.15 1.27 2 2 2 153183 1.10 0.12 1.24 2 2 2 153184 0.94 0.11 0.93 2 2 2 153184 0.97 0.11 0.91 2 2 2 153185 40.49 1.48 19.96 2 2 2 153185 40.84 1.40 20.24 2 2 2 153186 39.07 1.41 19.42 2 2 2 153186 39.85 1.40 19.92 2 2 2 153187 37.95 1.40 19.37 2 2 2 153187 38.07 1.40 19.46 2 2 2 153188 37.17 1.39 19.82 2 2 2 153188 36.82 1.39 19.47 2 2 2 153189 35.27 1.35 19.02 2 2 2 153189 36.01 1.35 19.60 2 2 2 153190 33.69 1.35 18.86 2 2 2 153190 33.86 1.35 18.91 2 2 2 153191 31.95 1.41 18.36 2 2 2 153191 32.07 1.34 18.31 2 2 2 153192 30.44 1.33 18.22 2 2 2 153192 30.60 1.33 18.39 2 2 2 153193 25.94 1.26 17.85 2 2 2 153193 26.13 1.27 17.94 2 2 2 153194 22.50 1.25 17.24 2 2 2 153194 22.60 1.26 17.45 2 2 2 153195 21.02 1.26 18.02 2 2 2 153195 20.83 1.26 17.67 2 2 2 153196 17.75 1.23 17.84 2 2 2 153196 18.10 1.25 18.04 2 2 2 153197 15.95 1.23 17.51 2 2 2 153197 15.98 1.23 17.23 2 2 2 153198 13.16 1.21 17.18 2 2 2 153198 13.25 1.22 17.25 2 2 2 153199 13.28 1.30 17.13 2 2 2 153199 13.21 1.25 17.44 2 2 2 153201 12.15 1.25 18.13 2 2 2 153201 12.18 1.27 17.96 2 2 2 153202 12.60 1.33 18.87 2 2 2 153202 12.63 1.34 19.24 2 2 2 153203 13.14 1.40 19.95 2 2 2 153203 13.46 1.40 20.14 2 2 2 153204 10.60 1.34 20.04 2 2 2 153204 10.54 1.31 20.06 2 2 2 153205 2.94 0.46 8.00 2 2 2 153205 2.91 0.51 7.78 2 2 2 153206 0.92 0.14 1.42 2 2 2 153206 0.92 0.11 1.45 2 2 2 153207 0.34 0.07 0.00 2 2 2 153207 0.34 0.07 0.00 2 2 2 153208 46.34 1.48 21.13 2 2 2 153208 46.34 1.62 20.77 2 2 2 153209 42.27 1.46 20.29 2 2 2 153209 42.43 1.46 20.68 2 2 2 153210 39.83 1.44 19.66 2 2 2 153210 39.51 1.44 19.46 2 2 2 153211 36.89 1.43 19.78 2 2 2 153211 36.92 1.40 19.80 2 2 2 153212 32.77 1.36 18.83 2 2 2 153212 32.58 1.35 19.11 2 2 2 153213 30.50 1.33 18.40 2 2 2 153213 30.43 1.35 18.54 2 2 2 153214 27.67 1.31 18.15 2 2 2 153214 27.70 1.32 18.31 2 2 2 153215 24.11 1.29 17.80 2 2 2 153215 24.53 1.29 18.17 2 2 2 153216 22.02 1.28 18.10 2 2 2 153216 22.41 1.34 18.25 2 2 2 153217 19.94 1.28 17.69 2 2 2 153217 20.10 1.28 17.77 2 2 2 153218 17.08 1.25 17.70 2 2 2 153218 17.05 1.26 17.58 2 2 2 153219 14.84 1.23 17.53 2 2 2 153219 14.97 1.22 17.77 2 2 2 153220 12.47 1.23 17.35 2 2 2 153220 12.57 1.24 17.53 2 2 2 153221 12.31 1.25 17.89 2 2 2 153221 12.37 1.25 17.74 2 2 2 153222 8.34 0.96 13.51 2 2 2 153222 8.43 0.92 13.47 2 2 2 153223 12.39 1.34 19.08 2 2 2 153223 12.52 1.36 19.23 2 2 2 153224 13.06 1.49 20.39 2 2 2 153224 13.12 1.42 20.58 2 2 2 153225 9.99 1.28 18.99 2 2 2 153225 9.95 1.26 18.77 2 2 2 153226 6.69 0.99 14.73 2 2 2 153226 6.69 0.97 14.80 2 2 2 153227 4.48 0.73 11.11 2 2 2 153227 4.51 0.74 11.06 2 2 2 153228 2.37 0.41 6.54 2 2 2 153228 2.40 0.39 6.50 2 2 2 153229 1.06 0.14 2.12 2 2 2 153229 1.12 0.15 2.10 2 2 2 153230 0.32 0.06 0.00 2 2 2 153230 0.42 0.05 0.00 2 2 2 153231 43.77 1.53 20.49 2 2 2 153231 44.19 1.52 21.01 2 2 2 153232 42.95 1.43 20.26 2 2 2 153232 43.95 1.51 20.28 2 2 2 153233 42.54 1.49 20.66 2 2 2 153233 41.96 1.42 20.34 2 2 2 153234 38.29 1.37 20.22 2 2 2 153234 38.65 1.39 20.41 2 2 2 153235 34.08 1.31 18.87 2 2 2 153235 34.38 1.32 19.58 2 2 2 153236 29.43 1.28 18.38 2 2 2 153236 29.63 1.28 18.36 2 2 2 153237 26.78 1.28 18.36 2 2 2 153237 26.69 1.33 18.24 2 2 2 153238 24.21 1.26 17.85 2 2 2 153238 24.08 1.26 18.22 2 2 2 153239 22.48 1.30 17.95 2 2 2 153239 22.68 1.30 17.44 2 2 2 153240 19.70 1.24 18.32 2 2 2 153240 19.82 1.26 18.32 2 2 2 153241 16.94 1.30 18.05 2 2 2 153241 17.04 1.28 17.71 2 2 2 153242 15.71 1.19 17.97 2 2 2 153242 15.80 1.27 18.20 2 2 2 153243 13.40 1.18 17.32 2 2 2 153243 13.38 1.21 17.77 2 2 2 153244 12.53 1.26 17.53 2 2 2 153244 12.59 1.20 17.67 2 2 2 153245 12.67 1.21 17.45 2 2 2 153245 12.45 1.21 17.89 2 2 2 153246 12.79 1.27 18.34 2 2 2 153246 12.56 1.26 18.36 2 2 2 153247 12.15 1.28 18.29 2 2 2 153247 12.30 1.25 18.72 2 2 2 153248 13.07 1.45 22.51 2 2 2 153248 13.16 1.45 22.70 2 2 2 153249 4.87 0.69 10.67 2 2 2 153249 4.91 0.69 10.83 2 2 2 153250 3.05 0.41 6.73 2 2 2 153250 3.17 0.42 6.58 2 2 2 153251 1.69 0.16 2.03 2 2 2 153251 1.60 0.15 2.11 2 2 2 153252 1.59 0.15 1.92 2 2 2 153252 1.64 0.13 1.95 2 2 2 153253 0.71 0.05 0.00 2 2 2 153253 0.75 0.06 0.00 2 2 2 153254 43.07 1.45 20.47 2 2 2 153254 43.72 1.40 20.37 2 2 2 153255 40.60 1.38 20.04 2 2 2 153255 40.54 1.45 20.18 2 2 2 153256 36.45 1.33 19.45 2 2 2 153256 36.57 1.35 19.57 2 2 2 153257 33.53 1.34 19.10 2 2 2 153257 33.73 1.34 19.20 2 2 2 153258 30.59 1.28 17.97 2 2 2 153258 30.86 1.27 18.32 2 2 2 153259 28.25 1.28 17.89 2 2 2 153259 28.50 1.27 18.40 2 2 2 153260 25.35 1.26 17.85 2 2 2 153260 25.84 1.24 17.97 2 2 2 153261 23.65 1.26 18.54 2 2 2 153261 23.50 1.25 18.22 2 2 2 153262 22.03 1.25 18.37 2 2 2 153262 22.03 1.26 17.87 2 2 2 153263 18.80 1.27 17.57 2 2 2 153263 19.22 1.24 18.23 2 2 2 153264 16.28 1.20 17.89 2 2 2 153264 16.34 1.20 17.54 2 2 2 153265 13.82 1.19 17.50 2 2 2 153265 13.98 1.20 17.77 2 2 2 153266 12.87 1.19 17.26 2 2 2 153266 12.75 1.20 17.75 2 2 2 153267 12.18 1.22 17.57 2 2 2 153267 12.19 1.22 17.57 2 2 2 153268 12.72 1.27 18.77 2 2 2 153268 12.81 1.25 18.49 2 2 2 153269 12.67 1.30 19.31 2 2 2 153269 12.74 1.29 18.87 2 2 2 153270 12.34 1.34 20.18 2 2 2 153270 12.22 1.34 20.65 2 2 2 153271 10.51 1.26 19.57 2 2 2 153271 10.49 1.29 19.08 2 2 2 153272 8.77 1.08 16.80 2 2 2 153272 8.82 1.07 17.08 2 2 2 153273 3.36 0.51 7.54 2 2 2 153273 3.50 0.44 7.71 2 2 2 153274 2.48 0.35 5.40 2 2 2 153274 2.52 0.35 5.43 2 2 2 153275 1.29 0.15 1.62 2 2 2 153275 1.29 0.13 1.64 2 2 2 153276 1.25 0.14 1.38 2 2 2 153276 1.21 0.13 1.42 2 2 2 153277 43.06 1.45 19.54 2 2 2 153277 43.78 1.50 19.96 2 2 2 153278 41.45 1.42 19.58 2 2 2 153278 41.33 1.42 19.42 2 2 2 153279 37.20 1.41 18.54 2 2 2 153279 36.84 1.38 18.56 2 2 2 153280 30.75 1.31 17.85 2 2 2 153280 30.93 1.28 18.33 2 2 2 153281 29.18 1.28 17.91 2 2 2 153281 29.93 1.28 18.15 2 2 2 153282 28.40 1.28 17.68 2 2 2 153282 28.55 1.28 17.70 2 2 2 153283 26.60 1.26 17.28 2 2 2 153283 27.29 1.26 17.19 2 2 2 153284 24.14 1.26 18.03 2 2 2 153284 23.98 1.26 17.77 2 2 2 153285 20.52 1.20 16.70 2 2 2 153285 20.65 1.20 17.21 2 2 2 153286 19.89 1.23 17.21 2 2 2 153286 20.06 1.22 17.05 2 2 2 153287 17.15 1.21 16.82 2 2 2 153287 17.32 1.24 16.76 2 2 2 153288 15.89 1.21 17.21 2 2 2 153288 15.89 1.22 17.38 2 2 2 153289 12.99 1.20 16.95 2 2 2 153289 13.01 1.17 16.56 2 2 2 153290 12.39 1.23 16.82 2 2 2 153290 12.56 1.20 16.60 2 2 2 153291 11.81 1.21 16.86 2 2 2 153291 11.87 1.18 16.55 2 2 2 153292 11.85 1.29 17.07 2 2 2 153292 11.95 1.24 16.95 2 2 2 153293 12.26 1.23 17.79 2 2 2 153293 12.45 1.22 17.46 2 2 2 153294 13.02 1.30 19.08 2 2 2 153294 12.83 1.31 19.43 2 2 2 153295 16.00 1.61 23.98 2 2 2 153295 15.88 1.74 24.79 2 2 2 153296 6.09 0.90 13.82 2 2 2 153296 6.10 0.85 13.76 2 2 2 153297 4.42 0.68 10.91 2 2 2 153297 4.47 0.67 10.61 2 2 2 153298 1.29 0.14 2.25 2 2 2 153298 2.73 0.17 2.16 4 2 2 153299 0.35 0.08 0.30 2 2 2 153299 0.37 0.08 0.26 2 2 2 153300 41.41 1.61 20.37 2 4 2 153300 41.38 1.35 20.49 2 2 2 153301 30.66 1.24 18.56 2 2 2 153301 31.41 1.20 18.46 2 2 2 153302 36.33 1.33 20.18 2 2 2 153302 36.95 1.34 20.22 2 2 2 153303 33.02 1.38 19.89 2 2 2 153303 33.12 1.28 19.71 2 2 2 153304 30.19 1.24 19.54 2 2 2 153304 30.29 1.28 18.90 2 2 2 153305 27.86 1.25 18.78 2 2 2 153305 27.98 1.25 18.61 2 2 2 153306 25.01 1.23 18.43 2 2 2 153306 25.07 1.23 18.47 2 2 2 153307 21.06 1.19 18.16 2 2 2 153307 20.64 1.19 18.28 2 2 2 153308 17.73 1.27 17.52 2 2 2 153308 17.76 1.17 17.58 2 2 2 153309 16.34 1.15 17.76 2 2 2 153309 16.37 1.15 17.80 2 2 2 153310 13.47 1.12 17.72 2 2 2 153310 13.54 1.13 17.84 2 2 2 153311 12.73 1.12 17.84 2 2 2 153311 12.76 1.12 17.86 2 2 2 153312 11.61 1.15 18.29 2 2 2 153312 11.64 1.15 18.30 2 2 2 153313 11.76 1.17 18.24 2 2 2 153313 11.92 1.17 18.22 2 2 2 153314 11.54 1.16 18.03 2 2 2 153314 11.57 1.17 18.18 2 2 2 153315 13.30 1.37 21.41 2 2 2 153315 13.23 1.34 21.53 2 2 2 153316 13.41 1.55 23.55 2 3 2 153316 13.48 1.41 23.04 2 2 2 153317 7.94 1.04 17.15 2 2 2 153317 8.00 1.03 17.38 2 2 2 153318 4.11 0.56 9.76 2 2 2 153318 4.11 0.61 9.84 2 2 2 153319 3.31 0.51 9.35 2 2 2 153319 3.37 0.50 9.35 2 2 2 153320 1.21 0.14 2.32 2 2 2 153320 1.15 0.16 2.24 2 2 2 153321 0.90 0.11 1.05 2 2 2 153321 0.96 0.11 1.03 2 2 2 153322 0.58 0.07 0.32 2 2 2 153322 0.58 0.08 0.34 2 2 2 153323 41.51 1.48 20.63 2 2 2 153323 41.70 1.35 21.00 2 2 2 153324 36.35 1.43 20.03 2 3 2 153324 36.38 1.31 20.27 2 2 2 153325 34.17 1.29 19.66 2 2 2 153325 34.20 1.30 19.43 2 2 2 153326 32.35 1.27 19.27 2 2 2 153326 32.35 1.28 19.28 2 2 2 153327 28.24 1.21 18.85 2 2 2 153327 27.95 1.21 18.93 2 2 2 153328 27.78 1.22 19.12 2 2 2 153328 27.94 1.21 19.16 2 2 2 153329 26.13 1.20 19.13 2 2 2 153329 26.16 1.22 18.87 2 2 2 153330 21.11 1.16 17.97 2 2 2 153330 21.24 1.16 18.07 2 2 2 153331 18.83 1.15 17.96 2 2 2 153331 18.80 1.21 17.76 2 3 2 153332 17.02 1.25 18.22 2 2 2 153332 17.12 1.14 17.97 2 2 2 153333 15.23 1.15 17.75 2 2 2 153333 15.26 1.14 18.03 2 2 2 153334 14.27 1.15 17.95 2 2 2 153334 14.27 1.20 17.77 2 3 2 153335 13.47 1.15 17.97 2 2 2 153335 13.21 1.13 18.05 2 2 2 153336 7.46 0.83 14.25 2 2 2 153336 7.46 0.87 14.33 2 2 2 153339 11.74 1.18 18.68 2 2 2 153339 11.84 1.16 18.80 2 2 2 153340 12.41 1.24 19.62 2 2 2 153340 12.44 1.29 19.37 2 2 2 153341 14.38 1.46 23.56 2 2 2 153341 14.41 1.42 23.66 2 2 2 153342 11.63 1.40 21.45 2 2 2 153342 11.72 1.28 21.53 2 2 2 153343 8.17 1.04 16.17 2 2 2 153343 8.11 1.00 15.98 2 2 2 153344 3.34 0.45 7.65 2 2 2 153344 3.34 0.50 7.59 2 2 2 153345 0.67 0.13 0.88 2 2 2 153345 0.67 0.10 0.94 2 2 2 153346 37.60 1.42 20.15 2 2 2 153346 37.57 1.32 20.50 2 2 2 153347 36.65 1.30 20.42 2 2 2 153347 37.17 1.31 20.27 2 2 2 153348 33.34 1.27 19.60 2 2 2 153348 33.47 1.27 19.23 2 2 2 153349 29.62 1.23 18.67 2 2 2 153349 29.74 1.24 18.61 2 2 2 153350 26.02 1.30 18.52 2 2 2 153350 26.57 1.19 18.81 2 2 2 153351 25.21 1.20 18.07 2 2 2 153351 24.89 1.19 18.44 2 2 2 153352 23.28 1.19 17.90 2 2 2 153352 23.35 1.19 17.94 2 2 2 153353 18.61 1.15 17.39 2 2 2 153353 18.64 1.16 17.55 2 2 2 153354 16.82 1.13 17.71 2 2 2 153354 17.37 1.16 17.63 2 2 2 153355 16.79 1.15 18.36 2 2 2 153355 16.73 1.16 18.30 2 2 2 153356 15.32 1.15 17.93 2 2 2 153356 15.39 1.15 17.97 2 2 2 153357 14.40 1.15 17.83 2 2 2 153357 14.40 1.15 17.77 2 2 2 153358 12.93 1.14 18.00 2 2 2 153358 13.06 1.27 17.80 2 2 2 153359 12.96 1.22 18.00 2 2 2 153359 13.15 1.15 18.00 2 2 2 153360 11.98 1.14 17.65 2 2 2 153360 12.04 1.16 17.59 2 2 2 153361 11.88 1.19 17.91 2 2 2 153361 11.79 1.16 17.73 2 2 2 153362 11.94 1.19 18.48 2 2 2 153362 11.91 1.19 18.38 2 2 2 153363 11.69 1.17 18.75 2 2 2 153363 11.72 1.18 18.89 2 2 2 153364 12.09 1.21 19.21 2 2 2 153364 12.16 1.24 19.46 2 2 2 153365 12.47 1.28 19.81 2 2 2 153365 12.57 1.28 20.14 2 2 2 153366 12.24 1.33 21.36 2 2 2 153366 12.34 1.50 21.24 2 2 2 153367 3.16 0.42 7.53 2 2 2 153367 3.06 0.51 7.45 2 2 2 153368 0.50 0.12 0.00 2 2 2 153368 0.53 0.12 0.00 2 2 2 153369 36.94 1.41 19.80 2 2 2 153369 37.98 1.30 20.08 2 3 2 153370 34.01 1.25 19.79 2 2 2 153370 34.27 1.27 19.98 2 2 2 153371 31.31 1.27 19.50 2 2 2 153371 31.64 1.23 19.46 2 2 2 153372 28.63 1.24 18.95 2 2 2 153372 28.83 1.24 19.21 2 2 2 153373 26.38 1.22 18.19 2 2 2 153373 26.48 1.24 18.29 2 2 2 153374 24.23 1.27 18.39 2 2 2 153374 24.22 1.21 18.83 2 2 2 153375 21.00 1.19 18.62 2 2 2 153375 21.12 1.18 18.34 2 2 2 153376 20.38 1.19 18.28 2 2 2 153376 20.54 1.19 18.44 2 2 2 153377 18.80 1.19 18.41 2 2 2 153377 18.90 1.20 18.53 2 2 2 153378 16.14 1.18 18.47 2 2 2 153378 16.17 1.18 18.35 2 2 2 153379 13.93 1.14 17.79 2 2 2 153379 13.96 1.15 18.33 2 2 2 153380 13.03 1.15 17.94 2 2 2 153380 13.19 1.14 18.08 2 2 2 153381 12.10 1.13 18.26 2 2 2 153381 12.36 1.13 18.12 2 2 2 153382 11.81 1.15 18.38 2 2 2 153382 11.75 1.20 18.15 2 2 2 153383 11.71 1.13 18.22 2 2 2 153383 11.74 1.16 18.66 2 2 2 153384 11.33 1.14 18.32 4 4 4 153384 11.33 1.14 18.14 4 4 4 153385 6.43 0.67 10.61 2 2 2 153385 6.43 0.65 10.73 2 2 2 153386 12.15 1.18 18.92 2 2 2 153386 12.06 1.23 19.27 2 2 2 153387 15.79 1.57 25.27 2 2 2 153387 15.89 1.55 25.51 2 2 2 153388 3.82 0.55 9.41 2 2 2 153388 3.95 0.50 9.51 2 2 2 153389 1.36 0.12 2.20 2 2 2 153389 1.42 0.10 2.32 2 2 2 153390 0.85 0.08 1.19 2 2 2 153390 0.88 0.11 1.17 2 2 2 153391 0.84 0.11 1.07 2 2 2 153391 3.21 0.10 1.03 4 2 2 153392 36.71 1.33 20.41 2 2 2 153392 40.27 1.37 20.23 4 2 2 153393 34.45 1.29 19.55 2 2 2 153393 34.45 1.32 20.21 2 2 2 153394 32.20 1.27 19.31 2 2 2 153394 32.30 1.28 19.52 2 2 2 153395 27.88 1.25 19.02 2 2 2 153395 28.20 1.26 18.90 2 2 2 153396 27.59 1.24 18.54 2 2 2 153396 27.59 1.24 18.70 2 2 2 153397 25.32 1.21 18.50 2 2 2 153397 25.38 1.23 18.69 2 2 2 153398 21.96 1.19 18.18 2 2 2 153398 22.09 1.23 17.85 2 2 2 153399 18.64 1.17 18.34 2 2 2 153399 18.87 1.18 18.12 2 2 2 153400 17.07 1.15 17.78 2 2 2 153400 17.04 1.17 18.04 2 2 2 153401 16.23 1.17 18.59 2 2 2 153401 16.49 1.18 18.33 2 2 2 153402 15.08 1.19 18.73 2 2 2 153402 15.21 1.20 18.64 2 2 2 153403 13.99 1.18 18.20 2 2 2 153403 14.06 1.19 18.70 2 2 2 153404 13.00 1.16 18.30 2 2 2 153404 13.07 1.14 18.00 2 2 2 153405 12.07 1.16 18.23 2 2 2 153405 12.11 1.16 18.39 2 2 2 153406 12.04 1.23 18.96 2 2 2 153406 12.23 1.20 18.90 2 2 2 153407 12.22 1.21 18.75 2 2 2 153407 12.19 1.22 19.14 2 2 2 153408 12.19 1.23 19.17 2 2 2 153408 12.29 1.21 18.95 2 2 2 153409 12.60 1.34 21.42 2 2 2 153409 12.76 1.34 21.16 2 2 2 153410 11.74 1.37 22.21 2 2 2 153410 11.83 1.35 22.17 2 2 2 153411 4.81 0.65 11.44 2 2 2 153411 4.84 0.69 11.50 2 2 2 153412 2.65 0.40 6.65 2 2 2 153412 2.72 0.40 6.86 2 2 2 153413 1.39 0.15 2.36 2 2 2 153413 1.39 0.15 2.42 2 2 2 153414 0.94 0.10 1.07 2 2 2 153414 0.97 0.11 1.03 2 2 2 153415 33.02 1.29 19.33 2 2 2 153415 33.02 1.26 19.67 2 2 2 153416 29.97 1.24 19.41 2 2 2 153416 30.10 1.26 19.27 2 2 2 153417 27.84 1.24 18.81 2 2 2 153417 28.32 1.25 18.79 2 2 2 153418 25.44 1.19 18.74 2 2 2 153418 25.57 1.18 18.54 2 2 2 153419 24.25 1.20 18.78 2 2 2 153419 23.99 1.20 18.86 2 2 2 153420 22.28 1.22 18.65 2 2 2 153420 22.38 1.21 18.50 2 2 2 153421 20.42 1.21 18.97 2 2 2 153421 20.51 1.22 19.01 2 2 2 153422 18.42 1.19 18.82 2 2 2 153422 18.42 1.22 18.64 2 2 2 153424 14.96 1.16 18.45 2 2 2 153424 15.09 1.16 17.84 2 2 2 153425 12.98 1.13 17.67 2 2 2 153425 13.04 1.13 17.62 2 2 2 153426 12.75 1.15 18.42 2 2 2 153426 12.85 1.14 18.23 2 2 2 153427 11.32 1.12 17.93 2 2 2 153427 11.44 1.14 17.39 2 2 2 153428 11.86 1.16 17.96 2 2 2 153428 11.92 1.15 17.92 2 2 2 153429 12.08 1.18 18.81 2 2 2 153429 12.17 1.16 18.61 2 2 2 153430 11.53 1.18 18.87 2 2 2 153430 11.69 1.18 18.37 2 2 2 153431 11.56 1.24 18.60 2 2 2 153431 11.75 1.19 18.40 2 2 2 153432 13.41 1.29 20.70 2 2 2 153432 13.34 1.32 20.50 2 2 2 153433 12.48 1.39 22.91 2 2 2 153433 12.48 1.36 22.73 2 2 2 153434 6.21 0.86 14.07 2 2 2 153434 6.24 0.83 14.37 2 2 2 153435 2.12 0.30 5.31 2 2 2 153435 2.15 0.27 5.41 2 2 2 153436 0.95 0.09 1.29 2 2 2 153436 0.92 0.11 1.29 2 2 2 153437 0.92 0.09 1.23 2 2 2 153437 0.91 0.09 1.21 2 2 2 153438 28.09 1.26 18.35 2 2 2 153438 28.19 1.17 18.57 2 2 2 153439 25.18 1.20 18.08 2 2 2 153439 25.34 1.20 17.86 2 2 2 153440 23.12 1.16 18.08 2 2 2 153440 23.38 1.17 18.23 2 2 2 153441 22.80 1.25 18.15 2 2 2 153441 22.96 1.16 17.51 2 2 2 153442 22.38 1.17 17.69 2 2 2 153442 22.25 1.16 17.85 2 2 2 153443 20.93 1.16 18.10 2 2 2 153443 21.03 1.15 18.26 2 2 2 153444 20.54 1.16 17.40 2 2 2 153444 20.45 1.15 17.70 2 2 2 153445 15.80 1.12 17.32 2 2 2 153445 15.77 1.13 17.38 2 2 2 153446 14.65 1.14 17.67 2 2 2 153446 14.78 1.12 17.55 2 2 2 153447 14.61 1.13 17.70 2 2 2 153447 14.74 1.20 17.40 2 2 2 153448 13.65 1.13 17.87 2 2 2 153448 13.68 1.14 17.63 2 2 2 153449 12.69 1.15 17.65 2 2 2 153449 12.79 1.17 17.59 2 2 2 153451 12.02 1.14 17.97 2 2 2 153451 11.96 1.14 18.28 2 2 2 153452 11.83 1.17 18.79 2 2 2 153452 11.89 1.18 18.38 2 2 2 153453 12.24 1.23 18.61 2 2 2 153453 12.18 1.23 19.23 2 2 2 153454 12.59 1.29 19.70 2 2 2 153454 12.59 1.28 19.48 2 2 2 153455 13.19 1.38 22.05 2 2 2 153455 13.22 1.39 22.15 2 2 2 153456 13.25 1.48 22.71 2 2 2 153456 13.41 1.42 22.49 2 2 2 153457 6.63 0.93 14.56 2 2 2 153457 6.66 0.89 14.85 2 2 2 153458 3.90 0.57 8.97 2 2 2 153458 3.99 0.57 9.00 2 2 2 153459 1.36 0.20 2.85 2 2 2 153459 1.36 0.18 2.93 2 2 2 153460 0.70 0.11 1.15 2 2 2 153460 0.70 0.12 1.19 2 2 2 153461 30.68 1.27 18.86 2 2 2 153461 30.84 1.29 19.16 2 2 2 153462 27.61 1.30 18.47 2 2 2 153462 28.00 1.24 18.17 2 2 2 153463 23.53 1.19 18.05 2 2 2 153463 23.53 1.19 17.79 2 2 2 153464 22.44 1.19 17.97 2 2 2 153464 22.56 1.19 17.71 2 2 2 153465 20.80 1.16 17.39 2 2 2 153465 20.89 1.22 17.43 2 2 2 153466 18.33 1.18 17.50 2 2 2 153466 18.46 1.18 17.64 2 2 2 153467 18.30 1.18 17.75 2 2 2 153467 17.95 1.17 17.70 2 2 2 153468 15.99 1.18 17.29 2 2 2 153468 15.99 1.17 17.73 2 2 2 153469 15.07 1.19 17.43 2 2 2 153469 15.16 1.18 17.59 2 2 2 153470 13.68 17.81 2 5 2 153470 13.64 1.10 17.52 2 3 2 153471 12.02 1.10 17.53 2 3 2 153471 12.04 1.12 17.24 2 3 2 153472 12.25 17.98 2 5 2 153472 12.00 1.16 17.83 2 3 2 153473 11.64 1.13 18.45 2 3 2 153473 11.84 1.20 18.22 2 3 2 153474 11.96 1.16 18.85 2 3 2 153474 11.93 1.18 19.14 2 3 2 153475 12.66 1.25 19.69 2 3 2 153475 12.73 1.24 19.53 2 3 2 153477 12.88 1.39 21.71 2 3 2 153477 13.10 1.39 21.65 2 3 2 153478 11.52 1.28 21.03 2 3 2 153478 11.58 1.35 21.40 2 3 2 153479 8.14 17.46 2 5 2 153479 8.40 17.19 2 5 2 153480 4.24 9.86 2 5 2 153480 4.24 9.98 2 5 2 153481 2.06 5.16 2 5 2 153481 2.16 5.14 2 5 2 153482 2.29 5.59 2 5 2 153482 2.65 5.67 2 5 2 153483 1.23 2.01 2 5 2 153483 1.00 2.02 2 5 2 153484 27.74 18.38 2 5 2 153484 27.90 18.96 2 5 2 153485 27.79 19.05 2 5 2 153485 27.89 19.21 2 5 2 153486 24.19 17.97 2 5 2 153486 24.39 18.22 2 5 2 153487 22.97 1.28 17.74 2 3 2 153487 22.78 1.22 17.48 2 3 2 153488 20.84 1.21 17.79 2 3 2 153488 20.78 1.18 17.48 2 3 2 153489 18.30 1.20 18.05 2 3 2 153489 19.47 18.47 2 5 2 153490 16.95 1.19 17.73 2 3 2 153490 17.17 1.17 17.63 2 3 2 153491 17.23 1.30 18.11 2 3 2 153491 17.42 1.18 18.31 2 3 2 153492 15.10 18.68 2 5 2 153492 15.53 18.62 2 5 2 153493 13.62 18.58 2 5 2 153493 13.52 18.52 2 5 2 153494 13.06 18.26 2 5 2 153494 12.79 1.25 17.65 2 3 2 153495 12.16 1.47 17.58 2 3 2 153495 12.06 1.32 17.54 2 3 2 153496 12.43 18.61 2 5 2 153496 11.99 1.27 18.00 2 3 2 153497 11.82 1.26 18.72 2 3 2 153497 12.13 19.08 2 5 2 153498 12.04 1.29 19.02 2 3 2 153498 12.42 18.84 2 5 2 153499 12.57 1.28 19.64 2 3 2 153499 12.61 1.29 19.34 2 3 2 153500 12.18 1.27 20.13 2 3 2 153500 12.28 1.28 19.91 2 3 2 153501 11.06 1.23 19.33 2 3 2 153501 11.03 1.33 19.97 2 3 2 153502 9.61 19.09 2 5 2 153502 9.64 19.13 2 5 2 153503 4.00 0.65 10.02 2 3 2 153503 4.17 10.39 2 5 2 153504 1.57 0.52 3.53 2 3 2 153504 1.61 0.65 3.55 2 3 2 153505 0.96 0.44 1.70 2 3 2 153505 1.00 0.15 1.71 2 3 2 153506 0.92 1.15 2 5 2 153506 1.35 1.18 2 5 2 153507 33.26 1.54 19.77 2 2 2 153507 33.54 1.29 20.01 2 2 2 153508 28.45 1.23 18.49 2 2 2 153508 28.36 1.25 18.84 2 2 2 153509 24.11 1.18 17.85 2 2 2 153509 24.40 1.18 17.92 2 2 2 153510 23.74 1.15 17.95 2 2 2 153510 23.80 1.17 18.13 2 2 2 153511 21.68 1.14 18.15 2 2 2 153511 21.86 1.15 18.29 2 2 2 153512 19.74 1.13 18.21 2 2 2 153512 19.77 1.16 18.02 2 2 2 153513 21.36 1.16 18.07 2 2 2 153513 21.48 1.16 18.16 2 2 2 153514 20.59 1.18 18.74 2 2 2 153514 20.98 1.18 18.59 2 2 2 153515 21.20 1.34 19.56 2 2 2 153515 21.39 1.20 19.35 2 2 2 153516 15.86 1.13 18.19 2 2 2 153516 15.85 1.17 18.24 2 2 2 153517 13.21 1.10 18.10 2 2 2 153517 13.56 1.13 18.36 2 2 2 153518 12.58 1.09 18.40 2 2 2 153518 12.64 1.17 18.56 2 2 2 153519 12.24 1.13 18.17 2 2 2 153519 12.24 1.12 18.54 2 2 2 153520 12.29 1.12 18.70 2 2 2 153520 12.26 1.13 18.55 2 2 2 153521 12.18 1.14 19.19 2 2 2 153521 12.21 1.15 19.43 2 2 2 153522 12.42 1.16 19.97 2 2 2 153522 12.43 1.17 20.03 2 2 2 153523 12.65 1.42 20.94 2 2 2 153523 12.74 1.28 20.99 2 2 2 153524 13.00 1.35 21.25 2 2 2 153524 13.09 1.36 21.48 2 2 2 153525 11.74 1.25 20.62 2 2 2 153525 11.88 1.25 20.32 2 2 2 153526 2.45 0.35 5.79 2 2 2 153526 2.58 0.25 5.92 2 2 2 153527 1.69 0.20 3.12 2 2 2 153527 1.73 0.19 3.17 2 2 2 153530 31.19 1.23 19.44 2 2 2 153530 31.69 1.39 18.97 2 2 2 153531 30.89 1.22 19.66 2 2 2 153531 30.96 1.24 19.72 2 2 2 153532 27.79 1.19 18.81 2 2 2 153532 27.85 1.20 18.65 2 2 2 153533 26.03 1.32 18.55 2 2 2 153533 26.25 1.30 18.43 2 2 2 153534 25.04 1.19 18.15 2 2 2 153534 25.21 1.17 18.00 2 2 2 153535 23.34 1.18 18.26 2 2 2 153535 23.47 1.19 18.34 2 2 2 153536 23.36 1.17 18.71 2 2 2 153536 23.17 1.16 18.51 2 2 2 153537 19.48 1.15 17.49 2 2 2 153537 19.49 1.14 17.90 2 2 2 153538 18.30 1.16 18.17 2 2 2 153538 18.66 1.18 18.14 2 2 2 153539 17.13 1.13 18.32 2 2 2 153539 17.25 1.15 18.41 2 2 2 153540 15.84 1.13 17.82 2 2 2 153540 15.85 1.15 17.91 2 2 2 153541 13.02 1.23 17.49 2 2 2 153541 13.11 1.11 17.36 2 2 2 153542 12.36 1.11 17.55 2 2 2 153542 12.49 1.14 17.70 2 2 2 153543 12.08 1.13 18.36 2 2 2 153543 12.06 1.13 18.22 2 2 2 153544 6.93 0.63 10.89 4 4 4 153544 6.95 0.69 10.74 4 4 4 153545 12.61 1.30 19.61 2 2 2 153545 12.64 1.23 19.56 2 2 2 153546 12.60 1.28 20.33 2 2 2 153546 12.73 1.29 20.22 2 2 2 153547 12.49 1.31 20.85 2 2 2 153547 12.56 1.29 20.99 2 2 2 153548 11.28 1.22 19.99 2 2 2 153548 11.31 1.23 19.81 2 2 2 153549 3.89 0.56 8.79 2 2 2 153549 3.89 0.63 9.00 2 2 2 153550 1.91 0.23 4.06 2 2 2 153550 1.94 0.28 4.09 2 2 2 153551 1.63 0.20 3.19 2 2 2 153551 1.61 0.20 3.18 2 2 2 153552 1.53 0.20 3.10 2 2 2 153552 1.56 0.19 3.03 2 2 2 153553 29.83 1.31 18.79 2 2 2 153553 30.12 1.25 18.90 2 2 2 153554 27.91 1.22 18.73 2 2 2 153554 28.10 1.22 18.39 2 2 2 153555 25.86 1.23 17.97 2 2 2 153555 25.64 1.21 17.77 2 2 2 153556 22.53 1.19 17.61 2 2 2 153556 22.66 1.18 17.87 2 2 2 153557 21.25 1.22 17.97 2 2 2 153557 21.32 1.16 17.84 2 2 2 153558 18.98 1.16 17.84 2 2 2 153558 19.20 1.16 17.87 2 2 2 153559 18.98 1.18 17.60 2 2 2 153559 19.49 1.18 17.49 2 2 2 153560 15.36 1.15 17.53 2 2 2 153560 15.36 1.14 17.62 2 2 2 153561 13.13 1.13 17.03 2 2 2 153561 13.45 1.20 17.24 2 2 2 153562 12.14 1.12 17.42 2 2 2 153562 12.14 1.13 17.53 2 2 2 153563 12.01 1.15 17.86 2 2 2 153563 12.14 1.14 17.88 2 2 2 153564 12.01 1.19 17.89 2 2 2 153564 12.02 1.16 17.63 2 2 2 153565 11.89 1.17 17.93 2 2 2 153565 11.92 1.18 17.78 2 2 2 153566 11.80 1.19 18.71 2 2 2 153566 11.92 1.19 18.40 2 2 2 153567 11.99 1.21 18.99 2 2 2 153567 11.96 1.22 19.10 2 2 2 153568 12.31 1.28 19.75 2 2 2 153568 12.37 1.27 19.80 2 2 2 153569 12.48 1.40 21.18 2 2 2 153569 12.64 1.34 21.51 2 2 2 153570 10.46 1.24 19.02 2 2 2 153570 10.62 1.22 19.56 2 2 2 153571 8.51 1.05 16.39 2 2 2 153571 8.45 1.06 16.33 2 2 2 153572 2.50 0.39 5.94 2 2 2 153572 2.50 0.35 5.94 2 2 2 153573 1.57 0.24 3.47 2 2 2 153573 1.61 0.21 3.35 2 2 2 153574 1.58 0.20 3.32 2 2 2 153574 1.58 0.20 3.31 2 2 2 153575 1.51 0.19 3.27 2 2 2 153575 1.55 0.21 3.32 2 2 2 153576 30.54 1.30 19.05 2 2 2 153576 30.92 1.27 19.35 2 2 2 153577 26.93 1.23 18.20 2 2 2 153577 26.64 1.28 17.91 2 2 2 153578 25.04 1.21 18.24 2 2 2 153578 25.20 1.22 18.16 2 2 2 153579 25.46 1.24 18.39 2 2 2 153579 25.14 1.23 18.16 2 2 2 153580 23.83 1.22 17.64 2 2 2 153580 23.35 1.23 17.96 2 2 2 153581 19.13 1.19 17.58 2 2 2 153581 19.26 1.16 17.44 2 2 2 153582 17.91 1.16 17.40 2 2 2 153582 17.95 1.16 17.65 2 2 2 153583 15.93 1.16 17.53 2 2 2 153583 16.00 1.17 17.27 2 2 2 153584 14.43 1.16 17.51 2 2 2 153584 14.62 1.16 17.45 2 2 2 153585 13.13 1.15 17.25 2 2 2 153585 13.13 1.20 17.36 2 2 2 153586 12.68 1.17 17.59 2 2 2 153586 12.68 1.17 17.86 2 2 2 153587 12.04 1.16 18.09 2 2 2 153587 11.95 1.19 17.98 2 2 2 153588 11.95 1.19 18.40 2 2 2 153588 11.98 1.19 18.48 2 2 2 153589 11.95 1.21 18.52 2 2 2 153589 11.98 1.22 18.40 2 2 2 153590 12.21 1.25 19.22 2 2 2 153590 12.27 1.29 18.93 2 2 2 153591 12.85 1.36 20.85 2 2 2 153591 13.01 1.36 20.97 2 2 2 153592 12.88 1.38 21.02 2 2 2 153592 12.95 1.38 20.94 2 2 2 153593 11.48 1.36 19.51 2 2 2 153593 11.61 1.31 19.87 2 2 2 153594 7.68 0.98 15.44 2 2 2 153594 7.78 0.99 15.42 2 2 2 153595 2.41 0.37 5.81 2 2 2 153595 2.47 0.35 5.96 2 2 2 153596 1.42 0.19 2.82 2 2 2 153596 1.42 0.19 2.70 2 2 2 153597 1.30 0.19 2.76 2 2 2 153597 1.36 0.19 2.72 2 2 2 153598 1.37 0.19 2.84 2 2 2 153598 1.40 0.20 2.84 2 2 2 153599 31.98 1.30 18.93 2 2 2 153599 32.21 1.41 19.01 2 2 2 153600 31.76 1.29 19.29 2 2 2 153600 31.89 1.30 19.09 2 2 2 153601 29.24 1.26 18.59 2 2 2 153601 29.11 1.33 18.37 2 2 2 153602 27.77 1.25 18.67 2 2 2 153602 28.00 1.26 18.85 2 2 2 153604 23.40 1.22 17.89 2 2 2 153604 23.62 1.24 18.26 2 2 2 153605 20.46 1.21 18.23 2 2 2 153605 20.52 1.23 18.17 2 2 2 153606 17.94 1.20 17.74 2 2 2 153606 18.00 1.17 17.64 2 2 2 153608 14.84 1.20 17.41 2 2 2 153608 15.13 1.18 17.83 2 2 2 153609 12.70 1.16 17.20 2 2 2 153609 12.73 1.15 17.54 2 2 2 153610 12.48 1.17 17.80 2 2 2 153610 12.45 1.15 17.39 2 2 2 153611 12.04 1.23 17.47 2 2 2 153611 12.07 1.16 17.77 2 2 2 153612 11.66 1.18 17.49 2 2 2 153612 11.75 1.19 17.88 2 2 2 153613 12.07 1.24 18.81 2 2 2 153613 12.08 1.25 18.79 2 2 2 153614 12.49 1.30 19.71 2 2 2 153614 12.52 1.31 19.73 2 2 2 153615 12.53 1.38 20.38 2 2 2 153615 12.75 1.37 20.87 2 2 2 153616 12.08 1.36 20.47 2 2 2 153616 12.21 1.35 20.71 2 2 2 153617 6.37 0.91 13.98 2 2 2 153617 6.52 0.89 14.63 2 2 2 153618 4.81 0.76 10.28 2 2 2 153618 4.77 0.74 10.10 2 2 2 153619 3.63 0.61 9.43 2 2 2 153619 3.66 0.67 9.13 2 2 2 153620 1.24 0.19 3.01 2 2 2 153620 1.30 0.21 2.88 2 2 2 153621 1.18 0.19 2.71 2 2 2 153621 1.21 0.20 2.68 2 2 2 153622 31.29 1.29 18.94 2 2 2 153622 30.80 1.30 18.59 2 2 2 153623 30.23 1.27 19.23 2 2 2 153623 30.43 1.27 18.64 2 2 2 153624 24.19 1.19 18.19 2 2 2 153624 24.49 1.18 18.03 2 2 2 153625 22.72 1.18 17.92 2 2 2 153625 22.82 1.16 17.41 2 2 2 153626 21.77 1.17 18.15 2 2 2 153626 22.06 1.16 17.64 2 2 2 153627 19.07 1.16 17.89 2 2 2 153627 19.16 1.13 17.67 2 2 2 153628 16.60 1.15 17.31 2 2 2 153628 16.69 1.13 17.55 2 2 2 153629 14.53 1.13 17.75 2 2 2 153629 14.75 1.12 17.17 2 2 2 153631 12.33 1.14 17.40 2 2 2 153631 12.39 1.12 17.32 2 2 2 153632 12.23 1.11 17.75 2 2 2 153632 12.36 1.12 18.00 2 2 2 153633 11.84 1.12 17.97 2 2 2 153633 12.13 1.12 17.48 2 2 2 153634 11.65 1.14 17.87 2 2 2 153634 11.81 1.12 17.71 2 2 2 153635 11.71 1.18 18.11 2 2 2 153635 11.65 1.16 18.52 2 2 2 153636 6.15 0.65 10.51 2 2 2 153636 6.18 0.64 10.29 2 2 2 153637 12.38 1.26 19.89 2 2 2 153637 12.42 1.26 19.68 2 2 2 153638 12.16 1.27 20.66 2 2 2 153638 12.29 1.28 20.12 2 2 2 153639 11.15 1.27 20.65 2 2 2 153639 10.93 1.28 20.62 2 2 2 153640 5.24 0.73 12.22 2 2 2 153640 5.08 0.77 12.52 2 2 2 153641 2.65 0.42 6.60 2 2 2 153641 2.71 0.43 6.55 2 2 2 153642 1.37 0.19 2.86 2 2 2 153642 1.40 0.20 2.93 2 2 2 153643 1.11 0.18 2.45 2 2 2 153643 1.11 0.18 2.51 2 2 2 153644 1.11 0.18 2.46 2 2 2 153644 1.14 0.17 2.46 2 2 2 153645 31.71 1.28 18.85 2 2 2 153645 31.48 1.28 19.34 2 2 2 153646 31.44 1.31 19.45 2 2 2 153646 32.06 1.30 19.19 2 2 2 153647 25.77 1.21 18.39 2 2 2 153647 25.29 1.23 17.94 2 2 2 153648 24.57 1.22 17.60 2 2 2 153648 23.96 1.21 18.09 2 2 2 153649 23.28 1.22 18.22 2 2 2 153649 23.53 1.21 17.79 2 2 2 153650 19.68 1.16 17.49 2 2 2 153650 19.97 1.18 17.77 2 2 2 153651 17.29 1.16 17.51 2 2 2 153651 17.68 1.19 17.25 2 2 2 153652 16.42 1.18 17.87 2 2 2 153652 16.58 1.19 17.34 2 2 2 153653 16.10 1.18 17.77 2 2 2 153653 16.03 1.26 17.95 2 2 2 153654 14.13 1.17 17.64 2 2 2 153654 14.23 1.18 17.32 2 2 2 153655 12.33 1.10 17.48 2 2 2 153655 12.52 1.14 16.92 2 2 2 153656 12.01 1.12 17.20 2 2 2 153656 12.04 1.13 17.17 2 2 2 153657 11.88 1.14 17.76 2 2 2 153657 11.68 1.14 17.77 2 2 2 153658 11.59 1.16 17.98 2 2 2 153658 11.88 1.15 17.63 2 2 2 153659 11.68 1.20 18.30 2 2 2 153659 11.75 1.23 17.77 2 2 2 153660 11.75 1.24 18.46 2 2 2 153660 11.78 1.24 18.80 2 2 2 153661 12.10 1.36 18.92 2 2 2 153661 12.19 1.25 19.32 2 2 2 153662 11.10 1.29 20.53 2 2 2 153662 11.23 1.29 20.49 2 2 2 153663 8.78 1.14 17.34 2 2 2 153663 8.53 1.13 17.71 2 2 2 153664 5.70 0.83 12.85 2 2 2 153664 5.70 0.81 12.66 2 2 2 153665 1.66 0.25 3.55 2 2 2 153665 1.73 0.24 3.61 2 2 2 153666 1.66 0.25 3.54 2 2 2 153666 1.66 0.25 3.50 2 2 2 153667 1.63 0.23 3.49 2 2 2 153667 1.63 0.23 3.53 2 2 2 153668 28.09 1.27 18.07 2 2 2 153668 28.25 1.26 18.39 2 2 2 153669 27.73 1.26 18.53 2 2 2 153669 27.50 1.26 18.35 2 2 2 153670 23.22 1.21 17.20 2 2 2 153670 23.25 1.26 17.62 2 2 2 153671 22.31 1.19 17.35 2 2 2 153671 22.63 1.19 17.34 2 2 2 153672 20.62 1.18 17.19 2 2 2 153672 20.85 1.18 17.51 2 2 2 153673 18.39 1.21 17.42 2 2 2 153673 18.42 1.21 17.48 2 2 2 153674 16.96 1.21 17.19 2 2 2 153674 17.22 1.20 17.42 2 2 2 153675 15.24 1.20 17.20 2 2 2 153675 15.54 1.20 17.01 2 2 2 153677 13.27 1.18 16.84 2 2 2 153677 13.17 1.19 17.24 2 2 2 153678 12.55 1.17 17.21 2 2 2 153678 12.78 1.19 17.19 2 2 2 153679 12.10 1.18 17.34 2 2 2 153679 12.20 1.21 17.51 2 2 2 153680 11.87 1.22 17.56 2 2 2 153680 11.87 1.20 17.69 2 2 2 153681 7.90 0.89 12.89 2 2 2 153681 7.93 0.89 12.79 2 2 2 153682 11.67 1.24 17.79 2 2 2 153682 11.77 1.22 17.64 2 2 2 153683 11.64 1.24 18.24 2 2 2 153683 11.70 1.24 18.47 2 2 2 153684 12.15 1.28 19.32 2 2 2 153684 12.18 1.30 19.33 2 2 2 153685 12.37 1.32 19.75 2 2 2 153685 12.33 1.33 19.75 2 2 2 153686 13.23 1.48 22.36 2 2 2 153686 13.27 1.49 22.31 2 2 2 153687 7.10 1.01 14.79 2 2 2 153687 7.10 1.02 14.87 2 2 2 153688 1.55 0.27 3.57 2 2 2 153688 1.59 0.26 3.64 2 2 2 153689 1.42 0.25 3.21 2 2 2 153689 1.42 0.25 3.23 2 2 2 153691 19.27 1.16 16.65 2 2 2 153691 19.50 1.17 16.35 2 2 2 153692 20.69 1.20 16.59 2 2 2 153692 20.88 1.19 16.63 2 2 2 153693 20.56 1.20 16.93 2 2 2 153693 20.78 1.20 17.09 2 2 2 153694 20.81 1.19 16.69 2 2 2 153694 20.87 1.17 16.96 2 2 2 153695 19.35 1.18 17.18 2 2 2 153695 19.35 1.18 17.01 2 2 2 153696 16.89 1.18 17.13 2 2 2 153696 16.92 1.23 17.12 2 2 2 153697 16.63 1.19 16.83 2 2 2 153697 16.66 1.21 16.84 2 2 2 153698 14.66 1.17 16.85 2 2 2 153698 14.75 1.17 16.72 2 2 2 153699 13.36 1.14 16.88 2 2 2 153699 13.52 1.15 16.89 2 2 2 153700 12.97 1.16 16.80 2 2 2 153700 13.04 1.17 17.01 2 2 2 153701 12.16 1.16 16.68 2 2 2 153701 12.23 1.16 16.56 2 2 2 153702 11.67 1.17 16.87 2 2 2 153702 11.57 1.17 17.08 2 2 2 153703 11.51 1.17 16.78 2 2 2 153703 11.51 1.17 16.75 2 2 2 153704 11.08 1.16 17.10 2 2 2 153704 11.18 1.18 17.33 2 2 2 153705 11.37 1.19 17.55 2 2 2 153705 11.47 1.19 17.59 2 2 2 153706 11.50 1.22 17.72 2 2 2 153706 11.43 1.22 17.47 2 2 2 153707 11.53 1.22 17.69 2 2 2 153707 11.43 1.22 17.60 2 2 2 153708 11.78 1.25 18.59 2 2 2 153708 11.82 1.24 18.43 2 2 2 153709 12.62 1.34 19.97 2 2 2 153709 12.68 1.33 19.91 2 2 2 153710 11.67 1.39 21.31 2 2 2 153710 11.83 1.39 21.44 2 2 2 153711 6.60 0.95 13.05 2 2 2 153711 6.67 0.96 12.87 2 2 2 153712 2.86 0.44 4.86 2 2 2 153712 2.82 0.44 4.89 2 2 2 153713 2.88 0.43 4.86 2 2 2 153713 2.89 0.43 4.87 2 2 2 153714 11.44 1.18 16.52 2 2 2 153714 11.34 1.23 16.46 2 2 2 153715 10.95 1.18 16.38 2 2 2 153715 10.83 1.18 16.44 2 2 2 153716 10.82 1.15 16.12 2 2 2 153716 10.88 1.16 16.31 2 2 2 153717 8.73 1.09 13.88 4 4 4 153717 8.80 1.08 13.75 4 4 4 153718 10.59 1.20 16.30 2 2 2 153718 10.68 1.18 16.30 2 2 2 153719 11.00 1.19 16.62 2 2 2 153719 11.03 1.19 16.87 2 2 2 153720 10.84 1.20 16.98 2 2 2 153720 10.64 1.19 16.96 2 2 2 153721 10.80 1.21 16.56 2 2 2 153721 10.90 1.21 16.69 2 2 2 153722 10.89 1.18 16.61 2 2 2 153722 10.73 1.21 16.27 2 2 2 153723 10.63 1.20 16.95 2 2 2 153723 10.63 1.19 16.85 2 2 2 153724 10.66 1.22 17.31 2 2 2 153724 10.69 1.22 16.87 2 2 2 153725 10.30 1.19 16.66 2 2 2 153725 10.36 1.19 16.85 2 2 2 153726 10.71 1.23 17.53 2 2 2 153726 10.94 1.24 17.45 2 2 2 153727 10.74 1.23 16.90 2 2 2 153727 10.77 1.25 17.47 2 2 2 153728 11.47 1.25 17.56 2 2 2 153728 11.54 1.26 17.90 2 2 2 153729 10.25 1.18 16.42 2 2 2 153729 10.38 1.18 16.50 2 2 2 153730 9.28 1.13 15.08 2 2 2 153730 9.18 1.12 15.04 2 2 2 153732 2.13 0.69 4.21 2 2 2 153732 2.20 0.67 4.31 2 2 2 153733 1.72 0.64 3.40 2 2 2 153733 1.75 0.62 3.44 2 2 2 153734 10.45 1.19 16.63 2 2 2 153734 10.55 1.19 16.90 2 2 2 153735 10.38 1.20 16.99 2 2 2 153735 10.52 1.18 17.09 2 2 2 153736 10.25 1.20 16.61 2 2 2 153736 10.29 1.19 16.78 2 2 2 153737 10.12 1.19 16.57 2 2 2 153737 10.12 1.20 16.59 2 2 2 153738 10.09 1.19 16.74 2 2 2 153738 10.09 1.20 16.68 2 2 2 153739 10.07 1.17 16.78 2 2 2 153739 10.26 1.16 17.10 2 2 2 153740 9.97 1.14 15.83 2 2 2 153740 10.03 1.15 15.94 2 2 2 153741 9.71 1.10 14.50 2 2 2 153741 9.81 1.10 14.63 2 2 2 153742 10.25 1.06 13.47 2 2 2 153742 10.35 1.06 13.58 2 2 2 153743 9.23 0.99 9.82 2 2 2 153743 9.42 0.98 10.01 2 2 2 153744 5.80 0.89 5.22 2 2 2 153744 5.70 0.81 5.45 2 2 2 153745 0.86 0.41 0.00 2 2 2 153745 0.89 0.47 0.00 3 3 2 153746 10.36 1.17 16.64 2 2 2 153746 10.51 1.16 16.55 2 2 2 153747 10.41 1.17 16.64 2 2 2 153747 10.42 1.17 16.68 2 2 2 153748 10.32 1.16 16.81 2 2 2 153748 10.47 1.15 16.92 2 2 2 153749 9.96 1.16 16.54 2 2 2 153749 10.25 1.15 16.81 2 2 2 153750 10.21 1.15 15.38 2 2 2 153750 10.24 1.16 15.34 2 2 2 153751 10.35 1.03 10.59 2 2 2 153751 10.47 1.04 10.72 2 2 2 153752 9.03 1.02 9.74 2 2 2 153752 8.97 1.01 9.63 2 2 2 153753 0.82 0.44 0.00 2 2 2 153753 0.86 0.49 0.00 2 2 2 153754 10.35 1.16 15.84 2 2 2 153754 10.48 1.12 16.18 2 2 2 153755 10.51 1.14 16.46 2 2 2 153755 10.54 1.13 16.35 2 2 2 153756 10.28 1.13 15.23 2 2 2 153756 10.25 1.12 15.46 2 2 2 153757 11.24 1.21 15.62 2 2 2 153757 11.21 1.20 15.57 2 2 2 153758 10.21 1.02 11.22 2 2 2 153758 10.25 1.02 11.16 2 2 2 153759 9.19 1.06 8.63 2 2 2 153759 9.32 1.02 8.78 2 2 2 153760 3.36 0.63 3.46 2 2 2 153760 3.46 0.66 3.44 2 2 2 153761 9.62 1.00 10.57 2 2 2 153761 9.68 0.97 10.66 2 2 2 153763 4.69 0.87 4.13 2 2 2 153763 4.66 0.84 4.19 2 2 2 153764 1.20 0.54 0.74 2 2 2 153764 1.20 0.54 0.61 2 2 2 153765 17.73 1.09 16.31 2 2 2 153765 17.54 1.14 16.03 2 2 2 153766 17.15 1.08 15.95 2 2 2 153766 17.05 1.09 16.44 2 2 2 153767 16.67 1.10 16.23 2 2 2 153767 16.73 1.10 16.60 2 2 2 153768 6.65 0.77 10.19 2 2 2 153768 6.75 0.77 10.17 2 2 2 153769 15.29 1.12 16.67 2 2 2 153769 15.52 1.12 16.99 2 2 2 153770 14.53 1.09 16.66 2 2 2 153770 14.62 1.10 16.27 2 2 2 153771 14.82 1.15 16.79 2 2 2 153771 14.79 1.11 17.03 2 2 2 153772 13.42 1.15 16.41 2 2 2 153772 13.59 1.15 16.80 2 2 2 153773 13.11 1.13 16.37 2 2 2 153773 13.39 1.20 16.92 2 2 2 153774 12.16 1.12 16.61 2 2 2 153774 12.22 1.14 16.78 2 2 2 153775 11.84 1.19 16.83 2 2 2 153775 11.97 1.12 16.53 2 2 2 153776 11.43 1.12 16.60 2 2 2 153776 11.52 1.14 17.01 2 2 2 153777 11.28 1.15 16.61 2 2 2 153777 11.38 1.11 16.61 2 2 2 153778 11.24 1.14 16.98 2 2 2 153778 11.20 1.13 16.94 2 2 2 153779 11.09 1.15 16.86 2 2 2 153779 11.19 1.15 16.86 2 2 2 153780 11.01 1.21 17.08 2 2 2 153780 11.04 1.10 16.89 2 2 2 153781 11.08 1.18 16.88 2 2 2 153781 11.22 1.14 17.21 2 2 2 153782 10.19 1.16 16.61 2 2 2 153782 10.36 1.14 16.95 2 2 2 153783 10.56 1.14 16.59 2 2 2 153783 10.59 1.16 16.79 2 2 2 153784 12.65 1.36 19.48 2 2 2 153784 12.71 1.33 18.99 2 2 2 153785 11.45 1.28 18.12 2 2 2 153785 11.61 1.29 18.43 2 2 2 153786 6.34 0.89 11.46 2 2 2 153786 6.27 0.88 11.39 2 2 2 153787 2.49 0.50 4.30 2 2 2 153787 2.56 0.47 4.32 2 2 2 153788 17.48 1.13 15.61 2 2 2 153788 17.68 1.13 15.85 2 2 2 153789 18.87 1.13 16.39 2 2 2 153789 19.28 1.23 16.36 2 2 2 153790 19.09 1.10 16.35 2 2 2 153790 18.86 1.20 16.15 2 2 2 153791 17.43 1.15 16.20 2 2 2 153791 17.49 1.16 15.95 2 2 2 153792 15.48 1.11 16.08 2 2 2 153792 15.55 1.20 16.36 2 2 2 153793 15.07 1.14 16.43 2 2 2 153793 15.13 1.14 16.33 2 2 2 153794 14.92 1.13 16.79 2 2 2 153794 14.99 1.14 16.63 2 2 2 153795 14.74 1.13 16.29 2 2 2 153795 14.94 1.14 16.62 2 2 2 153796 12.87 1.17 16.91 2 2 2 153796 12.97 1.15 16.99 2 2 2 153797 12.54 1.21 16.45 2 2 2 153797 12.63 1.14 16.84 2 2 2 153798 11.38 1.14 16.58 2 2 2 153798 11.41 1.15 16.35 2 2 2 153799 11.23 1.13 16.74 2 2 2 153799 11.30 1.13 16.96 2 2 2 153800 11.05 1.14 16.62 2 2 2 153800 11.32 1.18 16.80 2 2 2 153801 11.08 1.14 17.19 2 2 2 153801 11.17 1.16 17.19 2 2 2 153802 10.73 1.23 16.59 2 2 2 153802 10.86 1.17 16.61 2 2 2 153803 11.69 1.19 17.58 2 2 2 153803 11.70 1.20 17.64 2 2 2 153804 11.89 1.23 17.84 2 2 2 153804 11.85 1.23 18.15 2 2 2 153805 12.63 1.44 19.70 2 2 2 153805 12.66 1.26 19.16 2 2 2 153806 13.06 1.35 20.22 2 2 2 153806 13.16 1.32 20.47 2 2 2 153807 14.13 1.52 22.76 2 2 2 153807 14.26 1.53 22.16 2 2 2 153808 10.18 1.13 15.02 2 2 2 153808 10.24 1.15 15.15 2 2 2 153809 2.97 0.56 4.68 2 2 2 153809 3.08 0.52 4.70 2 2 2 153810 2.70 0.42 5.44 2 2 2 153810 2.76 0.43 5.38 2 2 2 153811 10.54 1.13 15.93 2 2 2 153811 10.46 1.06 16.10 2 2 2 153812 10.39 1.06 16.38 2 2 2 153812 10.49 1.06 16.50 2 2 2 153813 10.17 1.05 16.05 2 2 2 153813 10.24 1.07 15.81 2 2 2 153814 10.19 1.04 16.08 2 2 2 153814 10.20 1.09 16.07 2 2 2 153815 9.94 1.04 16.45 2 2 2 153815 10.01 1.04 16.40 2 2 2 153816 9.90 1.04 16.35 2 2 2 153816 9.96 1.05 16.35 2 2 2 153817 10.06 1.05 16.46 2 2 2 153817 10.13 1.04 16.10 2 2 2 153818 10.12 1.05 16.35 2 2 2 153818 10.12 1.05 16.24 2 2 2 153820 10.23 1.04 16.51 2 2 2 153820 9.99 1.11 16.21 2 2 2 153821 9.87 1.02 16.74 2 2 2 153821 9.94 1.02 16.68 2 2 2 153822 9.87 1.04 16.72 2 2 2 153822 9.93 1.06 16.73 2 2 2 153823 10.13 1.08 16.49 2 2 2 153823 10.13 1.07 16.55 2 2 2 153824 10.22 1.08 16.92 2 2 2 153824 10.19 1.09 16.60 2 2 2 153825 10.14 1.07 17.09 2 2 2 153825 10.18 1.07 17.09 2 2 2 153826 9.93 1.06 16.57 2 2 2 153826 9.99 1.06 16.46 2 2 2 153827 10.40 1.08 16.64 2 2 2 153827 10.53 1.08 16.83 2 2 2 153829 9.03 1.00 14.24 2 2 2 153829 9.07 1.07 13.99 2 2 2 153830 0.93 0.47 4.74 2 3 2 153830 1.00 0.56 4.68 2 3 2 153831 17.29 1.04 15.76 2 2 2 153831 17.36 1.02 15.68 2 2 2 153832 17.17 1.04 16.17 2 2 2 153832 17.35 1.04 16.03 2 2 2 153833 16.38 1.03 16.38 2 2 2 153833 16.47 1.04 16.32 2 2 2 153834 14.20 1.03 15.94 2 2 2 153834 14.36 1.03 16.07 2 2 2 153835 14.04 1.03 16.14 2 2 2 153835 14.05 1.03 16.09 2 2 2 153836 13.30 1.10 16.09 2 2 2 153836 13.33 1.04 16.36 2 2 2 153837 13.01 1.07 16.61 2 2 2 153837 13.01 1.06 16.83 2 2 2 153838 12.00 1.06 16.96 2 2 2 153838 12.21 1.04 16.80 2 2 2 153839 10.55 1.04 16.16 2 2 2 153839 10.65 1.04 16.08 2 2 2 153840 10.40 1.07 16.31 2 2 2 153840 10.47 1.04 16.41 2 2 2 153841 10.39 1.05 16.72 2 2 2 153841 10.25 1.03 16.34 2 2 2 153842 10.31 1.04 16.22 2 2 2 153842 10.11 1.04 16.18 2 2 2 153843 10.20 1.04 16.54 2 2 2 153843 10.34 1.04 16.45 2 2 2 153844 10.00 1.10 16.15 2 2 2 153844 10.13 1.05 16.42 2 2 2 153845 10.57 1.07 17.14 2 2 2 153845 10.71 1.08 16.97 2 2 2 153846 10.49 1.06 16.55 2 2 2 153846 10.53 1.04 16.86 2 2 2 153847 10.17 1.05 16.68 2 2 2 153847 10.11 1.05 16.42 2 2 2 153848 11.12 1.11 17.61 2 2 2 153848 11.20 1.10 17.46 2 2 2 153849 10.47 1.10 17.23 2 2 2 153849 10.43 1.08 17.17 2 2 2 153850 11.89 1.14 18.07 2 2 2 153850 11.83 1.15 18.41 2 2 2 153851 12.16 1.18 18.71 2 2 2 153851 12.19 1.19 18.50 2 2 2 153852 10.18 1.03 13.52 2 2 2 153852 10.31 0.98 13.83 2 2 2 153853 2.11 0.51 2.76 2 2 2 153853 2.14 0.47 2.84 2 2 2 153854 14.89 1.04 15.40 2 2 2 153854 15.02 1.00 15.39 2 2 2 153855 16.28 1.04 16.03 2 2 2 153855 16.08 1.03 15.65 2 2 2 153856 15.72 1.05 16.09 2 2 2 153856 16.10 1.05 15.99 2 2 2 153857 14.78 1.05 16.51 2 2 2 153857 14.62 1.07 16.40 2 2 2 153858 14.09 1.05 16.01 2 2 2 153858 14.13 1.06 16.21 2 2 2 153859 14.42 1.07 16.54 3 3 3 153859 14.59 1.07 16.69 3 3 3 153860 13.09 1.12 16.22 2 2 2 153860 13.22 1.05 16.47 2 2 2 153861 11.33 1.06 16.70 2 2 2 153861 11.61 1.06 16.63 2 2 2 153862 10.67 1.07 16.68 2 2 2 153862 10.84 1.04 16.56 2 2 2 153863 10.66 1.06 16.41 2 2 2 153863 10.77 1.04 16.34 2 2 2 153864 10.79 1.06 16.85 2 2 2 153864 10.86 1.07 16.66 2 2 2 153865 10.71 1.07 17.06 2 2 2 153865 10.84 1.09 16.73 2 2 2 153866 10.87 1.09 16.53 2 2 2 153866 10.94 1.08 16.66 2 2 2 153867 10.93 1.09 16.97 2 2 2 153867 11.00 1.07 17.14 2 2 2 153868 11.18 1.15 17.03 2 2 2 153868 11.20 1.09 17.22 2 2 2 153869 10.89 1.12 17.68 2 2 2 153869 11.06 1.12 17.45 2 2 2 153870 11.08 1.12 17.20 2 2 2 153870 11.09 1.13 18.00 2 2 2 153871 11.69 1.15 17.74 2 2 2 153871 11.69 1.16 17.84 2 2 2 153872 11.92 1.18 18.53 2 2 2 153872 11.92 1.17 18.28 2 2 2 153873 12.32 1.27 19.00 2 2 2 153873 12.32 1.26 19.39 2 2 2 153874 11.80 1.26 18.51 2 2 2 153874 11.93 1.26 18.51 2 2 2 153875 8.30 1.02 14.50 2 2 2 153875 8.41 0.99 14.22 2 2 2 153876 1.99 0.54 2.81 2 2 2 153876 2.02 0.50 2.87 2 2 2 153877 15.60 1.04 15.96 2 2 2 153877 15.81 1.07 15.67 2 2 2 153878 24.88 1.17 17.03 2 2 2 153878 24.86 1.18 17.66 2 2 2 153879 22.90 1.14 16.89 2 2 2 153879 23.16 1.14 17.12 2 2 2 153880 17.21 1.08 16.59 2 2 2 153880 17.49 1.08 16.50 2 2 2 153881 14.44 1.07 16.30 2 2 2 153881 14.54 1.08 15.95 2 2 2 153882 13.06 1.06 15.82 2 2 2 153882 13.06 1.07 15.85 2 2 2 153883 13.60 1.06 16.32 2 2 2 153883 13.63 1.08 16.36 2 2 2 153884 12.58 1.16 16.53 2 2 2 153884 12.74 1.07 16.45 2 2 2 153885 11.61 1.08 16.20 2 2 2 153885 11.75 1.08 16.43 2 2 2 153886 10.55 1.09 16.52 2 2 2 153886 10.51 1.09 16.19 2 2 2 153887 10.57 1.07 16.20 2 2 2 153887 10.63 1.08 16.39 2 2 2 153888 10.52 1.10 16.62 2 2 2 153888 10.63 1.09 16.76 2 2 2 153889 10.59 1.09 16.35 2 2 2 153889 10.61 1.09 16.48 2 2 2 153890 11.12 1.11 16.90 2 2 2 153890 10.84 1.11 17.09 2 2 2 153891 11.31 1.15 16.87 2 2 2 153891 11.32 1.14 17.08 2 2 2 153892 11.35 1.21 16.77 2 2 2 153892 11.62 1.15 17.27 2 2 2 153893 11.58 1.18 18.03 2 2 2 153893 11.65 1.17 17.82 2 2 2 153894 11.97 1.20 17.70 2 2 2 153894 11.98 1.19 17.85 2 2 2 153895 12.34 1.28 19.13 2 2 2 153895 12.48 1.28 18.73 2 2 2 153896 12.85 1.35 20.17 2 2 2 153896 12.98 1.32 19.84 2 2 2 153897 13.48 1.47 22.22 2 2 2 153897 13.92 1.47 22.19 2 2 2 153899 3.05 0.49 6.08 2 2 2 153899 3.12 0.43 6.27 2 2 2 153900 17.89 1.13 15.57 2 2 2 153900 17.92 1.10 15.76 2 2 2 153901 20.48 1.20 16.36 2 2 2 153901 20.71 1.15 16.03 2 2 2 153902 22.78 1.15 16.39 2 2 2 153902 22.84 1.16 16.73 2 2 2 153903 22.57 1.17 17.03 2 2 2 153903 22.36 1.19 16.88 2 2 2 153904 21.87 1.18 16.53 2 2 2 153904 22.24 1.17 16.79 2 2 2 153905 19.10 1.17 16.86 2 2 2 153905 19.51 1.16 16.75 2 2 2 153906 15.46 1.13 16.06 2 2 2 153906 15.62 1.11 15.67 2 2 2 153907 15.58 1.14 16.56 2 2 2 153907 15.48 1.14 16.03 2 2 2 153908 14.62 1.15 16.96 2 2 2 153908 14.58 1.14 16.36 2 2 2 153909 14.08 1.19 16.35 2 2 2 153909 14.11 1.13 16.67 2 2 2 153910 12.81 1.14 16.84 2 2 2 153910 12.84 1.15 16.79 2 2 2 153911 12.32 1.24 16.49 2 2 2 153911 12.52 1.12 16.81 2 2 2 153912 11.49 1.16 16.63 2 2 2 153912 11.57 1.14 16.88 2 2 2 153913 11.72 1.13 16.75 2 2 2 153913 11.59 1.16 16.55 2 2 2 153914 11.44 1.16 17.11 2 2 2 153914 11.82 1.14 16.96 2 2 2 153915 11.23 1.18 16.70 2 2 2 153915 11.13 1.18 16.95 2 2 2 153916 11.42 1.15 17.38 2 2 2 153916 11.32 1.19 17.14 2 2 2 153917 11.42 1.16 17.87 2 2 2 153917 11.60 1.27 17.82 2 2 2 153918 11.93 1.19 17.89 2 2 2 153918 11.99 1.18 18.15 2 2 2 153919 12.56 1.26 19.66 2 2 2 153919 12.63 1.26 19.40 2 2 2 153920 10.62 1.16 16.33 2 2 2 153920 10.65 1.14 15.93 2 2 2 153921 3.55 0.53 6.25 2 2 2 153921 3.55 0.57 6.34 2 2 2 153922 2.25 0.54 3.58 2 2 2 153922 2.25 0.53 3.75 2 2 2 153923 23.44 1.16 16.96 2 2 2 153923 23.65 1.20 16.62 2 2 2 153924 23.13 1.17 17.24 2 2 2 153924 23.36 1.18 17.33 2 2 2 153925 23.53 1.17 16.93 2 2 2 153925 23.03 1.25 16.80 2 2 2 153926 22.71 1.18 17.13 2 2 2 153926 22.74 1.19 17.09 2 2 2 153927 5 5 5 153927 22.02 1.19 16.99 2 2 2 153927 22.29 1.16 16.82 2 2 2 153928 20.07 1.18 16.57 2 2 2 153928 20.48 1.16 16.63 2 2 2 153929 16.71 1.16 16.17 2 2 2 153929 16.84 1.14 15.84 2 2 2 153930 16.53 1.15 16.65 2 2 2 153930 16.70 1.14 16.35 2 2 2 153931 14.79 1.14 16.67 2 2 2 153931 14.89 1.15 16.17 2 2 2 153932 12.00 1.13 15.94 2 2 2 153932 12.07 1.12 16.22 2 2 2 153933 11.27 1.13 16.77 2 2 2 153933 11.57 1.13 16.58 2 2 2 153934 11.60 1.12 17.38 2 2 2 153934 11.66 1.19 16.89 2 2 2 153935 11.56 1.14 17.66 2 2 2 153935 11.70 1.11 17.03 2 2 2 153936 11.89 1.16 17.98 2 2 2 153936 12.00 1.15 17.65 2 2 2 153937 8.85 0.93 13.99 2 2 2 153937 8.61 0.92 14.24 2 2 2 153938 11.89 1.23 18.40 2 2 2 153938 12.26 1.19 18.19 2 2 2 153939 12.22 1.23 19.18 2 2 2 153939 12.43 1.22 18.71 2 2 2 153940 12.16 1.23 18.42 2 2 2 153940 12.29 1.21 18.37 2 2 2 153941 12.59 1.29 19.12 2 2 2 153941 12.69 1.27 19.12 2 2 2 153942 12.65 1.43 20.73 2 2 2 153942 12.75 1.37 20.84 2 2 2 153943 8.49 1.07 16.88 2 2 2 153943 8.69 1.06 16.87 2 2 2 153944 2.58 0.42 5.70 2 3 2 153944 2.55 0.38 5.70 2 2 2 153945 2.38 0.34 5.08 2 2 2 153945 2.41 0.35 5.17 2 2 2 153946 18.60 1.18 15.89 2 2 2 153946 18.67 1.12 15.66 2 2 2 153947 20.33 1.13 16.45 2 2 2 153947 20.46 1.21 16.61 2 2 2 153948 25.05 1.21 17.59 2 2 2 153948 25.49 1.21 17.99 2 2 2 153949 22.46 1.16 17.02 3 3 3 153949 23.65 1.27 18.81 2 2 2 153950 21.27 1.14 17.24 2 2 2 153950 21.34 1.15 16.91 2 2 2 153951 18.01 1.14 16.58 2 2 2 153951 18.34 1.11 16.73 2 2 2 153952 17.32 1.13 17.06 2 2 2 153952 16.92 1.13 16.87 2 2 2 153953 15.66 1.13 17.23 2 2 2 153953 15.93 1.11 16.85 2 2 2 153954 13.75 1.12 16.85 2 2 2 153954 13.78 1.10 17.12 2 2 2 153955 11.65 1.12 17.22 2 2 2 153955 11.78 1.10 16.75 2 2 2 153956 11.68 1.10 16.89 2 2 2 153956 11.68 1.09 17.24 2 2 2 153957 12.29 1.14 17.27 2 2 2 153957 12.56 1.12 17.30 2 2 2 153958 11.94 1.15 17.53 2 2 2 153958 12.04 1.13 17.06 2 2 2 153959 11.91 1.16 18.01 4 4 4 153959 11.94 1.15 17.80 4 4 4 153960 6.69 0.71 10.99 4 4 4 153960 6.90 0.70 11.30 4 4 4 153961 8.42 0.88 13.71 2 2 2 153961 8.62 0.90 13.58 2 2 2 153962 12.23 1.30 18.89 2 2 2 153962 12.43 1.23 18.56 2 2 2 153963 12.50 1.31 20.00 2 2 2 153963 12.70 1.29 19.55 2 2 2 153964 10.13 1.20 18.80 2 2 2 153964 10.19 1.21 19.01 2 2 2 153965 5.32 0.78 12.41 2 2 2 153965 5.42 0.78 12.41 2 2 2 153966 2.42 0.39 5.92 2 2 2 153966 2.49 0.37 5.79 2 2 2 153967 1.57 0.24 3.46 2 2 2 153967 1.64 0.24 3.41 2 2 2 153968 0.56 0.16 2.06 2 2 2 153968 0.56 0.15 2.01 2 2 2 153969 30.11 1.29 18.33 2 2 2 153969 30.34 1.23 18.57 2 2 2 153970 28.54 1.20 18.45 2 2 2 153970 28.85 1.25 17.88 2 2 2 153971 26.30 1.22 17.55 2 2 2 153971 26.64 1.22 17.83 2 2 2 153972 24.27 1.22 17.45 2 2 2 153972 24.23 1.18 17.06 2 2 2 153973 21.89 1.25 17.23 2 2 2 153973 21.48 1.16 17.12 2 2 2 153974 18.84 1.15 16.63 2 2 2 153974 18.97 1.16 16.85 2 2 2 153975 5 5 5 153975 18.19 1.17 16.84 2 2 2 153975 18.33 1.15 17.37 2 2 2 153976 16.77 1.17 17.22 2 2 2 153976 16.70 1.17 17.10 2 2 2 153977 14.47 1.12 16.97 2 2 2 153977 14.67 1.13 16.99 2 2 2 153978 7.95 0.73 11.71 4 4 4 153978 8.05 0.76 11.91 4 4 4 153979 12.17 1.14 16.75 2 2 2 153979 12.17 1.16 16.95 2 2 2 153980 11.66 1.17 17.33 2 2 2 153980 11.76 1.16 17.15 2 2 2 153981 11.55 1.24 17.15 2 2 2 153981 11.58 1.18 17.27 2 2 2 153982 11.78 1.21 17.73 2 2 2 153982 11.99 1.21 17.87 2 2 2 153983 12.05 1.23 17.77 2 2 2 153983 12.18 1.23 18.13 2 2 2 153984 12.65 1.34 20.20 2 2 2 153984 12.45 1.32 20.28 2 2 2 153985 11.34 1.26 19.33 2 2 2 153985 11.43 1.31 19.55 2 2 2 153986 7.22 1.00 15.15 2 2 2 153986 7.49 0.99 15.42 2 2 2 153987 4.85 0.72 10.99 2 2 2 153987 4.86 0.70 10.91 2 2 2 153988 2.66 0.43 6.21 2 2 2 153988 2.66 0.40 6.32 2 2 2 153989 1.65 0.29 3.43 2 2 2 153989 1.61 0.26 3.47 2 2 2 153990 1.64 0.26 3.53 2 2 2 153990 1.64 0.27 3.61 2 2 2 153991 1.64 0.26 3.69 2 2 2 153991 1.64 0.25 3.63 2 2 2 153992 30.01 1.24 18.04 2 2 2 153992 30.38 1.31 18.28 2 2 2 153993 29.03 1.25 18.08 2 2 2 153993 29.06 1.26 18.16 2 2 2 153994 26.89 1.23 17.39 2 2 2 153994 27.40 1.23 17.65 2 2 2 153995 24.70 1.21 17.45 2 2 2 153995 24.36 1.21 17.27 2 2 2 153996 22.06 1.19 16.90 2 2 2 153996 21.82 1.20 16.86 2 2 2 153997 18.24 1.17 16.64 2 2 2 153997 18.24 1.22 16.45 2 2 2 153998 17.26 1.16 16.46 2 2 2 153998 17.46 1.19 16.63 2 2 2 153999 15.70 1.17 16.65 2 2 2 153999 15.90 1.19 16.79 2 2 2 154000 14.59 1.17 16.55 2 2 2 154000 14.65 1.17 16.80 2 2 2 154001 13.41 1.17 16.95 2 2 2 154001 13.37 1.19 16.79 2 2 2 154002 11.42 1.14 16.12 2 2 2 154002 11.65 1.15 16.34 2 2 2 154003 11.78 1.16 16.61 2 2 2 154003 11.82 1.15 16.25 2 2 2 154004 11.71 1.18 16.55 2 2 2 154004 11.81 1.18 16.88 2 2 2 154005 11.74 1.23 16.90 2 2 2 154005 11.80 1.18 17.08 2 2 2 154005 5 5 5 154006 5 5 5 154006 11.84 1.19 16.86 2 2 2 154006 11.84 1.20 17.23 2 2 2 154007 5 5 5 154007 11.90 1.25 17.51 2 2 2 154007 11.93 1.25 17.80 2 2 2 154008 12.54 1.30 18.78 2 2 2 154008 12.67 1.28 19.03 2 2 2 154009 12.60 1.34 20.14 2 2 2 154009 12.67 1.35 19.98 2 2 2 154010 9.40 1.18 17.04 2 2 2 154010 9.57 1.17 17.26 2 2 2 154011 4.38 0.70 10.20 2 2 2 154011 4.38 0.67 10.24 2 2 2 154012 1.96 0.33 4.51 2 2 2 154012 2.06 0.31 4.55 2 2 2 154013 1.35 0.26 3.21 2 2 2 154013 1.35 0.29 3.13 2 2 2 154014 1.11 0.23 2.73 2 2 2 154014 1.11 0.22 2.75 2 2 2 154015 29.82 1.35 17.66 2 2 2 154015 30.66 1.31 17.91 2 2 2 154016 29.14 1.22 18.02 2 2 2 154016 29.41 1.22 18.08 2 2 2 154017 24.62 1.20 16.83 2 2 2 154017 24.72 1.18 17.16 2 2 2 154018 24.95 1.23 16.65 2 2 2 154018 24.99 1.22 16.81 2 2 2 154019 24.62 1.24 16.71 2 2 2 154019 24.45 1.24 16.78 2 2 2 154020 23.00 1.23 16.80 2 2 2 154020 23.03 1.24 16.78 2 2 2 154021 20.23 1.25 17.10 2 2 2 154021 20.33 1.18 17.20 2 2 2 154022 16.69 1.14 16.63 2 2 2 154022 16.96 1.15 16.77 2 2 2 154023 15.71 1.17 16.81 2 2 2 154023 15.75 1.17 16.75 2 2 2 154024 13.73 1.16 16.71 2 2 2 154024 13.73 1.16 16.67 2 2 2 154025 12.85 1.17 16.82 2 2 2 154025 12.82 1.17 16.78 2 2 2 154026 11.60 1.16 16.84 2 2 2 154026 11.54 1.16 16.80 2 2 2 154027 11.77 1.19 17.15 2 2 2 154027 11.80 1.19 17.21 2 2 2 154028 11.73 1.20 17.21 2 2 2 154028 11.73 1.19 17.27 2 2 2 154029 11.69 1.39 17.54 2 2 2 154029 11.72 1.15 17.58 2 2 2 154030 12.23 1.24 18.58 2 2 2 154030 12.40 1.22 18.89 2 2 2 154031 12.70 1.30 20.16 2 2 2 154031 12.60 1.29 20.20 2 2 2 154032 11.67 1.27 20.29 2 2 2 154032 11.73 1.28 20.14 2 2 2 154033 9.81 1.13 18.52 2 2 2 154033 9.80 1.16 18.43 2 2 2 154034 4.68 0.68 10.66 2 2 2 154034 4.72 0.58 10.77 2 2 2 154035 1.85 0.29 4.60 2 2 2 154035 1.86 0.22 4.67 2 2 2 154036 0.90 0.16 2.65 2 2 2 154036 0.90 0.17 2.72 2 2 2 154037 0.78 0.18 2.42 2 2 2 154037 0.82 0.14 2.40 2 2 2 154038 32.18 1.39 18.30 2 2 2 154038 32.46 1.22 18.37 2 2 2 154039 5 5 5 154039 30.52 1.21 18.08 2 2 2 154039 30.63 1.20 17.97 2 2 2 154040 26.85 1.15 17.40 2 2 2 154040 26.85 1.17 17.33 2 2 2 154041 24.65 1.13 17.05 2 2 2 154041 24.58 1.13 17.16 2 2 2 154042 24.08 1.14 17.12 2 2 2 154042 24.12 1.13 17.03 2 2 2 154043 20.09 1.13 16.66 2 2 2 154043 20.17 1.11 16.74 2 2 2 154044 17.98 1.12 16.84 2 2 2 154044 18.09 1.12 16.81 2 2 2 154045 16.00 1.27 16.38 2 2 2 154045 16.13 1.08 16.36 2 2 2 154046 14.75 1.08 16.23 2 2 2 154046 14.68 1.07 16.03 2 2 2 154047 13.92 1.13 16.74 2 2 2 154047 13.92 1.08 16.72 2 2 2 154048 12.65 1.11 16.56 2 2 2 154048 12.64 1.04 16.48 2 2 2 154049 12.26 1.04 16.41 2 2 2 154049 12.57 1.04 16.39 2 2 2 154050 12.25 1.06 16.39 2 2 2 154050 12.29 1.06 16.55 2 2 2 154051 11.98 1.06 16.44 2 2 2 154051 12.01 1.06 16.33 2 2 2 154052 11.93 1.10 16.60 2 2 2 154052 12.00 1.10 16.73 2 2 2 154053 11.77 1.30 17.14 2 2 2 154053 11.80 1.13 16.85 2 2 2 154054 11.97 1.13 17.14 2 2 2 154054 12.00 1.14 17.09 2 2 2 154055 12.57 1.24 18.94 2 2 2 154055 12.47 1.25 18.78 2 2 2 154056 12.12 1.24 19.29 2 2 2 154056 12.09 1.26 19.14 2 2 2 154057 7.25 0.91 14.43 2 2 2 154057 7.32 0.85 14.65 2 2 2 154058 6.09 0.79 12.30 2 2 2 154058 6.09 0.75 12.43 2 2 2 154059 1.68 0.22 3.11 3 3 3 154059 1.72 0.11 3.17 3 3 3 154060 3 3 3 154060 0.94 0.11 1.42 3 3 3 154060 0.94 0.10 1.46 3 3 3 154061 26.05 1.34 16.37 2 2 2 154061 26.15 1.14 16.48 2 2 2 154062 26.07 1.16 16.64 2 2 2 154062 26.11 1.14 16.59 2 2 2 154063 25.16 1.14 16.66 2 2 2 154063 24.99 1.14 16.59 2 2 2 154064 22.80 1.12 16.53 2 2 2 154064 22.91 1.13 16.46 2 2 2 154065 21.83 1.11 16.71 2 2 2 154065 22.04 1.09 16.53 2 2 2 154066 20.17 1.09 16.45 2 2 2 154066 20.24 1.09 16.54 2 2 2 154067 17.87 1.08 16.54 2 2 2 154067 17.90 1.08 16.52 2 2 2 154068 15.91 1.08 16.61 2 2 2 154068 15.94 1.07 16.56 2 2 2 154069 13.19 1.22 15.86 2 2 2 154069 13.32 1.14 16.13 2 2 2 154070 11.82 1.02 16.22 2 2 2 154070 11.82 0.99 16.04 2 2 2 154071 12.49 1.05 16.60 2 2 2 154071 12.60 1.08 16.62 2 2 2 154072 12.45 1.06 16.60 2 2 2 154072 12.48 1.10 16.49 2 2 2 154073 12.04 1.08 16.45 2 2 2 154073 12.10 1.08 16.40 2 2 2 154074 11.89 1.12 16.76 2 2 2 154074 11.92 1.10 16.83 2 2 2 154075 12.12 1.12 17.50 2 2 2 154075 12.06 1.12 17.34 2 2 2 154076 12.42 1.15 18.03 2 2 2 154076 12.45 1.16 18.23 2 2 2 154077 12.77 1.41 18.42 2 2 2 154077 12.80 1.21 18.69 2 2 2 154078 13.20 1.30 19.94 2 2 2 154078 13.24 1.29 19.87 2 2 2 154079 11.67 1.24 19.65 2 2 2 154079 11.70 1.26 19.63 2 2 2 154080 4.73 0.50 9.62 2 2 2 154080 4.69 0.62 9.44 2 2 2 154081 4.09 0.53 8.57 2 2 2 154081 4.15 0.58 8.55 2 2 2 154082 2.19 0.25 4.24 2 2 2 154082 2.20 0.18 4.26 2 2 2 154083 1.72 0.15 1.81 2 2 2 154083 1.72 0.15 1.85 2 2 2 154084 25.80 1.31 16.46 2 2 2 154084 26.04 1.13 16.73 2 2 2 154085 26.49 1.31 16.73 2 2 2 154085 26.62 1.15 16.94 2 2 2 154086 25.17 1.14 17.18 2 2 2 154086 25.48 1.13 17.00 2 2 2 154087 23.42 1.12 16.96 2 2 2 154087 23.65 1.12 16.61 2 2 2 154088 22.62 1.09 16.32 2 2 2 154088 22.65 1.10 16.41 2 2 2 154089 21.51 1.11 16.66 2 2 2 154089 21.82 1.10 16.55 2 2 2 154090 20.54 1.11 16.57 2 2 2 154090 20.45 1.11 16.73 2 2 2 154091 18.94 1.11 16.15 2 2 2 154091 19.03 1.11 16.29 2 2 2 154092 17.25 1.09 16.51 2 2 2 154092 17.29 1.10 16.40 2 2 2 154093 15.39 1.10 16.63 2 2 2 154093 15.50 1.25 16.36 2 2 2 154094 13.56 1.06 16.61 2 2 2 154094 13.62 1.12 16.65 2 2 2 154095 12.06 1.06 16.08 2 2 2 154095 12.06 1.05 15.70 2 2 2 154096 12.43 1.07 16.06 2 2 2 154096 12.56 1.08 16.22 2 2 2 154097 11.64 1.07 16.35 2 2 2 154097 11.71 1.08 16.57 2 2 2 154098 11.50 1.10 16.51 2 2 2 154098 11.56 1.10 16.24 2 2 2 154099 11.79 1.11 16.91 2 2 2 154099 11.80 1.13 16.80 2 2 2 154100 7.07 0.78 11.16 2 2 2 154100 7.17 0.66 11.12 2 2 2 154101 12.27 1.34 17.92 2 2 2 154101 12.03 1.16 18.21 2 2 2 154102 12.80 1.32 19.04 2 2 2 154102 12.70 1.25 19.31 2 2 2 154103 12.46 1.23 19.76 2 2 2 154103 12.52 1.27 19.96 2 2 2 154104 5.05 0.71 10.69 2 2 2 154104 5.12 0.61 10.64 2 2 2 154105 2.17 0.34 4.74 2 2 2 154105 2.17 0.24 4.86 2 2 2 154106 0.33 0.11 1.43 2 2 2 154106 0.33 0.10 1.45 2 2 2 154107 23.04 1.24 16.27 2 2 2 154107 22.77 1.18 16.56 2 2 2 154108 22.72 1.19 16.34 2 2 2 154108 22.73 1.08 16.61 2 2 2 154109 23.17 1.07 16.64 2 2 2 154109 22.94 1.37 16.73 2 2 2 154110 22.04 1.11 16.35 2 2 2 154110 22.14 1.18 16.24 2 2 2 154111 20.67 1.10 16.27 2 2 2 154111 20.74 1.03 16.18 2 2 2 154112 19.41 1.09 16.49 2 2 2 154112 19.47 1.12 16.47 2 2 2 154113 17.74 1.11 16.18 2 2 2 154113 17.87 1.11 16.05 2 2 2 154114 15.66 1.08 16.27 2 2 2 154114 15.73 1.08 16.10 2 2 2 154115 13.23 1.10 16.32 2 2 2 154115 13.26 1.15 16.25 2 2 2 154116 11.88 1.01 15.88 2 2 2 154116 11.87 1.03 15.57 2 2 2 154116 5 5 5 154117 11.55 1.07 15.53 2 2 2 154117 11.45 1.25 15.71 2 2 2 154118 11.58 1.09 15.96 2 2 2 154118 11.71 1.07 16.38 2 2 2 154119 11.43 1.07 16.83 2 2 2 154119 11.46 1.16 16.92 2 2 2 154120 11.56 1.08 16.34 2 2 2 154120 11.49 1.02 16.76 2 2 2 154121 11.65 1.12 16.59 2 2 2 154121 11.72 1.10 16.74 2 2 2 154122 11.74 1.22 17.41 2 2 2 154122 11.78 1.14 17.37 2 2 2 154123 12.24 1.24 18.26 2 2 2 154123 12.34 1.17 17.95 2 2 2 154124 12.94 1.28 18.87 2 2 2 154124 12.94 1.27 18.94 2 2 2 154125 10.94 1.36 18.30 2 2 2 154125 11.07 1.21 18.57 2 2 2 154126 8.82 0.99 16.53 2 2 2 154126 8.92 1.08 16.47 2 2 2 154127 5.54 0.72 11.41 2 2 2 154127 5.57 0.71 11.17 2 2 2 154128 2.40 0.33 4.91 2 2 2 154128 2.40 0.27 4.91 2 2 2 154129 1.93 0.21 2.58 2 2 2 154129 1.97 0.22 2.56 2 2 2 154130 26.36 1.31 17.11 2 2 2 154130 26.59 1.15 17.00 2 2 2 154131 26.24 1.20 16.62 2 2 2 154131 26.44 1.11 16.64 2 2 2 154132 24.74 1.11 16.49 2 2 2 154132 24.77 1.15 16.53 2 2 2 154133 22.74 1.11 16.56 2 2 2 154133 23.25 1.28 16.54 2 2 2 154134 21.65 1.10 16.45 2 2 2 154134 21.75 1.12 16.30 2 2 2 154135 19.96 1.17 15.68 2 2 2 154135 20.05 1.08 15.64 2 2 2 154136 17.45 1.17 15.86 2 2 2 154136 17.15 1.10 16.17 2 2 2 154137 16.40 1.10 16.51 2 2 2 154137 16.50 1.08 16.51 2 2 2 154138 14.21 1.08 15.66 2 2 2 154138 14.21 1.15 16.00 2 2 2 154139 12.63 1.08 15.53 2 2 2 154139 12.76 1.08 15.62 2 2 2 154140 12.42 1.15 15.87 2 2 2 154140 12.48 1.05 15.87 2 2 2 154141 11.89 1.08 16.23 2 2 2 154141 11.83 1.27 16.21 2 2 2 154142 11.42 1.11 15.81 2 2 2 154142 11.48 1.09 15.84 2 2 2 154143 11.38 1.11 16.64 2 2 2 154143 11.41 1.11 16.31 2 2 2 154144 11.44 1.10 17.25 2 2 2 154144 11.44 1.13 17.22 2 2 2 154145 11.67 1.15 17.07 2 2 2 154145 11.73 1.15 16.62 2 2 2 154146 12.02 1.19 17.30 2 2 2 154146 12.06 1.20 17.18 2 2 2 154147 12.45 1.30 18.87 2 2 2 154147 12.48 1.28 18.98 2 2 2 154148 11.71 1.27 19.23 2 2 2 154148 11.74 1.28 19.21 2 2 2 154149 6.82 0.95 14.94 2 2 2 154149 6.88 0.89 14.88 2 2 2 154150 2.68 0.41 6.68 2 2 2 154150 2.71 0.48 6.66 2 2 2 154151 1.86 0.28 4.46 2 2 2 154151 1.83 0.29 4.46 2 2 2 154153 29.27 1.24 18.66 2 2 2 154153 29.54 1.22 18.96 2 2 2 154154 25.52 1.17 18.12 2 2 2 154154 25.56 1.17 18.38 2 2 2 154155 22.84 1.13 17.52 2 2 2 154155 23.01 1.15 17.67 2 2 2 154156 21.82 1.13 17.73 2 2 2 154156 21.89 1.17 17.92 2 2 2 154157 21.17 1.17 17.70 2 2 2 154157 20.86 1.13 17.69 2 2 2 154158 18.99 1.11 17.58 2 2 2 154158 19.20 1.11 17.81 2 2 2 154159 16.92 1.10 17.49 2 2 2 154159 17.16 1.11 17.83 2 2 2 154160 13.70 1.07 17.25 2 2 2 154160 13.83 1.09 17.56 2 2 2 154161 13.12 1.09 17.73 2 2 2 154161 13.22 1.09 17.75 2 2 2 154162 11.90 1.06 17.21 2 2 2 154162 12.04 1.05 17.29 2 2 2 154163 11.29 1.09 17.64 2 2 2 154163 11.22 1.05 17.65 2 2 2 154164 11.73 1.12 17.64 2 2 2 154164 11.59 1.05 17.57 2 2 2 154165 11.25 1.07 17.71 2 2 2 154165 11.42 1.05 18.15 2 2 2 154166 11.62 1.07 18.52 2 2 2 154166 11.73 1.07 18.22 2 2 2 154167 11.52 1.10 18.37 2 2 2 154167 11.52 1.09 18.15 2 2 2 154168 11.86 1.13 18.87 2 2 2 154168 11.89 1.14 19.05 2 2 2 154169 12.50 1.20 20.15 2 2 2 154169 12.40 1.22 19.78 2 2 2 154170 12.84 1.29 20.72 2 2 2 154170 12.91 1.28 21.03 2 2 2 154171 12.36 1.23 21.40 2 2 2 154171 12.23 1.25 21.17 2 2 2 154172 6.11 0.75 13.50 2 2 2 154172 6.14 0.77 13.12 2 2 2 154173 4.96 0.71 11.88 2 2 2 154173 5.09 0.76 11.70 2 2 2 154174 2.03 0.28 4.79 2 2 2 154174 2.09 0.27 4.77 2 2 2 154175 1.52 0.17 2.59 2 2 2 154175 1.52 0.17 2.57 2 2 2 154176 29.27 1.21 19.18 2 2 2 154176 29.68 1.23 18.89 2 2 2 154177 25.67 1.16 18.75 2 2 2 154177 25.70 1.15 18.87 2 2 2 154178 25.19 1.18 18.26 2 2 2 154178 25.06 1.16 18.46 2 2 2 154179 23.12 1.19 18.13 2 2 2 154179 22.51 1.20 18.18 2 2 2 154180 21.15 1.16 18.19 2 2 2 154180 21.22 1.13 18.35 2 2 2 154181 18.88 1.16 17.93 2 2 2 154181 18.95 1.10 17.98 2 2 2 154182 17.35 1.12 17.61 2 2 2 154182 17.39 1.09 17.70 2 2 2 154183 14.85 1.14 17.68 2 2 2 154183 14.88 1.12 17.82 2 2 2 154184 13.63 1.09 17.92 2 2 2 154184 13.60 1.11 18.03 2 2 2 154185 12.35 1.09 17.43 2 2 2 154185 12.35 1.11 17.69 2 2 2 154186 11.64 1.12 17.89 2 2 2 154186 11.74 1.11 18.00 2 2 2 154187 11.50 1.17 18.39 2 2 2 154187 11.57 1.13 18.06 2 2 2 154188 11.91 1.14 18.37 2 2 2 154188 11.87 1.15 18.20 2 2 2 154189 11.73 1.17 18.59 2 2 2 154189 12.01 1.17 18.25 2 2 2 154190 11.87 1.18 19.14 2 2 2 154190 11.97 1.18 19.29 2 2 2 154191 12.58 1.24 20.47 2 2 2 154191 12.71 1.23 20.14 2 2 2 154192 12.74 1.30 20.95 2 2 2 154192 12.88 1.28 20.63 2 2 2 154193 11.39 1.30 21.60 2 2 2 154193 11.46 1.29 21.49 2 2 2 154194 5.20 0.71 12.00 2 2 2 154194 5.17 0.69 12.27 2 2 2 154195 3.76 0.52 8.97 2 2 2 154195 3.73 0.55 9.06 2 2 2 154196 2.25 0.32 5.60 2 2 2 154196 2.25 0.33 5.59 2 2 2 154197 1.75 0.28 4.51 2 2 2 154197 1.82 0.30 4.46 2 2 2 154198 0.68 0.18 2.68 2 2 2 154198 0.68 0.18 2.63 2 2 2 154199 26.80 1.20 18.68 2 2 2 154199 27.14 1.21 18.37 2 2 2 154200 28.02 1.24 19.25 2 2 2 154200 27.65 1.25 19.12 2 2 2 154201 26.22 1.20 18.80 2 2 2 154201 26.42 1.19 18.58 2 2 2 154202 22.12 1.15 17.72 2 2 2 154202 21.64 1.17 17.95 2 2 2 154203 21.13 1.17 18.32 2 2 2 154203 21.17 1.17 18.23 2 2 2 154204 18.26 1.17 17.87 2 2 2 154204 18.26 1.17 18.14 2 2 2 154205 16.60 1.19 17.79 2 2 2 154205 16.84 1.13 17.63 2 2 2 154206 14.68 1.15 17.72 2 2 2 154206 14.92 1.13 17.47 2 2 2 154207 12.79 1.13 17.76 2 2 2 154207 12.86 1.12 17.66 2 2 2 154208 13.63 1.13 18.03 2 2 2 154208 13.67 1.15 17.83 2 2 2 154209 13.36 1.16 17.77 2 2 2 154209 13.13 1.17 17.99 2 2 2 154210 12.25 1.18 18.12 2 2 2 154210 12.19 1.19 18.01 2 2 2 154211 11.58 1.16 17.91 2 2 2 154211 11.65 1.18 17.59 2 2 2 154212 11.54 1.15 18.10 2 2 2 154212 11.68 1.16 17.88 2 2 2 154213 11.68 1.19 18.46 2 2 2 154213 11.81 1.20 18.09 2 2 2 154214 11.84 1.22 19.07 2 2 2 154214 11.84 1.23 18.94 2 2 2 154215 12.35 1.24 19.09 2 2 2 154215 12.28 1.27 19.48 2 2 2 154216 12.48 1.33 20.66 2 2 2 154216 12.65 1.33 20.40 2 2 2 154217 11.30 1.30 20.72 2 2 2 154217 11.24 1.31 20.72 2 2 2 154218 5.55 0.81 12.55 2 2 2 154218 5.58 0.83 12.37 2 2 2 154219 2.05 0.34 4.60 2 2 2 154219 2.08 0.31 4.63 2 2 2 154220 0.88 0.20 2.61 2 2 2 154220 0.92 0.19 2.62 2 2 2 154222 18.39 1.15 16.77 2 2 2 154222 18.49 1.12 16.55 2 2 2 154223 22.34 1.16 17.33 2 2 2 154223 22.44 1.17 17.27 2 2 2 154224 22.10 1.18 17.64 2 2 2 154224 22.34 1.19 17.84 2 2 2 154225 20.48 1.17 17.63 2 2 2 154225 20.54 1.18 17.20 2 2 2 154226 5.18 0.65 9.72 4 4 4 154226 5.22 0.64 9.70 4 4 4 154227 17.34 1.17 17.27 2 2 2 154227 17.37 1.16 17.49 2 2 2 154228 15.12 1.14 17.13 2 2 2 154228 15.19 1.15 16.82 2 2 2 154229 14.65 1.16 17.16 2 2 2 154229 14.75 1.16 17.34 2 2 2 154230 12.97 1.14 17.28 2 2 2 154230 13.24 1.17 16.98 2 2 2 154231 11.43 1.14 17.28 2 2 2 154231 11.43 1.15 17.09 2 2 2 154232 12.23 1.14 17.02 2 2 2 154232 12.26 1.23 16.92 2 2 2 154233 11.16 1.15 17.41 2 2 2 154233 10.92 1.16 17.57 2 2 2 154234 11.29 1.18 17.91 2 2 2 154234 11.42 1.19 17.74 2 2 2 154235 10.99 1.20 17.39 2 2 2 154235 11.15 1.21 17.57 2 2 2 154236 11.15 1.21 18.22 2 2 2 154236 11.39 1.22 18.12 2 2 2 154237 11.75 1.24 19.06 2 2 2 154237 11.79 1.26 18.83 2 2 2 154238 12.25 1.32 19.93 2 2 2 154238 12.29 1.35 19.80 2 2 2 154239 12.09 1.40 20.37 2 2 2 154239 12.29 1.40 20.57 2 2 2 154240 11.38 1.35 20.34 2 2 2 154240 11.15 1.34 20.46 2 2 2 154241 5.55 0.82 13.15 2 2 2 154241 5.52 0.84 12.90 2 2 2 154242 2.90 0.49 6.92 2 2 2 154242 2.93 0.49 6.95 2 2 2 154243 1.11 0.28 3.19 2 2 2 154243 1.11 0.28 3.19 2 2 2 154244 1.05 0.21 2.42 2 2 2 154244 1.05 0.21 2.40 2 2 2 154245 24.76 1.18 17.99 2 2 2 154245 25.13 1.22 17.55 2 2 2 154246 25.90 1.18 18.34 2 2 2 154246 25.57 1.17 18.42 2 2 2 154247 24.14 1.17 17.53 2 2 2 154247 24.18 1.17 17.67 2 2 2 154248 23.24 1.20 17.83 2 2 2 154248 23.33 1.16 17.67 2 2 2 154249 22.73 1.18 18.01 2 2 2 154249 22.79 1.20 17.77 2 2 2 154250 21.31 1.16 17.68 2 2 2 154250 21.18 1.16 17.78 2 2 2 154251 19.57 1.15 17.44 2 2 2 154251 19.67 1.15 17.32 2 2 2 154252 18.59 1.15 17.78 2 2 2 154252 18.69 1.15 17.60 2 2 2 154253 16.44 1.16 17.49 2 2 2 154253 16.57 1.11 17.23 2 2 2 154254 14.53 1.10 17.35 2 2 2 154254 14.57 1.11 17.44 2 2 2 154255 16.00 1.12 17.13 2 2 2 154255 16.13 1.12 17.12 2 2 2 154256 14.53 1.12 17.40 2 2 2 154256 14.29 1.14 17.58 2 2 2 154257 13.42 1.11 17.67 2 2 2 154257 13.32 1.11 17.74 2 2 2 154258 12.02 1.10 17.30 2 2 2 154258 12.09 1.11 17.10 2 2 2 154259 11.05 1.10 17.54 2 2 2 154259 11.19 1.11 17.36 2 2 2 154260 11.25 1.11 17.81 2 2 2 154260 11.35 1.12 17.78 2 2 2 154261 11.64 1.13 18.08 2 2 2 154261 11.73 1.11 17.67 2 2 2 154262 11.70 1.14 18.17 2 2 2 154262 11.60 1.21 18.31 2 2 2 154263 12.00 1.17 19.27 2 2 2 154263 12.16 1.19 19.43 2 2 2 154264 12.99 1.29 20.71 2 2 2 154264 12.99 1.30 20.72 2 2 2 154265 11.26 1.30 19.13 2 2 2 154265 11.46 1.29 19.06 2 2 2 154266 2.92 0.43 6.45 2 2 2 154266 3.03 0.39 6.66 2 2 2 154267 1.30 0.20 3.12 2 2 2 154267 1.37 0.19 3.09 2 2 2 154268 20.88 1.11 17.25 2 2 2 154268 20.98 1.10 17.47 2 2 2 154269 25.99 1.16 18.33 2 2 2 154269 26.02 1.20 18.30 2 2 2 154270 25.25 1.16 17.98 2 2 2 154270 25.41 1.16 17.90 2 2 2 154271 21.73 1.14 17.77 2 2 2 154271 21.73 1.13 17.49 2 2 2 154272 20.75 1.13 17.68 2 2 2 154272 20.92 1.11 17.54 2 2 2 154273 18.81 1.11 17.30 2 2 2 154273 19.25 1.11 17.29 2 2 2 154274 16.21 1.11 17.26 2 2 2 154274 16.27 1.10 17.50 2 2 2 154275 15.17 1.10 17.49 2 2 2 154275 15.20 1.08 17.10 2 2 2 154276 14.70 1.09 17.46 2 2 2 154276 14.37 1.10 17.66 2 2 2 154277 13.23 1.12 17.43 2 2 2 154277 13.32 1.12 17.86 2 2 2 154278 15.19 1.10 17.60 2 2 2 154278 15.68 1.10 17.44 2 2 2 154279 11.39 1.08 17.30 2 2 2 154279 11.76 1.09 17.20 2 2 2 154280 11.39 1.10 17.77 2 2 2 154280 11.42 1.11 17.76 2 2 2 154281 11.51 1.10 17.78 2 2 2 154281 11.35 1.12 17.90 2 2 2 154282 11.31 1.11 17.89 2 2 2 154282 11.65 1.12 17.79 2 2 2 154283 11.41 1.16 18.63 2 2 2 154283 11.54 1.14 18.66 2 2 2 154284 11.67 1.16 19.03 2 2 2 154284 11.77 1.17 18.90 2 2 2 154285 12.42 1.24 19.58 2 2 2 154285 12.49 1.22 19.56 2 2 2 154286 13.32 1.34 21.19 2 2 2 154286 13.38 1.35 21.47 2 2 2 154287 8.93 1.08 18.25 2 2 2 154287 8.89 1.10 18.25 2 2 2 154288 2.24 0.28 5.19 2 2 2 154288 2.20 0.29 5.04 2 2 2 154289 1.97 0.25 4.32 2 2 2 154289 2.00 0.25 4.30 2 2 2 154290 1.93 0.21 3.57 2 2 2 154290 1.93 0.21 3.57 2 2 2 154291 13.93 1.00 15.79 2 2 2 154291 13.96 1.00 16.07 2 2 2 154292 26.02 1.18 18.29 2 2 2 154292 26.05 1.18 17.96 2 2 2 154293 23.94 1.15 17.78 2 2 2 154293 23.73 1.13 17.66 2 2 2 154294 5 5 5 154294 22.63 1.16 17.83 2 2 2 154294 22.76 1.15 17.96 2 2 2 154296 20.56 1.14 17.48 2 2 2 154296 20.86 1.11 17.34 2 2 2 154297 19.96 1.12 17.62 2 2 2 154297 19.55 1.14 17.75 2 2 2 154298 14.20 1.07 16.94 2 2 2 154298 14.23 1.07 16.67 2 2 2 154299 14.06 1.07 16.95 2 2 2 154299 14.20 1.07 16.64 2 2 2 154300 13.23 1.07 17.25 2 2 2 154300 13.23 1.08 17.19 2 2 2 154301 14.65 1.10 16.97 2 2 2 154301 14.69 1.09 17.49 2 2 2 154302 11.42 1.10 16.68 2 2 2 154302 11.45 1.09 16.77 2 2 2 154303 10.49 1.06 16.79 2 2 2 154303 10.56 1.07 17.02 2 2 2 154304 10.29 1.06 16.54 2 2 2 154304 10.32 1.07 16.85 2 2 2 154305 9.99 1.07 16.86 2 2 2 154305 10.02 1.07 16.98 2 2 2 154306 9.98 1.06 17.05 2 2 2 154306 10.05 1.08 17.15 2 2 2 154307 10.01 1.07 16.86 2 2 2 154307 10.01 1.06 16.66 2 2 2 154308 9.74 1.06 16.95 2 2 2 154308 9.78 1.06 17.22 2 2 2 154309 9.74 1.06 17.16 2 2 2 154309 9.77 1.07 17.20 2 2 2 154310 9.40 1.07 16.61 2 2 2 154310 9.43 1.07 16.80 2 2 2 154311 10.29 1.08 16.22 2 2 2 154311 10.19 1.07 16.30 2 2 2 154312 11.45 1.21 17.68 2 2 2 154312 11.48 1.22 17.72 2 2 2 154313 3.27 0.50 4.34 2 2 2 154313 3.40 0.49 4.44 2 2 2 154314 14.29 1.05 15.83 2 2 2 154314 14.35 1.03 16.08 2 2 2 154315 14.88 1.04 16.25 2 2 2 154315 15.05 1.04 16.17 2 2 2 154316 17.40 1.08 16.26 2 2 2 154316 17.57 1.08 16.61 2 2 2 154317 17.49 1.09 16.73 2 2 2 154317 17.56 1.10 16.59 2 2 2 154318 18.01 1.16 16.97 2 2 2 154318 18.01 1.13 17.24 2 2 2 154319 16.25 1.12 16.68 2 2 2 154319 16.32 1.13 16.84 2 2 2 154320 12.70 1.07 16.47 2 2 2 154320 12.74 1.09 16.39 2 2 2 154321 12.03 1.08 16.68 2 2 2 154321 12.04 1.07 16.65 2 2 2 154322 11.60 1.08 16.90 2 2 2 154322 11.70 1.09 16.51 2 2 2 154323 10.97 1.09 16.53 2 2 2 154323 10.87 1.09 16.40 2 2 2 154324 11.26 1.09 16.57 2 2 2 154324 11.30 1.09 16.61 2 2 2 154325 9.97 1.10 17.00 2 2 2 154325 10.00 1.10 16.78 2 2 2 154326 10.12 1.12 16.79 2 2 2 154326 10.29 1.11 16.48 2 2 2 154327 9.99 1.11 16.96 2 2 2 154327 10.09 1.11 17.13 2 2 2 154328 10.08 1.09 17.23 2 2 2 154328 10.01 1.10 17.21 2 2 2 154329 9.78 1.10 17.07 2 2 2 154329 9.85 1.10 16.78 2 2 2 154330 9.51 1.09 16.10 2 2 2 154330 9.61 1.09 16.34 2 2 2 154331 9.18 1.05 16.08 2 2 2 154331 9.21 1.08 16.10 2 2 2 154332 8.71 1.02 15.32 2 2 2 154332 8.75 1.02 15.26 2 2 2 154333 8.01 0.98 13.66 2 2 2 154333 8.02 0.97 13.62 2 2 2 154334 6.55 0.86 10.48 2 2 2 154334 6.55 0.86 10.60 2 2 2 154335 6.28 0.82 10.16 2 2 2 154335 6.35 0.83 10.12 2 2 2 154336 3.04 0.60 7.46 2 2 2 154336 3.17 0.60 7.39 2 2 2 154337 12.66 1.08 16.28 2 2 2 154337 12.79 1.08 16.01 2 2 2 154338 12.92 1.11 16.01 2 2 2 154338 12.85 1.10 15.97 2 2 2 154339 12.35 1.08 16.29 2 2 2 154339 12.35 1.08 16.18 2 2 2 154340 12.51 1.09 16.64 2 2 2 154340 12.58 1.09 16.60 2 2 2 154341 7.88 0.93 12.83 4 4 4 154341 7.98 0.94 12.99 4 4 4 154342 10.48 1.09 16.58 2 2 2 154342 10.48 1.10 16.77 2 2 2 154343 11.21 1.13 16.58 2 2 2 154343 11.04 1.14 16.78 2 2 2 154344 10.87 1.12 16.98 2 2 2 154344 11.00 1.12 17.20 2 2 2 154345 10.07 1.13 16.93 2 2 2 154345 10.08 1.11 17.08 2 2 2 154346 9.97 1.14 16.65 2 2 2 154346 10.24 1.13 16.57 2 2 2 154347 9.97 1.11 16.79 2 2 2 154347 10.13 1.10 16.97 2 2 2 154348 10.82 1.15 17.63 2 2 2 154348 10.82 1.16 17.84 2 2 2 154349 9.43 1.09 15.83 2 2 2 154349 9.40 1.09 16.01 2 2 2 154350 7.07 0.91 12.30 2 2 2 154350 7.04 0.92 11.99 2 2 2 154351 5.74 0.72 9.46 2 2 2 154351 5.81 0.74 9.25 2 2 2 154352 11.28 1.15 17.75 2 2 2 154352 11.41 1.13 17.23 2 2 2 154353 9.88 1.13 17.38 2 2 2 154353 9.95 1.16 17.09 2 2 2 154354 10.17 1.14 17.63 2 2 2 154354 10.21 1.14 17.26 2 2 2 154355 8.28 1.01 14.03 2 2 2 154355 8.07 1.00 14.28 2 2 2 154356 2.42 0.62 7.11 2 2 2 154356 2.46 0.61 7.15 2 2 2 154358 10.82 1.15 17.25 2 2 2 154358 10.76 1.14 17.58 2 2 2 154359 9.02 1.06 14.49 2 2 2 154359 9.25 1.02 14.60 2 2 2 154360 6.82 0.87 11.00 2 2 2 154360 6.85 0.87 10.61 2 2 2 154361 0.23 0.33 3.93 2 2 2 154361 0.23 0.31 3.94 2 2 2 154362 10.53 1.09 15.50 2 2 2 154362 10.63 1.10 15.00 2 2 2 154363 7.13 0.90 11.50 2 2 2 154363 7.20 0.89 11.61 2 2 2 154364 0.24 0.40 4.26 2 2 2 154364 0.28 0.38 4.46 2 2 2 154365 10.45 1.09 15.06 2 2 2 154365 10.38 1.09 15.18 2 2 2 154366 7.02 0.87 10.72 2 2 2 154366 6.85 0.85 10.85 2 2 2 154367 0.22 0.36 3.70 2 2 2 154367 0.22 0.35 3.76 2 2 2 154368 12.22 1.20 16.81 2 2 2 154368 12.42 1.20 17.23 2 2 2 154369 6.26 0.85 9.68 2 2 2 154369 6.36 0.84 9.52 2 2 2 154370 0.23 0.42 4.05 2 2 2 154370 0.27 0.40 4.09 2 2 2 154371 13.20 1.24 17.82 2 2 2 154371 12.93 1.25 18.21 2 2 2 154372 7.04 0.93 11.60 2 2 2 154372 7.04 0.90 11.70 2 2 2 154373 13.32 1.23 18.42 2 2 2 154373 13.52 1.27 18.13 2 2 2 154374 0.28 0.43 4.08 2 2 2 154374 0.35 0.40 4.12 2 2 2 154375 14.57 1.31 18.62 2 2 2 154375 14.53 1.29 19.16 2 2 2 154376 8.27 0.98 13.40 2 2 2 154376 8.44 0.98 13.17 2 2 2 154377 6.27 0.85 9.78 2 2 2 154377 6.31 0.83 9.86 2 2 2 154378 0.31 0.43 4.22 2 2 2 154378 0.35 0.43 4.38 2 2 2 154379 11.75 1.18 17.48 2 2 2 154379 11.95 1.19 17.64 2 2 2 154380 10.95 1.16 17.11 2 2 2 154380 11.15 1.15 16.80 2 2 2 154381 8.92 1.00 13.70 2 2 2 154381 8.81 1.02 13.85 2 2 2 154382 0.29 0.44 4.69 2 2 2 154382 0.29 0.45 4.64 2 2 2 154383 10.52 1.12 17.19 2 2 2 154383 10.65 1.15 16.65 2 2 2 154384 11.31 1.16 17.34 2 2 2 154384 11.35 1.18 17.44 2 2 2 154385 8.58 1.01 14.14 2 2 2 154385 8.65 1.02 13.71 2 2 2 154386 0.19 0.44 4.52 2 2 2 154386 0.23 0.43 4.57 2 2 2 154387 12.20 1.14 17.00 2 2 2 154387 11.96 1.13 17.37 2 2 2 154388 10.49 1.14 17.04 2 2 2 154388 10.56 1.12 17.48 2 2 2 154389 9.96 1.10 16.15 2 2 2 154389 9.89 1.08 16.54 2 2 2 154390 7.19 0.91 11.12 2 2 2 154390 7.19 0.94 11.36 2 2 2 154391 10.93 1.13 16.86 2 2 2 154391 11.16 1.11 16.76 2 2 2 154392 10.46 1.10 17.27 2 2 2 154392 10.59 1.13 16.82 2 2 2 154393 10.66 1.14 17.36 2 2 2 154393 10.69 1.11 17.24 2 2 2 154394 10.68 1.14 17.80 2 2 2 154394 10.89 1.15 17.51 2 2 2 154395 10.81 1.18 17.63 2 2 2 154395 10.84 1.17 17.97 2 2 2 154396 7.72 0.97 12.08 2 2 2 154396 7.85 0.98 11.88 2 2 2 154397 1.92 0.51 3.11 2 2 2 154397 1.96 0.50 3.22 2 2 2 154398 12.00 1.18 17.58 2 2 2 154398 12.06 1.17 18.02 2 2 2 154399 11.08 1.15 17.93 2 2 2 154399 11.18 1.21 17.49 2 2 2 154400 10.54 1.16 17.62 2 2 2 154400 10.57 1.17 17.41 2 2 2 154401 11.27 1.21 18.44 2 2 2 154401 11.20 1.21 18.41 2 2 2 154402 10.57 1.18 16.21 2 2 2 154402 10.63 1.16 16.44 2 2 2 154403 2.04 0.53 2.69 4 4 4 154403 2.08 0.57 2.82 4 4 4 154404 10.59 1.09 16.24 2 2 2 154404 10.62 1.08 16.42 2 2 2 154405 10.09 1.07 16.04 2 2 2 154405 10.12 1.07 16.23 2 2 2 154406 10.31 1.09 16.29 2 2 2 154406 10.28 1.08 16.22 2 2 2 154407 10.51 1.09 16.45 2 2 2 154407 10.54 1.09 16.52 2 2 2 154408 10.54 1.10 16.77 2 2 2 154408 10.60 1.10 16.85 2 2 2 154409 10.80 1.13 17.19 2 2 2 154409 10.83 1.13 17.21 2 2 2 154410 10.00 1.07 15.57 2 2 2 154410 10.06 1.10 15.67 2 2 2 154412 12.01 1.14 17.06 2 2 2 154412 12.08 1.14 17.00 2 2 2 154413 11.40 1.15 17.49 2 2 2 154413 11.33 1.14 17.58 2 2 2 154416 10.80 1.08 16.58 2 2 2 154416 10.80 1.10 16.59 2 2 2 154417 10.83 1.10 16.66 2 2 2 154417 10.89 1.11 16.77 2 2 2 154418 10.69 1.11 16.85 2 2 2 154418 10.72 1.12 16.93 2 2 2 154419 11.01 1.13 17.15 2 2 2 154419 11.08 1.13 17.18 2 2 2 154420 11.08 1.16 17.51 2 2 2 154420 11.11 1.16 17.58 2 2 2 154421 8.99 0.99 14.08 2 2 2 154421 8.96 1.00 13.98 2 2 2 154422 10.08 1.01 13.74 2 2 2 154422 10.08 1.02 13.72 2 2 2 154423 1.24 0.36 0.48 2 2 2 154423 1.24 0.37 0.49 2 2 2 154424 11.28 1.08 16.08 2 2 2 154424 11.34 1.08 16.25 2 2 2 154425 11.10 1.09 16.27 2 2 2 154425 11.17 1.08 16.30 2 2 2 154426 10.31 1.08 16.38 2 2 2 154426 10.37 1.08 16.35 2 2 2 154427 10.13 1.09 16.40 2 2 2 154427 10.17 1.09 16.33 2 2 2 154428 9.93 1.08 16.26 2 2 2 154428 9.96 1.08 16.24 2 2 2 154429 9.20 1.06 15.46 2 2 2 154429 9.27 1.07 15.41 2 2 2 154430 9.33 1.04 14.99 2 2 2 154430 9.30 1.05 15.00 2 2 2 154431 9.62 1.00 13.64 2 2 2 154431 9.58 1.00 13.75 2 2 2 154433 10.72 1.11 16.64 2 2 2 154433 10.73 1.11 16.42 2 2 2 154434 10.13 1.10 16.61 2 2 2 154434 10.33 1.10 16.71 2 2 2 154435 9.43 1.08 16.28 2 2 2 154435 9.50 1.06 16.23 2 2 2 154436 9.29 1.06 15.97 2 2 2 154436 9.30 1.08 15.94 2 2 2 154437 9.29 1.04 15.51 2 2 2 154437 9.22 1.04 15.58 2 2 2 154438 8.96 1.00 14.36 2 2 2 154438 9.06 1.01 14.40 2 2 2 154439 10.57 0.99 12.58 2 2 2 154439 10.64 1.00 12.66 2 2 2 154440 1.11 0.30 0.00 2 2 2 154440 1.14 0.41 0.00 2 3 2 154441 10.21 1.02 13.96 2 2 2 154441 10.18 1.02 13.80 2 2 2 154442 11.96 1.06 13.72 2 2 2 154442 12.05 1.05 13.76 2 2 2 154443 9.32 0.91 9.66 2 2 2 154443 9.46 0.91 9.74 2 2 2 154444 1.68 0.41 0.00 2 2 2 154444 1.71 0.39 0.00 2 2 2 154445 12.08 1.02 10.86 2 2 2 154445 12.18 1.03 10.91 2 2 2 154446 9.64 0.97 8.00 2 2 2 154446 9.64 0.97 7.95 2 2 2 154447 2.98 0.55 0.93 2 2 2 154447 2.91 0.54 1.31 2 2 3 154448 11.92 1.04 9.91 2 2 2 154448 11.89 1.04 9.84 2 2 2 154449 9.35 0.97 8.36 2 2 2 154449 9.36 0.97 8.33 2 2 2 154450 0.51 0.40 0.00 2 2 2 154450 0.51 0.41 0.00 2 2 2 154451 12.89 1.19 9.95 2 2 2 154451 12.93 1.19 10.09 2 2 2 154452 2.59 0.64 1.38 2 2 2 154452 2.66 0.64 1.58 2 2 2 154454 16.74 1.04 17.62 2 2 2 154454 16.21 1.06 16.87 2 2 2 154455 16.07 1.06 17.76 2 2 2 154455 16.15 1.07 17.47 2 2 2 154456 15.31 1.12 17.57 2 2 2 154456 12.54 1.01 14.01 2 2 2 154457 13.01 1.08 17.57 2 2 2 154457 13.34 1.02 16.08 2 2 2 154458 11.48 1.08 17.08 2 2 2 154458 11.56 1.02 14.10 2 2 2 154459 11.09 1.05 16.44 2 2 2 154459 12.25 1.15 17.48 2 2 2 154460 9.59 1.07 14.94 2 2 2 154460 11.15 1.14 17.07 2 2 2 154461 15.67 1.41 22.74 2 2 2 154461 16.79 1.33 20.65 2 2 2 154462 12.82 1.30 21.88 2 2 2 154462 13.80 1.31 22.04 2 2 2 154463 6.38 0.74 11.28 2 2 2 154463 6.11 0.78 12.05 2 2 2 154464 4.11 0.57 8.55 2 2 2 154464 3.98 0.56 8.10 2 2 2 154465 1.65 0.35 0.64 2 2 2 154465 1.71 0.36 0.69 2 2 2 154466 10.91 1.02 16.46 2 2 2 154466 12.00 1.09 18.12 2 2 2 154467 10.39 1.06 15.76 2 2 2 154467 11.43 1.08 17.13 2 2 2 154468 12.64 18.74 2 5 2 154468 14.04 20.78 2 5 2 154469 13.49 1.43 21.57 2 2 2 154469 13.33 1.29 21.51 2 2 2 154470 11.82 1.24 20.57 2 2 2 154470 11.89 1.27 20.14 2 2 2 154471 6.66 0.83 11.12 2 2 2 154471 5.40 0.75 8.94 2 2 2 154472 1.10 0.37 0.25 2 2 2 154472 1.42 0.44 0.41 2 2 2 154473 1.17 0.49 0.24 2 2 2 154473 1.23 0.49 0.25 2 2 2 154474 0.78 0.48 0.00 2 2 2 154474 0.85 0.53 0.00 2 2 2 154475 0.39 0.40 0.00 2 2 2 154475 0.46 0.43 0.00 2 2 2 154476 10.07 1.07 10.03 2 2 2 154476 10.43 1.09 9.99 2 2 2 154477 9.53 1.03 8.93 2 2 2 154477 9.85 1.08 9.54 2 2 2 154478 6.72 0.99 7.59 2 2 2 154478 6.91 1.00 7.46 2 2 2 154479 0.63 0.36 0.00 2 2 2 154479 3.51 0.36 0.00 2 2 2 154480 8.02 0.98 7.46 2 2 2 154480 9.00 1.06 8.41 2 2 2 154481 1.99 0.70 2.02 2 2 2 154481 2.04 0.68 1.98 2 2 2 154482 0.72 0.36 0.00 2 2 2 154482 0.73 0.38 0.00 2 2 2 154483 11.53 1.08 10.32 2 2 2 154483 11.86 1.08 10.79 2 2 2 154484 2.11 0.70 3.01 2 2 2 154484 2.15 0.71 3.12 2 2 2 154485 2.08 0.61 1.66 2 2 2 154485 2.09 0.61 1.64 2 2 2 154486 1.61 0.42 0.00 2 2 2 154486 1.32 0.36 0.00 2 2 2 154487 8.18 0.95 8.04 2 2 2 154487 8.51 1.00 8.32 2 2 2 154488 3.31 0.67 3.32 2 2 2 154488 3.55 0.66 3.61 2 2 2 154489 0.75 0.37 0.00 2 2 2 154489 0.88 0.39 0.00 2 2 2 154490 0.83 0.33 0.00 2 2 2 154490 0.84 0.34 0.00 2 2 2 154491 2.54 0.65 2.13 2 2 2 154491 2.56 0.66 2.12 2 2 2 154492 1.57 0.49 0.59 2 2 2 154492 1.65 0.51 0.67 2 2 2 154493 2.69 0.39 0.00 2 2 2 154493 1.26 0.32 0.00 2 2 2 5. Dissolved Inorganic Carbon in Seawater Bob Gershey a. Description of Equipment and Technique The total dissolved inorganic carbon content of seawater is defined as the total concentration of carbonate ion, bicarbonate ion and unionized species of carbon dioxide. Before analysis, the sample was treated with acid to convert all ionized species to the unionized form, which was then separated from the liquid phase and subsequently measured using the coulometric titration technique. This involved the reaction of carbon dioxide gas with a dimethysulfoxide solution of ethanoline to produce hydroxyethylcarbamic acid. The acidic solution was titrated with hydroxide ion formed by the electrolytic decomposition of water. The progress of the titration was followed through colorimetric measurement of the absorbance of a pH indicator dye (thymolphthalein) in the ethanolamine solution. A known volume of seawater was dispensed into a stripping chamber from a pipet of known volume and temperature controlled to within 0.4 °C. It was then acidified with ten percent its volume of an eight percent solution of carbon dioxide-free phosphoric acid. The solution was stripped of carbon dioxide gas by bubbling with a stream of nitrogen gas directed through a glass frit. The carrier gas exiting the stripper passed through a magnesium perchlorate trap to remove water vapour and acidic water droplets. The gas stream was then directed into the coulometric titrator where the total amount of carbon dioxide gas was quantified. The coulometer was calibrated in two ways. Calibration using gas loops was accomplished by filling stainless steel sample loops (1.5, 2.5 ml) with 99.995% carbon dioxide gas and injecting these into the coulometer. The temperature and pressure of the gas within the loops must be known to within 0.05 °C and 20 Pa respectively. Standard solutions of sodium carbonate were also used to calibrate the system. These samples were treated in the same manner as a seawater sample. Values were reported in units of µmol/kg. The overall precision of the analysis should have been at least 1.5 µmol/kg for samples with concentrations in the range of 1800-2300 µmol/kg. b. Sampling Procedure and Data Processing Technique Water samples were initially collected using a 10 litre rosette bottle. Samples for analysis of total inorganic carbon were drawn immediately following the drawing of the oxygen samples in order to minimize exchange of carbon dioxide gas with the head space in the sampler. This exchange typically results in a loss of carbon dioxide. It was desirable that the samples be drawn before half the sampler was emptied and within ten minutes of recovery. Clean borosilicate glass bottles were rinsed twice with 30 - 50 ml of the sample. The bottle was then filled from the bottom using a length of vinyl tubing attached to the spigot of the sampler. The sample was overflowed by at least a half of the volume of the bottle (typically 250 ml). A head space of 1% was left to allow for expansion without leakage. If samples were not to be analyzed within four to five hours, the sample were poisoned with 100 µl/250 ml of 50% saturated mercuric chloride solution. The bottle was tightly sealed and stored preferably at the temperature of collection. c. Replicate Analysis In total, 85 replicate carbonate measurements were obtained for 84 sample id numbers. Eighty-three sample id numbers had one replicate, while one sample id number had two replicates. No replicate difference could be calculated for four sample id numbers because at least one of the two sample values was unacceptable or unavailable. Thus, only 80 sample id numbers were used in calculating 82 replicate difference statistics. The following is a statistical summary of the absolute value of the replicate differences. Table C.6 lists all 85 replicate measurements. Number of Replicate Differences = 1 id had two replicates * 3 possible differences + 79 ids had one replicate * 1 possible difference = 3 + 79 = 82 Statistic Value Number of Replicate 82 Differences Minimum (µmoles/kg) 0 Maximum (µmoles/kg) 77.0 Mean (µmoles/kg) 3.6 Median (µmoles/kg) 1.4 Standard Deviation 9.4 (µmoles/kg) Table C.6 Replicate water sample total carbon values in µmoles/kg. Sample ID Total WOCE Number Carbon QF -------- ------ ---- 152937 2244.8 2 152937 2240.3 2 152948 2247.0 2 152948 2248.1 2 152951 2103.6 2 152951 2107.1 2 152954 2163.1 2 152954 2165.6 2 152974 2057.9 2 152974 2060.0 2 152978 2056.1 2 152978 2048.0 2 152989 2161.8 2 152989 2164.2 2 153000 2163.7 2 153000 2163.9 2 153022 2168.6 2 153022 2170.7 2 153034 2154.6 2 153034 2154.6 2 153042 2169.2 2 153042 2167.2 2 153078 2149.3 2 153078 5 153095 2175.7 2 153095 2177.2 2 153124 2154.2 2 153124 2158.5 2 153140 2189.2 2 153140 2189.5 2 153163 2171.2 2 153163 2174.9 2 153173 2152.3 2 153173 2153.1 2 153254 2184.6 2 153254 2184.4 2 153301 2165.0 2 153301 2175.8 2 153312 2152.5 2 153312 2152.9 2 153334 2151.4 2 153334 2153.0 2 153351 2163.9 2 153351 2165.4 2 153369 2179.4 2 153369 2180.9 2 153420 2163.3 2 153420 2164.1 2 153461 2175.2 2 153461 2175.8 2 153482 2090.6 2 153482 2096.4 2 153492 2154.5 2 153492 2153.0 2 153498 2094.3 2 153498 2112.9 2 153507 2178.2 2 153507 2178.4 2 153534 2160.7 2 153534 2162.8 2 153553 2171.4 2 153553 2171.8 2 153577 2170.3 2 153577 2168.5 2 153589 2163.5 2 153589 2161.8 2 153611 2154.1 2 153611 2156.8 2 153632 5 153632 5 153645 5 153645 5 153674 2156.3 2 153674 2158.3 2 153698 2155.3 2 153698 2156.7 2 153720 2151.5 2 153720 2151.0 2 153737 2155.4 2 153737 2155.4 2 153753 2040.9 2 153753 2043.7 2 153757 2148.7 2 153757 2151.4 2 153763 2087.5 2 153763 2087.4 2 153765 2158.1 2 153765 2158.9 2 153778 2150.6 2 153778 2151.2 2 153791 2151.2 2 153791 2158.5 2 153806 2171.1 2 153806 2174.7 2 153812 2153.1 2 153812 2152.7 2 153816 2151.7 2 153816 2152.3 2 153835 2156.1 2 153835 2156.2 2 153842 2153.6 2 153842 2154.2 2 153860 2155.3 2 153860 2157.2 2 153866 2177.7 2 153866 2155.7 2 153877 2160.3 2 153877 2159.4 2 153887 2153.3 2 153887 2153.4 2 153893 2162.7 2 153893 2162.8 2 153940 2163.1 2 153940 2169.1 2 153940 2169.8 2 153941 2170.1 2 153941 2163.1 2 153949 2165.4 2 153949 2165.5 2 153995 2168.8 2 153995 2169.1 2 154015 9 154015 2174.7 2 154061 2167.6 2 154061 2172.4 2 154080 2121.9 2 154080 2119.7 2 154087 2170.2 2 154087 2166.1 2 154107 2166.6 2 154107 2168.0 2 154126 2079.4 2 154126 2156.4 2 154144 2160.3 2 154144 2160.5 2 154181 2159.5 2 154181 2159.8 2 154205 2158.4 2 154205 2158.1 2 154212 2158.2 2 154212 2159.6 2 154248 2166.7 2 154248 2167.1 2 154273 2160.6 2 154273 2161.1 2 154315 2158.4 2 154315 2158.9 2 154321 2155.9 2 154321 2155.8 2 154340 2157.7 2 154340 2156.0 2 154362 2149.7 2 154362 2150.1 2 154380 2159.3 2 154380 2159.4 2 154385 2140.4 2 154385 2141.7 2 154399 2050.7 2 154399 2077.5 2 154412 2095.5 2 154412 2100.5 2 154420 2160.7 2 154420 2160.1 2 154439 2132.6 2 154439 2133.2 2 154449 2108.7 2 154449 2110.4 2 154451 2143.4 2 154451 2143.2 2 6. Alkalinity Frank Zemlyak a. Description of Equipment and Technique Total alkalinity was determined using the Marine Chemistry automated titration system. Total alkalinity was determined using a potentiometric titration of the sea water sample using hydrochloric acid. Once the sample was connected to the system, the operation proceeded automatically, from the reaction vessel being rinsed and filled with the sea water sample, to the final calculations at the conclusion of the titration. When the reaction vessel was filled, the semi-micro combination Ross electrode sensed when the sample had come to equilibrium, the initial relative mvolt reading was then logged, at the same time, the cell temperature was also recorded. At this point, a rather large quantity of 0.2N hydrochloric acid, was added to the cell with a Metrohm E-655 Dosimat. This large quantity of acid titrated the sample beyond the carbonate endpoint, at this point, smaller aliquots (0.040ml) of acid were added until the sample has been titrated to and beyond the second inflection point. With each addition of acid the sample was allowed to come to equilibrium, the mvolt reading was logged. Thus, with these relative changes in the voltage in the cell, the endpoint was calculated by using a modified Gran function. Corrections to the final total alkalinity result were made by using the sample salinity, sample temperature and the nutrients, silicate and phosphate. b. Sampling Procedure and Data Processing Technique The 500ml samples used for alkalinity analysis were collected from 10 litre rosette bottles in much the same fashion as the total carbonate samples. The alkalinity samples were drawn immediately following the drawing of the total carbonate samples. The samples were stored in a cold water bath whilst awaiting analysis. Note: The alkalinity data is currently under quality review. c. Replicate Analysis No replicate information is currently available. 7. CFC's Mike Hingston a. Description of Equipment and Technique The analyses were carried out on two purge and trap systems developed at the Bedford Institute of Oceanography. The water samples were injected into the systems directly from the syringes. To ensure proper rinsing, at least two volumes of water was passed through the sample pipette before the actual sample volume. The samples were purged for 4 minutes with ultra high purity nitrogen at a flow rate of 60 ml/min. The components were trapped in Porapak-N trap which was cooled to a temperature of less than 10_°C. They were then desorbed by heating the trap up to at least 170_°C. The contents of the trap were then passed through a 75m DB-624 megabore column. b. Sampling Procedure and Data Processing Technique All samples were collected directly from the Niskin bottles using 100ml syringes. The syringes were rinsed three times before they were filled. To prevent contamination, the CFC samples were the first samples which were collected from the Niskin bottles. The samples were then stored in a water bath of continuously flowing surface sea water until analysis. Air samples from the winch room were taken periodically to ensure that it had not become contaminated. The analysis of the samples was always completed within 24 hours after they had been drawn. c. Replicate Analysis A total of 62 unique sample id numbers had replicate CFC water samples drawn. In total, three sample id numbers had duplicate samples drawn and 59 sample id numbers had triplicate samples drawn. Replicates were taken at each station, with some of these being run on each system to ensure that the results were comparable. A statistical summary of the absolute value of the replicate differences is below. Only acceptable sample values were used when calculating replicate differences. All replicates and their quality flags are given in Table C.7. Statistic CFC11 CFC12 CFC113 Carbon Tet. Methyl Chl. Number of Replicate 166 166 163 137 168 Differences Minimum (pmoles/kg) 0.000 0.000 0 0.004 0 Maximum (pmoles/kg) 0.654 1.208 0.240 7.441 4.265 Mean (pmoles/kg) 0.108 0.184 0.039 1.773 0.835 Median (pmoles/kg) 0.078 0.133 0.027 1.430 0.480 Standard Deviation 0.109 0.195 0.040 1.521 0.918 (pmoles/kg) Detection Limits 0.022 0.017 0.010 0.040 0.017 (pmoles/kg) Table C.7 Replicate water sample CFC values in pmoles/kg. Sample ID Freon 11 Freon 12 Freon 113 Carbon Tet Methyl Chl. WOCE QF Number --------- --------- -------- --------- ---------- ---------- ------------- 152956 2.736 1.483 0.186 6.972 11.879 2 2 2 2 2 152956 2.673 1.583 0.197 4.471 11.895 2 2 2 2 2 152956 2.575 1.167 0.155 7.898 10.447 2 2 2 2 2 152968 2.966 1.419 0.190 7.762 10.019 2 2 2 2 2 152968 2.998 1.690 0.204 5.134 10.051 2 2 2 2 2 152968 3.272 1.771 0.217 6.183 12.783 2 2 2 2 2 152987 2.447 1.233 0.132 9.558 7.847 2 2 2 2 2 152987 2.318 1.254 0.122 7.124 7.840 2 2 2 2 2 152987 2.530 1.290 0.131 7.560 8.467 2 2 2 2 2 153010 2.149 0.815 0.102 8.503 8.036 2 2 2 2 2 153010 2.024 0.948 0.106 6.596 7.121 2 2 2 2 2 153010 2.188 1.063 0.100 4.529 8.366 2 2 2 2 2 153030 0.732 0.141 0.000 8.381 3.454 2 2 2 2 2 153030 0.580 0.362 0.062 6.891 1.779 2 2 2 2 2 153030 0.585 0.373 0.069 4.814 1.532 2 2 2 2 2 153059 2.010 0.993 0.130 5.089 7.127 2 2 2 2 2 153059 2.122 1.078 0.125 8.204 6.837 2 2 2 2 2 153059 2.133 1.937 0.222 7.646 2 2 2 5 2 153085 1.772 0.865 0.118 16.244 11.081 2 2 2 4 2 153085 1.815 0.870 0.169 7.373 10.810 2 2 2 2 2 153085 1.760 0.928 0.120 4.315 10.472 2 2 2 2 2 153100 0.254 0.493 0.073 1.318 2 2 2 5 2 153100 0.000 0.106 0.040 5.232 0.220 2 2 2 2 2 153100 0.262 0.286 0.064 2.172 0.983 2 2 2 2 2 153121 0.527 0.186 0.085 1.218 2.437 2 2 2 2 2 153121 0.334 0.148 0.034 4.931 1.492 2 2 2 2 2 153121 0.340 0.178 0.035 4.888 1.784 2 2 2 2 2 153160 1.908 0.877 0.147 6.878 8.550 2 2 2 2 2 153160 2.053 0.936 0.135 16.009 9.576 2 2 2 4 2 153160 1.906 1.290 0.101 2.434 8.559 2 2 2 2 2 153165 0.412 0.000 0.050 5.639 1.856 3 3 3 3 3 153165 0.203 0.117 0.039 4.336 1.019 2 2 2 2 2 153165 0.170 0.122 0.012 7.102 0.633 2 2 2 2 2 153203 0.962 0.538 0.069 4.255 3.059 2 2 2 2 2 153203 0.963 0.488 0.030 2.830 3.149 2 2 2 2 2 153203 0.957 0.489 0.069 5.061 2.683 2 2 2 2 2 153220 0.936 0.792 0.053 6.911 2.479 2 2 2 2 2 153220 1.038 0.458 0.037 7.520 2.472 2 2 2 2 2 153220 1.019 0.485 0.052 6.377 2.135 2 2 2 2 2 153240 5 5 5 5 5 153240 0.173 0.114 0.024 4.119 0.000 2 2 2 2 2 153240 0.249 0.174 0.031 4.807 0.872 2 2 2 2 2 153260 0.206 0.000 0.000 2.452 1.561 2 2 2 2 2 153260 0.178 0.073 0.014 3.882 1.364 2 2 2 2 2 153260 0.252 0.324 0.013 8.463 1.200 2 2 2 2 2 153283 0.288 0.097 0.035 2.253 2.176 2 2 2 2 2 153283 0.325 0.220 0.016 2.737 1.366 2 2 2 2 2 153283 0.330 0.301 0.000 4.108 1.187 2 2 2 2 2 153303 0.231 0.103 0.029 4.478 0.878 2 2 2 2 2 153303 0.238 0.139 0.047 5.320 0.627 2 2 2 2 2 153303 0.325 0.161 0.000 3.486 1.462 2 2 2 2 2 153359 5 5 5 5 5 153359 1.313 0.462 0.116 5.059 2 2 2 5 2 153359 1.162 0.473 0.074 4.825 3.714 2 2 2 2 2 153385 1.830 0.663 0.128 6.900 5.918 2 2 2 2 2 153385 1.967 0.970 0.088 6.896 5.764 2 2 2 2 2 153385 1.996 1.168 0.109 6.064 6.226 2 2 2 2 2 153399 0.385 0.183 0.000 3.378 0.993 2 2 2 2 2 153399 0.495 0.222 0.091 1.634 1.208 2 2 2 2 2 153399 0.556 0.156 0.083 3.195 1.369 2 2 2 2 2 153429 1.127 0.576 0.000 2.973 2 2 2 5 2 153429 1.164 0.587 0.104 3.531 2.969 2 2 2 2 2 153429 1.091 0.458 0.000 6.610 3.074 2 2 2 2 2 153447 0.089 2.771 3.134 5 5 2 2 2 153447 0.811 0.392 0.033 9.978 1.649 2 2 2 2 2 153447 0.794 0.425 0.060 2.537 2.780 2 2 2 2 2 153475 1.405 0.682 0.092 3.298 5.445 2 2 2 2 2 153475 1.262 0.656 0.118 3.092 4.744 2 2 2 2 2 153475 1.399 0.671 0.069 3.213 5.036 2 2 2 2 2 153490 0.663 0.482 0.026 2.897 2.598 2 2 2 2 2 153490 0.638 0.389 0.000 3.927 2.608 2 2 2 2 2 153490 0.662 0.391 0.032 3.961 1.884 2 2 2 2 2 153520 1.219 0.583 0.037 2.382 3.607 2 2 2 2 2 153520 1.281 0.623 0.062 2.975 0.000 2 2 2 2 2 153520 1.225 0.678 0.000 3.590 3.557 2 2 2 2 2 153538 0.416 0.133 0.016 10.455 0.000 2 2 2 3 2 153538 0.409 0.184 0.000 3.910 0.000 2 2 2 2 2 153538 0.490 0.322 0.000 3.184 0.833 2 2 2 2 2 153572 2.119 1.323 0.185 1.607 5.922 2 2 2 2 2 153572 1.993 0.994 0.137 4.608 5.753 2 2 2 2 2 153572 2.218 1.005 0.067 2.067 1.657 2 2 2 2 2 153578 0.759 0.426 0.037 10.615 2.208 2 2 2 3 2 153578 0.731 0.182 0.065 4.803 2.341 2 2 2 2 2 153578 0.806 0.366 0.042 3.839 2.783 2 2 2 2 2 153617 1.671 0.631 0.190 1.569 3.550 2 2 2 2 2 153617 1.505 0.666 0.049 7.702 0.672 2 2 2 2 2 153617 1.708 0.717 0.196 2.671 6.009 3 3 3 3 3 153634 1.570 0.704 0.073 5.438 0.777 2 2 2 2 2 153634 1.596 0.793 0.202 5.873 0.520 2 2 2 2 2 153634 1.552 0.802 0.133 5.526 4.468 2 2 2 2 2 153651 0.762 0.498 0.029 4.029 0.000 2 2 2 2 2 153651 0.777 0.522 0.078 4.456 1.583 2 2 2 2 2 153651 0.790 0.411 0.038 2.429 1.477 2 2 2 2 2 153675 0.852 0.323 0.090 7.942 0.000 2 2 2 2 2 153675 0.750 0.477 0.025 5.784 0.000 2 2 2 2 2 153675 0.831 0.612 0.077 4.371 2.225 2 2 2 2 2 153704 2.432 1.199 0.153 3.896 5.675 2 2 2 2 2 153704 2.248 1.326 0.105 4.447 7.546 2 2 2 2 2 153704 2.268 1.477 0.094 4.262 7.382 2 2 2 2 2 153721 2.469 0.977 0.235 7.544 8.235 2 2 2 2 2 153721 2.480 1.126 0.155 9.149 7.771 2 2 2 2 2 153721 2.259 1.366 0.145 6.701 7.508 2 2 2 2 2 153743 4.992 2.579 0.429 8.575 14.784 2 2 2 2 2 153743 4.970 2.612 0.492 7.752 15.135 2 2 2 2 2 153743 5.337 2.538 0.455 9.515 15.820 2 2 2 2 2 153753 6.257 2.749 0.562 11.756 18.170 2 2 3 3 2 153753 5.838 2.548 0.686 11.117 17.202 2 2 3 3 2 153785 1.896 0.905 0.152 6.163 2 2 2 5 2 153785 1.998 1.086 0.235 2.500 6.564 2 2 2 2 2 153785 2.166 1.123 0.152 6.537 3.772 2 2 2 2 2 153792 1.324 0.585 0.132 4.348 1.667 2 2 2 2 2 153792 1.119 0.612 0.028 2.258 3.998 2 2 2 2 2 153792 1.303 0.792 0.043 10.515 1.626 2 2 2 3 2 153829 4.234 2.317 0.345 8.350 11.286 2 2 2 2 2 153829 4.571 3.346 0.367 7.732 11.670 2 2 2 2 2 153829 4.213 2.138 0.430 9.126 10.885 2 2 2 2 2 153840 3.096 1.733 0.214 6.164 8.459 2 2 2 2 2 153840 3.080 1.777 0.188 10.241 8.370 2 2 2 3 2 153840 2.787 1.486 0.199 6.060 7.459 2 2 2 2 2 153870 2.184 0.983 0.121 6.868 7.492 2 2 2 2 2 153870 2.194 1.306 0.132 3.865 7.619 2 2 2 2 2 153870 2.439 1.546 0.156 7.962 6.877 2 2 2 2 2 153899 2.524 1.255 0.434 8.017 9.298 2 2 2 2 2 153899 2.741 1.280 0.194 4.456 7.316 2 2 2 2 2 153899 2.739 1.285 0.202 10.554 7.058 2 2 2 3 2 153906 1.181 0.631 0.055 4.522 3.256 2 2 2 2 2 153906 1.062 0.720 0.069 2.069 3.624 2 2 2 2 2 153906 1.050 0.554 0.078 4.206 3.750 2 2 2 2 2 153950 0.862 0.393 0.042 3.305 2.317 2 2 2 2 2 153950 0.762 0.611 0.020 5.048 2.593 2 2 2 2 2 153950 0.857 0.298 0.053 3.229 1.923 2 2 2 2 2 153975 0.555 0.044 0.036 1.366 0.879 2 2 2 2 2 153975 0.554 0.366 0.000 6.277 0.993 2 2 2 2 2 153975 0.552 0.448 0.058 3.413 0.825 2 2 2 2 2 154010 1.481 0.765 0.059 4.209 4.446 2 2 2 2 2 154010 1.842 0.809 0.042 4.225 4.275 2 2 2 2 2 154030 1.270 0.826 0.057 3.821 4.288 2 2 2 2 2 154030 1.382 0.911 0.052 3.282 4.428 2 2 2 2 2 154030 1.299 0.692 0.069 2.175 4.340 2 2 2 2 2 154040 0.745 0.320 0.076 3.464 2.558 2 2 2 2 2 154040 0.748 0.649 0.039 2.375 2.488 2 2 2 2 2 154040 0.721 0.313 0.067 4.045 2.357 2 2 2 2 2 154080 2.080 0.936 0.165 2.522 3.795 2 2 2 2 2 154080 2.245 1.142 0.138 3.462 6.136 2 2 2 2 2 154080 2.041 1.203 0.136 6.796 3.095 2 2 2 2 2 154110 0.867 0.211 0.062 2.005 2.010 2 2 2 2 2 154110 0.872 0.363 0.052 2.792 2.798 2 2 2 2 2 154110 0.842 0.557 0.056 1.996 0.370 2 2 2 2 2 154144 1.714 0.832 0.134 6.653 5.783 2 2 2 2 2 154144 1.818 1.083 0.052 4.855 5.447 2 2 2 2 2 154144 1.702 0.696 0.095 6.040 5.586 2 2 2 2 2 154154 0.844 0.228 0.033 4.878 2.478 2 2 2 2 2 154154 1.005 0.374 0.348 8.684 3.908 3 3 3 3 3 154154 0.820 0.000 0.035 3.304 2.447 2 2 2 2 2 154180 0.768 0.217 0.034 9.658 2.597 2 2 2 2 2 154180 0.788 0.448 0.019 3.498 1.655 2 2 2 2 2 154180 0.788 0.576 0.000 5.207 1.846 2 2 2 2 2 154227 0.868 0.463 0.000 2.870 1.880 2 2 2 2 2 154227 0.841 0.476 0.034 2.967 2.233 2 2 2 2 2 154261 1.678 0.770 0.071 5.443 5.154 2 2 2 2 2 154261 1.556 0.960 0.072 3.183 5.217 2 2 2 2 2 154261 1.561 0.634 0.037 3.753 5.232 2 2 2 2 2 154288 2.199 1.174 0.174 12.992 6.209 2 2 2 3 2 154288 2.191 1.239 0.146 5.401 5.407 2 2 2 2 2 154288 2.059 0.907 0.101 13.304 5.497 2 2 2 3 2 154327 2.992 1.664 0.205 8.686 9.851 2 2 2 2 2 154327 3.248 1.762 0.308 5.108 11.098 2 2 2 2 2 154327 3.158 1.969 0.088 5.843 11.103 3 3 3 3 3 154345 3.320 1.583 0.245 8.140 11.222 2 2 2 2 2 154345 3.073 1.651 0.187 6.477 10.224 2 2 2 2 2 154345 3.325 1.658 0.198 6.333 10.987 2 2 2 2 2 154380 3.583 1.523 0.282 5.125 11.224 2 2 2 2 2 154380 3.762 1.728 0.290 5.603 12.958 2 2 2 2 2 154380 3.546 1.332 0.157 7.580 11.058 2 2 2 2 2 154397 4.735 2.326 0.442 7.924 14.065 2 2 2 2 2 154397 4.764 2.345 0.457 7.764 13.815 2 2 2 2 2 154397 4.674 1.965 0.557 8.742 14.702 2 2 3 2 2 154427 3.192 1.605 0.118 13.226 10.634 2 2 2 3 2 154427 3.177 1.762 0.219 5.589 10.524 2 2 2 2 2 154427 3.454 1.829 0.225 6.931 12.037 2 2 2 2 2 154438 4.276 3.084 0.204 6.552 13.268 2 2 2 2 2 154438 4.557 2.233 0.357 9.745 13.602 2 2 2 2 2 154438 3.904 2.275 0.519 10.580 14.715 2 2 3 3 2 d. Standards Used Standardization was carried out using gas standards made up at Brookhaven National Laboratories. Standard volumes were corrected for lab temperature and pressure. Results were reported in units of pmol/kg of sea water. Clean air samples were also analyzed with each station, as a check on the standardization. 8. Reversing Thermometers Anthony W. Isenor a. Description of Equipment and Technique Sensoren-Instrumente-Systeme digital reversing thermometers model RTM 4002 were used to verify CTD thermistor readings on most deep stations. The thermometers had a depth range of up to 10000 m. The pressure housing was made of a glass tube closed at the ends by metal stoppers. One end contained the platinum sensor and the other end was the battery compartment. The thermometers were placed on bottles 1 and 3 on the rosette, thus sampling temperature at the deepest and third deepest bottle trips. The thermometers were placed in standard reversing thermometer racks on the Niskin bottles. Before deployment, a magnet was passed over the thermometers to clear the display and place the thermometer in sample mode. A new temperature was then recorded upon reversal of the thermometer. On the deepest stations, unprotected mercury in glass thermometers were also attached to the deepest and third deepest bottle trips. The following table lists the number of readings from each thermometer. Digital thermometers are indicated with a 'T' in the serial number. Thermometer Ser. No. Number of Readings -------------------- -------------------- 000T345 72 000T347 72 000T350 11 000T352 11 000T354 55 000T881 54 0010984 84 0010986 76 b. Sampling Procedure and Data Processing Technique The thermometers indicated the temperature reading either via a digital display or column or mercury. The temperature was read and noted on log sheets. The readings were later digitized and calibrations applied using the water sample database system. c. Calibration Data The digital reversing thermometers were calibrated at BIO in February 1991 while the mercury thermometers were last calibrated in March 1968. The digital thermometers were calibrated after the cruise, in March 1994, and were found to have significant drift over this period. The March 1994 calibration also improved the thermometer intercomparison and therefore was used for calibrations of this temperature dataset. d. Replicate Analysis A total of 135 sample id numbers had digital thermometer temperature replicates. All but two of these sample id numbers had one replicate. The remaining two sample id numbers had two replicates. The following is a statistical summary of the absolute value of the replicate differences. Only acceptable values were used in calculating the statistics. Statistic Value Number of Replicate 139 Differences Minimum (°C) 0.000 Maximum (°C) 1.763 Mean (°C) 0.027 Median (°C) 0.007 Standard Deviation (°C) 0.166 All of the replicate reversing thermometer temperature values, along with the reversing thermometer pressure values are given in Table C.8. Table C.8 Replicate Reversing Thermometer samples. Temperature is in °C and ITS-90 scale. Pressure is in dbars. Sample ID Thermometer Serial Main Thermomenter WOCE Number Number Corrected Pressure QF ------ --------------- --------- ----------- ------ 152925 000T345 6.415 2 9 152925 000T347 6.423 2 9 152927 000T350 6.314 2 9 152927 000T352 6.324 2 9 152949 000T345 -0.830 2 9 152949 000T347 -0.815 2 9 152951 000T350 -0.942 2 9 152951 000T352 -0.939 2 9 152959 000T345 3.007 2 9 152959 000T347 3.019 2 9 152975 000T345 2.252 2 9 152975 000T347 2.262 2 9 152998 000T345 2.215 2 9 152998 000T347 2.226 2 9 152998 0010984 3552.8 9 2 153000 000T350 2.348 2 9 153000 000T352 2.355 2 9 153022 000T345 2.234 2 9 153022 000T347 2.245 2 9 153022 0010984 3966.5 9 2 153022 0010984 3966.5 9 2 153024 000T350 2.274 2 9 153024 000T352 2.279 2 9 153024 0010986 3802.0 9 2 153024 0010986 3800.8 9 2 153046 000T345 2.177 2 9 153046 000T347 2.188 2 9 153046 0010984 4067.2 9 2 153046 0010984 4054.5 9 2 153048 000T350 2.284 2 9 153048 000T352 2.291 2 9 153048 0010986 3773.8 9 2 153048 0010986 3761.1 9 2 153070 000T345 3.971 2 9 153070 000T347 2.208 2 9 153070 0010984 4006.5 9 2 153070 0010984 4041.9 9 2 153093 000T345 2.223 2 9 153093 000T347 2.232 2 9 153093 0010984 5452.4 9 2 153093 0010984 5453.5 9 2 153095 000T350 2.257 2 9 153095 000T352 2.263 2 9 153095 0010986 4974.7 9 2 153095 0010986 4971.0 9 2 153116 000T345 2.237 2 9 153116 000T347 2.247 2 9 153116 0010984 5486.2 9 2 153116 0010984 5484.9 9 2 153118 000T350 2.267 2 9 153118 000T352 2.272 2 9 153118 0010986 5205.6 9 2 153118 0010986 5205.4 9 2 153139 000T345 2.225 2 9 153139 000T347 2.234 2 9 153139 0010984 5455.4 9 2 153141 000T350 2.256 2 9 153141 000T352 2.264 2 9 153141 0010986 5190.1 9 2 153162 000T345 2.225 2 9 153162 000T347 2.234 2 9 153162 0010984 5477.0 9 2 153164 000T350 2.256 2 9 153164 000T352 2.266 2 9 153164 0010986 4975.2 9 2 153185 000T345 2.282 2 9 153185 000T347 2.290 2 9 153185 0010984 5520.0 9 2 153185 0010984 5519.3 9 2 153187 000T350 2.256 2 9 153187 000T352 2.265 2 9 153187 0010986 5092.6 9 2 153187 0010986 5094.6 9 2 153208 000T345 2.203 2 9 153208 000T347 2.212 2 9 153208 0010984 5504.5 9 2 153210 000T352 2.267 2 9 153210 000T354 2.101 2 9 153210 0010986 5001.6 9 2 153232 000T345 2.203 2 9 153232 000T347 2.212 2 9 153232 0010984 5357.8 9 2 153232 0010984 5357.8 9 2 153234 000T354 2.236 2 9 153234 0010986 4799.5 9 2 153234 0010986 4799.5 9 2 153255 000T345 2.256 2 9 153255 000T347 2.264 2 9 153255 0010984 4730.8 9 2 153278 000T345 2.244 2 9 153278 000T347 2.253 2 9 153278 0010984 5374.2 9 2 153278 0010984 5374.8 9 2 153280 000T354 2.292 2 9 153280 000T881 2.294 2 9 153280 0010986 4800.5 9 2 153280 0010986 4798.4 9 2 153324 000T345 2.283 2 9 153324 000T347 2.292 2 9 153324 000T347 2.286 2 9 153324 0010984 5218.0 9 2 153324 0010984 5213.4 9 2 153326 000T354 5.349 2 9 153326 000T881 5.353 2 9 153347 000T345 2.271 2 9 153347 000T347 2.240 2 9 153347 0010984 4911.2 9 2 153347 0010984 4907.6 9 2 153349 000T354 2.227 2 9 153349 000T881 2.268 2 9 153349 0010986 5524.3 9 2 153349 0010986 5525.9 9 2 153370 000T345 2.241 2 9 153370 000T347 2.251 2 9 153370 0010984 4707.6 9 2 153370 0010984 4707.6 9 2 153372 000T354 2.297 2 9 153372 000T881 2.297 2 9 153372 0010986 4076.8 9 2 153372 0010986 4072.8 9 2 153393 000T345 2.240 2 9 153393 000T347 2.251 2 9 153393 0010984 4768.5 9 2 153393 0010984 4769.7 9 2 153395 000T354 2.283 2 9 153395 000T881 2.283 2 9 153395 0010986 4294.7 9 2 153395 0010986 4295.7 9 2 153416 000T345 2.244 2 9 153416 000T347 2.254 2 9 153416 0010984 4428.9 9 2 153418 000T354 2.345 2 9 153418 000T881 2.347 2 9 153418 0010986 3840.9 9 2 153439 000T345 2.289 2 9 153439 000T347 2.297 2 9 153439 0010984 4519.3 9 2 153439 0010984 4519.0 9 2 153441 000T354 2.323 2 9 153441 000T881 2.324 2 9 153441 0010986 3989.5 9 2 153441 0010986 3990.7 9 2 153462 000T345 2.265 2 9 153462 000T347 2.274 2 9 153462 0010984 4666.4 9 2 153464 000T354 2.352 2 9 153464 000T881 2.353 2 9 153464 0010986 4038.5 9 2 153485 000T345 2.281 2 9 153485 000T347 2.289 2 9 153485 0010984 4433.5 9 2 153485 0010984 4433.5 9 2 153487 000T354 2.407 2 9 153487 000T881 2.408 2 9 153487 0010986 3901.2 9 2 153487 0010986 3900.7 9 2 153508 000T345 2.294 2 9 153508 000T347 2.301 2 9 153508 0010984 4893.7 9 2 153508 0010984 4892.5 9 2 153510 000T354 2.348 2 9 153510 000T881 2.349 2 9 153510 0010986 4402.9 9 2 153510 0010986 4403.4 9 2 153531 000T345 2.290 2 9 153531 000T347 2.299 2 9 153531 0010984 4894.2 9 2 153531 0010984 4893.7 9 2 153533 000T354 2.328 2 9 153533 000T881 2.330 2 9 153533 0010986 4410.9 9 2 153533 0010986 4409.4 9 2 153554 000T345 2.305 2 9 153554 000T347 2.313 2 9 153554 0010984 4916.8 9 2 153554 0010984 4907.9 9 2 153556 000T354 2.386 2 9 153556 000T881 2.387 2 9 153556 0010986 4297.1 9 2 153556 0010986 4283.1 9 2 153577 000T345 2.312 2 9 153577 000T347 2.319 2 9 153577 0010984 4766.8 9 2 153600 000T345 2.298 2 9 153600 000T347 2.306 2 9 153600 0010984 4909.8 9 2 153600 0010984 4907.7 9 2 153602 000T354 2.316 2 9 153602 000T881 2.316 2 9 153602 0010986 4377.8 9 2 153602 0010986 4383.7 9 2 153623 000T345 2.291 2 9 153623 000T347 2.299 2 9 153623 0010984 4808.2 9 2 153623 0010984 4810.8 9 2 153625 000T354 2.377 2 9 153625 000T881 2.378 2 9 153625 0010986 4217.7 9 2 153625 0010986 4207.5 9 2 153646 000T345 2.264 2 9 153646 000T347 2.272 2 9 153646 0010984 4746.9 9 2 153646 0010984 4734.9 9 2 153648 000T354 2.346 2 9 153648 000T881 2.347 2 9 153648 0010986 4193.2 9 2 153648 0010986 4200.9 9 2 153669 000T345 2.267 2 9 153669 000T347 2.274 2 9 153669 0010984 4604.6 9 2 153671 000T354 2.357 2 9 153671 000T881 2.358 2 9 153671 0010986 3973.7 9 2 153692 000T345 2.227 2 9 153692 000T347 2.235 2 9 153692 0010984 4114.0 9 2 153692 0010984 4113.8 9 2 153694 000T354 2.316 2 9 153694 000T881 2.317 2 9 153694 0010986 3784.0 9 2 153694 0010986 3782.5 9 2 153715 000T345 3.046 2 9 153715 000T347 3.054 2 9 153717 000T354 3.095 2 9 153717 000T881 3.097 2 9 153735 000T345 3.334 2 9 153735 000T347 3.341 2 9 153737 000T354 3.495 2 9 153737 000T881 3.500 2 9 153747 000T345 3.452 2 9 153747 000T347 3.459 2 9 153749 000T354 3.582 2 9 153749 000T881 3.586 2 9 153755 000T345 3.235 2 9 153755 000T347 3.245 2 9 153757 000T354 3.344 2 9 153757 000T881 3.350 2 9 153766 000T345 2.299 2 9 153766 000T347 2.307 2 9 153768 000T354 2.595 2 9 153768 000T881 2.597 2 9 153789 000T345 2.141 2 9 153789 000T347 2.148 2 9 153789 0010984 3740.5 9 2 153789 0010984 3740.5 9 2 153791 000T354 2.473 2 9 153791 000T881 2.491 2 9 153812 000T345 2.997 2 9 153812 000T347 3.005 2 9 153814 000T354 2.976 2 9 153814 000T881 2.977 2 9 153832 000T345 2.197 2 9 153832 000T347 2.205 2 9 153834 000T354 2.693 2 9 153834 000T881 2.694 2 9 153855 000T345 2.217 2 9 153855 000T347 2.225 2 9 153855 0010984 3478.6 9 2 153857 000T354 2.595 2 9 153857 000T881 2.597 2 9 153878 000T345 2.203 2 9 153878 000T347 3.080 2 9 153878 0010984 3916.7 9 2 153880 000T354 2.424 2 9 153880 000T881 2.426 2 9 153901 000T345 2.191 2 9 153901 000T347 2.199 2 9 153901 0010984 4301.6 9 2 153901 0010984 4302.4 9 2 153902 000T354 2.296 2 9 153902 000T881 2.297 2 9 153902 0010986 3869.9 9 2 153902 0010986 3869.0 9 2 153924 000T345 2.320 2 9 153924 000T347 2.328 2 9 153924 0010984 4661.1 9 2 153926 000T354 2.295 2 9 153926 000T881 2.297 2 9 153926 0010986 4130.9 9 2 153926 0010986 4131.4 9 2 153947 000T345 2.259 2 9 153947 000T347 2.265 2 9 153947 0010984 4835.5 9 2 153947 0010984 4838.7 9 2 153949 000T354 2.336 2 9 153949 000T881 2.338 2 9 153949 0010986 4298.8 9 2 153949 0010986 4301.4 9 2 153970 000T345 2.289 2 9 153970 000T347 2.296 2 9 153970 0010984 4795.8 9 2 153970 0010984 4794.0 9 2 153972 000T354 2.327 2 9 153972 000T881 2.328 2 9 153972 0010986 4194.5 9 2 153972 0010986 4194.0 9 2 153993 000T345 2.298 2 9 153993 000T347 2.305 2 9 153993 0010984 4793.2 9 2 153995 000T354 2.334 2 9 153995 000T881 2.336 2 9 153995 0010986 4199.0 9 2 153995 0010986 4201.2 9 2 154016 000T345 2.305 2 9 154016 000T347 2.313 2 9 154016 0010984 4902.1 9 2 154016 0010984 4902.3 9 2 154018 000T354 2.353 2 9 154018 000T881 2.355 2 9 154018 0010986 4300.0 9 2 154018 0010986 4301.3 9 2 154039 000T345 2.290 2 9 154039 000T347 2.297 2 9 154039 0010984 4892.8 9 2 154041 000T354 2.329 2 9 154041 000T881 2.330 2 9 154041 0010986 4380.6 9 2 154062 000T345 2.304 2 9 154062 000T347 2.311 2 9 154062 0010984 5157.2 9 2 154064 000T354 2.378 2 9 154064 000T881 2.380 2 9 154064 0010986 4294.4 9 2 154085 000T345 2.295 2 9 154085 000T347 2.302 2 9 154085 0010984 4830.1 9 2 154087 000T354 2.344 2 9 154087 000T881 2.344 2 9 154087 0010986 4411.0 9 2 154108 000T345 2.286 2 9 154108 000T347 2.294 2 9 154108 0010984 4802.7 9 2 154110 000T354 2.370 2 9 154110 000T881 2.371 2 9 154110 0010986 4189.3 9 2 154131 000T345 2.300 2 9 154131 000T347 2.308 2 9 154131 0010984 4755.1 9 2 154131 0010984 4754.8 9 2 154133 000T354 2.350 2 9 154133 000T881 2.351 2 9 154133 0010986 4296.1 9 2 154133 0010986 4297.1 9 2 154154 000T345 2.295 2 9 154154 000T347 2.303 2 9 154154 0010984 4725.6 9 2 154154 0010984 4724.8 9 2 154156 000T354 2.366 2 9 154156 000T881 2.367 2 9 154156 0010986 4189.8 9 2 154156 0010986 4190.0 9 2 154200 000T345 2.289 2 9 154200 000T347 2.296 2 9 154200 0010984 4512.0 9 2 154200 0010984 4512.3 9 2 154202 000T354 2.414 2 9 154202 000T881 2.414 2 9 154202 0010986 3895.1 9 2 154202 0010986 3906.8 9 2 154223 000T345 2.282 2 9 154223 000T347 2.289 2 9 154223 0010984 4563.4 9 2 154223 0010984 4560.4 9 2 154225 000T354 2.359 2 9 154225 000T881 2.361 2 9 154225 0010986 4155.7 9 2 154225 0010986 4155.3 9 2 154246 000T345 2.293 2 9 154246 000T347 2.300 2 9 154246 0010984 4692.0 9 2 154248 000T354 2.335 2 9 154248 000T881 2.336 2 9 154248 0010986 4303.1 9 2 154269 000T345 2.266 2 9 154269 000T347 2.273 2 9 154269 0010984 4651.7 9 2 154271 000T354 2.345 2 9 154271 000T881 2.348 2 9 154271 0010986 4019.8 9 2 154292 000T345 2.181 2 9 154292 000T347 2.188 2 9 154292 000T881 2.239 2 9 154292 0010984 3932.6 9 2 154292 0010984 3930.6 9 2 154292 0010986 3713.3 9 2 154292 0010986 3715.1 9 2 154315 000T345 2.097 2 9 154315 000T347 2.104 2 9 154315 0010984 3844.9 9 2 154317 000T345 2.307 2 9 154317 000T881 2.306 2 9 154338 000T345 2.759 2 9 154338 000T347 2.767 2 9 154340 000T354 2.871 2 9 154340 000T881 2.874 2 9 154359 000T345 2.587 2 9 154359 000T347 2.594 2 9 154361 000T354 4.845 2 9 154361 000T881 4.846 2 9 154380 000T345 3.248 2 9 154380 000T347 3.258 2 9 154382 000T354 4.453 2 9 154382 000T881 4.460 2 9 154399 000T345 3.679 2 9 154399 000T347 3.686 2 9 154401 000T354 4.339 2 9 154401 000T881 4.378 2 9 154417 000T345 3.190 2 9 154417 000T347 3.198 2 9 154419 000T354 3.599 2 9 154419 000T881 3.603 2 9 154434 000T345 3.300 2 9 154434 000T347 3.307 2 9 154436 000T354 3.355 2 9 154436 000T881 3.356 2 9 154446 000T345 -1.648 2 9 154446 000T347 -1.638 2 9 154448 000T354 -0.959 2 9 154448 000T881 -0.953 2 9 154455 000T345 3.128 2 9 154455 000T347 3.136 2 9 154457 000T354 3.441 2 9 154457 000T881 3.442 2 9 154477 000T345 0.911 2 9 154477 000T347 0.920 2 9 154479 000T354 2.367 2 9 154479 000T881 2.370 2 9 D. MOORED MEASUREMENTS - DESCRIPTIONS, TECHNIQUES AND CALIBRATIONS 1. Current Meter Moorings Allyn Clarke a. Description of the Equipment and Technique The BIO deep sea moorings recovered consisted of a large streamlined subsurface buoyancy package supporting one or more Aanderaa Current Meters, back up buoyancy packages and an acoustic release. The subsurface buoyancy packages (i.e. Braincon main floats) were either constructed using 10( glass balls supported in a fibreglass structure or using deep sea syntactic foam formed in the same streamlined shape as the older glass floats. All of the moorings recovered on 95003 were constructed using jacketed 1/4" wire and 5/16" or 1/4" kevlar. Stainless steel shackles and swivels were used to connect the instruments and backup buoyancy packages to the wire lengths. All shackles were secured with a piece of wire (jacketed or kevlar) as the mooring was assembled and deployed. The acoustic releases were 723A EG&G DAC model releases. The moorings were designed for a 22 month deployment. The back-up buoyancy packages consisted of two 17" glass balls contained in plastic hard hats and fastened to a stainless steel tension bar one metre in length. These backup buoyancy packages were shackled together to form doubles and triples before they are shackled into the mooring line. b. Sampling Procedure and Data Processing Techniques The recovered Aanderaa current meters were set with a sampling interval of three hours. The data will be processed using standard software packages within the BIO Oceans suite of programs. c. Calibration Data The temperature, pressure, conductivity and direction sensors of the Aanderaa current meters were calibrated in the laboratory prior to deployment. These calibrations were not included in this cruise report. d. Deployment and Recovery logs Recovery Mooring No: 1121 Ship: Hudson Cruise No: 95003 Date: 04/05/95 Mooring Tech: d'Entremont / Boyce Type of Nav: GPS Sea State: 2 m swell, moderate sea Weather Conditions: 20 kt winds 060°T, gusty, rain showers Recovery Log Time (Z) Instrument Remarks ------- ----------- ----------------------------------------------- 1024 release 3 cables to go, enable command, 1 /2 sec for 1 min, transpond echo hidden in bottom echo 1029 release command, 1 /sec for 1 min, on its way up 1034 beacon heard off starboard, buoy spotted 2 cables off port beam 1040 approaching buoy upwind, 2 bb packages on surface 1102 hooked tag line, buoy moved under port bow 1113 could not move vessel back up into the wind, attached floats to the end of the grapnel line and let go of float. manoeuvring vessel to try to pickup with head to wind. 1125 pick up tag line again, buoy against starboard side 1130 line over the block, light working 1135 ACM 7136 buoy and ACM out of water, rotor spinning, bb packages leading abaft the port beam 1150 2 bb out of water 1201 ACM 8696 out of water, rotor spinning 1212 2 bb out of water in wire tangle 1244 ACM 7012 out of water, rotor spinning, loop of wire loosely across ACM 1248 2 bb, out of water, recovery complete release Recovery Mooring No: 1122 Ship: Hudson Cruise No: 95003 Dates: 03/05/95, 04/05/95 and 14/05/95 Mooring Tech: d'Entremont / Boyce Type of Nav: GPS Sea State: 3 May, small sea, 4 May, building sea, 14 May, small sea Weather Conditions: 3 May, light winds, fog, 4 May, winds 30-35, increasing, 14 May, light winds, fog Recovery Log Time (Z) Instrument Remarks ------- ----------- ----------------------------------------------- 3/5 release enable command sent, no reply 1957 1959 enable command sent, no reply 2000 enable command sent, no reply 2003 enable command sent, no reply/no transpond 2006 enable command sent, no reply 2008 enable command sent, no reply 2010 over the side transducer, enable command, no reply 2012 over the side transducer, enable command, no reply 2014 enable command sent, no reply 2016 enable command sent, no reply, going to exact site to see if we can see Braincon float on sounder 2018 enable command sent, no reply 2020 enable command sent, no reply, passed over site twice using sounder, got probable echo from Braincon both times at a minimum range of 170 fathoms 2045 fog bank rolled in, sent disable, will try again tomorrow 4/5 enable command sent, no reply 1526 1539 disable command sent, abandon recovery attempt due to weather 14/5 enable command sent, no reply 0900 0915 saw float? on sounder, manouvering to return to site. 0925 saw float? on sounder, release command sent, no reply 0937 high flyer deployed 1 cable south of site 0955 returned to original site, spotted buoyancy on sounder 0958 release command sent, still see float on sounder, no release. 1005 saw float on sounder 1006 disable command sent, end mooring recovery operation Recovery Mooring No: 1123 Ship: Hudson Cruise No: 95003 Date: 03/05/95 Mooring Tech: d'Entremont / Boyce Type of Nav: GPS Sea State: 1 m swell Weather Conditions: light breeze Recovery Log Time (Z) Instrument Remarks ------- ----------- -------------------------------------------- 1537 release enable command, 1/2 sec for 1 min 1600 4.3 cables acoustics, 1.8 cables from anchor site, release command sent, 1/sec for 1 min 1605 float spotted, beacon working but direction 180o off 1621 2 sets of bb on surface 1629 hooked tag line 1634 ACM 5578 buoy, ACM out of water, light flashing, antenna intact, rotor spinning 1640 hauling wire, removing fairing 1650 join in wire, continuing recovering fairing 1707 ACM 4603 fairing complete, ACM out of water, rotor spinning 1714 3 bb out of water 1722 ACM 820 out of water, rotor spinning 1730 3 bb out of water, tangle with Kevlar 1744 ACM 5032 out of water, tangle with Kevlar 1750 2 bb out of water, in a tangle of Kevlar 1805 ACM 828 out of water, rotor spinning 1807 2 bb, out of water, mooring recovery complete release Recovery Mooring No: 1124 Ship: Hudson Cruise No: 95003 Date: 3/05/95 Mooring Tech: d'Entremont / Boyce Type of Nav: GPS Sea State: Weather Conditions: 25 kt winds Recovery Log Time (Z) Instrument Remarks ------- ----------- -------------------------------------------- 1131 release enable command, 1/2 sec for 1 min 1144 release 4 cables from site, release command, 1/2 sec for 1 min. no release 1148 release command, 1/2 sec for 1 min, no release 1150 disable command, no transpond 1151 enable command, 1/2 sec for 1 min, transponding 1154 release command, 1/2 sec for 1 min, no release 1156 release command, 1/2 sec for 1 min, no release 1200 release command, 1/2 sec for 1 min 1205 transducer over side, release command, 1/2 sec for 1 min, no release 1207 transducer over side, release command, 1/2 sec for 1 min 1223 ram transducer, release command, 1/2 sec for 1 min, 3 cables from site 1225 release command, 1/2 sec for 1 min 1227 release command, 1/2 sec for 1 min, no release 1229 release command, 1/2 sec for 1 min, no release 1232 release command, 1/2 sec for 1 min, no release 1235 disable command, release disabled, finished with recovery operation Recovery Mooring No: 1125 Ship: Hudson Cruise No: 95003 Date: 02/05/95 Mooring Tech: d'Entremont / Boyce Type of Nav: GPS Sea State: 1 m swell Weather Conditions: overcast, calm Recovery Log Time (Z) Instrument Remarks ------- ----------- -------------------------------------------- 1639 release send wake up call, no reply 1640 send enable, no reply 1642 ram down, send wake up, weak 1/2 sec for 1 min, not transponding 1649 send enable, weak 1/2 sec for 1 min 1651 send enable, weak 1/2 sec for 1 min 1703 still not transponding, send enable, no clear reply 1706 send release command, weak 1/sec for 1 min; however transponder is working and release is rising. 1749 no sign of Braincon at surface, release has stopped rising at about 330 ft from surface. (this distance from surface was subsequently seen to be an incorrect interpretation of the sounder traces) 1814 4 bb packages sighted on surface 1836 3 bb hooked 3 bb package, probably topmost package 1842 3 bb on board - both Kevlar and jacketed wire attached. hauling jacketed wire first. 1850 ACM 4154 out of water, rotor spinning, tangled in Kevlar 1853 hauling jacketed wire 1859 3 bb these packages were submerged, out of water 1905 ACM 3196 out of water, snarled in faired jacketed cable 1934 ACM 4349 out of water, rotor spinning, short length of wire to Braincon was broken off at the thimble. 1943 hauling Kevlar, problems with the winch, switched to the Pengo 2026 ACM 2037, both tangled together, out of water ACM 1039 2037 2 bb out of water in a loop 2108 ACM 8695 out of water, rotor is broken 2112 2 bb, out of water and on board 2 bb, release 2118 all wire now on board, recovery complete Recovery Mooring No: 1126 Ship: Hudson Cruise No: 95003 Date: 02/05/95 Mooring Tech: d'Entremont / Boyce Type of Nav: GPS Sea State: 1-2 m swell, light sea Weather Conditions: light breeze, NW Recovery Log Time (Z) Instrument Remarks ------- ----------- -------------------------------------------- 1151 release send wakeup call, 2/sec for 1 min 1208 release 5 cables away, release command, 1/sec for 1 min 1213 buoy sighted on starboard beam 1230 buoyancy hooked tag line, 42° 27.218 N 45° 59.802 W 1233 ACM 1283 buoy, ACM out of water, rotor spinning, light working, beacon antennae on, beacon not working 1245 ACM 786 ACM out of water, rotor spinning, vane may be bent 1251 2 bb out of water, note these bb were not at surface 1259 ACM 9261 out of water, rotor spinning 1308 2 bb out of water, Kevlar jacket off 1 m from splice 1316 ACM 217 out of water, rotor spinning, radio beacon now working 1324 ACM 1277 out of water, rotor spinning 1337 ACM 4209 out of water, rotor spinning 1343 2 bb out of water, in separate loop, single line leading to ACM 1349 ACM 7524 out of water, rotor spinning 1352 2 bb, release out of water, recovery complete Recovery Mooring No: 1127 Ship: Hudson Cruise No: 95003 Date: 01/05/95 Mooring Tech: d'Entremont / Boyce Type of Nav: GPS Sea State: 2-3 m swell and sea Weather Conditions: 15 -20 kt winds, rain squalls Recovery Log Time (Z) Instrument Remarks ------- ----------- -------------------------------------------------- 1622 release sent wakeup command, reply 2/sec for 1 min, range .75 nm, transponder working, range to site closing to .6 nm. 1626 release sent release command. 1/sec for 1 min 1908 no sign of surface float or beacons. Did search on release using range on transponder. Finally spotted bb at range of 300 fathoms 1925 2 bb, release 2 bb hooked with light grapnel, trying to get heavier grapnel hooked for recovery 1935 2 bb, release 2bb, release out of water and on board. Wire leading under bow of Hudson. Rotating vessel to get ship off wire. 1947 start hauling in wire 1949 ACM 6187 ACM out of water, rotor spinning 1952 hauling, problems with winch 1956 end of 100 m length 2002 2 bb out of water 2010 ACM 6402 out of water, rotor spinning 2023 ACM 9324 out of water, rotor spinning 2044 ACM 9267 out of water, rotor spinning when not shielded by the rotor shield 2057 2 bb out of water, switch to wire lengths 2059 change spools 2110 ACM 9592 out of water, rotor spinning, back end cap missing 2118 2 bb out of water 2124 ACM 5002 out of water, rotor spinning, wire tangled around CM, meter is flooded, tension rod of its spindle 2141 ACM 4351 ACM out of water, rotor spinning, spindle broken, rotor bottom pivot broken, only the thimble left on bottom of ACM, mooring recovery complete Recovery Mooring No: 1128 Ship: Hudson Cruise No: 95003 Date: 01/05/95 Mooring Tech: d'Entremont / Boyce Type of Nav: GPS Sea State: 2-3 m swell, 1/2 m sea Weather Conditions: overcast, 15 kt winds, rain squalls Recovery Log Time (Z) Instrument Remarks ------- ----------- -------------------------------------------- 1012 release sent wake up command, 2/sec reply for 1 min 1015 release release transponding, ranging with sounder 1030 release release command sent, 1/sec for 1 min, 664 ft slant range 1036 buoyancy main buoyancy package on surface, beacon not working, waiting for bb to appear 1104 along side, light working, beacon working 1105 buoy recovery loop hooked on 1108 ACM 5395 ACM 5395 out of water, rotor spinning 1110 ACM 5395 buoyancy and ACM 5395 on board, antenna on beacon is broken 1131 ACM 1607 out of water, rotor spinning 1141 2 bb out of water 1153 ACM 9269 out of water, rotor spinning 1203 2 bb out of water, start hauling Kevlar 1212 ACM 9687 ACM out of water, rotor spinning 1227 ACM 9591 out of water, rotor spinning 1233 changed the spool on the winch after the end of the 984 m length 1244 ACM 4201 ACM out of water, rotor spinning 1252 2 bb wire snarled around bb, appears to be 300 m length 1259 ACM 5572 ACM out of water, rotor spinning 1303 2 bb, release out of water, recovery complete E. ACKNOWLEDGEMENTS F. REFERENCES Carritt, D.E. and J.H. Carpenter. 1966. Comparison and Evaluation of Currently Employed Modifications of the Winkler Method for Determining Dissolved Oxygen in Seawater. A NASCO Report, Jour. Mar. Res., 24, 268-318. Jones, E.P., F. Zemlyak and P. Stewart. 1992. Operating Manual for the Bedford Institute of Oceanography Automated Dissolved Oxygen Titration System. Can. Tech. Rep. of Hydrography and Ocean Sci. 138: iv+51p. Levy, E.M., C.C. Cunningham, C.D.W. Conrad and J.D. Moffatt. 1977. The Determination of Dissolved Oxygen in Sea Water, Bedford Institute of Oceanography Report Series, BI-R-77-9, August 1977. * All figures are shown in PDF file.