Last updated 11/1/2001 All Figures are available in PDF version A. Cruise Narrative AR07W (LABRADOR SEA) A.1. Highlights WHP Cruise Summary Information WOCE section designation AR07W, AR13, AR27 Expedition designation (EXPOCODE) 18HU97009_1 Chief Scientist(s) and their affiliation R. Allyn Clarke* Dates 1997.05.09 - 1997.06.11 Ship CCGS Hudson Ports of call BIO, Dartmouth, NS, Canada Number of stations 113 Full depth WHP small volume CTD stns. 62° N Geographic boundaries of the stations 62° W 50° E 50° N Floats and drifters deployed 6 ALACE floats; 9 RAFOS floats Moorings deployed or recovered 1 mixed layer Lagrangian drifter recovered Contributing Authors: M. Levasseur, J. Anning, J. Bugden, K. Clemente, L Harris, R. Campbell, A. Isenor, B. Ryan, I Yashayaev, R. Boyce, P. Strain, P. Clement, M. Poliquin, B. Gershey, M. Hingston, R. Ugstad, A. Clarke, *Chief Scientist Ocean Sciences Division Department of Fisheries and Oceans Bedford Institute of Oceanography PO Box 1006 Dartmouth, NS, Canada B2Y 2A4 FAX 902 426 7827 Internet ClarkeA@mar.dfo-mpo.gc.ca WHP Cruise and Data Information Cruise Summary Information Hydrographic Measurements Description of scientific program CTD - general Geographic boundaries of the survey CTD - pressure Cruise track (figure) CTD - temperature CTD - conductivity/salinity Description of stations CTD - dissolved oxygen Description of parameters sampled Bottle depth distributions (figure) Salinity Floats and drifters deployed Oxygen Moorings deployed or recovered Nutrients CFCs Principal Investigators for all measurements CO2 system parameters Cruise Participants Other parameters Problems and goals not achieved References Other incidents of note Data Processing Notes Underway Data Information Navigation Bathymetry Acoustic Doppler Current Profiler (ADCP) Meteorological observations Atmospheric chemistry data 2. Cruise Summary Information a. Cruise Track A cruise track is shown in Figure 1. Ship position at midnight on each day of the cruise is indicated with an asterisk. Figure 1. Cruise track for 18HU97009/1; * marks Hudson's position at 0000Z each day with some day labels indicated. b. Total Number of Stations Occupied The CTD and ROS station positions are shown in Figure 2. The WHP stations are all contained in the box defined by 50-62(N and 43-60(W. Test CTD stations were also occupied outside of this box and are not shown here. 113 Full depth WHP small volume CTD stations with up to 24 rosette bottles. Depending on the station, water samples were analyzed for CFCs, carbon tetrachloride, methyl chloroform, total carbonate, alkalinity, oxygen, salinity, nutrients, oxygen isotopes, helium and tritium, DMS, DOC, and chlorophyll. Figure 2. CTD/ROS/Tracer station positions for Hudson 18HU97009/1. 15 Shallow small volume CTD casts for DMS sampling 1 CTD cast with no water samples 7 aborted CTD casts 29 spectral radiometer profile stations to 100 metres 26 pump lowerings to 100 metres 12 stations sampled for DOC profiles 22 stations sampled for plankton respiration and size fractionation of DOC 167 vertical net hauls between 100 to 3000 metres c. Floats and Drifters Deployed or Recovered The profiling ALACE floats (o) and RAFOS floats (+) deployment sites are shown in Figure 3. 6 profiling ALACE floats launched at 6 stations 9 RAFOS floats launched at 9 stations 1 mixed layer Lagrangian drifter recovered Figure 3. RAFOS (+) and ALACE (o) float deployment positions during Hudson 18HU97009_1. d. Moorings Deployed or Recovered The deployment and recovery sites of the various moorings are shown in Figure 4. The following summarizes the mooring operations and provides a legend for Figure 4. Recovered 1 (BIO number M1226) multi-instrument mooring was recovered near OWS Bravo on AR7W. The mooring consisted of 6 Seacat temperature/conductivity recorders, 6 Aanderaa current meters, 1 acoustic doppler current profiler (ADCP), 1 WOTAN (weather observations through ambient noise) and 1 CTD with a device for measuring the total partial pressure of dissolved gas in the water; denoted in Figure 4 as 1226. 1 (BIO number M1227) mooring consisting of 1 current meter positioned 15 m off the bottom on the 1000 m isobath on the Labrador side of AR7W; denoted in Figure 4 as 1227. 1 surface mooring of a SIO/OSU meteorological buoy located near OWS Bravo site (deployed during 18HU96026) ; denoted in Figure 4 as Met. 1 profiling CTD mooring on AR7W section for WHOI (deployed during 18HU96026) ; denoted in Figure 4 as CTD. 1 profiling CTD system set by IMF-Kiel from the ship Validivia in July 1996; denoted in Figure 4 as K5. 2 IMF-Kiel tomographic moorings around the periphery of the Labrador Sea; denoted in Figure 4 as K1 and L0. 3 Transponder array around K1; denoted in Figure 4 as K1-T1, K1-T2 and K1-T3. 1 top of the WHOI moored vertical profiler (MVP) mooring was recovered. This was the surface instrumentation of the WHOI mooring recovered previously in the cruise. The top was recovered at the location denoted in Figure 4 as TOP. Figure 4. Mooring positions during Hudson 18HU97009/1. See text for label description. Deployed 1 (BIO number M1255) multi-instrument mooring was deployed near OWS Bravo on AR7W replacing the mooring M1226 set in 1996 (WOCE Expocode 18HU96026). The deployed mooring consisted of 6 Seacat temperature/conductivity recorders, 6 Aanderaa current meters, 1 acoustic doppler current profiler (ADCP), 1 WOTAN (weather observations through ambient noise) and 1 CTD with a device for measuring the total partial pressure of dissolved gas in the water; denoted in Figure 4 as 1255. 1 (BIO number M1256) mooring consisted of 1 current meter positioned 15 m off the bottom on the 1000 m isobath on the Labrador side of AR7W; denoted in Figure 4 as 1256. 3. List of Principal Investigators Name Affiliation Responsibility ---------------------------------------------------------------------------- Allyn Clarke BIO Senior scientist ClarkeA@mar.dfo-mpo.gc.ca Overall co-ordination Glenn Cota Old Dominion Univ Bio-Optical properties cota@ccpo.odu.edu of the upper ocean Russ Davis SIO Profiling ALACE floats davis@nemo.ucsd.edu John Smith BIO 129I, 137Cs smithj@mar.dfo-mpo.gc.ca Bob Gershey BDR Research Alkalinity, carbonate, CFCs rgershey@fox.nstn.ns.ca Glen Harrison BIO Coordinator biological HarrisonG@mar.dfo-mpo.gc.ca program nitrate and ammonium utilization by phytoplankton Erica Head BIO Macrozooplankton distribution, HeadE@mar.dfo-mpo.gc.ca abundance and metabolism Robert Houghton LDEO Oxygen isotopes Houghton@ldeo.columbia.edu Paul Kepkay BIO Dissolved organic carbon, KepkayP@mar.dfo-mpo.gc.ca colloid chemistry and plankton respiration Maurice Levasseur IML Dimethyl sulphide levasseur@dfo-mpo.gc.ca Peter Jones BIO Alkalinity, carbonate, CFCs JonesP@mar.dfo-mpo.gc.ca John R. N. Lazier BIO Oxygen, CTD data, LazierJ@mar.dfo-mpo.gc.ca moored instrument data Bill Li BIO Pico-plankton distribution LiB@maritimes.dfo.ca and abundance Mark Prater URI RAFOS floats and Sound Sources mark@seip.gso.uri.edu Peter Rhines UW Moored instrumentation data rhines@killer.ocean.washington.edu Peter Schlosser LDEO Helium, Tritium peters@ldeo.columbia.edu Uwe Send IFM Kiel Tomography mooring usend@ifm.uni-kie.de Peter Strain BIO Nutrients StrainP@mar.dfo-mpo.gc.ca John Toole WHOI CTD profiling mooring toole@whoi.edu See Section 7 for addresses. 4. Scientific Program and Methods 4.1 Physical - Chemical Program a. Narrative This cruise resulted in a complete physical and biological occupation of the Halifax section with all systems fully functioning. In the Labrador Sea, 3.5 of the planned hydrographic / tracer sampling sections (see Figure 5 for the planned sections) were completed, plus the longitudinal section that was occupied in November 1996 by Hudson (Expocode 18HU96026) and March 1997 by Knorr (Expocode 316N147/5). On this voyage the longitudinal section was extended northward to the 2000 metre isobath in Davis Strait. The quality of the CTD data is very good. The entire expedition was completed using the same two sensor sets, a new Seabird carousel unit, a new package frame and a new set of SIO bottles. This cruise will provide a good mapping of the waters sampled during the Knorr winter cruise and hence achieve our objective of locating the waters transformed during the 1996/97 winter cooling season. Our deployments of six ALACE floats and nine RAFOS floats along the inflow regions for the Labrador Sea should ensure a continued coverage of the Labrador Sea through the coming summer and fall seasons. The completed tracer program included sampling for He, tritium, 18O, 129I (denoted in the WOCE SUM file as parameter number 129), and 137Cs along AR7W and along the Greenland and Labrador shelves and slopes. Samples for the other tracers were collected and analyzed for nearly all the stations. All planned mooring operations were successfully completed. Six full depth moorings, three bottom-moored transponders, and a surface meteorological buoy were recovered and two current meter moorings were deployed. Unfortunately two of the current meters recovered had leaked so that our data recovery rate might be less than 100%. This cruise also allowed an extensive inter-comparison between a modified BIO oxygen titration system and a Scripps oxygen titration system. The precision of the two systems are identical, however, there is a small but significant offset between the systems. Since both systems were standardized using the same standards, the source of this offset is unknown. It is believed to have arisen from the various corrections that are applied by the Scripps system. A detailed comparison of the datasets originating from the two systems is carried out and reported in the oxygen section of this document. Figure 5. Initially planned lines L1 to L5. Refer to Figure 1 for actual cruise track. 4.2 Biological Program a. Narrative The objectives of the biological program of Hudson 97009 were two fold: * to provide a historical perspective on the large-scale distribution of the major plankton groups in the Labrador Sea for comparison with studies done in the mid-60's and mid 80's and * to provide new information on other important biogeochemical properties of the region as background for the proposed Phase III of Canadian JGOFS. Objective (1) will contribute to the debate about the link between northern fish stock declines and long-term changes in food chain structure; objective (2) will contribute to DFO's role in Canadian Climate Change research. 4.2.1 DMS (Maurice Levasseur) Our objectives were fourfold: * map the distribution of DMSP, DMS and DMSO in the upper 200 m of the Labrador Sea, * determine the distribution of DMSP in different particle size classes, * determine the bacterial net production rate of DMS and, * quantify the contribution of microzooplankton grazing to DMS production. The cruise has been successful and all objectives have been achieved. Samples have been collected at 48 stations providing a good coverage of the study area. More than 25 incubation experiments on bacterial and microzooplankton production of DMS have been performed. A total of 3,500 DMSP and DMS samples have been analyzed on board. Additional samples have been collected for nutrients, chlorophyll a, phytoplankton enumeration, and particulate carbon and nitrogen. These data will soon feed a coupled ocean-atmosphere model of DMS production currently developed at IML aiming to explore the potential role of ocean DMS production on climate. The highlight of the cruise has been the encounter of a Phaeocystis bloom in the Labrador Sea. Phaeocystis is known as a strong DMS producer in many parts of the world. This represented a unique opportunity to look at the dynamics of DMS production and the contribution of bacteria in such bloom. Overall, this cruise will provide the first extensive data set on DMS dynamics in cold waters including bacterial and zooplankton activity. 4.2.2 Primary Production Program (Jeff Anning) Profiles of the water column were collected at the stations listed in Table 1. Samples were drawn at 10 m intervals for chlorophyll, and nutrients at all these stations. At the stations where the biological pumping system was used (see Figure 6), water was also collected at two depths in the photic zone for Photosynthesis vs. Irradiance (P.I.) incubations. Date Station Cast Type ------------------------------- 05/09/97 HFX 1 2 CTD 05/09/97 HFX 2 3 CTD 05/10/97 HFX 3 4 CTD 05/10/97 HFX 4 5 CTD 05/10/97 HFX 5 6 CTD 05/10/97 HFX 6 7 CTD 05/10/97 HFX 7 8 CTD 05/11/97 LL 14 9 CTD 05/12/97 Cape Race 10 PUMP 05/13/97 BON 1 11 CTD 05/13/97 BON3 13 CTD 05/13/97 BON 6 16 PUMP 05/13/97 BON 9 19 CTD 05/14/07 BON 10 20 CTD 05/14/07 BON 11 21 CTD 05/14/07 BON 12 22 PUMP 05/14/07 BON 13 23 CTD 05/15/97 BON 16 26 PUMP 05/17/97 L5 16 33 PUMP 05/18/97 L5 20 37 PUMP 05/19/97 L5 23 40 PUMP 05/20/97 L5 27 42 PUMP 05/21/97 L3 27 44 CTD 05/21/97 L3 26 45 PUMP 05/22/97 L3 22 49 PUMP 05/22/97 L3 21 50 PUMP 05/23/97 L3 18 53 PUMP 05/28/97 L3 05 76 CTD 05/29/97 L2 B7 78 CTD 05/24/97 L3 16 57 PUMP 05/26/97 L3 12 67 PUMP 05/27/97 L3 08 73 PUMP 05/27/97 L3 07 74 CTD 05/29/97 L2 01 79 CTD 05/29/97 L2 02 80 PUMP 05/30/97 PHAEO 88 PUMP 05/31/97 L2 11 92 PUMP 05/31/97 L2 12 93 PUMP 06/01/97 L2 15 96 PUMP 06/01/97 L2 17 98 CTD 06/01/97 L2 18 99 CTD 06/02/97 L2 19 100 CTD 06/03/97 L6 16 103 PUMP 06/04/97 L6 11.5 108 PUMP 05/05/97 L6 07 111 PUMP 06/05/97 K1 T1 112 CTD 06/06/97 L6 04 114 PUMP 06/07/97 L6 01 119 PUMP 06/08/97 L4 08 123 PUMP 06/08/97 L4 05 126 CTD 06/09/97 L4 04 127 CTD 06/09/97 L4 03 128 CTD 06/09/97 L4 02 129 CTD 06/09/97 L4 01 130 CTD Figure 6. Biological pump locations for 18HU97009/1. 4.2.3 Sea Surface Monitoring System (Jeff Anning) See Part B, section 3 4.2.4 DOC Sampling (Jay Bugden) Samples for DOC profiles, size fractionation of DOC (ultrafiltration), and community respiration were collected. Twenty-two (22) stations (see Table 2) were sampled for ultrafiltration and respiration (lines BON, L2, L3, L5 and L6), and 12 stations were sampled for DOC profiles (line L3 or AR7W / WOCE). Ultrafiltration and rates of respiration for seawater samples were carried out at the time of sample collection - the ultrafiltration samples were frozen for laboratory analysis. The DOC profile samples were filtered and then frozen for laboratory analysis. Additional samples were collected for flow cytometry (38 stations) and phytoplankton identification (14 stations) (W. Li and P. Dickie, BOS, OSD) at various stations (see Table 1). The flow cytometry samples were frozen in liquid nitrogen and the phytoplankton samples were preserved with fixative and cold stored, for laboratory analysis. As well, samples for microzooplankton identification (17 stations) were collected at various stations from the biological pump (see Table 2). This was performed for a group from Newfoundland. The samples were preserved and stored cold for transportation to this group. Table 2. DOC and related sampling during 18HU97009/1. Station Date Respi Ultra Flow DOC Phyto Microzoo # -ration filtration Cytometry plankton plankton ----------------------------------------------------------------------- Hfx-1 9-5-97 X Hfx-2 9-5-97 X Hfx-3 10-5-97 X Hfx-4 10-5-97 X Hfx-5 10-5-97 X Hfx-6 10-5-97 X Hfx-7 10-5-97 X (Ship 10) 11-5-97 X Bon-6 13-5-97 X X X X Bon-12 14-5-97 X X X X Bon-16 15-5-97 X X X X L5-16 17-5-97 X X X X L5-20 18-5-97 X X X X L5-23 19-5-97 X X X X L5-27 20-5-97 X L3-27 21-5-97 X X L3-26 21-5-97 X X X X X X L3-25 21-5-97 X X L3-24 21-5-97 X X L3-22 22-5-97 X X X X X L3-21 22-5-97 X X X X X X L3-20 22-5-97 X X L3-18 23-5-97 X X X X X X L3-16 24-5-97 X X X X X X L3-14 25-5-97 X X X L3-13 26-5-97 X X L3-12 26-5-97 X X X X X X L3-11 26-5-97 X X L3-9 27-5-97 X X L3-8 27-5-97 X X X X X L3-7 27-5-97 X X L3-6 27-5-97 X X X L3-5 27-5-97 X X L2-2 29-5-97 X X X X L2-7 30-5-97 X L2-PH 30-5-97 X X X X X L2-11 31-5-97 X X X X L2-15 1-6-97 X X X X L6-16 3-6-97 X X L6-11.5 4-6-97 X X L6-7 5-6-97 X X L6-4 6-6-97 X X L6-1 7-6-97 X X 4.2.5 Radiometer and Spectrophotometer (Kurt Clemente) Satlantic Profiling Multichannel Radiometer Profiles of spectral light characteristics were taken at 28 stations (see Figure 7) from the surface to below 0.01% surface PAR (Photosynthetically Active Radiation) (in most cases >70 m). On 06 June the instrument developed problems not rectifiable on board and the last 4 stations were not sampled. Spectral profiles will be processed to calculate values of water-leaving radiance at 13 wavelengths. Two and three channel band ratios will be correlated with values of biomass and production in the Labrador Sea. Shimadzu Scanning Spectrophotometer Particulate (ap), non-pigmented (an) and dissolved (ad/as) absorption spectrum samples were taken at 33 stations from the biological pump, CTD and bucket samples. In most cases, depths sampled were 0, 10, 20 and 30 m. In certain instances where the fluorescence trace indicated a sinking bloom, as many as 8 depths were sampled. At two stations depth samples were duplicated to test precision of ap measurements. One station was chosen to test differences between surface sampling using the biological pump and bucket. Figure 7. Light meter stations during 18HU97009/1. Satlantic Sea WIFS Aircraft Simulator A 7 channel Ed sensor was deployed above the bridge before leaving port, and a corresponding 7 channel Lu sensor was placed on the starboard rail approximately 20 m behind the bow of the ship, fixed with two "C" clamps. The Ed sensor was aimed straight up and was reasonably free from shading. The Lu sensor was pointed at the water approximately 40( away from the ship. Soon after clearing Bedford Basin, it became obvious that the clamps did not secure the Lu sensor in even moderate weather. A hole was drilled in the base of the Lu mount and in the rail only 10m from the bow of the ship. This made the sensor more secure to weather and was more satisfactorily placed to "see" the water beyond the ships wake. The weather soon built, however, and a decision was reached with the Captain's consent to drill another hole in the rail above the bridge (near the Ed sensor) which would secure the Lu sensor in all but the most severe weather. Band ratio data from these two instruments will be used to calculate water- leaving radiance values, which will then be used to generate chlorophyll- predicting algorithms in a manner similar to the Profiling Radiometer. 4.2.6 Vertical Net Tows (Les Harris) A total of 167 vertical net tows were taken at 86 stations (see Figure 8) using a 3/4 metre 200 (m mesh ring net. At all of these stations tows from 100 - 0 metres were carried out, at 9 stations, additional deep tows were taken from depths between 400 and 2500 metres to the surface. Samples will be analyzed for species composition, copepod stage distribution and biomass. Water Column Sampling At 18 stations water was collected at the chlorophyll maximum and size fractionated at 3 (m. The fractions were then filtered to collect samples for HPLC pigments and particulate carbon and nitrogen. These samples were collected in order to assess the phytoplankton composition and the proportion of the total particulate matter that would be available for copepod grazing. Measurements of Copepod Metabolic Rates Respiration rates (CO2 production) of the copepod communities were determined at 8 stations. 4.2.7 Egg Production Rates and Hatching Success of Calanus finmarchicus (Rob Campbell) Egg Production Rates Female C. finmarchicus were collected with vertical net tows (200 (m mesh) from 0 - 75 m (daylight hours) or 0 - 50 m (at night). Subsamples of 30 females were incubated individually in 50 ml Petri dishes at approximate ambient temperatures for 24h, and the number of eggs produced in that time counted. The size of clutches produced by each female and the frequency of spawning events (inferred from the number of females who spawned over the incubation period) will be used to calculate egg production rates. Hatching Success In order to test the hypothesis that certain diatom species reduce the hatching success of copepod eggs; eggs collected from the egg production experiments above were incubated for 72 hours in one of three treatments. The experiments were: (1) filtered salt water, (2) water taken from the depth of the chlorophyll maximum, and (3) a concentrated culture of Thalassiosira sp. (a diatom species which may contain a compound which inhibits the development of copepod eggs). Hatching success (% hatching) will be determined by comparing the initial number of eggs in each treatment to the number of unhatched eggs after the 72 hour incubation period. Figure 8. Net tow locations during 18HU97009/1. 5. Major Problems and Goals Not Achieved The inshore station denoted Site 28 on the Greenland side and inshore stations denoted Sites 4 to 1 on the Labrador side of AR7W were missed because of ice conditions. A station was missed off Cape Farewell because of strong and persistent winds. 6. Other Incidents of Note This was a remarkably problem free voyage from the point of view of the scientific party once we got to sea. Intensive use of the GeoChem laboratory was made during this trip. Before departing BIO, the fume hood in the lab failed its inspection and it was only after considerable bureaucratic effort that a temporary modification was made and a certificate was issued. The odour problem in the lab is less than it has been but still exists. Taping over all of the scuppers solved the problem. This was acceptable because the lab was being used as a dry chemical analysis laboratory. The laser printer connected to the MicroVAX failed during this trip. There was no spare to replace this unit. But two other printers brought on board by the science programs we were able to replace its functions. This unit will be repaired on return to BIO and perhaps a spare unit should be placed on board as well. There was also considerable difficulty with the EXABYTE units on the MicroVAX. The MicroVAX computers are completely obsolete and are only being used as file storage devices. Unfortunately, we are losing our ability to manage this relatively complicated operating system when something goes wrong. It is past due that a modern computer with an operating system that is in common use in the region (i.e. UNIX or NT) should replace these systems. The transducers on the ram were lost (and perhaps the ram itself) in the last week of operations. Fortunately the intensive use of this facility was complete by this time and the weather conditions were such that we were able to complete our deep CTD casts using the hull transducers. The navigation logging PC experienced unknown problems on June 9 (day 160) that resulted in a navigation data gap of about 23 hours, between June 9 and 10, 1997. However, it may be possible to retrieve this data from the ADCP data stream, which merges the velocity data with the navigation data in real-time. This problem resulted in no position for June 10 at 0000Z in Figure 1. Date and times incorporated into the header of the CTD files are obtained from two sources: the PC clock running the acquisition software and the GPS strings. The date/time strings from the PC clock were noted to have an inconsistent offset from GMT. Some casts had the correct time in GMT, while others were off by -3 hours or +3 hours. To correct this problem, all CTD cast times were corrected to the independent time noted in the Station Summary file (WOCE SUM file). The UTC string contained within the header of the original Seabird DAT file can be used as a check on the start_date_time parameter within the ODF file. 7. List of Cruise Participants Name Responsibility Affiliation --------------------------------------------------------------------- Jeff Anning Biological Underway Sampling BIO Larry Bellefontaine Watchkeeper BIO Rene Bouillon DMS IML Rick Boyce Salts, Moorings BIO Jay Bugden DOC Levels BIO Rob Campbell Net Tows Dal Guy Cantin DMS IML Allyn Clarke Chief Scientist BIO Kurt Clemente Ocean optics ODU Pierre Clement Nutrients/Oxygen BIO Bob Gershey CFC/Alkalinity/Carbonate BDR Research Les Harris Net Tows BIO Michael Hingston CFC/Alkalinity/Carbonate BDR Research Detlef Kindler Moorings/Watchkeeper IFM Anthony Isenor Data Quality/Watchkeeper BIO Maurice Levasseur Assistant Scientist, DMS IML Sonya Michaud DMS IML Manon Poliquin Oxygen Polytech Sci. Ser. Bob Ryan Technician, CTD BIO Sabina Schultes DMS IML Rochelle Ugstad Helium/Tritium LDEO Gordan Wolfe DMS IML Igor Yashayaev Scientist BIO BIO Bedford Institute of Oceanography PO Box 1006 Dartmouth, NS, B2Y 2A4 BDR BDR Research Ltd. Box 652, Station 'M' Halifax, N.S., IFM-Kiel Institut für Meereskunde an der Universität Kiel Düsternbrooker Weg 20 D-24105 Kiel, Germany IML Institute Maurice-Lamontagne C.P. 1000 850 Route de la Mer Monti Joli, P.Q. G5H 3Z4 IOS-Pat Bay Institute of Ocean Sciences P.O. Box 6000 Sidney, B.C., V8L 4B2 LDEO Lamont -Doherty Geological Observatory Columbia University Palisades, New York 10964 SIO Scripps Institute of Oceanography University of California at San Diego La Jolla, CA 92093 ODU CCPO Old Dominion University Norfolk, VA 23529 USA URI University of Rhode Island Narragansett Marine Lab South Ferry Road, Narragansett Rhode Island 02882 UW University of Washington Seattle, WA 98195 WHOI Woods Hole Oceanographic Institution Woods Hole, MA 02543 B. UNDERWAY MEASUREMENTS 1. Navigation and Bathymetry (Anthony W. Isenor) The navigation system onboard CCGS Hudson consisted of a Trimble Navigation Loran-GPS 10X decoder and AGCNAV software. AGCNAV is a PC based display, and waypoint setting software package developed at the Atlantic Geoscience Centre at BIO. This software graphically displayed the ship position, waypoints, course, speed, etc. to the various science working areas. The 10X decoder received the satellite fixes and decoded the signals to obtain NMEA strings (containing latitude, longitude, time, etc.) that were sent to a bridge PC running the AGCNAV software in master mode. The bridge PC then broadcasted the NMEA strings over the ships network, to be accessed by other PCs running AGCNAV in slave mode. These NMEA strings were broadcast at about 1 Hz. The navigation data were logged at one minute intervals on a dedicated logging PC. The echo sounder system used for collecting bathymetric data consisted of a Raytheon Line Scan Recorder, Model LSR 1811-2 (serial number A117) connected to a hull mounted 12kHz transducer. The transducer beam width was 15 degrees. The sweep rate of the recorder was adjusted throughout the course of data collection to aid in identifying the bottom signal. The recorder was also linked to a clock, and thus could indicate 5 minute intervals on the sounder paper. The system was used to collect bathymetric soundings at 5 minute intervals while underway between stations. Approximately 5500 kilometres of deep sea bathymetric sounding data was collected. 2. Acoustic Doppler Current Profiler (Bob Ryan) The Hudson was equipped with a hull mounted RDI Acoustic Doppler Current Profiler (ADCP). The transducer (serial number 177) had SC ADCP electronics (serial number 607) converted for ship board use. Logging, using Transect software on a HP Vectra 486 PC running Windows 95, was started on May 9, 1997 at 1545Z in Bedford Basin. The configuration of the equipment resulted in a bin length of 4 metres and a total of 128 bins. The raw data were stored to disk and backed up every few days to writable CD. The data were also averaged in real-time over 5 minute intervals, except along the Scotian Shelf Halifax Line where the averaging was every 2 minutes. ADCP logging was stopped on June 10, 1997 at 1510Z. In total, 750 hours of along track ADCP data was collected 3. Sea Surface Monitoring System (Jeff Anning) Water from approximately 4 m was pumped continuously up to the forward lab. The temperature, conductivity and fluorescence of this flow was continuously measured and logged every 30 seconds. The temperature and conductivity were measured with Seabird sensors and the fluorescence by a Wetlabs flowthrough fluorometer. Incident downward irradiance (Photosynthetically Active Radiation, or PAR) was measured with a Biospherical PAR sensor and the data merged with the sea water parameters. Exact positions were logged at the same time from a Northstar GPS. In total, 800 hours of along track surface temperature, salinity, chlorophyll and nutrient data was collected. Discrete water samples were collected every 15 minutes by an auto sampler for later analysis for phosphate, nitrate and silicate. A NAS 2E nitrate analyser was incorporated into the flowthrough system. Nitrate concentration was measured every 15 minutes. However the sensors performance was erratic and unreliable. In the Hudson's GP lab, a second set of conductivity, temperature and fluorescence sensors were employed in the ship's transducer well. This conductivity cell failed early in the cruise yielding very little useful data. 4. XBT and XCTD No probes were used 5. Meteorological observations The ship's crew carried out routine reporting of meteorological variables. 6. Atmospheric Chemistry There was no atmospheric chemistry programme. C. HYDROGRAPHIC MEASUREMENTS DESCRIPTIONS, TECHNIQUES AND CALIBRATIONS 1. CTD Measurements (Igor Yashayaev and Anthony Isenor) a. Description of the Equipment and technique The CTD measurements were made with a standard SEABIRD model 11 Plus deck unit (S/N 11P7032-0268) and a model 9 Plus CTD probe (S/N 09P15349-0475) equipped with a paroscientific digiquartz model 410K-105 pressure sensor (S/N 69009). This probe was replaced on station 107 due to a malfunction. The replacement probe (S/N 09P7356-0289) had a new pressure sensor (S/N 51403). There were also two temperature sensors (primary S/N 03P2298 and secondary S/N 03P2303), two conductivity sensors (primary S/N 041873 and secondary S/N 041874), two model 13-02 dissolved oxygen sensors (primary S/N 130265 and secondary S/N 130266) and a Chelsea fluorometer (S/N 088172) used. All sensors except the pressure sensor were mounted in one of two ducts through which separate pumps pulled seawater. Hence, the water flow past the actual sensors was independent of the lowering rate; this simplified the data processing considerably. The Seabird CTD was mounted vertically within a custom designed and built CTD/Rosette frame. All the pressure cases as well as the sample bottles are mounted vertically to improve the package's stability as it descends through the water column. In the centre of the frame is an aluminum tube, which contains at its upper end a Seabird Carousel 24 bottle rosette unit. The frame itself is subdivided into four quadriants. In one quadriant is a RDI 150 khz Broadband ADCP in a shortened pressure case. In the next quadriant is the pressure case for the Seabird CTD and directly below the CTD probe is a Benthos altimeter. The third quadriant contains the battery pack for the LADCP, the fluorometer and a General Oceanics model 6000 12 Khz pinger unit. The last quadriant contains the dual CTD sensors and pump. One unique aspect of this frame is the adjustable legs. The base of the frame is circular with six vertical tubes, or legs, extending upward from the base. These legs end, and can slide within, a slightly larger tube at the base of a second circular frame. Each vertical leg has two fixed positions within the larger tube, and is held in these positions by stainless steel pins. In the deployment position, the legs are retracted. When personnel are drawing water samples, the legs are extended thus raising the frame by about 40 cm. This makes drawing the water samples much easier. The rosette bottles were made by the Physical and Chemical Oceanographic Data Facility of the Scripps Institution of Oceanography (SIO). Each bottle collects 10 litres of water. b. Sampling Procedure and data processing techniques The CTD was deployed with a lowering rate of 60 metres/min (40 metres/min in the upper 200 metres or deeper if the conditions were rough). It was recovered at a rate of 75 metres/min (60 metres/min when deeper than 4000 metres or when conditions were rough). The CTD data was recorded onto disk by a 486 computer using SEABIRD SEASOFT Version 4.205 software. A screen display of temperature, oxygen and salinity profiles vs pressure was used to decide bottle trip locations on the up cast. The bottles were tripped using the enable and fire buttons on the SEABIRD deck unit. At the end of each station, the SEASAVE software was used to create 1 and 2 dbar processed data files, an IGOSS TESAC message and a processed rosette trip file. All the raw and processed data files associated with the station were then transferred to the ship's MicroVAX computer for archive and subsequent access and distribution to various users on the vessel. The data processing takes the following steps: DATCNV Converted the raw data to physical parameters. SPLIT Split the data into DOWN and UP cast. WILDEDIT This program took consecutive blocks of 12 scans and flagged all scans whose pressure, temperature and conductivity values differed from the mean by more than 2 standard deviations. Then the mean and standard deviation were recomputed using the unflagged data and all scans exceeding 4 standard deviations from this new mean were marked as bad. FILTER Low pass filtered pressure and conductivity channels. Time constant used for conductivity was 0.045 seconds, for pressure 0.150 seconds. LOOPEDIT Marked as bad, all cycles on the down trace for which the vertical velocity of the CTD unit was less than 0.1 meters/sec. ALIGNCTD Aligned the temperature, conductivity and oxygen values relative to the pressure values to account for the time delays in the system. The time offsets for the primary sensors were 0.010 seconds for conductivity, 0.000 seconds for temperature and 3.000 seconds for oxygen. The time offsets for the secondary sensors were 0.083 seconds for conductivity, 0.000 seconds for temperature and 3.000 seconds for oxygen (NOTE: the primary conductivity was adjusted by 0.073 seconds in the Deck unit while the secondary conductivity was not adjusted in the Deck unit). CELLTM A recursive filter was used to remove the thermal mass effects from the conductivity data. Thermal anomaly amplitude and time constants of 0.0300 and 9.0000 were used. DERIVE Computed oxygen values. BINAVG Averaged the down cast into 1 and 2 dbar pressure bins. DERIVE Computed salinity, potential temperature and sigma-theta. ROSSUM Averaged 3 seconds of CTD data after every bottle trip. Used in comparison with water sample data. c. Calibration data The CTD calibrations used during this cruise were supplied by Seabird Electronics. The applied calibrations are as follows: BIO Seabird CTD Probes Pressure Sensor (69009) pressure = c (1 - To2/T2) (1 - d[1 - To2/T2]) (psia) where T is the pressure period c = c1 + c2 U + c3 U2 d = d1 + d2 U To = T1 + T2 U + T3 U2 + T4 U3 + T5 U4 U is the temperature c1 = -5.396574 E+04 psia c2 = -1.03726 E-01 psia/°C c3 = 1.54367 E-02 psia/°C2 d1 = 3.8800 E-02 d2 = 0 T1 = 2.985151 E+01 (sec T2 = -3.76105 E-04 (sec/°C T3 = 3.76392 E-06 (sec/°C2 T4 = 3.18753 E-09 (sec/°C3 T5 = 0 AD590M = 1.28164 E-02 AD590B = -9.1487184 E+00 slope = 1.0, offset = 0.0 (Seabird calibration dated Feb. 26, 1997) Pressure Sensor (51403) pressure = c (1 - To2/T2) (1 - d[1 - To2/T2]) (psia) where T is the pressure period c = c1 + c2 U + c3 U2 d = d1 + d2 U To = T1 + T2 U + T3 U2 + T4 U3 + T5 U4 U is the temperature c1 = -3.862588 E+04 psia c2 = 2.78422 E-01 psia/°C c3 = 1.40578 E-02 psia/°C2 d1 = 3.8824 E-02 d2 = 0 T1 = 3.062824 E+01 (sec T2 = -1.73280 E-04 (sec/°C T3 = 4.72380 E-06 (sec/°C2 T4 = 3.33300 E-09 (sec/°C3 T5 = 0 AD590M = 1.14200 E-02 AD590B = -9.1170000 E+00 slope = 1.0, offset = 0.0 (Seabird calibration dated Feb. 26, 1997) BIO SEABIRD System # 9 Sensors Temperature Sensor (3P2298) T = 1/{a + b[ln(fo/f)] + c[ln2[fo/f] + d[ln3(fo/f)]} - 273.15 (°C) where ln indicates a natural logarithm, f is the frequency (Seabird calibration Feb. 20, 1997) a = 3.68023488 E-03 b = 6.00208161 E-04 c = 1.62157135 E-05 d = 2.22368203 E-06 fo = 2917.298 slope = 0.99998, offset = 0.0 (Calculated in March 1997) Tpcor = -2.060 E-07 (recommended by Seabird on Feb. 26, 1997) Conductivity Sensor (041873) conductivity = (g + hf2 + if3 + jf4)/[10(1 + {CTcor t} + {CPcor p})] (Siemens/m) where f is the frequency, p is pressure in dbar, t is the temperature in deg C (Seabird Calibration dated Feb. 21 1997) g = -4.13982358 E+00 h = 5.40882425 E-01 i = -8.15812766 E-04 j = 6.91367207 E-05 CPcor = -1.00 E-07 CTcor = 3.25 E-06 Slope = 1.000115 (Calculated March 1997) Offset = -0.00005 (Calculated May 25, 2000) BIO SEABIRD System # 10 Sensors Temperature Sensor (3P2303) T = 1/{a + b[ln(fo/f)] + c[ln2[fo/f] + d[ln3(fo/f)]} - 273.15 (°C) where ln indicates a natural logarithm, f is the frequency (Seabird calibration Feb. 20, 1997) a = 3.68023493 E-03 b = 5.98790237 E-04 c = 1.58353945 E-05 d = 2.23034109 E-06 fo = 2896.266 slope = 1.0, offset = -0.0005 (Calibration dated March 1997) Conductivity Sensor (041874) conductivity = (g + hf2 + if3 + jf4)/[10(1 + {CTcor t} + {CPcor p})] (Siemens/m) where f is the frequency, p is pressure (decibars), t is the temperature (°C) (Seabird Calibration dated Feb. 21 1997) g = -4.08770679 E+00 h = 5.15866320 E-01 i = -1.06080083 E-03 j = 7.93277368 E-05 CPcor = -1.00 E-07 CTcor = 3.25 E-06 Slope = 1.000113 (Calculated March 1997) Offset = 0.00011 (Calculated May 25, 2000) Oxygen Sensor (130265) Oxygen = (see PDF) where Seabird Calibration dated Feb. 12, 1992. Soc, Boc, tcor and pcor were produced from a calibration performed on Jan. 25, 2001. Soc = 3.2020 oc is the oxygen sensor current ((amps) oc = mV + b m = 2.4608 E-07 V is the oxygen temperature sensor voltage signal b = -4.9216 E-10 tau = 2.0 doc/dt is the time derivative of oc Boc = -0.0080 OXSAT is the oxygen saturation value dependent on T and S T is the water temperature (°C) S is salinity (psu) e is natural log base tcor = -0.036 wt = 0.670 To oxygen sensor internal temperature (°C) To = kV + c k = 8.9939 c = -6.8210 pcor = 1.39 E-04 P is the pressure (psia) Oxygen Sensor (130266) Oxygen = where Seabird Calibration dated Feb. 12, 1992. Soc, Boc, tcor and pcor were produced from a calibration performed on Jan. 25, 2001. Soc = 2.8330 oc is the oxygen sensor current ((amps) oc = mV + b m = 2.4692 E-07 V is the oxygen temperature sensor voltage signal b = -4.1977 E-10 tau = 2.0 is the time derivative of oc Boc = 0.0480 OXSAT is the oxygen saturation value dependent on T and S T is the water temperature (°C) S is salinity (psu) e is natural log base tcor = -0.041 wt = 0.670 To oxygen sensor internal temperature (°C) To = kV + c k = 8.9883 c = -7.0715 pcor = 1.27 E-04 (Calculated Jan. 25, 2001) P is the pressure (psia) Chelsea Fluorometer (088172) concentration [µg/l] = slope * (10 exp (V/sf) - 10 exp (VB) ) / (10 exp (V1µg/l) - 10 exp (Vacetone) ) + offset where Seabird Calibration dated Feb. 10, 1997. slope = 1.0 V (fluorometer output voltage in-situ) sf (scale factor ) = 1.0 VB (electrical zero) = 0.212 V1(fluorometer output voltage at 1 µg/l) = 1.974 Vacetone (fluorometer output voltage at zero chlorophyll) = 0.334 offset = 0.0 2. Salinity (Rick Boyce) a. Description of Equipment and Technique Salinity samples were analyzed using a Guildline Autosal model 8400B s/n 60968 salinometer. Samples were drawn into 150 ml medicine bottles. New caps, equipped with plastic liners, were placed on the sample bottles for each use. The caps were retightened when the samples reached room temperature. The salinometer cell was filled and rinsed three times with sample water before readings were recorded. Readings from the salinometer were recorded for every sample and standardization. The reading entered into the water sample database as the conductivity of the water sample represents the operators best determination of the conductivity of the sample. b. Sampling Procedure and Data Processing Technique Salinity samples were drawn into 150 ml medicine bottles after three rinses. The bottles were filled up to the shoulders and then capped with new caps with plastic liners. One conductivity file for the entire cruise was prepared. The file consisted of a sequential record number, the bath temperature, sample ID number, average conductivity ratio and a quality flag. A PC based program running under a commercial DBMS computed the salinity using the average conductivity ratio and the standard IAPSO formula. Any changes in the salinometer readings between successive standardizations were assumed to have occurred as a linear drift of the instrument. Thus, the program applied a correction to the ratios, which varied linearly with the samples analyzed. The salinity data was then placed in the water sample database. c. Laboratory and Sample Temperatures Full cases of samples were taken from the winch room to the GP lab where they were left for a period of at least 10 hours to equilibrate to laboratory temperature before being analyzed. The bath in the salinometer was kept at 21°C. d. Replicate Analysis One or two replicate salinity samples were drawn from one of the rosette bottles on every cast. In some cases, one or two samples from some of the bottles were analyzed within normal time frame (12-24 hours), while other replicate samples were stored in the laboratory until the last week of the cruise before being analyzed. The following is a list of the number of sample id numbers that had replicate samples and when the samples were analyzed: * 87 ids had two normal samples and no later samples * 12 ids had two normal samples and 1 later sample * 154 ids had one normal sample and one later sample * 1 id had one normal sample and 2 later samples Thus, there were: 87 + 12 = 99 normal - normal replicate differences (12 * 2) + 154 + (1 * 2) = 180 normal - later replicate differences The statistics of the normal - normal differences are as follows: Statistic Value -------------------------- Number of Points 99 Minimum 0.000 Maximum 0.1893 Mean 0.0032 Median 0.0004 Standard Deviation 0.0199 The later replicate values will be compared with the samples analyzed previously to determine the magnitude of instrument or standard drift during the cruise. Statistics of the (normal - later) replicate differences follow. Statistic Value -------------------------- Number of Points 180 Minimum -0.0147 Maximum 0.0831 Mean 0.0008 Median 0.0006 Standard Deviation 0.0067 Only acceptable values were used in calculating the replicate differences. All of the replicate sample values and their quality flags are listed in Table C.2 below. e. Standards Used The salinometer was standardized on May 11, 1997 using IAPSO standard water, Batch P129, prepared on November 22, 1995. During subsequent standardizations on May 11th and May 14th, the standardize dial of the Autosal was adjusted to force the salinometer to read the conductivity ratio of the new ampoules of standard seawater. However, it was determined later that a few ampoules of standard seawater must have been contaminated as the Autosal readings of some standards varied by more than what could be accounted for by the usual drift of the Autosal. At this point it was decided to not adjust the standardize dial when a new standard was used. The conductivity ratio of the Autosal was simply recorded for each new ampoule and then seawater samples were run. This way any contaminated standards could be immediately identified and discarded. Standards were run at the beginning and end of every 32 bottle case. Sample WOCE ID Number Salinity QF ----------------------------- 186050 32.3393 2 186050 32.3387 2 186132 32.6810 2 186132 32.7409 2 186144 31.9321 2 186144 31.9322 2 186150 32.9709 2 186150 32.9700 2 186241 34.7732 2 186241 34.7738 2 186266 34.6060 2 186266 34.6062 2 186298 34.8556 2 186298 34.8564 2 186319 34.8823 2 186319 34.8819 2 186340 34.8859 2 186340 34.8859 2 186373 34.8048 2 186373 34.8056 2 186411 34.9167 2 186411 34.9171 2 186430 34.8786 2 186430 34.8784 2 186432 34.8961 2 186432 34.8965 2 186446 34.7897 2 186446 34.7900 2 186456 34.9010 2 186456 34.9010 2 186493 34.9002 2 186493 34.9000 2 186523 34.9037 2 186523 34.9035 2 186543 34.9197 2 186543 34.9199 2 186606 34.9357 2 186606 34.9359 2 186633 34.9112 2 186633 34.9110 2 186657 34.9120 2 186657 34.9122 2 186693 34.9232 2 186693 34.9274 2 186714 34.9018 2 186714 34.9018 2 186741 34.9263 2 186741 34.9242 2 186780 34.9193 2 186780 34.9193 2 186804 34.8980 2 186804 34.8980 2 186827 33.2511 2 186827 33.2515 2 186845 34.8906 2 186845 34.8902 2 186857 34.3535 2 186857 34.3541 2 186880 34.8664 2 186880 34.8666 2 186910 34.8605 2 186910 34.8607 2 186931 34.8666 2 186931 34.8670 2 186954 34.8592 2 186954 34.8594 2 186974 34.9051 2 186974 34.9075 2 187018 34.8669 2 187018 34.8671 2 187045 34.8305 2 187045 34.8309 2 187065 34.8448 2 187065 34.8452 2 187099 34.9085 2 187099 34.9077 2 187124 34.9035 2 187124 34.9047 2 187171 34.9053 2 187171 34.9055 2 187215 34.8451 2 187215 34.8451 2 187229 34.8800 2 187229 34.8827 2 187279 34.8498 2 187279 34.8506 2 187312 34.8985 2 187312 34.9049 2 187339 34.8531 2 187339 34.8537 2 187361 34.8674 2 187361 34.8672 2 187373 34.8813 2 187373 34.8845 2 187403 34.8305 2 187403 34.8311 2 187413 34.7200 2 187413 34.7213 2 187434 34.1063 2 187434 34.1065 2 187439 33.7955 2 187439 33.7959 2 187453 33.8022 2 187453 33.8028 2 187468 34.4790 2 187468 34.4796 2 187490 34.8285 2 187490 34.8279 2 187516 34.8870 2 187516 34.8872 2 187531 34.9020 2 187531 34.9024 2 187554 34.8495 2 187554 34.8495 2 187575 34.9031 2 187575 34.9035 2 187596 34.8906 2 187596 34.8912 2 187642 34.9008 2 187642 34.9010 2 187670 34.8472 2 187670 34.8472 2 187705 34.7563 2 187705 34.5670 2 187718 34.8574 2 187718 34.8576 2 187736 34.9085 2 187736 34.9096 2 187767 34.8507 2 187767 34.8507 2 187779 34.8892 2 187779 34.8892 2 187818 34.8391 2 187818 34.8391 2 187830 34.9002 2 187830 34.9008 2 187857 34.8923 2 187857 34.8908 2 187877 34.9143 2 187877 34.9143 2 187893 33.5569 2 187893 33.5579 2 187908 34.8770 2 187908 34.8774 2 187909 34.8650 2 187909 34.8647 2 187909 34.8640 2 187910 34.8739 2 187910 34.8728 2 187911 34.8823 2 187911 34.8827 2 187912 34.8880 2 187912 34.8882 2 187913 34.8878 2 187913 34.8884 2 187915 34.8513 2 187915 34.8509 2 187916 34.8302 2 187916 34.8307 2 187922 34.8943 2 187922 34.8951 2 187923 34.8907 2 187923 34.8914 2 187924 34.8836 2 187924 34.8851 2 187926 34.8617 2 187926 34.8619 2 187927 34.8733 2 187927 34.8593 2 187927 34.8599 2 187928 34.8642 2 187928 34.8649 2 187929 34.8736 2 187929 34.8739 2 187931 34.8870 2 187931 34.8872 2 187940 34.8939 2 187940 34.8931 2 187942 34.8971 2 187942 34.8970 2 187944 34.9009 2 187944 34.9022 2 187945 34.8993 2 187945 34.9018 2 187946 34.8973 2 187946 34.8976 2 187946 34.8952 2 187947 34.8878 2 187947 34.8869 2 187948 34.8653 2 187948 34.8668 2 187950 34.8679 2 187950 34.8682 2 187964 34.8949 2 187964 34.8941 2 187966 34.9020 2 187966 34.8999 2 187968 34.9006 2 187968 34.9101 2 187969 34.8973 2 187969 34.8999 2 187970 34.8912 2 187970 34.8908 2 187971 34.8765 2 187971 34.8768 2 187973 34.8552 2 187973 34.8556 2 187974 34.8635 2 187974 34.8639 2 187974 34.8641 2 187988 34.8910 2 187988 34.8914 2 187990 34.8998 2 187990 34.8998 2 187990 34.9020 2 187992 34.9042 2 187992 34.9045 2 187993 34.9018 2 187993 34.9009 2 187994 34.8977 2 187994 34.8978 2 187995 34.8886 2 187995 34.8894 2 187997 34.8511 2 187997 34.8513 2 187998 34.8588 2 187998 34.8584 2 188011 34.8898 2 188011 34.8897 2 188013 34.7974 2 188013 34.8806 2 188014 34.9079 2 188014 34.9083 2 188015 34.9071 2 188015 34.9049 2 188016 34.9008 2 188016 34.9020 2 188017 34.8944 2 188017 34.8961 2 188018 34.8842 2 188018 34.8843 2 188020 34.8525 2 188020 34.8512 2 188021 34.8599 2 188021 34.8590 2 188034 34.8880 2 188034 34.8890 2 188036 34.8924 2 188036 34.8931 2 188037 34.9000 2 188037 34.8998 2 188038 34.9048 2 188038 34.9053 2 188039 34.9049 2 188039 34.9109 2 188040 34.9025 2 188040 34.9026 2 188041 34.8940 2 188041 34.8965 2 188043 34.8615 2 188043 34.8614 2 188044 34.8516 2 188044 34.8521 2 188064 34.8854 2 188064 34.8861 2 188065 34.8893 2 188065 34.8902 2 188068 34.9045 2 188068 34.9062 2 188069 34.9074 2 188069 34.9071 2 188070 34.9004 2 188070 34.9010 2 188071 34.8945 2 188071 34.8957 2 188073 34.8474 2 188073 34.8474 2 188074 34.8471 2 188074 34.8472 2 188074 34.8480 2 188075 34.8554 2 188075 34.8556 2 188088 34.8863 2 188088 34.8859 2 188090 34.8985 2 188090 34.8994 2 188092 34.9081 2 188092 34.9086 2 188093 34.9055 2 188093 34.9069 2 188094 34.9001 2 188094 34.8990 2 188095 34.8882 2 188095 34.8879 2 188097 34.8531 2 188097 34.8537 2 188097 34.8539 2 188098 34.8442 2 188098 34.8485 2 188112 34.8890 2 188112 34.8912 2 188114 34.8947 2 188114 34.8938 2 188115 34.9033 2 188115 34.9035 2 188116 34.9089 2 188116 34.9094 2 188117 34.9045 2 188117 34.9048 2 188118 34.8970 2 188118 34.8971 2 188119 34.8788 2 188119 34.8794 2 188120 34.8456 2 188120 34.8464 2 188122 34.8504 2 188122 34.8513 2 188136 34.8898 2 188136 34.8881 2 188137 34.8896 2 188137 34.8896 2 188138 34.8921 2 188138 34.8931 2 188140 34.9101 2 188140 34.9100 2 188141 34.9208 2 188141 34.9204 2 188142 34.9189 2 188142 34.9197 2 188143 34.9098 2 188143 34.9199 2 188145 34.8789 2 188145 34.8786 2 188146 34.8483 2 188146 34.8505 2 188161 34.7106 2 188161 34.7106 2 188171 34.8874 2 188171 34.8965 2 188172 34.8908 2 188172 34.8904 2 188173 34.8945 2 188173 34.8945 2 188175 34.9098 2 188175 34.9102 2 188176 34.9128 2 188176 34.9132 2 188177 34.9051 2 188177 34.9028 2 188178 34.8975 2 188178 34.9122 2 188180 34.8569 2 188180 34.8582 2 188181 34.8429 2 188181 34.8433 2 188195 34.8890 2 188195 34.8884 2 188197 34.8969 2 188197 34.8955 2 188199 34.9000 2 188199 34.9002 2 188200 34.9064 2 188200 34.9071 2 188201 34.9179 2 188201 34.9163 2 188202 34.9100 2 188202 34.9116 2 188204 34.8794 2 188204 34.8812 2 188205 34.8441 2 188205 34.8458 2 188207 34.8505 2 188207 34.8505 2 188219 34.8819 2 188219 34.8809 2 188221 34.8827 2 188221 34.8829 2 188223 34.9009 2 188223 34.9018 2 188224 34.9119 2 188224 34.9085 2 188225 34.9124 2 188225 34.9149 2 188226 34.9045 2 188226 34.9124 2 188227 34.9006 2 188227 34.9008 2 188228 34.8856 2 188228 34.8865 2 188229 34.8581 2 188229 34.8590 2 188243 34.8761 2 188243 34.8762 2 188245 34.8918 2 188245 34.8927 2 188247 34.9093 2 188247 34.9110 2 188248 34.9173 2 188248 34.9177 2 188249 34.9265 2 188249 34.9239 2 188250 34.9219 2 188250 34.9244 2 188252 34.9005 2 188252 34.9016 2 188253 34.8742 2 188253 34.8751 2 188253 34.8749 2 188267 34.8857 2 188267 34.8873 2 188269 34.8927 2 188269 34.8941 2 188271 34.9094 2 188271 34.9093 2 188272 34.9169 2 188272 34.9171 2 188273 34.9216 2 188273 34.9242 2 188274 34.9177 2 188274 34.9179 2 188274 34.9184 2 188276 34.8862 2 188276 34.8867 2 188277 34.8586 2 188277 34.8607 2 188291 34.8758 2 188291 34.8762 2 188293 34.8920 2 188293 34.8920 2 188295 34.9086 2 188295 34.9100 2 188296 34.9177 2 188296 34.9163 2 188297 34.9195 2 188297 34.9210 2 188298 34.9151 2 188298 34.9165 2 188300 34.8497 2 188300 34.8503 2 188301 34.8405 2 188301 34.8419 2 188302 34.8399 2 188302 34.8399 2 188315 34.8745 2 188315 34.8768 2 188317 34.8859 2 188317 34.8876 2 188317 34.8878 2 188319 34.9045 2 188319 34.9067 2 188320 34.9096 2 188320 34.9134 2 188321 34.9189 2 188321 34.9208 2 188322 34.9220 2 188322 34.9224 2 188324 34.9057 2 188324 34.9061 2 188325 34.8886 2 188325 34.8904 2 188341 34.8851 2 188341 34.8859 2 188343 34.8998 2 188343 34.9016 2 188344 34.9085 2 188344 34.9069 2 188345 34.9098 2 188345 34.9102 2 188346 34.9104 2 188346 34.9088 2 188346 34.9098 2 188348 34.8980 2 188348 34.8951 2 188349 34.8660 2 188349 34.8662 2 188363 34.8861 2 188363 34.8868 2 188365 34.8890 2 188365 34.8898 2 188365 34.8874 2 188367 34.9031 2 188367 34.9008 2 188368 34.9061 2 188368 34.9069 2 188369 34.8986 2 188369 34.9045 2 188370 34.8918 2 188370 34.8902 2 188372 34.8523 2 188372 34.8499 2 188373 34.8499 2 188373 34.8507 2 188387 34.9012 2 188387 34.9014 2 188389 34.9014 2 188389 34.9002 2 188391 34.9077 2 188391 34.9069 2 188391 34.9069 2 188392 34.8990 2 188392 34.9006 2 188393 34.8837 2 188393 34.8857 2 188394 34.8633 2 188394 34.8643 2 188396 34.8468 2 188396 34.8484 2 188397 34.8521 2 188397 34.8558 2 188422 34.8566 2 188422 34.8568 2 188436 34.8590 2 188436 34.8590 2 188467 33.2803 2 188467 33.2797 2 188474 34.6639 2 188474 34.6648 2 188490 34.6574 2 188490 34.6582 2 188510 33.8075 2 188510 33.8072 2 3. Oxygen (Peter Strain, Pierre Clement and Manon Poliquin) a. General Samples for the determination of dissolved oxygen were drawn from each rosette water-sampling bottle. Analyses were done using the Winkler titration technique with the computer driven automated system developed at BIO. In total 2013 samples were run for oxygen content. After about 300 samples had been run the values were found to be about 3% higher than those obtained on previous cruises to the region. This discrepancy was removed when the 0.01N Potassium Iodate standardization solution prepared by BDH Inc. of Toronto was replaced by the 0.1N solution prepared by Frank Zemlyak at BIO. The BIO standard was used for the remainder of the voyage. b. Description of Equipment and Technique The oxygen samples are analyzed using one of two systems: 1) an automated procedure developed by the Physical and Chemical Sciences Branch of the Bedford Institute of Oceanography (BIO) from a manual titration system (Levy et al. 1977), 2) the Scripps Institute of Oceanography (SIO) system. The BIO system uses a modified Winkler titration from Carritt and Carpenter (1966), using a whole bottle titration. In this method there is no starch indicator and a wetting agent (Wetting Agent A, BDH) is introduced to reduce bubble formation. The automated titration system consists of an IBM PC linked to a Brinkmann PC800 colorimeter and a Metrohm 665 Multi-Dosimat Automatic Titrator. A full description of the system and method can be found in Jones, et al. (1992) with the following exception: Page 2-4, section 2.3 Method - Sample titration should read, 'The stopper is not replaced and the acid rinsed down the stopper's end into the flask. The end is then rinsed into the flask with deionized water. One drop of wetting agent and the magnetic stirring bar are then added.' The SIO system also uses a modified Winkler titration from Carritt and Carpenter (1966), using a whole bottle titration. However, the SIO system differs from the Bedford Institute's titration system in several ways. Most significant is the 365nm UV light source, followed by different standard and titer concentrations. Standards and blanks are run at least once a day, or whenever the system had been idle for a number of hours. Before titrating with the SIO system, the top of the oxygen flask is washed a minimum of two times with deionized water before the glass stopper is withdrawn. At that point, 1.5ml of sulphuric acid is added to the sample, a magnetic stir bar is introduced, the sample is then titrated immediately. During the titration, the oxygen flask is immersed in a water bath and is held firm in the centre of the 365nm UV light path. Starch as an indicator is not needed and the addition of a wetting agent to minimize the formation of micro bubbles is unnecessary. c. Sampling Procedure and Data Processing Technique The sampling bottles are 125ml Iodine flasks with custom ground stoppers (Levy et al. 1977). The flask volumes are determined gravimetrically. The matched flasks and stoppers are etched with Identification numbers and entered into the Oxygen program database. For this cruise 10 litre rosette bottles were used to obtain the original sample. The oxygen subsamples are drawn following the CFC, DOC and Helium subsamples. The oxygen subsamples are drawn through the bottles spigot with a latex or silicone tube attached so as to introduce the water to the bottom of the flask. The flask and its stopper are thoroughly rinsed and filled to overflowing. The flow is allowed to continue until at least two to three flask volumes overflowed. The flask is then slowly retracted with continuous low flow to ensure that no air gets trapped in the flask. The flask is then brought to the reagent station and one ml each of the Alkaline Iodide and Manganous Chloride Reagents are added and the stoppers carefully inserted, again ensuring that no air gets into the flasks. The flasks are thoroughly shaken then carried to the lab for analysis. d. Replicate Analysis There were 2013 unique sample id numbers that were analyzed for dissolved oxygen, of which 1520 had one sample value, 419 had two sample values, 74 had three sample values. Statistics of the replicate differences follow. Only acceptable values were used in calculating the replicate differences. The calculated replicate statistics used the absolute value of the replicate differences. All of the replicate sample values and their quality flags are listed in Table C.3 below. Number of replicate differences = (419) sample id numbers having one replicate * (1) possible difference + (74) sample id numbers having two replicates * (3) possible differences = 641 Median of [(absolute difference/sample mean concentration of all samples) * 100%] = 0.21 % Statistic Value (µmoles/kg) ------------------------------- Minimum 0.0 Maximum 23.3 Mean 0.9 Median 0.5 Standard Deviation 1.4 Cumulative Oxygen Difference Frequency (µmoles/kg) 50% ¾ 0.6 68% ¾ 0.9 95% ¾ 2.4 The comparison of the BIO and SIO oxygen values posed two difficulties. In particular we needed to resolve the following questions: * What were the relative purities of the two different KIO3 standards used on the cruise ? (They were solid KIO3 from Aldrich and Fisher). * Can we determine an absolute reference for these batches of KIO3 ? (ie Can we establish the accuracy of the analysis?) Two reasonable answers now exist to both of these questions. In two separate lots, we analyzed over 600 standards, prepared from 9 different KIO3 or KH(IO3)2 sources. Our best estimate for the absolute purity of the Fisher standard used on 97009 is 99.61 %; for the Aldrich AA standard it is 102.29 %. Applying these purities to the 97009 data leads to an average difference in concentration of 0.22 % between the SIO and BIO systems (for this difference, n = 382, one standard dev. = 0.02 %). The large offset between the SIO and BIO data that occurred in the raw data when the systems were using different KIO3 standards has disappeared. This analysis has produced the following conclusions: * A few outliers have been removed on the basis of one analysis of a sample being different from two others, or because one analysis produced a near zero result. These edits are noted in processing documentation not included with this cruise report. Also, a small number of replicate samples with unusually large differences are identified in the processing documentation as 'suspect'. These differences are large enough that looking at the data in their oceanographic context will probably identify which analysis is correct. Note that the data from the BIO and SIO systems in this file have been processed in essentially the same way. A number of corrections have been applied for temperature effects: contraction of sample bottles at time of sampling, expansion/contraction of KIO3 and NaS2O3 solutions during sample and standard analyses. These corrections are usually each less than 0.04 %, and are not normally applied to the BIO system data. * It is strongly recommend that all future deep ocean work use GFS certified KIO3 solution (nominal normality 0.1) as the KIO3 standard. This material is traceable to a NIST primary reference for redox chemistry. Staff at NIST and GFS report that KIO3 is not a suitable primary standard at the required deep- ocean accuracy; it can not be made pure enough (in the redox sense). KH(IO3)2 (potassium bi-iodate or potassium hydrogen iodate) is a suitable primary standard. We included two different sources of KH(IO3)2 in our comparison of standards. Comparing these to the GFS 0.1 N KIO3 solution gives a range of 0.4% in purity, which is considered to be an upper limit on the accuracy of the data. We recommend the GFS solution because of its ease of use, and the belief that GFS are better equipped than we are to evaluate its absolute concentration. * It may be possible to use the information we have gained from this analysis to refine the data from other WOCE cruises. This will depend on whether we have a record of which suppliers and lot numbers of KIO3 were used on each cruise, and whether we have, or can get, comparative data on these standards. One disappointing note: two different lots of the BDH 0.01 N KIO3 that we 'traditionally' used as our standard were included in our tests. Their purities were 100.26 and 101.79 %, showing a lot-to-lot variation of more than 1.5 %. We are unlikely to have enough information to correct data from cruises using these standards. Table C.3 Replicate water sample oxygen values in µmoles/kg, along with their quality flags. Sample ID # Oxygen WOCE QF ------------------------------------- 186007 391.0 2 186007 390.4 2 186011 239.9 2 186011 246.8 2 186028 165.7 2 186028 165.8 2 186048 238.9 2 186048 237.8 2 186052 332.9 2 186052 333.2 2 186056 220.4 2 186056 220.6 2 186066 250.0 4 186066 250.2 4 186067 221.2 4 186067 221.0 4 186068 158.2 2 186068 158.2 2 186069 157.7 2 186069 158.2 2 186070 158.0 2 186070 158.4 2 186071 158.2 2 186071 158.0 2 186072 160.0 2 186072 160.3 2 186073 161.1 2 186073 161.6 2 186074 164.7 2 186074 165.2 2 186075 166.1 2 186075 166.7 2 186076 172.3 2 186076 173.5 2 186077 177.3 2 186077 177.9 2 186078 160.6 2 186078 183.9 2 186079 201.6 2 186079 201.7 2 186080 200.8 2 186080 200.8 2 186081 214.2 2 186081 213.9 2 186082 223.1 2 186082 223.5 2 186083 261.4 2 186083 261.8 2 186084 282.1 2 186084 282.5 2 186085 323.8 2 186085 343.5 4 186086 330.5 2 186086 330.6 2 186088 329.1 2 186088 329.6 2 186095 163.0 2 186095 163.1 2 186104 227.6 2 186104 227.0 2 186132 357.7 2 186132 362.5 2 186135 376.0 2 186135 384.5 2 186143 381.7 2 186143 381.5 2 186151 344.6 2 186151 342.5 2 186158 375.6 2 186158 378.4 2 186165 323.0 2 186165 323.3 2 186173 282.7 2 186173 282.0 2 186191 287.1 2 186191 287.3 2 186202 299.6 2 186202 300.1 2 186211 282.4 2 186211 282.5 2 186220 292.5 2 186220 292.3 2 186251 307.4 2 186251 307.0 2 186260 294.3 2 186260 294.5 2 186301 294.3 2 186301 295.1 2 186314 288.5 2 186314 288.5 2 186349 294.7 2 186349 294.7 2 186354 330.7 2 186354 330.7 2 186358 293.0 2 186358 294.2 2 186360 282.8 2 186360 281.8 2 186360 282.4 2 186361 280.6 2 186361 281.6 2 186362 278.7 2 186362 279.9 2 186363 281.0 2 186363 281.7 2 186363 281.8 2 186364 280.3 2 186364 279.7 2 186365 284.9 2 186365 286.2 2 186366 294.1 2 186366 294.1 2 186366 295.3 2 186368 292.8 2 186368 290.3 2 186368 291.8 2 186369 290.5 2 186369 289.3 2 186369 289.0 2 186370 284.5 2 186370 285.9 2 186371 280.6 2 186371 282.0 2 186372 294.6 2 186372 293.2 2 186373 291.7 2 186373 292.6 2 186374 283.1 2 186374 283.6 2 186375 288.7 2 186375 289.9 2 186376 308.1 2 186376 307.5 2 186377 310.8 2 186377 309.8 2 186378 318.7 2 186378 320.0 2 186386 278.5 2 186386 278.9 2 186405 296.6 2 186405 294.6 2 186441 285.4 2 186441 288.6 2 186453 291.9 2 186453 292.8 2 186454 290.4 2 186454 291.2 2 186455 286.7 2 186455 286.1 2 186456 281.1 2 186456 280.2 2 186456 280.2 2 186457 277.7 2 186457 279.3 2 186459 280.6 2 186459 281.4 2 186459 281.9 2 186460 279.5 2 186460 280.0 2 186460 280.3 2 186461 288.7 2 186461 289.3 2 186462 292.3 2 186462 292.4 2 186462 293.5 2 186463 292.4 2 186463 294.0 2 186463 293.1 2 186464 291.3 2 186464 292.4 2 186464 292.8 2 186465 288.2 2 186465 288.9 2 186466 285.7 2 186466 287.7 2 186467 279.5 2 186467 279.8 2 186467 278.5 2 186468 268.3 2 186468 271.1 2 186469 267.0 2 186469 266.4 2 186470 272.5 2 186470 269.5 2 186471 292.0 2 186471 294.1 2 186472 279.2 2 186472 280.3 2 186473 291.9 2 186473 290.3 2 186474 282.4 2 186474 283.9 2 186475 275.0 2 186475 276.1 2 186476 290.1 2 186476 290.9 2 186492 285.2 2 186492 285.3 2 186503 286.2 2 186503 286.4 2 186536 276.9 2 186536 277.4 2 186540 281.3 2 186540 281.5 2 186540 281.6 2 186541 278.4 2 186541 278.2 2 186542 276.4 2 186542 276.5 2 186543 276.1 2 186543 276.1 2 186544 271.0 2 186544 271.8 2 186545 273.8 2 186545 272.6 2 186546 275.4 2 186546 275.3 2 186546 274.7 2 186547 279.3 2 186547 279.8 2 186548 282.2 2 186548 282.4 2 186549 288.5 2 186549 288.6 2 186549 287.9 2 186550 291.0 2 186550 291.3 2 186550 290.7 2 186551 289.7 2 186551 290.5 2 186552 287.1 2 186552 286.7 2 186553 283.8 2 186553 282.8 2 186579 280.1 2 186579 280.5 2 186615 287.2 2 186615 287.4 2 186633 279.0 2 186633 278.8 2 186651 280.1 2 186651 282.7 2 186652 278.3 2 186652 278.3 2 186652 280.1 2 186653 276.9 2 186653 278.1 2 186654 276.2 2 186654 274.8 2 186655 274.8 2 186655 273.6 2 186656 274.4 2 186656 275.8 2 186656 275.9 2 186657 277.4 2 186657 278.8 2 186658 283.7 2 186658 283.7 2 186658 284.9 2 186659 291.5 2 186659 292.9 2 186660 295.8 2 186660 296.9 2 186661 247.3 4 186661 293.4 2 186662 292.9 2 186662 291.0 2 186662 291.2 2 186663 289.3 2 186663 290.8 2 186664 287.2 2 186664 288.7 2 186665 284.6 2 186665 281.9 2 186666 284.5 2 186666 282.7 2 186666 282.7 2 186667 286.3 2 186667 287.9 2 186668 305.1 2 186668 307.5 2 186669 311.6 2 186669 313.1 2 186670 312.2 2 186670 314.2 2 186671 315.7 2 186671 317.2 2 186672 325.6 2 186672 327.8 2 186673 328.3 2 186673 330.0 2 186674 329.0 2 186674 329.2 2 186674 327.1 2 186690 283.7 2 186690 284.0 2 186712 329.2 2 186712 329.3 2 186721 293.5 2 186721 293.8 2 186738 295.0 2 186738 296.1 2 186739 284.7 2 186739 285.0 2 186739 285.8 2 186740 286.7 2 186740 278.2 2 186741 275.5 2 186741 274.4 2 186741 274.8 2 186742 276.1 2 186742 276.5 2 186743 275.6 2 186743 276.5 2 186744 280.3 2 186744 282.0 2 186745 291.3 2 186745 292.1 2 186745 292.4 2 186746 294.9 2 186746 296.3 2 186747 296.3 2 186747 295.6 2 186748 294.2 2 186748 295.1 2 186749 292.9 2 186749 294.3 2 186750 290.4 2 186750 291.6 2 186751 289.1 2 186751 290.1 2 186752 288.2 2 186752 289.7 2 186753 305.0 2 186753 306.1 2 186754 307.3 2 186754 308.2 2 186755 303.4 2 186755 303.9 2 186756 304.3 2 186756 305.5 2 186757 306.4 2 186757 305.6 2 186758 311.2 2 186758 313.3 2 186759 315.8 2 186759 318.2 2 186779 289.8 2 186779 295.6 2 186803 284.0 2 186803 284.1 2 186819 324.4 2 186819 324.7 2 186842 287.4 2 186842 287.8 2 186857 320.8 2 186857 322.2 2 186857 322.4 2 186859 321.0 2 186859 322.6 2 186861 324.9 2 186861 326.6 2 186866 392.5 2 186866 390.0 2 186866 390.6 2 186876 290.1 2 186876 290.0 2 186905 284.9 2 186905 285.2 2 186928 283.9 2 186928 284.0 2 186951 283.3 2 186951 283.2 2 186967 296.6 2 186967 296.1 2 186967 296.4 2 186968 296.1 2 186968 296.4 2 186969 291.7 2 186969 293.0 2 186970 288.0 2 186970 288.2 2 186971 284.9 2 186971 284.9 2 186972 281.1 2 186972 281.2 2 186973 282.8 2 186973 282.5 2 186973 282.5 2 186974 281.4 2 186974 281.5 2 186975 283.7 2 186975 284.1 2 186976 289.1 2 186976 289.2 2 186976 289.5 2 186977 296.3 2 186977 295.8 2 186978 295.2 2 186978 295.1 2 186979 292.7 2 186979 292.9 2 186980 289.9 2 186980 290.0 2 186981 289.2 2 186981 288.6 2 186982 288.4 2 186982 289.4 2 186983 289.9 2 186983 290.3 2 186985 294.7 2 186985 295.0 2 186985 295.1 2 186986 299.9 2 186986 300.0 2 186987 301.0 2 186987 301.7 2 186988 318.3 2 186988 318.4 2 186989 343.7 2 186989 343.9 2 186990 382.8 2 186990 383.4 2 187017 296.3 2 187017 296.0 2 187035 281.2 2 187035 295.9 4 187042 294.9 2 187042 295.1 2 187054 296.6 2 187054 296.2 2 187055 295.3 2 187055 295.1 2 187056 290.0 2 187056 290.1 2 187056 291.2 2 187057 284.2 2 187057 286.6 2 187058 282.3 2 187058 282.3 2 187058 282.8 2 187059 280.9 2 187059 281.8 2 187060 280.2 2 187060 280.9 2 187061 279.6 2 187061 278.6 2 187062 282.3 2 187062 282.2 2 187063 290.8 2 187063 291.4 2 187064 294.8 2 187064 295.9 2 187065 296.3 2 187065 297.1 2 187065 296.3 2 187066 296.0 2 187066 295.5 2 187067 297.1 2 187067 297.9 2 187067 297.9 2 187068 296.5 2 187068 297.0 2 187069 295.2 2 187069 295.7 2 187070 292.6 2 187070 293.5 2 187071 295.3 2 187071 296.1 2 187072 294.7 2 187072 296.3 2 187073 300.1 2 187073 300.9 2 187074 303.7 2 187074 303.1 2 187075 314.0 2 187075 314.2 2 187076 320.2 2 187076 321.3 2 187077 326.4 2 187077 327.0 2 187108 297.7 2 187108 298.2 2 187128 296.4 2 187128 296.6 2 187178 295.3 2 187178 295.4 2 187219 291.6 2 187219 291.6 2 187228 298.5 2 187228 295.6 2 187229 297.4 2 187229 297.6 2 187230 294.8 2 187230 294.8 2 187230 294.8 2 187231 288.1 2 187231 288.1 2 187232 282.7 2 187232 283.3 2 187233 279.5 2 187233 279.9 2 187234 277.7 2 187234 278.1 2 187235 277.2 2 187235 277.4 2 187235 277.7 2 187236 278.1 2 187236 278.2 2 187237 282.1 2 187237 282.8 2 187238 292.1 2 187238 292.0 2 187239 296.3 2 187239 296.2 2 187240 295.6 2 187240 296.1 2 187241 294.3 2 187241 294.9 2 187242 294.5 2 187242 293.8 2 187243 293.7 2 187243 294.2 2 187244 295.1 2 187244 295.3 2 187245 298.4 2 187245 298.8 2 187246 298.3 2 187246 298.9 2 187247 298.0 2 187247 297.3 2 187248 300.4 2 187248 300.4 2 187248 301.1 2 187268 295.5 2 187268 295.6 2 187269 291.6 2 187269 291.4 2 187270 285.1 2 187270 283.1 2 187270 283.5 2 187271 280.8 2 187271 281.4 2 187272 280.1 2 187272 281.3 2 187273 277.4 2 187273 279.1 2 187273 277.9 2 187274 278.4 2 187274 279.3 2 187275 281.5 2 187275 282.6 2 187275 282.7 2 187276 292.6 2 187276 292.7 2 187276 293.5 2 187277 296.3 2 187277 297.3 2 187277 298.0 2 187278 295.4 2 187278 296.7 2 187279 295.0 2 187279 294.3 2 187280 296.1 2 187280 295.3 2 187281 297.5 2 187281 298.0 2 187282 296.1 2 187282 296.3 2 187282 297.0 2 187285 299.5 2 187285 299.6 2 187315 296.6 2 187315 296.2 2 187342 296.3 2 187342 296.4 2 187350 287.6 2 187350 288.4 2 187351 285.1 2 187351 286.2 2 187352 284.7 2 187352 285.8 2 187352 284.1 2 187353 283.7 2 187353 286.0 2 187354 285.0 2 187354 283.8 2 187355 284.1 2 187355 282.5 2 187355 283.7 2 187356 283.9 2 187356 285.1 2 187357 285.1 2 187357 285.4 2 187357 286.2 2 187358 291.1 2 187358 291.8 2 187359 293.0 2 187359 294.4 2 187360 291.6 2 187360 293.2 2 187361 289.5 2 187361 291.0 2 187362 290.1 2 187362 291.5 2 187363 295.0 2 187363 293.4 2 187364 294.6 2 187364 295.9 2 187365 294.8 2 187365 295.9 2 187366 294.7 2 187366 296.1 2 187367 294.4 2 187367 295.8 2 187368 291.9 2 187368 293.3 2 187369 372.9 2 187369 375.0 2 187376 294.4 2 187376 294.8 2 187418 315.1 2 187418 315.1 2 187435 315.8 2 187435 316.0 2 187440 327.2 2 187440 327.5 2 187454 319.7 2 187454 319.7 2 187478 329.4 2 187478 329.1 2 187487 288.5 2 187487 288.9 2 187515 284.4 2 187515 284.5 2 187536 294.1 2 187536 293.9 2 187549 289.9 2 187549 290.3 2 187572 293.5 2 187572 293.9 2 187572 294.4 2 187573 293.2 2 187573 294.1 2 187574 288.0 2 187574 288.9 2 187575 284.9 2 187575 284.7 2 187576 282.0 2 187576 283.2 2 187577 283.0 2 187577 282.5 2 187577 282.6 2 187578 284.4 2 187578 283.6 2 187578 284.2 2 187579 287.3 2 187579 287.7 2 187580 291.6 2 187580 292.1 2 187581 294.8 2 187581 294.0 2 187582 294.4 2 187582 293.6 2 187583 291.5 2 187583 292.8 2 187584 289.8 2 187584 290.5 2 187585 288.0 2 187585 287.2 2 187586 289.3 2 187586 289.6 2 187587 295.5 2 187587 295.8 2 187588 296.9 2 187588 297.1 2 187589 298.8 2 187589 295.1 2 187590 298.6 2 187590 298.2 2 187591 297.9 2 187591 298.6 2 187592 298.6 2 187592 299.6 2 187593 297.7 2 187593 297.3 2 187643 286.2 2 187643 286.7 2 187676 300.1 2 187676 300.2 2 187683 294.4 2 187683 294.8 2 187683 295.9 2 187684 294.3 2 187684 293.4 2 187685 288.6 2 187685 287.2 2 187686 281.2 2 187686 282.3 2 187687 280.1 2 187687 282.1 2 187688 279.6 2 187688 281.0 2 187688 279.6 2 187689 282.3 2 187689 281.2 2 187690 281.7 2 187690 282.4 2 187691 288.3 2 187691 290.1 2 187692 295.9 2 187692 297.4 2 187693 296.6 2 187693 298.0 2 187693 296.3 2 187694 295.5 2 187694 296.2 2 187695 296.1 2 187695 295.0 2 187696 299.7 2 187696 297.5 2 187696 299.3 2 187697 298.7 2 187697 298.9 2 187698 297.0 2 187698 299.3 2 187699 299.8 2 187699 299.9 2 187699 299.6 2 187700 300.0 2 187700 300.4 2 187716 295.2 2 187716 295.4 2 187731 295.1 2 187731 295.5 2 187759 282.8 2 187759 283.0 2 187780 295.2 2 187780 294.9 2 187803 289.8 2 187803 290.8 2 187803 291.4 2 187804 291.7 2 187804 287.4 2 187805 287.2 2 187805 285.1 2 187806 281.4 2 187806 283.6 2 187807 281.9 2 187807 282.1 2 187807 284.0 2 187808 280.9 2 187808 282.7 2 187810 285.4 2 187810 283.9 2 187811 290.8 2 187811 293.0 2 187812 295.6 2 187812 297.3 2 187812 297.5 2 187813 294.6 2 187813 296.5 2 187814 292.7 2 187814 294.9 2 187815 293.8 2 187815 296.3 2 187816 296.0 2 187816 33.7 4 187816 293.9 2 187817 297.9 2 187817 300.2 2 187818 298.9 2 187818 300.4 2 187819 295.0 2 187819 295.1 2 187820 301.6 2 187820 290.9 2 187820 291.9 2 187821 299.8 2 187821 298.8 2 187822 299.0 2 187822 299.2 2 187823 309.6 2 187823 316.6 2 187828 290.5 2 187828 290.1 2 187853 290.0 2 187853 290.1 2 187880 313.3 2 187880 313.6 2 187898 345.7 2 187898 345.7 2 187916 292.0 2 187916 292.2 2 187922 283.2 2 187922 284.0 2 187923 285.8 2 187923 286.1 2 187923 286.4 2 187924 287.6 2 187924 288.5 2 187925 289.8 2 187925 290.4 2 187925 289.5 2 187926 293.1 2 187926 292.8 2 187927 293.5 2 187927 294.3 2 187928 293.3 2 187928 292.5 2 187928 293.2 2 187929 289.6 2 187929 289.3 2 187930 285.6 2 187930 286.3 2 187931 281.8 2 187931 282.6 2 187932 285.5 2 187932 285.4 2 187933 293.0 2 187933 293.0 2 187934 289.7 2 187934 290.5 2 187935 291.0 2 187935 292.0 2 187936 289.4 2 187936 289.7 2 187937 297.6 2 187937 297.9 2 187938 356.4 2 187938 357.1 2 187948 292.3 2 187948 292.3 2 187971 290.0 2 187971 290.1 2 187999 290.2 2 187999 290.6 2 188020 296.0 2 188020 295.8 2 188034 295.6 2 188034 296.0 2 188035 295.3 2 188035 296.0 2 188036 292.8 2 188036 292.9 2 188037 287.1 2 188037 287.1 2 188038 283.7 2 188038 284.5 2 188039 282.8 2 188039 283.7 2 188040 283.7 2 188040 284.0 2 188041 285.6 2 188041 284.5 2 188042 287.4 2 188042 288.0 2 188043 293.3 2 188043 293.6 2 188043 293.6 2 188044 295.8 2 188044 296.3 2 188045 295.3 2 188045 296.0 2 188046 295.1 2 188046 296.1 2 188047 292.5 2 188047 293.6 2 188048 295.5 2 188048 295.7 2 188049 295.3 2 188049 294.9 2 188050 294.9 2 188050 295.3 2 188051 295.9 2 188051 295.6 2 188051 295.6 2 188052 295.1 2 188052 294.8 2 188054 298.3 2 188054 298.6 2 188055 301.7 2 188055 302.2 2 188056 315.2 2 188056 313.9 2 188084 296.3 2 188084 296.4 2 188088 296.0 2 188088 296.7 2 188089 292.5 2 188089 292.6 2 188089 292.8 2 188090 286.7 2 188090 286.7 2 188091 282.7 2 188091 282.3 2 188092 281.7 2 188092 281.7 2 188093 281.6 2 188093 282.0 2 188093 284.9 2 188094 283.4 2 188094 283.6 2 188095 286.7 2 188095 286.5 2 188096 288.3 2 188096 288.4 2 188097 295.3 2 188097 297.4 2 188098 295.0 2 188098 297.4 2 188099 296.0 2 188099 296.7 2 188100 292.5 2 188100 293.0 2 188100 293.2 2 188101 297.9 2 188101 297.7 2 188102 299.1 2 188102 299.3 2 188103 299.1 2 188103 299.2 2 188104 299.5 2 188104 299.7 2 188105 298.8 2 188105 299.5 2 188106 301.3 2 188106 301.8 2 188107 298.5 2 188107 298.9 2 188108 299.2 2 188108 299.4 2 188109 301.6 2 188109 301.6 2 188122 295.5 2 188122 295.6 2 188139 284.7 2 188139 284.5 2 188162 311.6 2 188162 311.7 2 188171 296.2 2 188171 298.2 2 188172 296.4 2 188172 295.3 2 188173 288.1 2 188173 287.5 2 188174 282.9 2 188174 283.0 2 188174 283.5 2 188175 281.0 2 188175 281.6 2 188176 279.3 2 188176 279.9 2 188177 281.9 2 188177 281.3 2 188178 283.8 2 188178 284.0 2 188178 284.0 2 188179 285.5 2 188179 285.0 2 188180 294.0 2 188180 293.6 2 188180 293.2 2 188181 298.9 2 188181 304.3 4 188182 296.9 2 188182 297.4 2 188183 296.3 2 188183 294.6 2 188184 298.0 2 188184 298.3 2 188185 297.7 2 188185 297.9 2 188186 298.3 2 188186 298.6 2 188187 299.2 2 188187 299.2 2 188188 299.7 2 188188 299.1 2 188189 303.6 2 188189 303.7 2 188190 298.1 2 188190 299.1 2 188191 295.4 2 188191 294.5 2 188201 279.1 2 188201 279.2 2 188224 282.7 2 188224 283.8 2 188243 297.8 2 188243 298.2 2 188244 294.9 2 188244 295.7 2 188244 294.8 2 188245 286.2 2 188245 286.7 2 188246 282.2 2 188246 282.4 2 188247 279.2 2 188247 278.7 2 188247 279.1 2 188248 277.5 2 188248 278.0 2 188249 275.8 2 188249 276.4 2 188249 276.5 2 188250 276.0 2 188250 276.5 2 188251 277.3 2 188251 277.9 2 188252 280.9 2 188252 280.9 2 188253 287.9 2 188253 288.3 2 188254 294.4 2 188254 294.8 2 188255 294.2 2 188255 294.7 2 188256 292.4 2 188256 291.6 2 188257 288.6 2 188257 289.4 2 188258 285.7 2 188258 286.8 2 188259 281.3 2 188259 281.3 2 188260 277.9 2 188260 276.4 2 188261 285.4 2 188261 285.5 2 188262 292.6 2 188262 293.3 2 188263 283.0 2 188263 282.6 2 188264 308.9 2 188264 309.5 2 188270 280.7 2 188270 280.7 2 188293 285.7 2 188293 285.8 2 188321 277.4 2 188321 277.4 2 188350 294.9 2 188350 295.2 2 188371 290.9 2 188371 291.0 2 188395 292.9 2 188395 297.0 2 188424 294.5 2 188424 294.6 2 188440 296.8 2 188440 296.9 2 188458 291.9 2 188458 291.8 2 188477 319.2 2 188477 319.8 2 188492 281.7 2 188492 281.8 2 188515 337.0 9 188515 336.2 9 4. Nutrients (Pierre Clement) a. Description of Equipment and Technique Nutrient concentrations were determined using a Technicon Autoanalyser II. The chemistries are standard Technicon (Silicate 186-72W, Phosphate 155-71W, Nitrate/Nitrite 158-71W) except for Phosphate which was modified by separating the Ascorbic Acid (4.0 gms/L) from the Mixed Reagent. This alteration was achieved by introducing the modified Mixed Reagent instead of water at the start of the sample stream at 0.23 ml/min and the Ascorbic Acid was pumped into the stream between the two mixing coils at 0.32 ml/min. b. Sampling Procedure and Data Processing Technique Duplicate nutrient subsamples were drawn into 30 ml HDPE (Nalge) wide mouth sample bottles from 10 L Niskin bottles. The bottles were washed with 10% HCl, rinsed once with tap water, rinsed three times with Super-Q and oven dried at >100 Degrees F. A sample run included six Working Standards run at the beginning and end. Duplicate Check Standards were run every 16 samples followed by blanks as a Baseline Check. These Standards were made up in 33 ppt NaCl (VWR, Analar grade), as is the wash water. The Standards were tested against CSK Solution Standards (Sagami Chemical Center, Japan). Analog data is converted to digital, processed and statistics calculated by a Pascal 6.0 in house program (Logger) on a PC. Chart recordings, hard copy and disk copies of the data are kept for reference. c. Replicate Analysis A total of 4573 seawater samples were analyzed for silicate, phosphate and NO2+NO3. Included in these samples were a total of 2023 duplicate samples and one quadruplicate sample. Statistics relating to the precision of the sample values follow. All values are given in µmoles/kg. All of the samples values were included in calculating the statistics. All replicate values and their quality flags are given in Table C.4. Precision is a measure of the variability of individual measurements and in the following analysis two categories of precision were determined: field and analytical precision. Analytical precision is based on the pooled estimate of the standard deviation of the check standards over the course of a complete autoanalyzer run and is a measure of the greatest precision possible for a particular analysis. Field precision is based on the analysis of two or more water samples taken from a single Niskin sampling bottle and has an added component of variance due to subsampling, storage and natural sample variability. The precision was calculated using the standard deviation and the full-scale values of 50, 2, and 30 µmole/litre for silicate, phosphate and NO2+NO3 respectively. Both categories of precision were determined by computing the variance, , of each replicate set, where "i" is the index of the replicate set. In the case of analytical (field) precision, a replicate set consisted of all the check standards (duplicate samples). Given p replicate sets and n samples within any replicate set, the mean standard deviation, , was determined from The precision expressed in percent was based on the mean concentration (M) of the check standards (analytical precision) or water samples (field precision) and was given by The following table indicates the analytical and field precision obtained for this cruise. Statistic Silicate Phosphate NO2+NO3 ---------------------------------------------------------------- Number of Samples 4045 4039 4042 Number of Replicates 1498 1492 1495 Mean concentration (µmoles/kg) 9.24 0.97 14.22 Field Precision (µmoles/kg) 0.13 0.03 0.15 Field Precision (%) 1.44 3.43 1.04 Analytical Precision (µmoles/kg) 0.38 0.05 0.38 Analytical Precision (%) 1.36 3.87 2.20 Detection Limit (µmoles/kg) 0.188 0.048 0.149 The laboratory temperature during all analyses was between 21 and 23 °C. The conversion to mass units for the analytical precision and detection limits used a standard density of 1.02443 kg/litre corresponding to 33 ppt and 15°C. The conversion of individual sample values from volume to mass units used a potential density with a fixed temperature of 15°C. Duplicate samples were drawn from each rosette bottle for the determination of silicate, phosphate and nitrate concentrations. The nutrient detection limits noted in the above table were applied to the data set. All values at or below the detection limits were set to zero. Table C.4 Replicate nutrient water sample values in µmoles/kg, along with their quality flags. ID SiO2 PO4 NO2+NO3 QF 186001 3.52 0.76 3.78 2 2 2 186001 3.40 0.78 3.71 2 2 2 186002 2.52 0.73 2.95 2 2 2 186002 2.54 0.75 2.93 2 2 2 186003 1.31 0.62 1.51 2 2 2 186003 1.35 0.63 1.51 2 2 2 186004 1.26 0.61 1.38 2 2 2 186004 1.33 0.62 1.40 2 2 2 186005 0.25 0.49 0.45 2 2 2 186005 0.39 0.49 0.43 2 2 2 186006 0.00 0.35 0.00 2 2 2 186006 0.00 0.37 0.00 2 2 2 186007 0.00 0.37 0.00 2 2 2 186007 0.00 0.33 0.00 2 2 2 186008 0.00 0.37 0.00 2 2 2 186008 0.00 0.35 0.00 2 2 2 186009 0.00 0.37 0.00 2 2 2 186009 0.00 0.35 0.00 2 2 2 186010 10.43 0.97 11.38 2 2 2 186010 10.59 0.96 11.60 2 2 2 186011 7.48 0.88 9.05 2 2 2 186011 7.54 0.88 9.35 2 2 2 186012 7.28 0.91 8.34 2 2 2 186012 7.37 0.89 8.36 2 2 2 186013 7.39 1.00 7.53 2 3 2 186013 7.30 0.90 7.59 2 3 2 186014 7.12 0.93 7.06 2 2 2 186014 7.13 0.89 7.03 2 2 2 186015 6.46 0.90 6.37 2 2 2 186015 6.47 0.87 6.33 2 2 2 186016 4.25 0.79 4.38 2 2 2 186016 4.25 0.77 4.44 2 2 2 186017 1.95 0.74 2.18 2 2 2 186017 1.97 0.69 2.21 2 2 2 186018 1.83 0.68 2.23 2 2 2 186018 1.87 0.65 2.21 2 2 2 186019 2.04 0.68 2.50 2 2 2 186019 2.11 0.70 2.57 2 2 2 186020 0.64 0.58 1.10 2 2 2 186020 0.65 0.57 1.04 2 2 2 186021 0.00 0.43 0.00 2 2 2 186021 0.00 0.44 0.00 2 2 2 186022 0.00 0.40 0.00 2 2 2 186022 0.00 0.40 0.00 2 2 2 186023 0.00 0.38 0.00 2 2 2 186023 0.00 0.38 0.00 2 2 2 186024 0.00 0.37 0.00 2 2 2 186024 0.58 0.38 0.00 2 2 2 186025 0.00 0.38 0.00 2 2 2 186025 0.00 0.41 0.00 2 2 2 186026 16.51 1.29 18.77 2 2 2 186026 16.60 1.24 18.84 2 2 2 186027 13.84 1.22 18.11 2 2 2 186027 14.04 1.23 17.85 2 2 2 186028 12.26 1.17 17.08 2 2 2 186028 12.36 1.16 16.92 2 2 2 186029 11.50 1.12 16.81 2 2 2 186029 11.46 1.15 16.79 2 2 2 186030 11.69 1.13 16.53 2 2 2 186030 11.75 1.14 16.44 2 2 2 186031 11.31 1.12 16.25 2 2 2 186031 11.35 1.10 15.83 2 2 2 186032 10.88 1.10 15.61 2 2 2 186032 10.91 1.09 15.61 2 2 2 186033 10.61 1.05 14.87 2 2 2 186033 10.65 1.10 14.61 2 2 2 186034 9.85 1.00 14.09 2 2 2 186034 9.95 1.03 14.09 2 2 2 186035 10.11 1.03 13.39 2 2 2 186035 10.17 1.03 13.30 2 2 2 186036 9.41 0.99 12.71 2 2 2 186036 9.50 0.99 12.85 2 2 2 186037 9.56 0.99 12.59 2 2 2 186037 9.59 1.01 12.43 2 2 2 186038 9.45 1.16 11.72 2 3 2 186038 9.45 1.03 11.59 2 3 2 186039 6.07 0.86 8.61 2 3 2 186039 6.00 1.17 8.64 2 3 2 186040 3.08 0.67 4.13 2 3 2 186040 3.01 0.80 4.13 2 3 2 186041 2.21 0.67 2.61 2 2 2 186041 2.32 0.67 2.61 2 2 2 186042 1.02 0.54 0.90 2 2 2 186042 1.03 0.53 0.90 2 2 2 186043 0.82 0.48 0.33 2 2 2 186043 0.81 0.47 0.29 2 2 2 186044 0.66 0.52 0.00 2 2 2 186044 0.70 0.46 0.00 2 2 2 186045 0.62 0.45 0.00 2 2 2 186045 0.66 0.44 0.00 2 2 2 186046 0.74 0.48 0.00 2 2 2 186046 0.76 0.60 0.00 2 2 2 186047 7.87 0.85 8.88 2 2 2 186047 7.84 0.86 8.91 2 2 2 186048 7.70 0.86 9.08 2 2 2 186048 7.66 0.85 8.97 2 2 2 186049 3.73 0.64 4.08 3 3 3 186049 3.74 0.64 4.16 3 3 3 186050 1.92 0.56 2.02 3 3 3 186050 1.97 0.58 2.08 3 3 3 186051 1.18 0.50 0.68 3 3 3 186051 1.11 0.48 0.68 3 3 3 186052 0.81 0.45 0.17 3 3 3 186052 0.82 0.45 0.17 3 3 3 186053 0.75 0.46 0.15 3 3 3 186053 0.84 0.46 0.15 3 3 3 186054 0.80 0.47 0.15 3 3 3 186054 0.81 0.47 0.20 3 3 3 186055 9.84 0.84 10.44 3 3 3 186055 9.44 0.85 10.24 3 3 3 186056 10.01 0.83 10.35 3 3 3 186056 9.91 0.85 10.20 3 3 3 186057 9.68 0.86 10.17 3 3 3 186057 9.85 0.87 10.04 3 3 3 186058 7.02 0.78 8.00 3 3 3 186058 7.15 0.78 7.84 3 3 3 186059 1.85 0.57 2.22 3 3 3 186059 1.80 0.58 2.24 3 3 3 186060 0.71 0.46 0.38 3 3 3 186060 0.77 0.47 0.38 3 3 3 186061 0.60 0.39 -0.06 3 3 3 186061 0.61 0.40 -0.09 3 3 3 186062 0.57 0.40 -0.05 3 3 3 186062 0.62 0.40 -0.11 3 3 3 186063 0.60 0.38 -0.11 3 3 3 186063 0.58 0.39 -0.08 3 3 3 186064 0.57 0.39 -0.10 3 3 3 186064 0.52 0.39 -0.10 3 3 3 186066 11.11 1.14 15.46 3 3 3 186066 11.23 1.12 15.30 3 3 3 186067 12.31 1.25 16.78 3 3 3 186067 12.40 1.28 16.76 3 3 3 186068 12.74 1.42 18.71 3 3 3 186068 12.97 1.39 18.73 3 3 3 186069 11.72 1.34 17.75 3 3 3 186069 11.77 1.34 18.18 3 3 3 186070 11.00 1.30 17.10 3 3 3 186070 11.16 1.30 17.27 3 3 3 186071 10.95 1.31 17.10 3 3 3 186071 11.05 1.31 17.06 3 3 3 186072 10.51 1.28 16.33 3 3 3 186072 10.56 1.38 16.61 3 3 3 186073 10.50 1.27 16.69 3 3 3 186073 10.53 1.26 16.87 3 3 3 186074 10.11 1.17 16.18 3 3 3 186074 10.13 1.21 16.90 3 3 3 186075 9.52 1.20 15.49 3 3 3 186075 9.69 1.17 15.54 3 3 3 186076 8.80 1.11 14.04 3 3 3 186076 8.92 1.25 14.23 3 3 3 186077 8.23 1.06 13.10 3 3 3 186077 8.03 1.07 12.99 3 3 3 186078 7.46 1.09 12.34 3 3 3 186078 7.48 1.01 12.35 3 3 3 186079 5.94 0.87 10.26 3 3 3 186079 6.00 0.85 10.32 3 3 3 186080 6.77 0.90 10.65 3 3 3 186080 6.82 0.91 10.64 3 3 3 186081 6.14 0.84 9.34 3 3 3 186081 6.34 0.82 9.35 3 3 3 186082 5.98 0.79 8.34 3 3 3 186082 6.11 0.82 8.40 3 3 3 186083 3.00 0.72 4.70 3 3 3 186083 3.02 0.61 4.67 3 3 3 186084 2.78 0.64 3.55 3 3 3 186084 2.80 0.64 3.62 3 3 3 186085 0.95 0.52 0.59 3 3 3 186085 0.94 0.53 0.51 3 3 3 186086 0.73 0.45 -0.01 3 3 3 186086 0.78 0.59 0.01 3 3 3 186088 0.75 0.44 -0.11 3 3 3 186088 0.77 0.44 -0.11 3 3 3 186089 10.32 1.12 13.65 3 3 3 186089 10.34 1.10 13.45 3 3 3 186090 10.00 1.14 13.76 3 3 3 186090 10.06 1.14 13.70 3 3 3 186091 11.16 1.30 14.86 3 3 3 186091 11.17 1.33 14.67 3 3 3 186092 10.26 1.34 15.49 3 3 3 186092 10.34 1.35 15.20 3 3 3 186093 9.27 1.27 14.48 3 3 3 186093 9.61 1.28 14.77 3 3 3 186094 9.31 1.24 14.42 3 3 3 186094 9.21 1.24 14.46 3 3 3 186095 8.67 1.19 13.98 3 3 3 186095 8.80 1.20 14.15 3 3 3 186096 8.36 1.16 13.64 3 3 3 186096 8.40 1.17 13.83 3 3 3 186097 7.78 1.13 12.84 3 3 3 186097 7.86 1.14 12.90 3 3 3 186098 7.64 1.26 12.80 3 3 3 186098 7.66 1.09 12.81 3 3 3 186099 7.26 1.00 12.13 3 3 3 186099 7.27 1.00 12.35 3 3 3 186100 6.62 0.95 11.22 3 3 3 186100 6.67 0.96 11.31 3 3 3 186101 5.61 0.83 9.44 3 3 3 186101 5.71 0.83 9.57 3 3 3 186102 5.57 0.78 8.66 3 3 3 186102 5.56 0.79 8.72 3 3 3 186103 5.17 0.76 8.38 3 3 3 186103 5.21 0.76 8.07 3 3 3 186104 5.02 0.76 8.05 3 3 3 186104 5.22 0.78 8.08 3 3 3 186105 4.94 0.75 7.32 3 3 3 186105 4.94 0.76 7.28 3 3 3 186106 3.45 0.68 4.90 3 3 3 186106 3.46 0.68 4.93 3 3 3 186107 1.62 0.58 1.67 3 3 3 186107 1.65 0.56 1.72 3 3 3 186108 1.17 0.47 0.46 3 3 3 186108 1.17 0.46 0.39 3 3 3 186109 1.14 0.45 0.28 3 3 3 186109 1.14 0.45 0.28 3 3 3 186110 1.24 0.46 0.26 3 3 3 186110 1.17 0.46 0.24 3 3 3 186111 9.49 1.10 12.52 3 3 3 186111 9.49 1.08 12.38 3 3 3 186112 1.24 0.46 0.22 3 3 3 186112 1.27 0.46 0.35 3 3 3 186130 10.05 0.90 7.96 2 2 2 186130 10.06 0.92 8.03 2 2 2 186131 7.78 0.81 6.53 2 2 2 186131 7.78 0.81 6.45 2 2 2 186132 6.60 0.77 5.49 2 2 2 186132 6.65 0.76 5.51 2 2 2 186133 6.17 0.76 5.28 2 2 2 186133 6.19 0.76 5.34 2 2 2 186134 5.54 0.74 4.96 2 2 2 186134 5.62 0.76 5.06 2 2 2 186135 2.69 0.60 2.91 2 2 3 186135 2.65 0.57 2.35 2 2 3 186136 1.73 0.50 1.78 2 2 3 186136 1.77 0.56 1.45 2 2 3 186137 0.79 0.41 0.18 2 3 2 186137 0.85 0.74 0.46 2 3 2 186138 0.20 0.36 0.00 2 2 2 186138 0.23 0.32 0.00 2 2 2 186139 9.80 0.89 7.95 2 2 2 186139 9.89 0.89 7.99 2 2 2 186140 9.15 0.89 7.76 2 2 2 186140 9.28 0.88 7.71 2 2 2 186141 7.47 0.83 6.27 2 2 2 186141 7.52 0.85 6.28 2 2 2 186142 7.45 0.84 6.30 2 2 2 186142 7.57 0.84 6.32 2 2 2 186143 2.31 0.60 1.76 2 2 2 186143 2.28 0.55 1.60 2 2 2 186144 0.71 0.38 0.00 2 2 2 186144 0.76 0.40 0.00 2 2 2 186145 0.72 0.33 0.00 2 2 2 186145 0.78 0.33 0.00 2 2 2 186146 14.42 1.06 16.27 2 2 2 186146 14.61 1.08 16.28 2 2 2 186147 12.87 0.98 12.61 2 2 2 186147 13.02 0.96 12.67 2 2 2 186148 11.19 0.94 9.93 2 2 2 186148 11.30 0.95 9.74 2 2 2 186149 10.57 0.92 8.76 2 2 2 186149 10.62 0.92 8.75 2 2 2 186150 10.19 0.92 8.34 2 2 2 186150 10.35 0.91 8.38 2 2 2 186151 10.01 0.94 8.25 2 2 2 186151 10.11 0.91 8.09 2 2 2 186152 9.61 0.92 8.08 2 3 2 186152 9.70 0.98 8.00 2 3 2 186153 9.65 0.93 7.87 2 2 2 186153 9.59 0.91 8.05 2 2 2 186154 8.16 0.94 7.01 2 2 2 186154 8.14 0.84 7.03 2 2 2 186155 6.96 0.78 6.35 2 2 2 186155 6.99 0.78 6.29 2 2 2 186156 8.30 0.86 7.05 2 2 2 186156 8.37 0.86 7.11 2 2 2 186157 8.04 0.96 6.85 2 3 2 186157 7.96 0.85 6.83 2 3 2 186158 2.64 0.55 1.83 2 2 3 186158 2.69 0.49 2.16 2 2 3 186159 1.13 0.45 0.23 2 2 3 186159 1.18 0.46 0.55 2 2 3 186160 0.89 0.38 0.00 2 3 2 186160 0.89 0.35 0.00 2 3 2 186161 0.84 0.43 0.00 2 3 2 186161 0.82 0.35 0.00 2 3 2 186162 12.01 1.07 15.32 2 2 2 186162 12.00 1.00 14.78 2 2 2 186163 12.85 0.96 13.29 2 2 2 186163 12.92 0.97 13.07 2 2 2 186164 10.60 0.87 11.93 2 2 2 186164 10.78 0.88 12.17 2 2 2 186165 11.12 0.92 9.99 2 2 2 186165 11.05 0.91 9.91 2 2 2 186166 9.61 0.88 8.87 2 2 2 186166 9.71 0.88 8.85 2 2 2 186167 6.69 0.83 7.90 2 2 2 186167 6.71 0.81 8.02 2 2 2 186168 5.44 0.71 5.57 2 2 2 186168 5.54 0.70 5.61 2 2 2 186169 3.42 0.45 2.15 2 2 3 186169 3.35 0.48 1.77 2 2 3 186170 1.98 0.36 0.02 2 2 3 186170 1.91 0.41 0.16 2 2 3 186171 1.82 0.38 0.04 2 2 3 186171 1.86 0.36 0.04 2 2 3 186173 12.33 1.02 13.09 2 2 2 186173 12.43 0.95 12.99 2 2 2 186174 10.39 0.90 11.83 2 2 2 186174 10.18 0.89 11.77 2 2 2 186175 11.80 0.93 10.83 2 2 2 186175 11.81 0.93 10.63 2 2 2 186176 9.84 0.90 9.29 2 2 2 186176 9.86 0.90 9.31 2 2 2 186177 7.88 0.85 8.39 2 2 2 186177 7.89 0.85 8.67 2 2 2 186178 5.48 0.72 5.82 2 2 2 186178 5.34 0.75 5.78 2 2 2 186179 3.89 0.65 2.45 2 2 2 186179 3.88 0.56 2.39 2 2 2 186180 2.60 0.46 0.40 2 3 3 186180 2.76 0.47 0.72 2 3 3 186181 2.47 0.49 0.30 2 3 3 186181 2.49 0.42 0.48 2 3 3 186182 2.53 0.45 0.28 2 3 3 186182 2.66 0.46 0.87 2 3 3 186190 11.84 1.15 16.62 2 2 2 186190 12.09 1.05 16.64 2 2 2 186191 11.10 1.00 15.59 2 2 2 186191 11.23 1.01 16.59 2 2 2 186192 12.46 1.01 14.30 2 2 2 186192 12.66 1.02 14.30 2 2 2 186193 11.36 0.94 12.63 2 2 2 186193 11.40 0.93 12.57 2 2 2 186194 10.88 1.05 11.27 2 2 2 186194 10.95 0.95 11.53 2 2 2 186195 9.24 0.87 9.24 2 2 2 186195 9.34 0.87 9.18 2 2 2 186196 5.60 0.82 6.44 2 3 2 186196 5.64 0.72 6.40 2 3 2 186197 1.83 0.46 1.43 2 3 3 186197 1.85 0.54 1.15 2 3 3 186198 2.48 0.53 1.77 2 2 3 186198 2.41 0.50 1.04 2 2 3 186199 2.48 0.53 0.68 2 2 3 186199 2.55 0.55 1.09 2 2 3 186200 11.93 1.08 16.18 2 2 2 186200 12.12 1.15 16.28 2 2 2 186201 10.94 1.03 15.11 2 2 2 186201 11.16 1.04 15.25 2 2 2 186202 9.68 0.98 12.00 2 2 2 186202 9.79 0.98 11.94 2 2 2 186203 10.33 1.03 10.94 2 2 2 186203 10.42 1.00 11.30 2 2 2 186204 10.54 0.94 9.56 2 2 2 186204 10.55 0.92 9.50 2 2 2 186205 10.36 0.97 8.88 2 2 2 186205 10.47 0.94 8.98 2 2 2 186206 6.94 0.79 6.54 2 2 2 186206 6.86 0.82 6.06 2 2 2 186207 1.06 0.47 0.00 2 2 2 186207 1.07 0.46 0.00 2 2 2 186208 0.53 0.41 0.00 2 2 2 186208 0.55 0.43 0.00 2 2 2 186209 0.56 0.41 0.00 2 2 2 186209 0.62 0.41 0.00 2 2 2 186211 12.11 1.19 15.37 2 2 2 186211 12.14 1.10 15.27 2 2 2 186212 10.73 1.02 13.63 2 2 2 186212 10.90 1.02 14.10 2 2 2 186213 11.73 1.02 12.38 2 2 2 186213 11.88 1.03 12.65 2 2 2 186214 10.00 0.94 11.50 2 2 2 186214 10.05 0.96 11.44 2 2 2 186215 7.30 0.78 7.19 2 2 2 186215 7.27 0.80 7.19 2 2 2 186216 4.02 0.59 3.74 2 2 2 186216 4.03 0.61 3.92 2 2 2 186217 3.08 0.50 2.26 2 2 2 186217 3.13 0.49 2.16 2 2 2 186218 2.88 0.49 1.70 2 2 2 186218 2.91 0.49 1.80 2 2 2 186219 11.90 1.11 15.46 2 2 2 186219 11.91 1.02 15.50 2 2 2 186220 10.32 0.96 15.38 2 2 2 186220 10.55 0.98 15.07 2 2 2 186221 10.81 1.01 14.65 2 2 2 186221 10.98 0.97 14.69 2 2 2 186222 12.64 1.00 14.00 2 2 2 186222 12.66 1.00 14.06 2 2 2 186223 9.76 0.91 12.51 2 2 2 186223 9.84 0.92 12.65 2 2 2 186224 9.80 0.90 11.80 2 2 2 186224 9.84 0.90 11.98 2 2 2 186225 9.88 0.93 11.18 2 2 2 186225 9.74 0.91 11.26 2 2 2 186226 10.76 0.94 10.41 2 2 2 186226 10.63 0.92 10.73 2 2 2 186227 9.91 0.84 10.15 2 2 2 186227 9.93 1.01 10.17 2 2 2 186228 9.50 0.87 10.05 2 2 2 186228 9.81 0.85 9.77 2 2 2 186229 9.12 0.88 9.54 2 2 2 186229 9.05 0.87 9.59 2 2 2 186230 8.82 0.85 8.92 2 2 2 186230 8.86 0.87 9.02 2 2 2 186231 7.03 0.76 7.02 2 2 2 186231 7.04 0.77 7.00 2 2 2 186232 4.73 0.66 4.84 2 2 2 186232 4.74 0.65 4.86 2 2 2 186233 4.56 0.62 4.28 2 2 2 186233 4.49 0.63 4.18 2 2 2 186234 4.52 0.61 4.12 2 2 2 186234 4.48 0.62 4.10 2 2 2 186235 4.49 0.60 4.10 2 2 2 186235 4.61 0.59 4.10 2 2 2 186238 10.18 1.06 16.80 2 2 3 186238 10.24 1.02 16.39 2 2 2 186239 9.03 1.00 15.97 2 2 2 186239 8.97 0.99 15.73 2 2 2 186240 8.84 0.98 15.54 2 2 2 186240 8.90 1.00 15.56 2 2 2 186241 8.95 0.98 15.28 2 2 2 186241 9.07 0.99 15.49 2 2 2 186242 9.00 0.95 15.13 2 2 2 186242 9.09 0.95 15.17 2 2 2 186243 10.22 0.98 14.76 2 2 2 186243 10.19 0.97 14.65 2 2 2 186244 10.33 0.95 14.46 2 2 2 186244 10.30 0.95 14.80 2 2 2 186245 10.60 0.94 14.16 2 2 2 186245 10.67 0.95 14.17 2 2 2 186246 10.58 0.95 14.03 2 2 2 186246 10.62 0.94 13.99 2 2 2 186247 10.40 0.96 13.60 2 2 2 186247 10.32 0.95 13.71 2 2 2 186248 10.32 0.96 13.81 2 2 2 186248 10.36 0.98 13.79 2 2 2 186249 10.03 0.94 13.51 2 2 2 186249 10.11 0.96 13.34 2 2 2 186250 9.79 0.92 12.94 2 2 2 186250 9.99 0.92 12.98 2 2 2 186251 9.83 0.92 12.45 2 2 2 186251 9.82 0.91 13.19 2 2 2 186252 9.80 0.88 12.04 2 2 3 186252 9.78 0.91 11.83 2 2 3 186253 2.98 0.52 1.51 2 3 3 186253 3.06 0.43 2.88 2 3 3 186254 1.88 0.32 0.00 2 3 2 186254 1.90 0.33 0.00 2 3 2 186255 1.92 0.36 0.00 2 3 2 186255 1.87 0.34 0.00 2 3 2 186256 9.83 1.01 16.56 2 2 2 186256 9.85 1.01 16.58 2 2 2 186257 9.57 1.01 16.71 2 2 2 186257 9.59 1.01 16.58 2 2 2 186258 9.51 1.01 16.66 2 2 2 186258 9.62 1.01 16.68 2 2 2 186259 9.55 1.02 16.50 2 2 2 186259 9.50 1.02 16.16 2 2 2 186260 9.20 1.00 16.31 2 2 2 186260 9.09 1.00 16.06 2 2 2 186261 9.13 1.04 16.08 2 3 2 186261 9.23 0.99 15.87 2 3 2 186262 8.91 0.97 15.70 2 2 2 186262 9.06 0.97 15.76 2 2 2 186263 9.08 0.97 15.82 2 2 2 186263 8.89 0.95 15.94 2 2 2 186264 9.00 0.95 15.71 2 2 2 186264 9.41 0.94 15.67 2 2 2 186265 9.21 0.93 15.26 2 2 2 186265 9.22 0.93 15.13 2 2 2 186266 9.23 0.93 14.60 2 2 2 186266 9.33 0.94 15.36 2 2 2 186267 9.32 0.91 14.01 2 2 2 186267 9.28 0.92 14.11 2 2 2 186268 9.45 0.93 14.23 2 2 2 186268 9.43 0.94 14.11 2 2 2 186269 9.59 0.91 13.69 2 2 2 186269 9.66 0.92 13.55 2 2 2 186270 9.96 0.93 13.84 2 2 2 186270 10.00 0.93 13.59 2 2 2 186271 10.20 0.92 13.14 2 2 2 186271 10.01 0.92 13.23 2 2 2 186272 10.45 0.91 12.51 2 2 2 186272 10.47 0.92 12.47 2 2 2 186273 10.41 0.89 11.27 2 2 2 186273 10.49 0.89 11.27 2 2 2 186274 10.41 0.83 9.22 2 2 2 186274 10.55 0.82 9.47 2 2 2 186275 8.09 0.65 5.74 2 2 2 186275 8.08 0.64 6.01 2 2 2 186276 10.37 0.76 7.40 2 2 2 186276 10.32 0.75 7.42 2 2 2 186277 10.51 0.76 7.62 2 2 2 186277 10.55 0.75 7.33 2 2 2 186294 11.92 0.98 16.25 2 2 2 186294 11.94 0.97 16.23 2 2 2 186295 11.74 0.99 16.22 2 2 2 186295 11.69 0.99 16.39 2 2 2 186296 11.01 1.00 16.32 2 2 2 186296 11.02 0.99 16.39 2 2 2 186297 10.66 0.99 16.86 2 2 2 186297 10.70 0.98 16.26 2 2 2 186298 10.04 1.01 16.97 2 2 2 186298 10.06 1.00 16.92 2 3 2 186299 9.90 1.07 16.90 2 3 2 186299 9.89 0.99 16.85 2 2 2 186300 9.91 1.01 16.91 2 2 2 186300 9.90 1.02 16.76 2 2 2 186301 9.53 1.00 16.98 2 2 2 186301 9.54 1.00 16.94 2 2 2 186302 9.10 0.99 16.45 2 2 2 186302 9.24 0.99 16.68 2 2 2 186303 9.11 0.99 16.36 2 2 2 186303 9.12 1.01 16.38 2 2 2 186304 8.94 0.99 16.32 2 2 2 186304 8.96 0.99 16.23 2 2 2 186305 8.92 0.97 16.02 2 2 2 186305 8.97 0.99 16.08 2 2 2 186306 8.95 0.98 16.10 2 2 2 186306 9.06 0.98 16.13 2 2 2 186307 8.79 0.97 16.02 2 2 2 186307 8.93 0.97 16.13 2 2 2 186308 8.78 0.96 15.48 2 2 2 186308 8.95 0.97 15.47 2 2 2 186309 8.95 0.92 14.96 2 2 2 186309 8.99 0.93 14.83 2 2 2 186310 8.66 0.80 12.07 2 2 2 186310 8.80 0.79 12.10 2 2 2 186311 9.04 0.74 9.61 2 2 2 186311 9.15 0.75 9.46 2 2 2 186312 9.67 0.79 9.75 2 2 2 186312 9.56 0.77 9.71 2 2 2 186313 11.74 1.12 15.69 2 3 2 186313 11.75 0.97 15.76 2 3 2 186314 11.86 0.96 15.66 2 2 2 186314 11.90 0.95 15.67 2 2 2 186315 12.12 0.98 15.77 2 2 2 186315 12.32 0.99 15.64 2 2 2 186316 12.03 1.05 16.14 2 2 2 186316 12.17 0.98 16.09 2 2 2 186317 11.68 0.97 16.02 2 2 2 186317 11.73 0.98 15.91 2 2 2 186318 11.24 1.01 16.24 2 2 2 186318 11.29 1.01 16.37 2 2 2 186319 10.65 1.01 16.84 2 2 2 186319 10.67 1.02 16.76 2 2 2 186320 10.26 1.04 16.69 2 2 2 186320 10.24 1.02 16.90 2 2 2 186321 9.83 1.03 16.64 2 2 2 186321 10.00 1.01 16.81 2 2 2 186322 9.77 1.04 16.47 2 2 2 186322 9.82 1.04 16.60 2 2 2 186323 9.49 1.01 16.72 2 2 2 186323 9.50 1.00 16.74 2 2 2 186324 9.14 1.01 16.34 2 2 2 186324 9.25 1.01 16.57 2 2 2 186325 9.04 0.99 16.30 2 2 2 186325 9.06 0.99 16.36 2 2 2 186326 9.05 0.99 15.92 2 2 2 186326 9.13 0.98 15.90 2 2 2 186327 8.96 0.99 15.50 2 2 2 186327 9.03 1.01 15.60 2 2 2 186328 9.12 0.97 15.68 2 2 2 186328 9.10 0.98 15.24 2 2 2 186329 8.93 0.95 14.97 2 3 2 186329 8.95 1.13 14.99 2 3 2 186330 8.72 0.90 13.20 2 2 2 186330 8.79 0.90 13.39 2 2 2 186331 8.83 0.84 12.08 2 2 2 186331 8.92 0.82 12.20 2 2 2 186333 10.88 0.95 14.91 2 2 2 186333 10.93 0.94 14.87 2 2 2 186334 10.90 0.94 14.75 2 2 2 186334 10.93 0.93 14.79 2 2 2 186335 11.00 0.95 15.02 2 2 2 186335 11.07 0.95 15.01 2 2 2 186336 12.23 1.00 15.70 2 2 2 186336 12.33 1.00 15.63 2 2 2 186337 12.08 1.02 15.96 2 2 2 186337 12.10 1.01 15.94 2 2 2 186338 12.03 1.03 16.48 2 2 2 186338 12.08 1.04 16.06 2 2 2 186339 11.71 1.03 16.68 2 2 2 186339 11.70 1.04 16.66 2 2 2 186340 10.99 1.05 16.45 2 2 2 186340 10.76 1.05 16.42 2 2 2 186341 10.04 1.04 16.36 2 2 2 186341 10.11 1.04 16.52 2 2 2 186342 9.79 1.09 16.53 2 2 2 186342 9.90 1.05 16.49 2 2 2 186343 9.62 1.04 16.34 2 2 2 186343 9.61 1.04 16.21 2 2 2 186344 9.92 1.06 16.64 2 2 2 186344 9.93 1.04 16.58 2 2 2 186345 9.49 1.05 16.12 2 2 2 186345 9.66 1.07 16.37 2 2 2 186346 9.20 1.03 15.97 2 2 2 186346 9.36 1.04 16.24 2 2 2 186347 9.19 1.03 16.07 2 2 2 186347 9.03 1.03 16.21 2 2 2 186348 9.22 1.05 16.13 2 2 2 186348 9.17 1.04 16.06 2 2 2 186349 9.11 1.01 15.54 2 2 2 186349 9.18 1.02 15.46 2 2 2 186350 8.95 1.01 15.38 2 2 2 186350 9.02 1.02 15.71 2 2 2 186351 9.00 1.00 14.86 2 2 2 186351 8.95 0.99 14.88 2 2 2 186352 9.06 0.98 15.00 2 2 2 186352 9.11 0.98 14.79 2 2 2 186353 8.70 0.97 14.19 2 2 2 186353 8.72 0.96 14.08 2 2 2 186354 8.58 0.74 9.55 2 2 2 186354 8.60 0.75 9.47 2 2 2 186355 8.63 0.75 9.65 2 2 2 186355 8.59 0.76 9.69 2 2 2 186358 11.77 0.99 14.62 2 2 2 186358 11.76 0.95 14.73 2 2 2 186359 13.46 1.00 15.39 2 2 2 186359 13.99 1.01 15.30 2 2 2 186360 14.26 1.02 15.78 2 2 2 186360 14.44 1.03 16.01 2 2 2 186361 12.95 1.01 15.72 2 2 2 186361 12.80 1.03 15.78 2 2 2 186362 12.73 1.03 16.28 2 2 2 186362 12.73 1.03 16.15 2 2 2 186363 11.56 1.03 16.26 2 2 2 186363 11.59 1.04 16.01 2 2 2 186364 11.54 1.04 16.50 2 2 2 186364 11.70 1.04 16.26 2 2 2 186365 10.75 1.04 16.55 2 2 2 186365 10.53 1.05 16.63 2 2 2 186366 9.76 1.03 16.63 2 2 2 186366 9.74 1.06 16.03 2 2 2 186367 9.67 1.05 16.67 2 2 2 186367 9.73 1.04 16.88 2 2 2 186368 9.74 1.04 16.90 2 2 2 186368 9.77 1.05 16.41 2 2 2 186369 9.79 1.06 16.99 2 2 2 186369 9.81 1.05 16.86 2 2 2 186370 9.97 1.05 17.46 2 2 2 186370 10.01 1.06 16.69 2 2 2 186371 9.77 1.08 17.24 2 2 2 186371 9.79 1.07 17.16 2 2 2 186372 8.91 1.01 16.27 2 2 2 186372 8.98 1.02 16.12 2 2 2 186373 8.91 1.03 16.31 2 2 2 186373 8.93 1.01 15.87 2 2 2 186374 8.89 1.03 16.42 2 2 2 186374 8.93 1.05 16.32 2 2 2 186375 8.65 1.01 16.00 2 2 2 186375 8.68 1.01 15.60 2 2 2 186376 7.92 0.94 14.59 2 2 2 186376 8.01 0.93 14.38 2 2 2 186377 7.88 0.91 13.77 2 2 2 186377 7.93 0.91 13.64 2 2 2 186378 7.78 0.85 12.32 2 2 2 186378 7.76 0.83 12.21 2 2 2 186379 7.22 0.70 9.35 2 2 2 186379 7.28 0.70 9.37 2 2 2 186382 11.19 0.98 15.35 2 2 2 186382 11.30 0.95 15.33 2 2 2 186383 13.53 1.01 15.56 2 2 2 186383 13.55 1.00 15.99 2 2 2 186384 14.53 1.01 16.24 2 2 2 186384 14.63 1.05 16.20 2 2 2 186385 14.23 1.03 16.66 2 2 2 186385 14.82 1.04 16.77 2 2 2 186386 12.30 1.07 16.30 2 2 2 186386 12.39 1.02 16.45 2 2 2 186387 11.36 1.02 16.75 2 2 2 186387 11.50 1.01 16.70 2 2 2 186388 11.09 1.04 16.66 2 2 2 186388 11.00 1.03 16.53 2 2 2 186389 10.39 1.03 17.15 2 2 2 186389 10.50 1.03 17.02 2 2 2 186390 9.88 1.06 17.04 2 2 2 186390 9.88 1.03 16.91 2 2 2 186391 9.69 1.04 17.19 2 2 2 186391 9.70 1.02 17.27 2 2 2 186392 9.83 2.30 16.93 2 3 2 186392 9.89 0.98 16.95 2 2 2 186393 9.79 1.10 17.01 2 2 2 186393 9.82 1.04 17.14 2 2 2 186394 9.69 1.07 17.37 2 2 2 186394 9.69 1.05 17.16 2 2 2 186395 9.65 1.05 17.33 2 2 2 186395 9.70 1.06 17.26 2 2 2 186396 9.87 1.08 17.86 2 2 2 186396 9.75 1.07 17.82 2 2 2 186397 9.27 1.32 16.97 2 3 2 186397 9.40 1.04 17.22 2 3 2 186398 8.63 1.17 16.01 2 3 2 186398 8.66 1.11 16.01 2 3 2 186399 8.45 0.99 15.80 2 2 2 186399 8.53 1.00 15.76 2 2 2 186400 8.01 0.98 15.06 2 2 2 186400 8.20 0.97 14.96 2 2 2 186401 8.08 0.96 14.94 2 2 2 186401 8.11 0.97 15.02 2 2 2 186402 7.47 0.87 13.07 2 3 2 186402 7.52 0.94 12.99 2 3 2 186403 4.86 0.54 7.30 2 3 2 186403 4.90 0.63 7.42 2 3 2 186404 4.76 0.55 7.24 2 2 2 186404 4.74 0.54 7.26 2 2 2 186405 11.38 1.00 15.19 2 2 2 186405 11.41 1.01 15.19 2 2 2 186406 11.84 0.97 15.28 2 2 2 186406 11.89 0.97 15.21 2 2 2 186407 13.27 1.00 16.08 2 2 2 186407 13.39 0.98 16.16 2 2 2 186408 14.90 1.05 16.25 2 2 2 186408 14.95 1.01 16.39 2 2 2 186409 14.06 1.04 16.26 2 2 2 186409 14.25 1.05 16.64 2 2 2 186410 14.26 1.14 16.78 2 3 2 186410 14.35 1.05 16.36 2 3 2 186411 12.85 1.03 16.88 2 2 2 186411 13.14 1.03 17.11 2 2 2 186412 11.82 1.04 16.89 2 2 2 186412 11.79 1.04 16.55 2 2 2 186413 10.62 1.04 16.63 2 2 2 186413 10.76 1.07 16.92 2 2 2 186414 10.06 1.04 16.88 2 2 2 186414 10.11 1.05 16.81 2 2 2 186415 9.73 1.03 16.74 2 3 2 186415 9.75 1.12 16.61 2 3 2 186416 9.75 1.05 16.98 2 2 2 186416 9.84 1.07 16.81 2 2 2 186417 9.77 1.03 17.14 2 2 2 186417 9.97 1.06 17.27 2 2 2 186418 10.05 1.07 16.99 2 2 2 186418 10.10 1.07 17.05 2 2 2 186419 10.17 1.07 17.35 2 2 2 186419 10.24 1.08 17.37 2 2 2 186420 10.34 1.11 17.77 2 2 2 186420 10.30 1.09 17.49 2 2 2 186421 9.40 1.05 16.43 2 2 2 186421 9.46 1.05 16.77 2 2 2 186422 9.68 1.07 17.74 2 2 2 186422 9.82 1.10 17.53 2 2 2 186423 9.20 1.03 16.51 2 2 2 186423 9.20 1.06 16.68 2 2 2 186424 8.93 1.06 15.99 2 2 2 186424 8.99 1.03 15.99 2 2 2 186425 9.09 1.03 16.46 2 2 2 186425 9.12 1.04 15.99 2 2 2 186426 7.86 0.95 14.40 2 2 2 186426 7.96 0.95 14.92 2 2 2 186427 6.81 0.79 11.02 2 2 2 186427 6.91 0.81 10.82 2 2 2 186428 4.76 0.51 6.62 2 2 2 186428 4.70 0.53 6.49 2 2 2 186429 11.30 0.95 14.95 2 2 2 186429 11.36 0.97 14.85 2 2 2 186430 11.78 0.96 14.82 2 2 2 186430 11.85 0.95 15.14 2 2 2 186431 12.53 1.00 15.02 2 2 2 186431 12.70 0.98 15.10 2 2 2 186432 14.70 1.02 16.13 2 2 2 186432 14.74 1.05 15.86 2 2 2 186433 14.54 1.05 16.14 2 2 2 186433 14.55 1.03 16.23 2 2 2 186434 13.31 1.04 16.54 2 2 2 186434 13.40 1.05 16.02 2 2 2 186435 12.31 1.03 16.75 2 2 2 186435 12.51 1.06 16.70 2 2 2 186436 11.33 1.04 16.34 2 2 2 186436 11.37 1.05 16.43 2 2 2 186437 10.43 1.04 16.40 2 2 2 186437 10.48 1.05 16.63 2 2 2 186438 10.13 1.07 16.69 2 2 2 186438 10.06 1.04 16.71 2 2 2 186439 10.08 1.05 16.62 2 2 2 186439 10.02 1.08 16.47 2 2 2 186440 10.08 1.09 16.75 2 2 2 186440 10.10 1.06 16.79 2 2 2 186441 10.27 1.07 17.12 2 2 2 186441 10.29 1.08 16.74 2 2 2 186442 10.14 1.07 16.75 2 2 2 186442 10.10 1.07 16.81 2 2 2 186443 9.69 1.07 16.85 2 2 2 186443 9.74 1.06 16.93 2 2 2 186444 10.32 1.11 17.45 2 2 2 186444 10.34 1.10 17.36 2 2 2 186445 10.62 1.13 17.42 2 2 2 186445 10.73 1.13 17.99 2 2 2 186446 9.36 1.06 16.33 2 2 2 186446 9.25 1.07 16.69 2 2 2 186447 9.32 1.06 16.01 2 2 2 186447 9.26 1.08 15.96 2 2 2 186448 7.92 0.90 13.48 2 2 2 186448 7.95 0.95 13.44 2 2 2 186449 7.54 0.94 14.08 2 2 2 186449 7.59 0.91 14.04 2 2 2 186450 7.38 0.86 12.02 2 2 2 186450 7.35 0.86 11.75 2 2 2 186451 5.64 0.62 7.70 2 2 2 186451 5.66 0.64 7.76 2 2 2 186452 5.27 0.64 7.10 2 2 2 186452 5.31 0.60 7.14 2 2 2 186453 12.29 0.97 14.75 2 2 2 186453 12.32 0.97 14.79 2 2 2 186454 12.43 0.98 14.73 2 2 2 186454 12.42 0.96 14.86 2 2 2 186455 14.15 1.01 15.27 2 2 2 186455 13.94 1.01 15.33 2 2 2 186456 14.86 1.06 16.16 2 2 2 186456 14.94 1.03 16.09 2 2 2 186457 14.56 1.03 16.22 2 2 2 186457 14.66 1.03 15.96 2 2 2 186459 11.63 1.03 15.88 2 2 2 186459 11.47 1.04 15.99 2 2 2 186460 11.81 1.05 16.22 2 2 2 186460 11.82 1.06 16.66 2 2 2 186461 10.29 1.04 16.44 2 2 2 186461 10.40 1.06 16.44 2 2 2 186462 9.96 1.02 16.66 2 2 2 186462 9.98 1.04 16.19 2 2 2 186463 10.02 1.04 16.69 2 2 2 186463 10.02 1.09 16.92 2 2 2 186464 9.94 1.04 16.56 2 2 2 186464 9.91 1.04 16.95 2 2 2 186465 10.28 1.05 17.06 2 2 2 186465 10.37 1.05 16.73 2 2 2 186466 10.01 1.07 17.19 2 2 2 186466 10.04 1.04 16.82 2 2 2 186467 10.11 1.05 16.91 2 2 2 186467 10.17 1.05 17.34 2 2 2 186468 10.24 1.08 17.56 2 2 2 186468 10.36 1.09 17.71 2 2 2 186469 10.03 1.12 17.32 2 2 2 186469 10.13 1.11 17.28 2 2 2 186470 9.59 1.07 16.65 2 2 2 186470 9.62 1.08 16.63 2 2 2 186471 8.29 0.98 14.92 2 2 2 186471 8.41 1.03 15.01 2 2 2 186472 8.59 0.99 14.94 2 2 2 186472 8.65 0.99 15.25 2 2 2 186473 7.43 0.90 13.44 2 2 2 186473 7.49 0.91 13.42 2 2 2 186474 6.46 0.77 10.57 2 2 2 186474 6.46 0.77 10.61 2 2 2 186475 5.54 0.66 9.45 2 2 2 186475 5.57 0.68 9.47 2 2 2 186476 4.84 0.57 7.97 2 2 2 186476 4.81 0.57 7.82 2 2 2 186492 13.72 1.01 15.42 2 2 2 186492 13.81 1.00 15.51 2 2 2 186493 15.44 1.02 15.94 2 2 2 186493 15.45 1.03 15.86 2 2 2 186494 15.14 1.06 16.38 2 2 2 186494 15.17 1.05 16.42 2 2 2 186495 15.42 1.06 16.66 2 2 2 186495 15.52 1.06 16.29 2 2 2 186496 14.23 1.06 16.38 2 2 2 186496 14.42 1.07 16.55 2 2 2 186497 13.29 1.05 16.66 2 2 2 186497 13.41 1.06 16.36 2 2 2 186498 12.25 1.04 16.34 2 2 2 186498 12.50 1.06 16.62 2 2 2 186499 11.64 1.07 16.64 2 2 2 186499 11.61 1.05 16.58 2 2 2 186500 10.51 1.06 16.43 2 2 2 186500 10.66 1.05 16.51 2 2 2 186501 10.30 1.04 16.50 2 2 2 186501 10.36 1.04 16.45 2 2 2 186502 10.29 1.07 16.97 2 2 2 186502 10.39 1.09 16.45 2 2 2 186503 10.19 1.06 16.71 2 2 2 186503 10.35 1.05 16.82 2 2 2 186504 10.56 1.20 17.17 2 2 2 186504 10.62 1.06 16.98 2 2 2 186505 10.30 1.07 16.76 2 2 2 186505 10.37 1.19 17.11 2 2 2 186506 10.36 1.07 17.33 2 2 2 186506 10.49 1.09 17.15 2 2 2 186507 10.45 1.09 17.11 2 2 2 186507 10.29 1.07 17.24 2 2 2 186508 10.11 1.10 17.46 2 2 2 186508 10.26 1.10 17.09 2 2 2 186509 9.68 1.06 16.77 2 2 2 186509 9.75 1.07 16.88 2 2 2 186510 8.38 0.98 14.65 2 2 2 186510 8.44 0.98 15.14 2 2 2 186511 8.13 0.96 14.54 2 2 2 186511 8.13 0.94 14.65 2 2 2 186512 7.97 0.95 13.76 2 2 2 186512 7.99 0.93 14.02 2 2 2 186513 7.93 0.93 13.68 2 2 2 186513 7.99 0.93 13.72 2 2 2 186514 4.43 0.63 8.29 2 2 2 186514 4.52 0.64 8.31 2 2 2 186515 1.27 0.44 6.00 2 2 2 186515 1.28 0.43 6.08 2 2 2 186516 13.93 0.99 15.21 2 2 2 186516 14.09 1.00 15.54 2 2 2 186517 15.71 1.03 15.50 2 2 2 186517 15.58 1.02 15.43 2 2 2 186518 15.83 1.05 16.23 2 2 2 186518 15.77 1.03 16.19 2 2 2 186519 15.40 1.04 16.32 2 2 2 186519 15.58 1.05 16.04 2 2 2 186520 14.36 1.06 16.34 2 2 2 186520 14.39 1.04 16.17 2 2 2 186521 13.33 1.04 16.39 2 2 2 186521 13.33 1.04 16.26 2 2 2 186522 12.45 1.04 16.24 2 2 2 186522 12.51 1.05 16.19 2 2 2 186523 11.82 1.06 16.28 2 2 2 186523 11.89 1.04 16.54 2 2 2 186524 10.54 1.04 16.28 2 2 2 186524 10.60 1.06 16.43 2 2 2 186525 10.31 1.03 16.63 2 2 2 186525 10.19 1.04 16.50 2 2 2 186526 10.28 1.04 16.72 2 2 2 186526 10.25 1.03 16.37 2 2 2 186527 10.22 1.06 16.37 2 2 2 186527 10.25 1.07 16.66 2 2 2 186528 10.47 1.05 16.66 2 2 2 186528 10.54 1.12 17.07 2 2 2 186529 10.60 1.07 17.03 2 2 2 186529 10.44 1.06 16.55 2 2 2 186530 10.63 1.07 17.18 2 2 2 186530 10.66 1.07 16.81 2 2 2 186531 10.63 1.09 17.20 2 2 2 186531 10.82 1.15 17.49 2 2 2 186532 10.10 1.08 16.62 2 2 2 186532 10.16 1.07 17.01 2 2 2 186533 9.17 1.01 15.97 2 2 2 186533 9.02 1.01 15.34 2 2 2 186534 8.51 0.96 14.74 2 2 2 186534 8.44 0.98 14.63 2 2 2 186535 7.55 0.92 13.58 2 2 2 186535 7.58 0.89 13.70 2 2 2 186536 7.88 0.90 13.84 2 2 2 186536 7.92 0.92 13.94 2 2 2 186537 3.28 0.57 7.81 2 2 2 186537 3.21 0.55 7.62 2 2 2 186538 2.80 0.52 7.49 2 2 2 186538 2.82 0.52 7.41 2 2 2 186539 2.75 0.54 7.39 2 2 2 186539 2.81 0.53 7.22 2 2 2 186540 15.23 1.04 16.23 2 2 2 186540 15.38 1.00 15.95 2 2 2 186541 15.59 1.02 16.22 2 2 2 186541 15.37 1.02 16.11 2 2 2 186542 15.70 1.06 17.02 2 2 2 186542 15.60 1.03 16.63 2 2 2 186543 14.90 1.03 16.62 2 2 2 186543 15.07 1.03 16.78 2 2 2 186544 14.49 1.04 16.75 2 2 2 186544 14.67 1.05 16.95 2 2 2 186545 13.42 1.04 16.76 2 2 2 186545 13.35 1.04 16.77 2 2 2 186546 12.31 1.05 17.10 2 2 2 186546 12.44 1.04 16.54 2 2 2 186547 11.61 1.04 17.06 2 2 2 186547 11.70 1.04 16.97 2 2 2 186548 10.98 1.04 16.61 2 2 2 186548 11.07 1.02 16.92 2 2 2 186549 10.47 1.04 17.27 2 2 2 186549 10.40 1.04 17.27 2 2 2 186550 10.03 1.04 17.05 2 2 2 186550 9.99 1.05 17.34 2 2 2 186551 10.11 1.05 17.55 2 2 2 186551 10.13 1.05 17.19 2 2 2 186552 10.09 1.03 17.30 2 2 2 186552 10.22 1.04 17.18 2 2 2 186553 10.27 1.06 17.67 2 2 2 186553 10.20 1.06 17.38 2 2 2 186579 15.17 1.02 16.64 2 2 2 186579 15.33 1.01 16.26 2 2 2 186580 14.56 1.04 16.44 2 2 2 186580 14.69 1.04 17.05 2 2 2 186581 14.22 1.04 17.04 2 2 2 186581 14.40 1.02 16.99 2 2 2 186582 13.80 1.03 16.84 2 2 2 186582 13.73 1.03 16.84 2 2 2 186583 12.53 1.06 17.12 2 2 2 186583 12.51 1.02 16.96 2 2 2 186584 11.87 1.04 16.95 2 2 2 186584 11.87 1.06 17.07 2 2 2 186585 10.96 1.04 16.92 2 2 2 186585 10.98 1.04 16.83 2 2 2 186586 10.20 1.05 17.28 2 2 2 186586 10.19 1.05 17.24 2 2 2 186587 9.81 1.02 17.00 2 2 2 186587 9.84 1.03 17.09 2 2 2 186588 9.73 1.03 17.34 2 2 2 186588 9.77 1.05 17.00 2 2 2 186589 9.67 1.04 16.68 2 2 2 186589 9.69 1.04 17.09 2 2 2 186590 9.80 1.04 17.18 2 2 2 186590 9.69 1.05 17.27 2 2 2 186591 9.89 1.04 17.30 2 2 2 186591 9.88 1.06 17.11 2 2 2 186592 9.94 1.05 17.39 2 2 2 186592 10.12 1.07 17.84 2 2 2 186593 9.83 1.07 17.52 2 2 2 186593 9.83 1.07 17.57 2 2 2 186594 8.46 0.99 15.94 2 2 2 186594 8.42 1.01 15.89 2 2 2 186595 9.13 1.05 16.60 2 2 2 186595 9.24 1.05 16.87 2 2 2 186596 8.55 1.02 15.96 2 2 2 186596 8.64 1.03 16.02 2 2 2 186597 8.54 1.02 15.99 2 2 2 186597 8.64 1.01 15.79 2 2 2 186598 8.19 0.97 15.31 2 2 2 186598 8.00 0.97 15.03 2 2 2 186599 7.75 0.95 14.62 2 2 2 186599 7.68 0.96 14.77 2 2 2 186600 3.80 0.70 10.47 2 2 2 186600 3.81 0.69 10.57 2 2 2 186601 2.37 0.60 9.03 2 2 2 186601 2.47 0.66 9.43 2 2 2 186602 2.34 0.61 9.09 2 2 2 186602 2.39 0.66 9.21 2 2 2 186603 14.61 1.06 15.89 2 2 2 186603 14.78 1.01 15.86 2 2 2 186604 14.35 1.04 16.15 2 2 2 186604 14.48 1.07 16.54 2 2 2 186605 14.39 1.06 16.15 2 2 2 186605 14.45 1.05 16.34 2 2 2 186606 13.72 1.05 16.42 2 2 2 186606 13.79 1.05 16.27 2 2 2 186607 13.24 1.07 16.23 2 2 2 186607 13.28 1.04 16.34 2 2 2 186608 12.45 1.08 16.48 2 2 2 186608 12.49 1.06 16.53 2 2 2 186609 11.20 1.05 16.44 2 2 2 186609 11.25 1.07 16.54 2 2 2 186610 10.50 1.06 16.57 2 2 2 186610 10.53 1.05 16.45 2 2 2 186611 9.93 1.06 16.24 2 2 2 186611 9.83 1.06 16.25 2 2 2 186612 9.67 1.06 16.53 2 2 2 186612 9.70 1.06 16.51 2 2 2 186613 9.82 1.07 15.64 2 2 2 186613 9.84 1.07 15.63 2 2 2 186614 9.90 1.06 16.31 2 2 2 186614 9.92 1.06 16.43 2 2 2 186615 10.13 1.08 16.28 2 2 2 186615 10.16 1.08 16.56 2 2 2 186616 10.15 1.07 16.97 2 2 2 186616 10.28 1.11 16.92 2 2 2 186617 10.11 1.10 17.11 2 2 2 186617 10.23 1.10 16.88 2 2 2 186618 8.51 1.03 15.49 2 2 2 186618 8.52 1.01 15.38 2 2 2 186619 8.90 1.04 15.82 2 2 2 186619 8.84 1.06 15.79 2 2 2 186620 8.76 1.07 14.72 2 2 2 186620 8.89 1.06 15.30 2 2 2 186621 8.01 1.07 12.80 2 2 2 186621 8.02 1.08 12.86 2 2 2 186622 7.64 1.05 12.48 2 2 2 186622 7.66 1.06 12.60 2 2 2 186623 7.69 1.04 12.47 2 2 2 186623 7.74 1.06 13.02 2 2 2 186624 7.36 1.02 12.47 2 2 2 186624 7.42 1.02 12.84 2 2 2 186625 4.20 0.73 8.91 2 2 2 186625 4.27 0.73 8.90 2 2 2 186626 4.13 0.72 8.85 2 2 2 186626 4.13 0.70 8.87 2 2 2 186627 14.60 1.09 14.50 2 2 2 186627 14.42 1.09 14.33 2 2 2 186628 14.28 1.09 14.49 2 2 2 186628 14.38 1.09 14.83 2 2 2 186629 14.40 1.09 14.80 2 2 2 186629 14.42 1.07 14.84 2 2 2 186630 13.45 1.08 15.11 2 2 2 186630 13.48 1.07 15.30 2 2 2 186631 12.76 1.08 15.18 2 2 2 186631 12.91 1.08 15.08 2 2 2 186632 12.27 1.11 15.32 2 2 2 186632 12.28 1.09 15.49 2 2 2 186633 11.43 1.10 15.34 2 2 2 186633 11.64 1.08 15.33 2 2 2 186634 10.79 1.09 15.40 2 2 2 186634 10.80 1.08 15.47 2 2 2 186635 9.79 1.07 15.26 2 2 2 186635 9.82 1.07 15.14 2 2 2 186636 9.71 1.08 15.39 2 2 2 186636 9.75 1.08 15.45 2 2 2 186637 9.98 1.05 15.47 3 3 3 186637 9.93 1.06 15.44 3 3 3 186638 10.01 1.07 16.02 3 3 3 186638 9.94 1.06 16.07 3 3 3 186639 10.02 1.07 16.14 3 3 3 186639 10.21 1.06 16.07 3 3 3 186640 9.89 1.06 16.49 3 3 3 186640 9.94 1.05 16.33 3 3 3 186641 10.12 1.07 16.56 3 3 3 186641 10.12 1.08 16.94 3 3 3 186642 9.89 1.07 16.91 3 3 3 186642 9.92 1.07 16.92 3 3 3 186643 9.29 1.03 16.10 3 3 3 186643 9.32 1.04 16.20 3 3 3 186644 8.87 1.02 15.82 3 3 3 186644 8.94 1.02 15.70 3 3 3 186645 8.44 0.98 15.54 3 3 3 186645 8.43 0.98 15.67 3 3 3 186646 8.33 0.96 15.21 3 3 3 186646 8.27 0.96 15.26 3 3 3 186647 8.17 0.93 14.40 3 3 3 186647 8.25 0.93 14.68 3 3 3 186648 4.30 0.68 10.37 3 3 3 186648 4.37 0.69 10.44 3 3 3 186649 3.58 0.65 9.80 3 3 3 186649 3.50 0.65 9.87 3 3 3 186650 3.51 0.65 9.81 4 3 3 186650 5.51 0.63 9.64 4 3 3 186651 14.30 1.03 15.76 2 2 2 186651 14.34 1.01 15.76 2 2 2 186652 14.94 1.02 15.88 2 2 2 186652 15.02 1.02 15.88 2 2 2 186653 14.77 1.03 16.19 2 2 2 186653 14.63 1.05 15.96 2 2 2 186654 13.89 1.02 16.44 2 2 2 186654 13.87 1.04 16.32 2 2 2 186655 13.27 1.04 16.32 2 2 2 186655 13.31 1.05 16.07 2 2 2 186656 12.57 1.06 16.55 2 2 2 186656 12.81 1.04 16.75 2 2 2 186657 11.75 1.04 16.65 2 2 2 186657 11.73 1.06 16.46 2 2 2 186658 10.77 1.05 16.48 2 2 2 186658 10.94 1.06 16.51 2 2 2 186659 10.11 1.02 16.63 2 2 2 186659 10.11 1.05 16.47 2 2 2 186660 9.79 1.03 16.67 2 2 2 186660 10.10 1.02 16.41 2 2 2 186661 10.19 1.01 16.88 2 2 2 186661 10.16 1.01 16.80 2 2 2 186662 10.28 1.05 16.95 2 2 2 186662 10.12 1.03 16.58 2 2 2 186663 10.12 1.03 16.64 2 2 2 186663 10.21 1.02 17.07 2 2 2 186664 10.18 1.04 16.95 2 2 2 186664 10.18 1.02 17.17 2 2 2 186665 10.86 1.05 17.03 3 2 2 186665 11.40 1.04 16.97 3 2 2 186666 10.01 1.04 17.14 2 2 2 186666 10.14 1.06 17.26 2 2 2 186667 9.49 1.05 16.97 2 2 2 186667 9.61 1.03 16.91 2 2 2 186668 8.62 0.98 15.81 2 2 2 186668 8.69 0.98 15.56 2 2 2 186669 8.39 0.98 15.72 2 2 2 186669 8.39 0.97 15.74 2 2 2 186670 8.28 0.97 15.46 2 2 2 186670 8.37 0.96 15.46 2 2 2 186671 8.23 0.95 15.40 2 2 2 186671 8.24 0.95 15.32 2 2 2 186672 7.72 0.75 11.55 2 2 2 186672 7.78 0.76 11.49 2 2 2 186673 7.58 0.75 11.39 2 2 2 186673 7.67 0.74 11.62 2 2 2 186674 7.60 0.73 11.31 2 2 2 186674 7.53 0.74 11.29 2 2 2 186690 14.27 1.01 15.47 2 2 2 186690 14.29 0.99 15.76 2 2 2 186691 14.75 1.00 16.03 2 2 2 186691 15.29 1.01 16.25 2 2 2 186692 14.74 1.03 16.17 2 2 2 186692 14.86 1.02 16.46 2 2 2 186693 13.60 1.01 16.46 2 2 2 186693 13.62 1.02 16.34 2 2 2 186694 12.55 1.03 16.44 2 2 2 186694 12.60 1.03 16.71 2 2 2 186695 11.94 1.02 16.65 3 2 2 186695 12.87 1.04 16.46 3 2 2 186696 10.89 1.03 16.65 2 2 2 186696 11.16 1.03 16.88 2 2 2 186697 10.08 1.02 16.40 2 2 2 186697 9.99 1.03 16.53 2 2 2 186698 9.75 1.02 16.76 2 2 2 186698 9.79 1.04 16.49 2 2 2 186699 9.77 1.03 16.53 3 2 2 186699 11.42 1.04 16.92 3 2 2 186700 9.80 1.02 16.54 2 2 2 186700 9.90 1.03 16.70 2 2 2 186701 9.94 1.03 16.80 2 2 2 186701 10.07 1.04 16.95 2 2 2 186702 10.04 1.03 16.76 2 2 2 186702 10.18 1.04 16.80 2 2 2 186703 9.86 1.06 16.87 2 2 2 186703 10.03 1.06 16.82 2 2 2 186704 9.06 1.01 16.56 2 2 2 186704 9.13 1.02 16.60 2 2 2 186705 9.04 1.02 16.25 2 2 2 186705 8.99 1.03 16.44 2 2 2 186706 9.07 1.03 16.18 2 2 2 186706 9.11 1.02 16.20 2 2 2 186708 8.49 1.00 15.97 2 2 2 186708 8.53 1.00 15.44 2 2 2 186709 8.35 0.98 15.69 3 2 2 186709 10.25 0.99 15.75 3 2 2 186710 8.17 0.93 14.35 2 2 2 186710 8.20 0.95 14.64 2 2 2 186711 6.89 0.77 11.89 2 2 2 186711 6.90 0.77 11.87 2 2 2 186712 6.46 0.73 11.12 2 2 2 186712 6.47 0.73 11.18 2 2 2 186713 6.66 0.73 11.35 2 2 2 186713 6.67 0.73 11.20 2 2 2 186714 13.13 0.99 15.39 2 2 2 186714 13.12 1.01 15.60 2 2 2 186715 14.51 1.05 15.76 2 2 2 186715 14.54 1.03 15.82 2 2 2 186716 14.48 1.03 16.36 2 2 2 186716 14.57 1.03 16.30 2 2 2 186717 13.94 1.08 16.26 2 2 2 186717 14.03 1.03 16.24 2 2 2 186718 12.90 1.06 16.38 2 2 2 186718 12.96 1.05 16.53 2 2 2 186719 12.20 1.05 16.24 2 2 2 186719 12.24 1.05 16.40 2 2 2 186720 11.42 1.06 16.20 2 2 2 186720 11.61 1.07 16.73 2 2 2 186721 10.10 1.09 16.57 2 2 2 186721 10.16 1.04 16.45 2 2 2 186722 9.91 1.09 16.47 2 2 2 186722 9.75 1.05 16.26 2 2 2 186723 9.94 1.05 16.25 2 2 2 186723 10.08 1.06 16.33 2 2 2 186724 9.97 1.05 16.19 2 2 2 186724 10.05 1.05 16.52 2 2 2 186725 10.04 1.06 16.47 2 2 2 186725 10.30 1.05 16.52 2 2 2 186726 10.16 1.06 16.64 2 2 2 186726 10.18 1.05 16.74 2 2 2 186727 10.01 1.07 16.74 2 2 2 186727 10.14 1.08 16.70 2 2 2 186728 9.16 1.03 16.25 2 2 2 186728 9.34 1.04 15.93 2 2 2 186729 9.23 1.04 16.15 3 2 2 186729 9.68 1.02 16.13 3 2 2 186730 9.19 1.04 16.18 2 2 2 186730 9.07 1.05 16.19 2 2 2 186731 8.80 1.03 15.63 2 2 2 186731 9.00 1.03 16.08 2 2 2 186732 8.79 1.03 15.69 2 2 2 186732 8.89 1.04 15.85 2 2 2 186733 8.74 1.07 16.06 2 2 2 186733 8.82 1.03 15.84 2 2 2 186734 8.79 1.01 15.92 3 2 2 186734 9.46 1.03 15.49 3 2 2 186735 8.73 1.01 15.22 2 2 2 186735 8.77 1.01 15.53 2 2 2 186736 8.17 0.88 13.43 2 2 2 186736 8.18 0.89 13.55 2 2 2 186737 8.07 0.85 12.48 2 2 2 186737 8.09 0.85 12.73 2 2 2 186738 8.70 0.91 13.70 2 2 2 186738 8.63 0.92 13.76 2 2 2 186739 11.84 0.98 14.93 2 2 2 186739 11.84 0.99 14.99 2 2 2 186740 13.59 1.02 16.09 2 2 2 186740 13.62 1.01 15.68 2 2 2 186741 13.45 1.04 16.34 2 2 2 186741 13.45 1.04 16.34 2 2 2 186742 12.51 1.13 16.21 2 2 2 186742 12.58 1.14 16.09 2 2 2 186743 12.03 1.15 16.36 2 2 2 186743 12.57 1.14 16.71 2 2 2 186744 11.00 1.14 16.48 2 2 2 186744 11.13 1.12 16.52 2 2 2 186745 9.81 1.14 16.19 2 2 2 186745 9.91 1.17 16.33 2 2 2 186746 9.47 1.03 16.44 2 2 2 186746 9.69 1.04 16.64 2 2 2 186747 9.62 1.03 16.60 2 2 2 186747 9.78 1.03 16.77 2 2 2 186748 9.74 1.04 16.48 2 2 2 186748 9.61 1.02 16.50 2 2 2 186749 9.73 1.04 16.54 2 2 2 186749 9.69 1.04 16.87 2 2 2 186750 9.82 1.04 16.87 2 2 2 186750 9.97 1.07 16.80 2 2 2 186751 9.77 1.05 16.95 2 2 2 186751 9.81 1.06 16.53 2 2 2 186752 9.60 1.05 17.03 2 2 2 186752 9.58 1.03 17.11 2 2 2 186753 8.83 1.02 16.18 2 2 2 186753 8.90 1.01 16.14 2 2 2 186754 8.75 0.98 15.68 2 2 2 186754 8.77 0.98 16.24 2 2 2 186755 8.70 1.00 16.34 2 2 2 186755 8.83 0.99 16.28 2 2 2 186756 8.76 1.01 16.11 2 2 2 186756 8.72 1.00 15.76 2 2 2 186757 8.59 1.00 16.28 2 2 2 186757 8.59 1.02 16.15 2 2 2 186758 8.52 0.99 15.82 2 2 2 186758 8.71 0.99 15.57 2 2 2 186759 8.45 0.96 15.32 2 2 2 186759 8.51 0.95 15.24 2 2 2 186760 8.02 0.85 13.05 2 2 2 186760 7.96 0.83 12.95 2 2 2 186761 7.82 0.81 12.47 2 2 2 186761 7.95 0.80 12.51 2 2 2 186777 8.31 0.88 13.93 2 2 2 186777 8.40 0.90 14.22 2 2 2 186778 11.55 0.97 15.19 2 2 2 186778 11.61 0.99 15.25 2 2 2 186779 9.44 0.96 4.82 2 2 2 186779 9.37 0.94 4.69 2 2 2 186780 13.35 1.02 15.83 2 2 2 186780 13.28 1.02 15.81 2 2 2 186781 12.80 1.04 16.54 2 2 2 186781 12.93 1.04 16.58 2 2 2 186782 11.51 1.04 16.18 2 2 2 186782 11.52 1.04 16.51 2 2 2 186783 10.39 1.03 16.18 2 2 2 186783 10.35 1.03 16.20 2 2 2 186784 9.77 1.03 16.57 2 2 2 186784 9.87 1.04 16.43 2 2 2 186785 9.69 1.00 16.36 2 2 2 186785 9.71 1.03 16.32 2 2 2 186786 9.74 1.04 16.57 2 2 2 186786 9.77 1.04 16.65 2 2 2 186787 9.82 1.05 16.80 2 2 2 186787 9.70 1.04 16.65 2 2 2 186788 9.88 1.04 17.05 2 2 2 186788 9.85 1.03 17.01 2 2 2 186789 9.75 1.06 17.00 2 2 2 186789 9.81 1.06 16.63 2 2 2 186790 8.81 1.01 15.92 2 2 2 186790 8.88 1.02 15.92 2 2 2 186791 8.80 1.03 16.19 2 2 2 186791 8.90 1.03 16.26 2 2 2 186792 8.76 1.02 16.15 2 2 2 186792 8.82 1.03 15.94 2 2 2 186793 8.74 1.01 15.90 2 2 2 186793 8.77 1.02 16.35 2 2 2 186794 8.73 1.02 16.23 2 2 2 186794 8.76 1.02 16.17 2 2 2 186795 8.81 1.02 16.21 2 2 2 186795 8.85 1.03 15.69 2 2 2 186796 8.68 1.04 15.81 2 2 2 186796 8.68 1.01 15.98 2 2 2 186797 8.19 0.91 13.80 2 2 2 186797 8.29 0.91 13.37 2 2 2 186798 8.28 0.88 13.43 2 2 2 186798 8.34 0.87 13.28 2 2 2 186800 8.43 0.87 13.30 2 2 2 186800 8.46 0.89 13.02 2 2 2 186801 10.08 1.07 15.06 2 3 2 186801 9.72 1.01 14.94 2 3 2 186802 10.21 0.98 15.02 2 2 2 186802 10.24 1.79 14.73 2 3 2 186803 10.59 1.11 15.72 2 2 2 186803 10.65 1.02 15.37 2 2 2 186804 10.89 1.86 16.42 2 3 2 186804 10.96 1.08 16.16 2 2 2 186805 9.90 1.16 16.07 2 2 2 186805 9.93 1.06 16.26 2 2 2 186806 9.57 1.10 16.63 2 2 2 186806 9.67 1.11 16.53 2 2 2 186807 9.75 1.12 16.69 2 2 2 186807 9.78 1.10 16.61 2 2 2 186808 9.65 1.04 16.73 2 2 2 186808 9.81 1.06 16.65 2 2 2 186809 8.97 1.03 16.07 2 2 2 186809 8.94 1.03 15.65 2 2 2 186810 9.33 1.04 15.94 2 2 2 186810 9.45 1.04 16.04 2 2 2 186811 9.22 1.03 16.13 2 2 2 186811 9.25 1.09 15.63 2 2 2 186812 8.80 1.04 14.28 2 2 2 186812 8.86 1.07 14.73 2 2 2 186813 8.34 1.05 12.95 2 2 2 186813 8.44 1.04 13.41 2 2 2 186814 7.88 1.03 12.31 2 2 2 186814 7.99 1.02 12.60 2 2 2 186815 7.75 1.05 11.11 2 2 2 186815 7.88 0.96 11.26 2 2 2 186816 7.77 1.01 10.64 2 2 2 186816 7.84 1.00 10.86 2 2 2 186817 7.80 1.07 10.88 2 2 2 186817 7.76 1.01 10.84 2 2 2 186819 5.90 0.75 10.60 2 2 2 186819 5.97 0.78 10.49 2 2 2 186821 5.04 0.68 7.85 2 2 2 186821 5.28 0.66 8.01 2 2 2 186823 4.67 0.64 7.34 2 2 2 186823 4.74 0.64 7.26 2 2 2 186825 4.60 0.62 7.12 2 2 2 186825 4.62 0.65 7.06 2 2 2 186827 4.47 0.62 6.88 2 2 2 186827 4.49 0.63 6.96 2 2 2 186832 4.39 0.63 6.63 2 2 2 186832 4.42 0.62 6.59 2 2 2 186842 9.00 1.01 15.68 2 2 2 186842 9.02 1.01 16.05 2 2 2 186843 8.81 1.04 16.37 2 2 2 186843 8.83 1.04 16.29 2 2 2 186844 8.90 1.05 16.42 2 2 2 186844 8.94 1.04 16.42 2 2 2 186845 8.87 1.03 16.48 2 2 2 186845 8.79 1.04 16.29 2 2 2 186847 8.23 1.01 15.53 2 2 2 186847 8.21 1.01 15.85 2 2 2 186848 7.81 0.97 15.19 2 2 2 186848 7.90 0.99 15.06 2 2 2 186849 7.33 0.94 14.68 2 2 2 186849 7.44 0.96 15.08 2 2 2 186850 7.11 0.94 14.03 2 2 2 186850 7.10 0.92 13.96 2 2 2 186851 6.61 0.86 12.50 2 2 2 186851 6.68 0.84 12.45 2 2 2 186852 6.58 0.85 12.50 2 2 2 186852 6.66 0.87 12.47 2 2 2 186853 6.34 0.83 12.11 2 2 2 186853 6.38 0.82 11.60 2 2 2 186854 6.30 0.84 11.93 2 2 2 186854 6.22 0.82 11.99 2 2 2 186855 6.08 0.80 11.33 2 2 2 186855 5.91 0.81 10.89 2 2 2 186856 5.80 0.76 10.65 2 2 2 186856 5.89 0.78 10.71 2 2 2 186857 6.18 0.79 10.61 2 2 2 186857 6.23 0.81 10.77 2 2 2 186859 6.20 0.80 10.90 2 2 2 186859 6.09 0.79 10.90 2 2 2 186861 5.78 0.76 10.27 2 2 2 186861 5.80 0.78 10.19 2 2 2 186866 1.50 0.27 0.47 2 2 2 186866 1.52 0.26 0.39 2 2 2 186873 8.81 1.05 15.95 2 2 2 186873 9.04 1.04 15.64 2 2 2 186874 8.59 1.02 15.62 2 2 2 186874 8.53 1.00 15.83 2 2 2 186875 8.81 1.02 15.62 2 2 2 186875 8.41 1.02 15.42 2 2 2 186876 8.04 0.99 15.33 2 2 2 186876 8.07 0.98 15.21 2 2 2 186877 7.99 1.01 15.37 2 2 2 186877 8.07 1.00 15.27 2 2 2 186878 7.93 0.98 15.19 2 2 2 186878 7.90 0.98 15.06 2 2 2 186879 7.61 0.98 15.12 2 2 2 186879 7.64 0.97 14.94 2 2 2 186880 7.58 0.95 14.75 2 2 2 186880 7.61 0.96 14.55 2 2 2 186881 7.46 14.51 2 5 2 186881 7.32 0.91 14.05 2 2 2 186882 6.95 0.90 12.83 2 2 2 186882 6.87 0.88 12.96 2 2 2 186883 6.18 0.81 11.73 2 2 2 186883 6.18 0.82 11.59 2 2 2 186884 3.43 0.50 5.64 2 2 2 186884 3.92 0.49 5.72 2 2 2 186902 10.74 1.02 15.48 2 2 2 186902 11.03 1.01 15.36 2 2 2 186903 10.91 1.00 15.05 2 2 2 186903 10.89 1.00 15.54 2 2 2 186904 10.71 1.02 15.50 2 2 2 186904 10.80 1.02 15.48 2 2 2 186905 10.77 1.02 15.28 2 2 2 186905 10.89 1.01 15.54 2 2 2 186907 10.51 1.05 15.80 2 2 2 186907 10.54 1.06 15.93 2 2 2 186908 11.21 1.08 15.52 3 2 2 186908 10.11 1.06 15.62 3 2 2 186909 10.00 1.06 15.68 2 2 2 186909 9.88 1.08 15.64 2 2 2 186910 9.68 1.07 16.23 2 2 2 186910 9.79 1.10 16.17 2 2 2 186911 9.82 1.05 16.63 2 2 2 186911 9.85 1.05 16.49 2 2 2 186912 9.74 1.06 16.65 2 2 2 186912 9.74 1.04 16.67 2 2 2 186913 9.39 1.06 16.79 2 2 2 186913 9.42 1.05 16.61 2 2 2 186914 9.19 1.03 16.56 2 2 2 186914 9.22 1.04 16.58 2 2 2 186915 8.41 1.01 15.69 2 2 2 186915 8.46 1.01 16.26 2 2 2 186916 8.00 0.97 15.57 2 2 2 186916 7.97 0.98 15.51 2 2 2 186917 7.54 0.95 14.28 2 2 2 186917 7.54 0.95 14.59 2 2 2 186918 7.33 0.94 14.00 2 2 2 186918 7.36 0.92 14.16 2 2 2 186920 4.89 0.68 8.99 2 2 2 186920 5.27 0.65 8.99 2 2 2 186921 2.34 0.38 2.64 2 3 2 186921 2.25 0.37 2.57 2 3 2 186922 9.45 0.97 14.56 2 2 2 186922 9.60 0.96 14.53 2 2 2 186923 9.45 0.96 14.69 2 2 2 186923 9.89 0.96 14.71 2 2 2 186924 9.85 15.18 2 5 2 186924 9.66 0.97 14.65 2 2 2 186925 9.98 0.97 15.17 2 2 2 186925 9.92 0.98 14.97 2 2 2 186926 11.52 1.02 15.48 2 2 2 186926 11.52 1.00 15.31 2 2 2 186927 11.44 1.01 15.66 2 2 2 186927 11.47 1.03 15.62 2 2 2 186928 11.24 1.03 15.55 2 2 2 186928 11.32 1.00 15.47 2 2 2 186929 10.30 1.03 16.02 2 2 2 186929 10.27 1.02 15.95 2 2 2 186930 10.21 1.06 15.85 2 2 2 186930 10.42 1.06 16.12 2 2 2 186931 9.42 1.04 16.62 2 2 2 186931 9.57 1.06 16.52 2 2 2 186932 9.63 1.05 16.60 2 2 2 186932 9.63 1.06 16.15 2 2 2 186933 9.54 1.07 16.77 2 2 2 186933 9.45 1.05 16.79 2 2 2 186934 9.66 1.10 16.43 2 2 2 186934 9.66 1.06 16.79 2 2 2 186935 9.28 1.07 16.25 2 2 2 186935 9.33 1.07 16.53 2 2 2 186936 16.92 5 5 2 186936 8.98 1.16 16.29 2 2 2 186937 8.78 1.01 16.04 2 2 2 186937 8.95 1.05 15.78 2 2 2 186938 8.39 1.02 15.82 2 2 2 186938 8.48 1.02 15.42 2 2 2 186939 8.13 0.97 15.01 2 2 2 186939 8.13 0.99 14.87 2 2 2 186940 7.69 0.90 13.72 2 2 2 186940 7.86 0.91 13.33 2 2 2 186941 7.51 0.85 12.55 2 2 2 186941 7.77 0.86 12.58 2 2 2 186943 9.32 0.93 14.34 2 2 2 186943 9.35 0.93 14.23 2 2 2 186944 9.60 0.92 14.37 2 2 2 186944 9.63 0.92 14.48 2 2 2 186945 9.51 0.93 14.64 2 2 2 186945 9.57 0.94 14.79 2 2 2 186946 11.13 0.95 15.00 2 2 2 186946 11.24 0.96 15.16 2 2 2 186947 11.51 0.98 15.47 2 2 2 186947 11.50 0.98 15.36 2 2 2 186948 11.88 0.98 15.54 2 2 2 186948 12.05 0.97 15.59 2 2 2 186949 12.43 1.00 16.15 2 2 2 186949 12.52 1.01 16.21 2 2 2 186950 11.26 1.00 15.85 2 2 2 186950 11.31 1.02 15.90 2 2 2 186951 10.57 1.02 16.27 2 2 2 186951 10.69 1.03 16.14 2 2 2 186952 9.93 1.02 16.42 2 2 2 186952 9.93 1.02 16.21 2 2 2 186953 9.75 1.04 16.54 3 2 2 186953 10.33 1.05 16.62 3 2 2 186954 9.43 1.04 16.67 3 2 2 186954 10.53 1.04 16.86 3 2 2 186955 9.71 1.06 17.01 2 2 2 186955 9.62 1.06 16.97 2 2 2 186956 9.50 1.05 16.94 2 2 2 186956 9.53 1.05 16.73 2 2 2 186957 9.12 1.04 17.03 2 2 2 186957 9.23 1.03 16.68 2 2 2 186958 8.99 1.03 16.54 2 2 2 186958 9.00 1.03 16.40 2 2 2 186959 8.86 1.01 16.43 2 2 2 186959 8.92 1.01 16.40 2 2 2 186960 8.45 0.98 15.79 2 2 2 186960 8.48 0.99 15.68 2 2 2 186961 8.01 0.97 15.38 2 2 2 186961 8.01 0.98 15.49 2 2 2 186962 7.69 0.94 14.68 2 2 2 186962 7.74 0.93 14.70 2 2 2 186963 7.60 0.93 14.13 2 2 2 186963 7.57 0.92 14.22 2 2 2 186964 7.21 0.85 13.00 2 2 2 186964 7.76 0.86 13.08 2 2 2 186965 7.18 0.80 12.10 2 2 2 186965 7.29 0.79 12.19 2 2 2 186966 0.75 0.26 2 2 5 186966 0.77 0.26 3.76 2 2 2 186967 10.12 0.93 14.80 2 2 2 186967 10.12 0.93 14.60 2 2 2 186968 9.91 0.94 14.68 2 2 2 186968 10.00 0.92 14.81 2 2 2 186969 10.00 0.95 15.01 2 2 2 186969 10.02 0.93 15.09 2 2 2 186970 11.55 0.98 15.45 2 2 2 186970 11.55 0.99 15.45 2 2 2 186971 11.51 1.03 15.79 2 2 2 186971 11.99 0.98 15.72 2 2 2 186972 12.22 1.02 16.09 2 2 2 186972 12.34 1.01 16.13 2 2 2 186973 11.18 1.00 16.18 2 2 2 186973 11.06 1.01 16.08 2 2 2 186974 11.47 1.01 16.44 2 2 2 186974 11.18 1.02 16.19 2 2 2 186975 10.31 1.02 16.44 2 2 2 186975 10.45 1.02 16.49 2 2 2 186976 9.94 1.05 16.84 2 2 2 186976 9.95 1.04 16.67 2 2 2 186977 9.53 1.04 17.02 2 2 2 186977 9.38 1.05 17.00 2 2 2 186978 9.52 1.06 16.81 2 2 2 186978 9.58 1.04 16.76 2 2 2 186979 9.52 1.07 16.72 2 2 2 186979 9.72 1.06 17.09 2 2 2 186980 9.57 1.05 16.85 2 2 2 186980 9.63 1.05 16.78 2 2 2 186981 9.27 1.04 16.81 2 2 2 186981 9.24 1.05 16.61 2 2 2 186982 9.18 1.04 16.75 2 2 2 186982 9.17 1.05 16.57 2 2 2 186983 8.95 1.04 16.22 2 2 2 186983 9.04 1.04 16.39 2 2 2 186985 8.24 1.01 16.20 2 2 2 186985 8.71 1.02 15.98 2 2 2 186986 8.18 0.98 15.83 2 2 2 186986 8.09 0.98 15.61 2 2 2 186987 7.67 0.96 14.81 2 2 2 186987 7.76 0.94 14.87 2 2 2 186988 7.43 0.88 13.40 2 2 2 186988 7.54 0.88 13.59 2 2 2 186989 5.90 0.65 9.82 2 2 2 186989 5.99 0.66 9.91 2 2 2 186990 1.01 0.24 2.74 2 2 2 186990 0.91 0.25 2 2 5 187006 10.09 0.96 15.04 2 2 2 187006 9.98 0.94 15.02 2 2 2 187007 9.72 0.96 14.82 2 2 2 187007 9.75 0.94 14.75 2 2 2 187008 10.10 0.97 15.14 2 2 2 187008 10.16 0.97 14.96 2 2 2 187009 12.34 1.01 16.05 2 2 2 187009 12.16 1.02 16.00 2 2 2 187010 10.51 1.01 15.81 2 2 2 187010 10.57 1.01 16.01 2 2 2 187011 10.53 1.02 15.91 2 2 2 187011 10.62 1.01 15.99 2 2 2 187012 10.38 1.02 15.96 2 2 2 187012 10.53 1.01 16.17 2 2 2 187013 10.43 1.02 16.10 2 2 2 187013 10.34 1.02 16.04 2 2 2 187014 11.17 1.06 16.79 2 2 2 187014 11.03 1.05 16.74 2 2 2 187015 9.96 1.04 16.55 2 2 2 187015 10.03 1.05 16.50 2 2 2 187016 9.66 1.05 17.05 2 2 2 187016 9.84 1.04 16.76 2 2 2 187017 9.71 1.07 16.90 2 2 2 187017 9.72 1.06 16.90 2 2 2 187018 9.68 1.05 17.00 2 2 2 187018 9.89 1.06 17.03 2 2 2 187019 9.73 1.06 17.13 2 2 2 187019 9.79 1.06 16.99 2 2 2 187020 9.49 1.05 17.02 2 2 2 187020 9.58 1.06 16.93 2 2 2 187021 9.60 1.07 17.05 2 2 2 187021 9.72 1.07 17.44 2 2 2 187022 9.30 1.05 16.72 2 2 2 187022 9.39 1.07 16.85 2 2 2 187023 9.19 1.02 16.47 2 2 2 187023 9.19 1.03 16.70 2 2 2 187024 8.85 1.03 16.44 2 2 2 187024 8.97 1.03 16.25 2 2 2 187025 8.79 1.02 16.47 2 2 2 187025 8.82 1.02 16.44 2 2 2 187026 8.51 1.00 16.15 2 2 2 187026 8.48 1.01 15.93 2 2 2 187027 8.06 0.98 15.26 2 2 2 187027 8.14 0.98 15.92 2 2 2 187029 7.31 0.76 11.55 2 2 2 187029 7.39 0.75 11.53 2 2 2 187030 9.72 0.94 14.87 2 2 2 187030 9.81 0.95 14.77 2 2 2 187031 10.38 0.94 15.32 2 2 2 187031 10.56 1.00 15.51 2 2 2 187032 11.60 0.97 15.63 2 2 2 187032 11.60 0.97 15.60 2 2 2 187033 13.62 1.04 15.68 3 2 2 187033 14.17 1.02 15.88 3 2 2 187034 13.07 1.02 16.46 2 2 2 187034 13.44 1.04 16.41 2 2 2 187035 13.01 1.04 16.53 2 2 2 187035 12.91 1.05 16.27 2 2 2 187036 12.00 1.05 16.30 2 2 2 187036 12.12 1.06 16.13 2 2 2 187037 11.39 1.05 16.48 2 2 2 187037 11.45 1.05 16.49 2 2 2 187038 10.54 1.07 16.36 2 2 2 187038 10.81 1.06 16.29 2 2 2 187039 9.78 1.08 16.69 2 2 2 187039 9.99 1.05 16.43 2 2 2 187040 9.55 1.06 16.53 2 2 2 187040 9.61 1.06 16.37 2 2 2 187041 9.54 1.07 16.31 2 2 2 187041 9.61 1.07 16.42 2 2 2 187042 9.63 1.09 16.50 2 2 2 187042 9.63 1.09 16.18 2 2 2 187043 9.29 1.08 16.44 2 2 2 187043 9.26 1.07 16.44 2 2 2 187044 8.68 1.04 15.99 2 2 2 187044 8.83 1.05 15.76 2 2 2 187045 8.70 1.04 15.98 2 2 2 187045 8.70 1.04 15.72 2 2 2 187046 8.33 1.03 15.64 2 2 2 187046 8.39 1.03 15.71 2 2 2 187047 8.27 1.02 15.53 2 2 2 187047 8.35 1.03 15.24 2 2 2 187048 8.30 1.01 15.26 2 2 2 187048 8.64 1.01 15.24 2 2 2 187049 8.15 1.00 14.90 2 2 2 187049 8.20 1.02 15.27 2 2 2 187050 7.86 1.01 14.91 2 2 2 187050 7.96 1.00 14.88 2 2 2 187051 7.61 0.93 13.41 2 2 2 187051 7.46 0.93 13.54 2 2 2 187052 7.52 0.92 13.07 2 2 2 187052 7.55 0.92 13.18 2 2 2 187053 7.17 0.81 11.36 2 2 2 187053 7.21 0.81 11.26 2 2 2 187054 9.96 0.94 14.41 3 2 2 187054 10.97 0.96 14.52 3 2 2 187055 9.79 0.94 14.41 2 2 2 187055 9.87 0.93 14.59 2 2 2 187056 10.97 0.98 15.10 2 2 2 187056 11.00 0.95 15.24 2 2 2 187057 11.79 1.02 15.39 2 2 2 187057 11.93 1.01 15.41 2 2 2 187058 12.72 1.07 16.09 2 2 2 187058 12.75 1.04 15.84 2 2 2 187059 12.05 1.04 15.95 2 2 2 187059 11.88 1.05 15.93 2 2 2 187060 11.64 1.05 16.18 2 2 2 187060 11.65 1.05 16.00 2 2 2 187061 11.46 1.07 16.24 2 2 2 187061 11.58 1.06 16.38 2 2 2 187062 10.63 1.07 16.42 2 2 2 187062 10.70 1.08 16.40 2 2 2 187063 9.83 1.08 16.31 2 2 2 187063 9.92 1.06 16.31 2 2 2 187064 9.33 1.06 16.65 2 2 2 187064 9.42 1.08 16.69 2 2 2 187065 9.47 1.08 16.60 2 2 2 187065 9.53 1.09 16.51 2 2 2 187066 9.38 1.08 16.78 2 2 2 187066 9.40 1.09 16.71 2 2 2 187067 9.17 1.08 16.33 2 2 2 187067 9.11 1.07 16.56 2 2 2 187068 9.10 1.08 16.22 2 2 2 187068 9.10 1.08 16.56 2 2 2 187069 8.86 1.07 16.54 2 2 2 187069 8.95 1.06 16.18 2 2 2 187070 8.78 1.07 15.96 2 2 2 187070 8.89 1.04 16.33 2 2 2 187071 8.60 1.04 15.84 2 2 2 187071 8.76 1.05 15.84 2 2 2 187072 8.38 1.03 16.11 2 2 2 187072 8.42 1.04 15.89 2 2 2 187073 8.49 1.04 15.51 3 2 2 187073 9.09 1.05 15.44 3 2 2 187074 7.86 1.02 15.31 2 2 2 187074 8.05 1.00 15.24 2 2 2 187075 7.65 0.95 13.71 2 2 2 187075 7.64 0.95 14.02 2 2 2 187076 7.44 0.90 12.96 2 2 2 187076 7.60 0.89 12.94 2 2 2 187077 7.31 0.85 12.14 2 2 2 187077 7.48 0.84 12.74 2 2 2 187093 9.98 0.97 14.51 2 2 2 187093 10.04 0.98 14.31 2 2 2 187094 9.80 0.98 14.40 2 2 2 187094 9.83 0.97 14.58 2 2 2 187095 10.19 1.00 14.96 2 2 2 187095 10.33 1.00 14.73 2 2 2 187096 12.26 1.03 15.74 2 2 2 187096 12.47 1.03 15.33 2 2 2 187097 13.48 1.06 15.96 2 2 2 187097 13.51 1.07 16.18 2 2 2 187098 12.56 1.06 16.36 2 2 2 187098 12.67 1.07 16.27 2 2 2 187099 11.40 1.06 16.00 2 2 2 187099 11.44 1.06 15.74 2 2 2 187100 11.06 1.06 16.36 2 2 2 187100 10.97 1.07 16.49 2 2 2 187101 10.43 1.07 16.52 2 2 2 187101 10.39 1.07 16.61 2 2 2 187102 9.62 1.07 16.61 2 2 2 187102 9.65 1.05 16.54 2 2 2 187103 9.41 1.06 16.58 2 2 2 187103 9.44 1.08 16.36 2 2 2 187104 9.54 1.07 16.87 2 2 2 187104 9.40 1.07 16.67 2 2 2 187105 9.49 1.09 16.67 3 2 2 187105 9.81 1.08 16.43 3 2 2 187106 9.05 1.06 16.47 2 2 2 187106 9.07 1.05 16.47 2 2 2 187107 9.17 1.06 16.72 2 2 2 187107 9.28 1.06 16.61 2 2 2 187108 8.99 1.05 16.21 2 2 2 187108 8.99 1.11 16.27 2 2 2 187109 8.59 1.04 15.76 2 2 2 187109 8.53 1.03 16.07 2 2 2 187110 8.43 1.03 15.90 2 2 2 187110 8.44 1.03 15.98 2 2 2 187111 8.26 1.02 15.72 2 2 2 187111 8.37 1.04 15.59 2 2 2 187112 9.10 1.05 15.61 3 2 2 187112 8.47 1.03 15.98 3 2 2 187113 8.29 1.03 15.65 2 2 2 187113 8.32 1.03 15.63 2 2 2 187114 7.89 0.98 14.46 3 2 2 187114 8.28 0.96 14.61 3 2 2 187115 7.53 0.91 13.99 2 2 2 187115 7.67 0.93 13.81 2 2 2 187116 2.83 0.50 7.76 2 2 2 187116 2.77 0.51 7.59 2 2 2 187117 10.31 0.98 14.83 2 2 2 187117 10.26 0.99 14.46 2 2 2 187118 10.25 1.00 14.81 2 2 2 187118 10.30 1.07 14.70 2 2 2 187119 10.43 1.00 14.92 2 2 2 187119 10.47 1.00 14.63 2 2 2 187120 12.06 1.04 15.43 3 2 2 187120 11.20 1.01 15.28 3 2 2 187121 11.96 1.04 15.54 2 2 2 187121 12.05 1.04 15.43 2 2 2 187122 11.67 1.04 16.03 2 2 2 187122 11.69 1.04 16.19 2 2 2 187123 10.86 1.08 15.92 2 2 2 187123 11.00 1.07 15.88 2 2 2 187124 11.16 1.11 16.32 2 2 2 187124 11.10 1.06 16.01 2 2 2 187125 10.76 1.08 16.30 2 2 2 187125 10.70 1.06 16.43 2 2 2 187126 9.64 1.07 16.72 2 2 2 187126 9.66 1.07 16.43 2 2 2 187127 9.48 1.08 16.41 2 2 2 187127 9.48 1.09 16.41 2 2 2 187128 9.56 1.08 16.34 2 2 2 187128 9.47 1.08 16.90 2 2 2 187129 9.35 1.08 16.74 2 2 2 187129 9.46 1.09 16.63 2 2 2 187130 8.96 1.06 16.23 2 2 2 187130 8.97 1.07 16.03 2 2 2 187131 8.81 1.07 16.32 2 2 2 187131 8.90 1.06 16.41 2 2 2 187132 8.72 1.06 15.92 2 2 2 187132 8.71 1.05 15.90 2 2 2 187133 8.60 1.04 15.90 2 2 2 187133 8.57 1.05 15.64 2 2 2 187134 8.36 1.03 16.12 2 2 2 187134 8.45 1.03 15.97 2 2 2 187135 8.38 1.05 15.88 2 2 2 187135 8.41 1.04 15.66 2 2 2 187136 8.23 1.02 15.33 2 2 2 187136 8.23 1.02 15.59 2 2 2 187137 8.13 1.01 15.46 2 2 2 187137 8.24 1.01 15.28 2 2 2 187138 7.75 0.94 13.83 2 2 2 187138 7.78 0.96 13.96 2 2 2 187140 3.10 0.53 8.29 2 2 2 187140 3.12 0.56 8.46 2 2 2 187165 10.20 0.97 14.72 2 2 2 187165 10.17 0.96 14.59 2 2 2 187166 10.37 0.97 14.75 2 2 2 187166 10.32 0.96 14.75 2 2 2 187167 11.12 1.02 15.42 2 2 2 187167 11.17 0.98 15.41 2 2 2 187168 12.00 1.02 15.66 2 2 2 187168 12.00 1.01 15.58 2 2 2 187169 12.03 1.02 16.11 2 2 2 187169 11.94 1.01 15.98 2 2 2 187170 11.69 1.03 16.18 2 2 2 187170 11.86 1.03 16.14 2 2 2 187171 11.13 1.04 16.08 3 2 2 187171 11.75 1.02 15.86 3 2 2 187172 10.85 1.03 16.48 2 2 2 187172 10.96 1.04 16.68 2 2 2 187173 10.25 1.03 16.48 2 2 2 187173 10.25 1.03 16.33 2 2 2 187174 9.68 1.01 16.44 2 2 2 187174 9.57 1.03 16.48 2 2 2 187175 9.64 1.04 16.77 2 2 2 187175 9.65 1.03 16.31 2 2 2 187176 9.58 1.02 16.64 2 2 2 187176 9.64 1.03 16.88 2 2 2 187177 9.80 1.03 16.31 2 2 2 187177 9.77 1.04 17.00 2 2 2 187178 9.51 1.03 16.80 2 2 2 187178 9.57 1.03 16.84 2 2 2 187179 9.19 1.02 16.45 2 2 2 187179 9.20 1.01 16.41 2 2 2 187180 9.11 1.01 16.63 2 2 2 187180 9.59 1.02 16.50 2 2 2 187181 8.71 1.01 15.86 2 2 2 187181 8.71 1.00 15.87 2 2 2 187182 8.67 1.02 16.02 2 2 2 187182 8.58 1.02 16.22 2 2 2 187183 8.63 1.00 15.65 2 2 2 187183 8.63 1.00 15.78 2 2 2 187184 8.25 0.99 15.47 2 2 2 187184 8.31 0.99 15.41 2 2 2 187185 8.01 0.97 15.23 2 2 2 187185 8.21 1.00 15.25 2 2 2 187186 7.71 0.95 14.46 3 2 2 187186 8.54 0.95 14.35 3 2 2 187187 7.19 0.82 12.36 2 2 2 187187 7.31 0.82 12.51 2 2 2 187188 6.69 0.78 11.55 2 2 2 187188 6.76 0.78 11.35 2 2 2 187204 10.39 0.95 14.30 2 2 2 187204 10.48 0.95 14.33 2 2 2 187205 9.99 0.95 14.59 3 2 2 187205 10.70 0.97 14.76 3 2 2 187206 10.35 0.98 14.87 2 2 2 187206 10.44 0.98 14.49 2 2 2 187207 12.60 1.02 15.59 2 2 2 187207 12.69 1.02 15.70 2 2 2 187208 12.03 1.03 15.67 3 2 2 187208 12.66 1.04 15.39 3 2 2 187209 13.23 1.05 16.35 2 2 2 187209 13.11 1.04 16.15 2 2 2 187210 13.45 1.08 16.26 2 2 2 187210 13.53 1.07 15.93 2 2 2 187211 12.61 1.06 16.54 2 2 2 187211 12.81 1.08 16.61 2 2 2 187212 11.85 1.07 16.20 2 2 2 187212 12.02 1.07 16.25 2 2 2 187213 11.64 1.07 16.71 2 2 2 187213 11.67 1.09 16.38 2 2 2 187214 10.14 1.07 16.38 2 2 2 187214 10.21 1.06 16.38 2 2 2 187215 9.71 1.06 16.64 2 2 2 187215 9.77 1.07 16.36 2 2 2 187216 9.90 1.09 16.40 2 2 2 187216 9.93 1.08 16.47 2 2 2 187217 9.97 1.07 16.84 2 2 2 187217 9.95 1.08 16.60 2 2 2 187218 10.00 1.10 16.67 2 2 2 187218 10.05 1.08 16.65 2 2 2 187219 9.67 1.09 16.78 2 2 2 187219 9.76 1.08 16.60 2 2 2 187220 9.16 1.06 16.14 2 2 2 187220 9.29 1.05 16.12 2 2 2 187221 9.05 1.07 16.12 2 2 2 187221 9.11 1.05 16.42 2 2 2 187222 9.06 1.05 16.29 2 2 2 187222 9.06 1.07 16.11 2 2 2 187223 8.84 1.06 16.05 2 2 2 187223 8.93 1.06 16.49 2 2 2 187224 8.46 1.03 15.43 2 2 2 187224 8.48 1.02 15.63 2 2 2 187225 9.21 1.02 15.23 3 2 2 187225 8.14 1.02 15.12 3 2 2 187226 7.73 0.87 12.42 2 2 2 187226 7.81 0.89 12.58 2 2 2 187227 7.51 0.82 11.61 2 2 2 187227 7.54 0.82 11.61 2 2 2 187228 10.28 0.96 14.34 2 2 2 187228 10.28 0.96 14.38 2 2 2 187229 10.39 0.97 14.51 2 2 2 187229 10.53 0.96 14.62 2 2 2 187230 10.39 0.99 14.68 2 2 2 187230 10.39 0.97 14.95 2 2 2 187231 11.68 1.00 15.12 2 2 2 187231 11.74 1.01 15.12 2 2 2 187232 13.23 1.03 15.77 2 2 2 187232 13.29 1.04 15.62 2 2 2 187233 13.20 1.04 16.03 2 2 2 187233 13.11 1.07 16.14 2 2 2 187234 12.79 1.06 16.16 2 2 2 187234 12.82 1.10 16.18 2 2 2 187235 12.39 1.06 16.42 2 2 2 187235 12.56 1.05 16.40 2 2 2 187236 11.76 1.05 16.48 2 2 2 187236 11.80 1.05 16.24 2 2 2 187237 11.04 1.05 16.61 2 2 2 187237 11.09 1.08 16.34 2 2 2 187238 9.98 1.06 16.45 2 2 2 187238 10.04 1.06 16.34 2 2 2 187239 9.65 1.06 16.58 2 2 2 187239 9.68 1.06 16.36 2 2 2 187240 9.57 1.07 16.29 2 2 2 187240 9.64 1.08 16.32 2 2 2 187241 9.74 1.07 16.25 2 2 2 187241 9.70 1.06 16.38 2 2 2 187242 9.61 1.06 16.58 3 2 2 187242 10.90 1.07 16.60 3 2 2 187243 9.45 1.06 16.42 2 2 2 187243 9.62 1.06 16.27 2 2 2 187244 9.07 1.06 15.95 2 2 2 187244 9.30 1.05 16.19 2 2 2 187245 8.86 1.02 16.08 2 2 2 187245 8.89 1.04 15.95 2 2 2 187246 8.86 1.05 16.10 2 2 2 187246 8.89 1.03 16.10 2 2 2 187247 8.59 1.03 15.43 2 2 2 187247 8.71 1.03 15.72 2 2 2 187248 8.62 1.02 15.87 2 2 2 187248 8.68 1.01 15.80 2 2 2 187249 8.64 1.00 15.10 2 2 2 187249 8.18 1.01 14.85 2 2 2 187250 7.92 0.87 12.74 2 2 2 187250 7.92 0.87 12.57 2 2 2 187251 7.68 0.80 11.41 2 2 2 187251 7.74 0.81 11.46 2 2 2 187267 10.42 1.00 14.45 2 2 2 187267 10.62 0.97 14.70 2 2 2 187268 10.19 0.95 14.59 2 2 2 187268 10.26 0.96 14.65 2 2 2 187269 10.63 0.98 15.26 2 2 2 187269 10.69 0.98 14.74 2 2 2 187270 12.54 1.00 15.73 2 2 2 187270 12.61 1.02 15.80 2 2 2 187271 12.09 1.04 15.64 2 2 2 187271 12.12 1.04 16.11 2 2 2 187272 12.16 1.02 16.02 2 2 2 187272 12.02 1.03 16.14 2 2 2 187273 12.24 1.04 16.04 2 2 2 187273 12.34 1.04 15.91 2 2 2 187274 11.82 1.03 16.38 2 2 2 187274 11.94 1.03 16.29 2 2 2 187275 10.75 1.07 16.37 2 2 2 187275 10.74 1.03 16.71 2 2 2 187276 9.79 1.01 16.48 2 2 2 187276 9.82 1.02 16.64 2 2 2 187277 9.52 1.04 16.50 2 2 2 187277 9.54 1.03 16.46 2 2 2 187278 9.44 1.07 16.86 2 2 2 187278 9.44 1.05 16.46 2 2 2 187279 9.55 1.05 16.84 2 2 2 187279 9.61 1.15 16.86 2 2 2 187280 9.30 1.07 16.36 2 2 2 187280 9.30 1.04 16.70 2 2 2 187281 9.06 1.06 16.25 2 2 2 187281 9.11 1.06 16.40 2 2 2 187282 8.99 1.05 16.49 2 2 2 187282 8.98 1.04 16.33 2 2 2 187283 8.56 1.02 16.15 2 2 2 187283 8.54 1.02 16.04 2 2 2 187284 8.49 1.02 15.74 2 2 2 187284 8.53 1.04 15.81 2 2 2 187285 8.49 1.03 15.85 2 2 2 187285 8.63 1.01 15.89 2 2 2 187286 8.60 1.03 16.23 2 2 2 187286 8.47 1.02 16.14 2 2 2 187287 8.23 1.00 15.39 2 2 2 187287 8.26 1.00 15.73 2 2 2 187288 8.01 0.94 14.81 2 2 2 187288 8.10 0.97 15.01 2 2 2 187290 7.59 0.76 11.03 2 2 2 187290 7.59 0.76 11.26 2 2 2 187306 10.35 0.93 14.53 2 2 2 187306 10.15 0.95 14.40 2 2 2 187307 10.26 0.95 14.61 2 2 2 187307 10.20 0.98 14.26 2 2 2 187308 10.13 0.94 14.93 2 2 2 187308 10.36 0.96 15.11 2 2 2 187309 11.62 1.00 15.31 2 2 2 187309 11.63 1.01 15.40 2 2 2 187310 12.44 1.02 15.64 2 2 2 187310 12.02 1.01 15.62 2 2 2 187311 11.24 1.02 16.09 2 2 2 187311 11.34 1.01 16.05 2 2 2 187312 10.82 1.02 15.75 3 2 2 187312 10.83 1.03 16.18 3 2 2 187314 9.78 1.02 16.38 2 2 2 187314 9.78 1.05 16.47 2 2 2 187315 9.68 1.05 16.58 2 2 2 187315 9.62 1.04 16.47 2 2 2 187316 9.59 1.04 16.85 2 2 2 187316 9.47 1.06 16.58 2 2 2 187317 9.58 1.06 16.69 2 2 2 187317 9.64 1.06 16.89 2 2 2 187318 9.15 1.03 16.48 2 2 2 187318 9.22 1.05 16.50 2 2 2 187319 9.17 1.03 16.68 2 2 2 187319 9.03 1.02 16.12 2 2 2 187320 9.19 1.03 16.68 2 2 2 187320 9.22 1.06 16.79 2 2 2 187321 8.91 1.02 16.14 2 2 2 187321 9.13 1.05 16.50 2 2 2 187322 8.49 1.01 15.73 2 2 2 187322 8.50 1.00 15.86 2 2 2 187323 8.81 1.02 16.06 2 2 2 187323 8.63 1.02 16.04 2 2 2 187324 8.66 1.04 15.68 2 2 2 187324 8.62 1.01 15.83 2 2 2 187325 8.67 1.01 16.06 2 2 2 187325 8.79 1.02 16.08 2 2 2 187326 8.64 0.99 15.78 2 2 2 187326 8.72 1.00 15.76 2 2 2 187327 8.77 1.00 15.49 2 2 2 187327 8.80 0.99 15.78 2 2 2 187328 8.64 0.91 13.89 2 2 2 187328 9.35 0.92 13.98 2 2 2 187329 6.65 0.60 6.70 2 2 2 187329 6.73 0.62 6.68 2 2 2 187330 10.39 0.96 14.90 2 2 2 187330 10.44 0.94 15.01 2 2 2 187331 10.32 0.96 14.94 2 2 2 187331 10.40 0.96 14.87 2 2 2 187332 10.39 0.96 15.00 2 2 2 187332 10.52 1.00 15.07 2 2 2 187333 11.30 0.99 15.56 2 2 2 187333 11.53 0.99 15.31 2 2 2 187334 11.31 1.01 15.99 2 2 2 187334 11.38 1.02 16.08 2 2 2 187335 10.96 1.02 16.12 2 2 2 187335 11.10 1.03 15.69 2 2 2 187336 10.65 1.04 16.59 2 2 2 187336 10.53 1.05 16.41 2 2 2 187337 9.75 1.05 16.18 2 2 2 187337 9.82 1.03 16.54 2 2 2 187338 9.48 1.04 16.79 2 2 2 187338 9.57 1.05 16.90 2 2 2 187339 9.50 1.05 16.72 2 2 2 187339 9.61 1.06 16.51 2 2 2 187340 9.00 1.07 16.37 2 2 2 187340 9.02 1.02 16.48 2 2 2 187341 8.99 1.05 16.28 2 2 2 187341 9.22 1.02 16.30 2 2 2 187342 9.68 1.02 16.10 2 2 2 187342 9.74 1.04 16.12 2 2 2 187343 8.55 1.03 16.05 2 2 2 187343 8.56 1.02 16.12 2 2 2 187344 8.55 1.03 16.03 2 2 2 187344 8.54 1.01 15.67 2 2 2 187345 8.39 0.98 15.48 2 2 2 187345 8.54 1.02 15.62 2 2 2 187346 8.76 1.01 15.48 3 2 2 187346 9.52 1.01 15.39 3 2 2 187347 8.69 0.97 15.17 2 2 2 187347 8.74 0.99 15.14 2 2 2 187348 8.33 0.86 11.13 2 2 2 187348 8.34 0.88 11.25 2 2 2 187349 4.95 0.29 0.20 2 2 2 187349 5.06 0.33 0.00 2 2 2 187350 11.03 1.00 15.42 2 2 2 187350 11.12 1.02 14.73 2 2 2 187351 11.14 1.01 15.74 2 2 2 187351 11.20 1.01 15.78 2 2 2 187352 11.19 1.02 15.58 2 2 2 187352 11.10 1.02 15.44 2 2 2 187353 11.30 1.01 15.67 2 2 2 187353 11.32 1.00 15.64 2 2 2 187354 11.13 1.04 15.89 2 2 2 187354 11.23 1.02 15.87 2 2 2 187355 11.15 1.02 15.50 2 2 2 187355 11.19 1.02 15.91 2 2 2 187356 10.66 1.06 15.88 2 2 2 187356 10.71 1.01 15.83 2 2 2 187357 10.46 1.05 16.17 2 2 2 187357 10.73 1.06 16.10 2 2 2 187358 9.87 1.07 16.50 2 2 2 187358 9.87 1.07 16.46 2 2 2 187359 9.62 1.07 16.59 2 2 2 187359 9.63 1.06 16.57 2 2 2 187360 9.50 1.06 16.63 2 2 2 187360 9.52 1.07 16.68 2 2 2 187361 9.43 1.08 16.23 2 2 2 187361 9.46 1.08 16.34 2 2 2 187362 9.25 1.06 16.04 2 2 2 187362 9.24 1.06 16.07 2 2 2 187363 9.26 1.04 16.02 3 2 2 187363 8.80 1.02 16.00 3 2 2 187364 8.56 1.06 15.32 2 2 2 187364 8.61 1.04 15.36 2 2 2 187365 8.67 1.02 15.74 2 2 2 187365 8.69 1.02 15.70 2 2 2 187366 8.66 1.02 15.61 2 2 2 187366 8.59 1.01 15.49 2 2 2 187367 8.58 1.01 15.36 2 2 2 187367 8.59 1.01 15.42 2 2 2 187368 8.40 0.99 14.86 2 2 2 187368 8.40 1.00 15.09 2 2 2 187369 6.21 0.53 2.69 2 2 2 187369 6.22 0.50 2.89 2 2 2 187370 11.12 1.03 16.27 2 2 2 187370 11.03 1.02 15.92 2 2 2 187371 11.08 1.04 16.02 2 2 2 187371 11.02 1.04 15.92 2 2 2 187372 10.70 1.05 16.02 2 2 2 187372 10.76 1.05 15.95 2 2 2 187373 10.32 1.05 16.54 2 2 2 187373 10.44 1.06 16.57 2 2 2 187374 9.71 1.05 16.32 2 2 2 187374 9.69 1.04 16.59 2 2 2 187375 9.52 1.06 16.59 2 2 2 187375 9.62 1.06 16.62 2 2 2 187376 9.52 1.08 16.74 2 2 2 187376 9.67 1.08 16.99 2 2 2 187377 9.54 1.08 16.81 2 2 2 187377 9.54 1.06 16.96 2 2 2 187378 9.15 1.04 16.51 2 2 2 187378 9.12 1.05 16.73 2 2 2 187379 8.99 1.02 16.55 2 2 2 187379 8.96 1.02 16.50 2 2 2 187380 8.61 1.02 16.03 2 2 2 187380 8.64 1.01 16.03 2 2 2 187381 8.45 1.02 16.05 2 2 2 187381 8.48 1.02 16.03 2 2 2 187382 8.76 1.01 16.25 2 2 2 187382 8.53 1.02 16.22 2 2 2 187383 8.60 1.04 16.10 2 2 2 187383 8.66 1.02 15.80 2 2 2 187384 8.49 0.99 15.97 2 2 2 187384 8.62 1.00 15.67 2 2 2 187385 8.46 0.97 14.70 2 2 2 187385 8.59 0.99 15.15 2 2 2 187386 5.29 0.46 3.26 2 2 2 187386 5.26 0.51 3.21 2 2 2 187402 8.76 1.02 16.03 2 2 2 187402 8.63 1.01 16.11 2 2 2 187403 8.57 0.99 15.98 2 2 2 187403 8.63 1.03 16.16 2 2 2 187404 8.72 1.00 16.23 2 2 2 187404 8.74 1.00 16.28 2 2 2 187405 8.71 0.99 16.05 2 2 2 187405 8.67 1.00 16.03 2 2 2 187406 8.64 0.99 16.18 2 2 2 187406 8.67 0.99 16.10 2 2 2 187407 8.60 0.99 15.53 2 2 2 187407 8.61 0.97 15.60 2 2 2 187408 8.53 0.95 15.33 2 2 2 187408 8.63 0.98 15.40 2 2 2 187409 8.18 0.97 14.90 2 2 2 187409 8.14 0.96 15.28 2 2 2 187410 7.47 0.90 13.49 2 2 2 187410 7.38 0.91 13.64 2 2 2 187411 5.12 0.75 8.94 2 2 2 187411 5.16 0.76 8.94 2 2 2 187412 5.37 0.55 2.50 2 2 2 187412 5.49 0.53 2.48 2 2 2 187413 8.90 0.97 15.12 2 2 2 187413 8.89 0.98 15.07 2 2 2 187414 8.63 0.96 14.82 3 2 2 187414 9.14 0.96 14.85 3 2 2 187415 8.71 1.00 14.87 2 2 2 187415 8.78 0.98 14.72 2 2 2 187416 8.60 0.99 14.89 2 2 2 187416 8.65 0.98 14.84 2 2 2 187417 8.74 0.95 13.61 2 2 2 187417 8.67 0.94 13.61 2 2 2 187418 11.53 1.02 11.28 2 2 2 187418 11.42 1.02 11.11 2 2 2 187421 12.13 1.04 9.35 2 2 2 187421 12.22 1.03 9.25 2 2 2 187426 11.42 1.01 8.03 2 2 2 187426 11.46 1.00 8.20 2 2 2 187430 9.82 0.84 5.75 2 2 2 187430 9.67 0.86 5.77 2 2 2 187433 8.19 0.95 13.46 2 2 2 187433 8.29 0.95 13.53 2 2 2 187434 11.53 1.00 13.48 2 2 2 187434 11.56 1.00 13.36 2 2 2 187435 11.48 1.01 11.18 2 2 2 187435 11.52 1.01 11.11 2 2 2 187436 12.25 1.03 9.84 2 2 2 187436 12.23 1.03 9.82 2 2 2 187437 11.85 1.00 8.61 2 2 2 187437 11.74 0.99 8.31 2 2 2 187438 9.23 0.81 5.32 2 2 2 187438 9.30 0.80 5.25 2 2 2 187439 12.45 1.02 12.31 2 2 2 187439 12.55 1.02 12.38 2 2 2 187440 10.39 0.94 9.45 2 2 2 187440 10.38 0.95 9.55 2 2 2 187441 12.21 1.03 10.09 2 2 2 187441 12.33 1.02 10.01 2 2 2 187444 12.10 1.04 8.53 2 2 2 187444 12.11 1.04 8.73 2 2 2 187448 11.50 0.99 7.73 2 2 2 187448 11.68 0.98 7.78 2 2 2 187451 10.24 0.90 6.31 2 2 2 187451 10.19 0.90 6.43 2 2 2 187453 10.78 0.93 10.09 2 2 2 187453 10.46 0.95 10.06 2 2 2 187454 9.88 0.93 9.87 2 2 2 187454 9.94 0.93 9.84 2 2 2 187459 10.92 1.02 8.64 2 2 2 187459 10.93 1.01 8.67 2 2 2 187465 9.71 0.91 6.51 2 2 2 187465 10.03 0.92 6.46 2 2 2 187468 7.47 0.91 11.41 2 2 2 187468 7.55 0.90 11.49 2 2 2 187469 8.54 0.92 11.85 2 2 2 187469 8.58 0.93 11.86 2 2 2 187470 5.72 0.77 8.73 2 2 2 187470 6.53 0.76 8.63 2 2 2 187473 8.05 0.85 10.02 2 2 2 187473 8.15 0.86 10.04 2 2 2 187478 9.61 0.91 8.41 2 2 2 187478 9.69 0.92 8.36 2 2 2 187482 8.11 0.84 6.52 2 2 2 187482 8.16 0.85 6.55 2 2 2 187485 10.52 1.04 16.49 2 2 2 187485 10.56 1.08 15.94 2 2 2 187486 9.94 1.04 16.61 2 2 2 187486 9.98 1.05 16.65 2 2 2 187487 9.90 1.03 16.26 2 2 2 187487 9.64 1.04 16.51 2 2 2 187488 9.39 1.03 16.24 2 2 2 187488 9.52 1.04 16.39 2 2 2 187489 8.64 1.00 15.92 2 2 2 187489 8.71 1.00 15.96 2 2 2 187490 8.56 0.99 15.81 2 2 2 187490 8.69 1.01 15.73 2 2 2 187491 8.58 0.99 15.87 2 2 2 187491 8.69 0.99 15.30 2 2 2 187492 8.67 0.99 15.84 2 2 2 187492 8.84 0.97 15.86 2 2 2 187493 8.07 0.92 13.78 2 2 2 187493 8.14 0.94 13.81 2 2 2 187494 9.04 0.99 15.57 2 2 2 187494 9.13 0.99 15.41 2 2 2 187495 8.06 0.92 13.65 2 2 2 187495 8.02 0.92 13.70 2 2 2 187496 5.94 0.77 9.56 2 2 2 187496 5.95 0.77 9.56 2 2 2 187497 8.02 0.95 13.89 2 2 2 187497 8.05 0.93 13.73 2 2 2 187513 11.12 1.04 15.81 2 2 2 187513 11.32 1.03 15.97 2 2 2 187514 11.01 1.03 16.54 2 2 2 187514 11.05 1.02 16.29 2 2 2 187515 10.87 1.03 16.45 2 2 2 187515 10.88 1.03 16.54 2 2 2 187516 10.71 1.03 16.46 2 2 2 187516 10.72 1.06 16.53 2 2 2 187517 10.43 1.04 16.37 2 2 2 187517 10.59 1.04 16.71 2 2 2 187518 9.91 1.03 16.66 2 2 2 187518 9.90 1.07 16.32 2 2 2 187519 9.95 1.06 16.23 2 2 2 187519 9.99 1.06 16.27 2 2 2 187520 10.00 1.05 16.00 2 2 2 187520 10.11 1.05 16.16 2 2 2 187521 9.74 1.05 16.50 2 2 2 187521 10.05 1.04 16.50 2 2 2 187522 9.26 1.01 15.91 2 2 2 187522 9.30 1.02 16.22 2 2 2 187523 8.87 0.99 16.02 2 2 2 187523 8.94 1.01 15.86 2 2 2 187524 8.85 1.00 15.97 2 2 2 187524 8.86 1.00 15.41 2 2 2 187525 8.97 0.99 15.79 2 2 2 187525 9.05 0.99 15.81 2 2 2 187526 8.76 0.97 15.45 2 2 2 187526 8.90 0.97 15.18 2 2 2 187527 7.91 0.90 12.38 2 2 2 187527 7.92 0.88 12.52 2 2 2 187528 6.06 0.42 3.59 2 2 2 187528 6.05 0.43 3.53 2 2 2 187529 11.57 0.98 15.29 2 2 2 187529 11.45 0.97 15.10 2 2 2 187530 11.77 0.98 15.62 2 2 2 187530 11.93 0.99 15.69 2 2 2 187531 11.72 1.00 15.67 2 2 2 187531 11.89 0.99 15.49 2 2 2 187532 11.91 1.00 15.89 2 2 2 187532 11.55 1.06 15.64 2 2 2 187533 11.03 1.03 16.23 2 2 2 187533 11.17 1.02 16.23 2 2 2 187534 10.68 1.03 16.37 2 2 2 187534 10.91 1.02 16.23 2 2 2 187535 10.50 1.04 16.21 2 2 2 187535 10.59 1.05 16.54 2 2 2 187536 9.90 1.05 17.04 2 2 2 187536 9.90 1.05 16.98 2 2 2 187537 10.27 1.04 16.73 2 2 2 187537 10.06 1.04 16.68 2 2 2 187538 10.35 1.06 16.59 2 2 2 187538 10.38 1.04 16.59 2 2 2 187539 9.97 1.03 16.97 2 2 2 187539 10.09 1.05 16.93 2 2 2 187540 9.65 1.04 16.53 2 2 2 187540 9.54 1.01 16.30 2 2 2 187541 9.06 1.00 15.90 2 2 2 187541 9.16 1.01 15.81 2 2 2 187542 9.14 0.99 15.88 2 2 2 187542 9.18 1.00 15.69 2 2 2 187543 8.90 0.99 15.69 2 2 2 187543 8.96 0.99 15.55 2 2 2 187544 8.95 0.99 15.72 2 2 2 187544 5 5 5 187545 8.79 0.84 14.89 2 2 2 187545 5 5 5 187546 5 5 5 187546 8.98 0.83 14.38 2 2 2 187547 5.23 0.27 0.73 2 2 2 187547 5.30 0.25 0.78 2 2 2 187548 10.79 0.95 14.40 2 2 2 187548 10.64 1.01 14.58 2 2 2 187549 11.35 0.98 14.59 2 2 2 187549 11.46 0.97 14.48 2 2 2 187550 11.91 1.04 15.24 2 2 2 187550 11.97 1.01 15.15 2 2 2 187551 11.39 1.02 15.56 2 2 2 187551 11.45 1.03 15.01 2 2 2 187552 10.80 1.04 15.32 2 2 2 187552 5 5 5 187553 10.46 1.04 15.41 2 2 2 187553 10.31 0.93 15.07 2 2 2 187554 9.68 1.06 15.29 2 2 2 187554 9.77 1.05 15.45 2 2 2 187555 9.69 1.07 15.33 2 2 2 187555 9.83 1.06 15.62 2 2 2 187556 9.80 1.06 14.76 2 2 2 187556 9.81 1.07 14.66 2 2 2 187557 9.89 1.06 14.91 2 2 2 187557 9.94 1.06 14.85 2 2 2 187558 9.86 1.04 15.39 2 2 2 187558 9.88 1.05 15.44 2 2 2 187559 9.83 1.10 15.44 2 2 2 187559 9.88 1.06 15.37 2 2 2 187560 9.24 1.04 14.99 2 2 2 187560 9.36 1.03 14.99 2 2 2 187561 8.76 1.01 14.86 2 2 2 187561 8.84 1.04 14.87 2 2 2 187562 8.55 1.03 14.61 2 2 2 187562 8.66 0.99 14.58 2 2 2 187563 8.36 0.99 14.39 2 2 2 187563 8.40 1.01 14.33 2 2 2 187564 8.15 0.97 14.15 2 2 2 187564 8.21 0.98 14.08 2 2 2 187566 4.14 0.42 4.45 2 2 2 187566 4.08 0.43 4.46 2 2 2 187572 10.33 0.95 12.96 2 2 2 187572 10.39 0.95 13.44 2 2 2 187573 10.28 0.93 13.70 2 2 2 187573 10.32 0.94 13.62 2 2 2 187574 11.16 1.00 14.29 2 2 2 187574 11.26 1.00 14.41 2 2 2 187575 11.73 1.00 15.06 2 2 2 187575 11.73 1.00 14.94 2 2 2 187576 11.46 1.01 15.13 2 2 2 187576 11.72 1.03 15.23 2 2 2 187577 11.09 1.05 15.56 2 2 2 187577 11.16 1.02 15.45 2 2 2 187578 10.70 1.02 15.51 2 2 2 187578 10.81 1.02 15.57 2 2 2 187579 10.55 1.03 15.73 2 2 2 187579 10.45 1.03 15.70 2 2 2 187580 10.03 1.10 16.10 2 2 2 187580 10.06 1.04 16.12 2 2 2 187581 9.74 1.05 16.12 2 2 2 187581 9.91 1.06 16.38 2 2 2 187582 9.80 1.05 16.14 2 2 2 187582 9.86 1.04 16.15 2 2 2 187583 9.94 1.06 16.19 2 2 2 187583 10.05 1.05 16.04 2 2 2 187584 9.93 1.04 16.56 2 2 2 187584 10.00 1.06 16.42 2 2 2 187585 9.92 1.06 16.05 2 2 2 187585 9.94 1.04 16.21 2 2 2 187586 9.56 1.05 16.17 2 2 2 187586 9.86 1.05 16.34 2 2 2 187587 8.86 1.01 15.87 2 2 2 187587 8.72 1.02 15.88 2 2 2 187588 8.73 1.00 15.44 2 2 2 187588 8.81 1.00 15.68 2 2 2 187589 8.40 0.95 14.48 2 2 2 187589 8.55 0.95 14.40 2 2 2 187590 8.39 1.00 15.28 2 2 2 187590 8.45 1.00 15.42 2 2 2 187591 8.40 0.99 15.27 2 2 2 187591 8.47 0.99 15.31 2 2 2 187592 8.45 0.98 14.87 2 2 2 187592 8.48 0.98 14.90 2 2 2 187593 8.15 0.98 14.98 2 2 2 187593 8.26 0.99 14.73 2 2 2 187594 7.99 0.94 14.41 2 2 2 187594 8.01 0.95 14.20 2 2 2 187595 6.78 0.62 7.05 2 2 2 187595 6.64 0.64 6.97 2 2 2 187596 10.24 1.02 14.18 2 2 2 187596 10.24 0.98 14.34 2 2 2 187597 10.18 1.00 14.54 2 2 2 187597 10.21 0.98 14.49 2 2 2 187599 11.24 1.06 15.61 2 2 2 187599 11.27 1.05 15.63 2 2 2 187600 11.56 1.06 15.96 2 2 2 187600 11.72 1.05 15.83 2 2 2 187601 11.14 1.06 15.92 2 2 2 187601 11.24 1.07 15.92 2 2 2 187602 10.98 1.09 16.21 2 2 2 187602 10.99 1.09 16.46 2 2 2 187603 10.09 1.08 16.48 2 2 2 187603 10.19 1.08 16.52 2 2 2 187604 9.71 1.08 16.17 2 2 2 187604 9.58 1.09 16.41 2 2 2 187605 9.54 1.07 16.57 2 2 2 187605 9.68 1.06 16.48 2 2 2 187606 9.60 1.08 16.44 2 2 2 187606 9.63 1.09 16.42 2 2 2 187607 9.65 1.11 16.17 2 2 2 187607 9.72 1.11 16.46 2 2 2 187608 9.29 1.11 16.22 2 2 2 187608 9.39 1.10 16.17 2 2 2 187609 9.28 1.08 16.18 2 2 2 187609 9.35 1.09 16.24 2 2 2 187610 9.04 1.07 16.29 2 2 2 187610 9.14 1.08 16.33 2 2 2 187611 9.17 1.09 16.31 2 2 2 187611 9.19 1.08 16.13 2 2 2 187612 9.09 1.08 16.07 2 2 2 187612 8.99 1.07 15.98 2 2 2 187614 8.60 1.03 15.76 2 2 2 187614 8.64 1.05 15.89 2 2 2 187615 8.53 1.05 15.69 2 2 2 187615 8.72 1.05 15.65 2 2 2 187616 8.61 1.03 15.47 2 2 2 187616 8.68 1.11 15.45 2 2 2 187617 8.35 0.98 15.00 2 2 2 187617 8.37 1.00 14.96 2 2 2 187618 8.07 0.90 13.47 2 2 2 187618 8.11 0.91 13.54 2 2 2 187619 4.13 0.43 6.43 2 2 2 187619 4.13 0.42 6.58 2 2 2 187635 10.31 0.97 14.29 2 2 2 187635 10.34 0.97 14.34 2 2 2 187636 10.10 0.98 14.49 2 2 2 187636 10.00 0.97 14.23 2 2 2 187637 11.04 0.99 15.07 2 2 2 187637 11.21 1.00 14.96 2 2 2 187638 13.11 1.06 15.76 2 2 2 187638 13.21 1.04 15.74 2 2 2 187639 11.66 1.05 15.76 2 2 2 187639 11.91 1.04 15.79 2 2 2 187640 11.67 1.07 15.72 2 2 2 187640 11.68 1.07 15.79 2 2 2 187641 11.21 1.05 15.81 2 2 2 187641 11.25 1.06 15.88 2 2 2 187642 11.01 1.09 16.41 2 2 2 187642 11.04 1.07 16.39 2 2 2 187643 10.64 1.09 16.35 2 2 2 187643 10.65 1.08 16.57 2 2 2 187644 9.86 1.09 16.39 2 2 2 187644 9.93 1.09 16.39 2 2 2 187645 9.50 1.08 16.00 2 2 2 187645 9.56 1.08 16.51 2 2 2 187646 9.63 1.07 16.46 2 2 2 187646 9.55 1.08 16.51 2 2 2 187647 10.09 1.08 16.26 2 2 2 187647 9.65 1.08 16.31 2 2 2 187648 9.44 1.08 16.22 2 2 2 187648 9.53 1.18 16.44 2 2 2 187649 9.23 1.09 16.36 2 2 2 187649 9.29 1.06 16.22 2 2 2 187650 9.18 1.08 16.16 2 2 2 187650 9.14 1.04 16.47 2 2 2 187651 8.97 1.06 16.20 2 2 2 187651 8.99 1.06 16.27 2 2 2 187652 8.84 1.05 15.71 2 2 2 187652 8.88 1.03 16.00 2 2 2 187653 8.75 1.02 15.65 2 2 2 187653 8.79 1.01 15.58 2 2 2 187654 8.74 1.02 15.58 2 2 2 187654 8.73 1.02 15.96 2 2 2 187655 8.61 1.02 15.69 2 2 2 187655 8.56 1.03 15.76 2 2 2 187656 8.38 1.02 15.43 2 2 2 187656 8.43 1.02 15.61 2 2 2 187657 8.39 0.95 13.96 2 2 2 187657 8.45 0.94 13.87 2 2 2 187658 7.51 0.74 10.11 2 2 2 187658 7.48 0.74 10.14 2 2 2 187659 10.51 0.97 14.65 2 2 2 187659 10.63 0.96 14.61 2 2 2 187660 10.16 0.97 14.41 2 2 2 187660 10.24 0.99 14.43 2 2 2 187661 11.71 1.01 15.30 2 2 2 187661 11.92 1.01 15.30 2 2 2 187662 13.96 1.06 15.81 2 2 2 187662 13.92 1.06 15.74 2 2 2 187663 12.05 1.03 15.63 2 2 2 187663 11.98 1.05 15.37 2 2 2 187664 11.58 1.06 16.04 2 2 2 187664 11.66 1.06 15.95 2 2 2 187665 11.28 1.08 16.10 2 2 2 187665 11.29 1.07 16.17 2 2 2 187666 11.05 1.09 16.24 2 2 2 187666 10.91 1.10 16.17 2 2 2 187667 10.29 1.10 16.35 2 2 2 187667 10.36 1.14 16.31 2 2 2 187668 9.64 1.14 16.51 2 2 2 187668 9.76 1.10 16.60 2 2 2 187669 9.53 1.08 16.53 2 2 2 187669 9.78 16.32 2 5 2 187670 9.96 17.10 2 5 2 187670 9.55 1.08 16.67 2 2 2 187671 9.67 1.14 16.44 2 2 2 187671 9.63 1.11 16.36 2 2 2 187672 9.33 1.08 16.29 2 2 2 187672 9.34 1.08 16.20 2 2 2 187673 9.26 1.10 16.51 2 2 2 187673 9.27 1.07 16.42 2 2 2 187674 8.87 1.08 15.98 2 2 2 187674 8.97 1.05 16.25 2 2 2 187675 9.05 1.08 16.22 2 2 2 187675 9.31 16.83 2 5 2 187676 8.88 1.07 16.09 2 2 2 187676 8.92 1.10 16.29 2 2 2 187677 8.75 1.04 15.96 2 2 2 187677 8.81 1.05 16.05 2 2 2 187678 8.67 1.04 15.67 2 2 2 187678 8.68 1.04 15.69 2 2 2 187679 8.41 1.04 15.61 2 2 2 187679 8.56 1.06 15.87 2 2 2 187680 8.65 1.04 15.72 2 2 2 187680 8.70 1.06 15.68 2 2 2 187681 8.34 0.99 13.99 2 2 2 187681 8.66 14.46 2 5 2 187682 4.86 0.68 9.41 2 2 2 187682 4.88 0.67 9.36 2 2 2 187683 10.48 0.97 14.53 2 2 2 187683 10.48 0.92 14.53 2 2 2 187684 10.51 0.92 14.69 2 2 2 187684 10.54 0.94 14.61 2 2 2 187685 11.77 0.96 15.42 2 2 2 187685 11.77 0.97 15.14 2 2 2 187686 13.04 1.02 15.87 2 2 2 187686 13.07 1.02 15.85 2 2 2 187687 12.15 1.03 15.76 2 2 2 187687 12.24 1.03 16.10 2 2 2 187688 11.58 1.03 16.33 2 2 2 187688 11.65 1.03 16.26 2 2 2 187689 11.12 1.04 16.05 2 2 2 187689 11.15 1.05 16.20 2 2 2 187690 11.01 1.03 16.22 2 2 2 187690 11.08 1.05 16.26 2 2 2 187691 10.20 1.05 16.31 2 2 2 187691 10.17 1.08 16.15 2 2 2 187692 9.47 1.04 16.59 2 2 2 187692 9.71 1.05 16.47 2 2 2 187693 9.53 1.04 16.64 2 2 2 187693 9.63 1.04 16.53 2 2 2 187694 9.59 1.05 16.49 2 2 2 187694 9.62 1.06 16.29 2 2 2 187695 9.38 1.05 16.84 2 2 2 187695 9.42 1.05 16.77 2 2 2 187696 9.18 1.05 16.27 2 2 2 187696 9.21 1.03 16.55 2 2 2 187697 9.01 1.04 16.21 2 2 2 187697 9.14 1.04 16.20 2 2 2 187698 8.97 1.04 16.39 2 2 2 187698 9.03 1.04 16.37 2 2 2 187699 8.81 1.03 16.38 2 2 2 187699 8.78 1.04 16.15 2 2 2 187700 8.70 1.04 15.89 2 2 2 187700 8.74 1.03 16.00 2 2 2 187701 8.49 1.01 16.04 2 2 2 187701 8.50 1.04 15.74 2 2 2 187702 8.19 1.02 15.75 2 2 2 187702 8.23 1.03 15.77 2 2 2 187703 8.12 1.00 14.80 2 2 2 187703 8.19 1.00 15.11 2 2 2 187704 7.92 0.93 14.08 2 2 2 187704 7.94 0.91 14.07 2 2 2 187705 1.78 0.31 4.56 2 2 2 187705 1.79 0.29 4.71 2 2 2 187706 0.79 0.21 3.78 2 2 2 187706 0.89 0.23 3.82 2 2 2 187707 10.20 0.91 14.60 2 2 2 187707 10.46 0.92 14.66 2 2 2 187708 10.42 0.94 14.54 2 2 2 187708 10.45 0.95 14.62 2 2 2 187709 10.67 0.95 14.95 2 2 2 187709 10.51 0.95 15.04 2 2 2 187710 11.95 1.00 15.47 2 2 2 187710 11.91 1.02 15.77 2 2 2 187711 11.48 1.00 15.80 2 2 2 187711 11.93 1.02 15.74 2 2 2 187712 11.27 1.02 15.78 2 2 2 187712 11.30 1.03 15.79 2 2 2 187713 10.94 1.03 16.34 2 2 2 187713 10.93 1.02 16.25 2 2 2 187714 10.66 1.01 16.33 2 2 2 187714 10.70 1.03 16.62 2 2 2 187715 10.11 1.02 16.65 2 2 2 187715 10.11 1.05 16.42 2 2 2 187716 9.64 1.04 16.41 2 2 2 187716 9.71 1.03 16.59 2 2 2 187717 9.63 1.04 16.44 2 2 2 187717 9.57 1.05 16.57 2 2 2 187718 9.76 1.05 16.31 2 2 2 187718 9.72 1.05 16.72 2 2 2 187719 9.65 1.04 16.89 2 2 2 187719 9.69 1.06 16.86 2 2 2 187720 9.28 1.04 16.44 2 2 2 187720 9.32 1.01 16.51 2 2 2 187721 9.24 1.05 16.34 2 2 2 187721 9.11 1.04 16.36 2 2 2 187722 8.77 1.02 16.30 2 2 2 187722 8.80 1.03 16.21 2 2 2 187723 8.51 1.01 15.82 2 2 2 187723 8.77 0.99 15.74 2 2 2 187724 8.53 1.01 15.81 2 2 2 187724 8.57 1.00 15.79 2 2 2 187725 8.52 1.01 15.94 2 2 2 187725 8.50 1.01 15.89 2 2 2 187726 8.06 0.98 15.35 2 2 2 187726 7.92 0.96 15.35 2 2 2 187727 7.72 0.94 14.73 2 2 2 187727 7.79 0.96 15.04 2 2 2 187728 7.44 0.94 14.44 2 2 2 187728 7.45 0.96 14.37 2 2 2 187729 6.29 0.90 13.76 2 2 2 187729 6.25 0.90 14.02 2 2 2 187730 0.00 0.13 0.65 2 2 2 187730 0.00 0.18 0.80 2 2 2 187731 9.70 0.96 14.91 2 2 2 187731 9.74 0.93 14.91 2 2 2 187732 9.43 0.97 14.71 2 2 2 187732 9.46 0.95 14.49 2 2 2 187733 10.81 0.96 15.13 2 2 2 187733 10.68 0.98 15.14 2 2 2 187734 12.75 1.03 15.76 2 2 2 187734 12.72 1.02 15.51 2 2 2 187735 11.98 1.03 16.11 2 2 2 187735 12.02 1.04 16.09 2 2 2 187736 11.68 1.05 16.21 2 2 2 187736 11.71 1.07 16.26 2 2 2 187737 11.43 1.07 16.13 2 2 2 187737 11.24 1.07 16.36 2 2 2 187738 11.03 1.03 16.25 2 2 2 187738 11.03 1.04 16.30 2 2 2 187739 10.48 1.08 16.62 2 2 2 187739 10.57 1.03 16.49 2 2 2 187740 9.71 1.09 16.63 2 2 2 187740 9.74 1.08 16.63 2 2 2 187741 9.67 1.08 16.46 2 2 2 187741 9.60 1.08 16.87 2 2 2 187742 9.69 1.08 16.95 2 2 2 187742 9.66 1.08 16.75 2 2 2 187743 9.75 1.07 16.62 2 2 2 187743 9.82 1.08 16.59 2 2 2 187744 9.54 1.08 16.69 2 2 2 187744 9.58 1.08 16.51 2 2 2 187745 9.66 1.05 16.54 2 2 2 187745 9.30 1.04 16.63 2 2 2 187746 9.20 1.07 16.52 2 2 2 187746 9.32 1.08 16.48 2 2 2 187747 8.84 1.06 16.09 2 2 2 187747 8.87 1.08 16.23 2 2 2 187748 8.76 1.06 15.62 2 2 2 187748 8.80 1.03 15.94 2 2 2 187749 8.82 1.03 15.95 2 2 2 187749 8.62 1.04 16.06 2 2 2 187750 8.64 1.05 15.59 2 2 2 187750 8.58 1.03 15.84 2 2 2 187751 8.33 1.03 15.09 2 2 2 187751 8.44 1.03 15.11 2 2 2 187752 7.96 0.97 14.50 2 2 2 187752 8.03 0.96 14.40 2 2 2 187753 7.79 0.96 14.09 2 2 2 187753 7.72 0.93 14.05 2 2 2 187754 2.54 0.37 5.69 2 2 2 187754 2.97 0.36 5.73 2 2 2 187755 10.22 0.92 14.40 2 3 2 187755 10.31 0.89 14.37 2 3 2 187756 10.26 0.90 14.49 2 3 2 187756 10.30 0.93 14.42 2 3 2 187757 10.51 0.87 15.02 2 3 2 187757 10.45 0.94 14.88 2 3 2 187758 12.58 0.95 15.76 2 3 2 187758 12.44 0.94 15.71 2 3 2 187759 12.00 0.94 15.80 2 3 2 187759 12.07 0.95 15.78 2 3 2 187760 11.56 0.94 16.01 2 3 2 187760 11.69 0.97 16.17 2 3 2 187761 10.98 1.00 16.17 2 3 2 187761 10.96 0.98 16.15 2 3 2 187762 10.34 1.00 16.27 2 3 2 187762 10.61 0.99 16.38 2 3 2 187763 9.91 1.00 16.54 2 3 2 187763 9.92 0.97 16.31 2 3 2 187764 9.53 1.03 16.50 2 3 2 187764 9.64 1.00 16.54 2 3 2 187765 9.69 0.97 16.91 2 3 2 187765 9.59 0.98 16.94 2 3 2 187766 9.81 0.97 17.01 2 3 2 187766 9.67 0.98 16.61 2 3 2 187767 9.69 0.96 16.85 2 3 2 187767 9.73 0.96 16.73 2 3 2 187768 9.39 0.92 16.73 2 3 2 187768 9.48 0.92 17.01 2 3 2 187769 9.47 0.89 16.91 2 3 2 187769 9.50 0.94 16.89 2 3 2 187770 9.29 0.96 16.73 2 3 2 187770 9.30 0.91 16.45 2 3 2 187771 8.86 0.91 16.13 2 3 2 187771 8.95 0.83 16.43 2 3 2 187772 8.81 0.96 16.55 2 3 2 187772 8.82 0.87 16.50 2 3 2 187773 8.47 0.85 16.71 2 3 2 187773 8.63 0.85 16.20 2 3 2 187774 8.53 0.86 15.99 2 3 2 187774 8.59 0.87 16.04 2 3 2 187775 8.05 0.80 15.07 2 3 2 187775 8.15 0.84 15.21 2 3 2 187776 7.88 0.79 15.74 2 3 2 187776 7.97 0.85 15.44 2 3 2 187777 6.35 0.68 13.49 2 3 2 187777 6.36 0.67 13.70 2 3 2 187778 1.16 0.15 3.45 2 3 2 187778 1.16 0.17 3.43 2 3 2 187779 10.26 1.22 14.38 2 3 2 187779 10.36 1.08 15.14 2 3 2 187780 10.28 1.09 15.19 2 3 2 187780 10.44 1.06 15.21 2 3 2 187781 11.91 1.12 15.65 2 3 2 187781 11.93 1.12 15.65 2 3 2 187782 12.22 1.16 16.23 2 3 2 187782 12.26 1.14 15.97 2 3 2 187783 11.91 1.15 16.62 2 3 2 187783 11.91 1.17 16.60 2 3 2 187784 11.40 1.15 16.32 2 3 2 187784 11.41 1.16 16.57 2 3 2 187785 10.87 1.15 16.48 2 3 2 187785 10.90 1.16 16.78 2 3 2 187786 10.63 1.18 17.11 2 3 2 187786 10.62 1.18 16.78 2 3 2 187787 10.06 1.20 17.25 2 3 2 187787 10.16 1.21 17.01 2 3 2 187788 9.94 1.19 17.06 2 3 2 187788 9.95 1.19 17.11 2 3 2 187789 9.93 1.18 16.99 2 3 2 187789 9.94 1.19 17.01 2 3 2 187790 9.88 1.19 17.43 2 3 2 187790 10.41 1.19 17.02 2 3 2 187791 9.93 1.18 17.34 2 3 2 187791 10.07 1.19 17.39 2 3 2 187792 9.95 1.20 17.13 2 3 2 187792 9.99 1.20 17.06 2 3 2 187793 9.78 1.19 17.25 2 3 2 187793 9.94 1.19 17.32 2 3 2 187794 9.51 1.19 16.99 2 3 2 187794 9.47 1.18 16.97 2 3 2 187795 9.44 1.17 16.83 2 3 2 187795 9.49 1.17 16.93 2 3 2 187796 9.23 1.15 16.65 2 3 2 187796 9.28 1.15 16.56 2 3 2 187797 9.02 1.16 16.44 2 3 2 187797 9.56 1.15 16.79 2 3 2 187798 8.42 1.12 16.14 2 3 2 187798 8.51 1.10 16.12 2 3 2 187799 8.20 1.10 15.57 2 3 2 187799 8.27 1.10 15.66 2 3 2 187800 8.00 1.07 15.13 2 3 2 187800 8.02 1.05 15.13 2 3 2 187801 7.49 0.99 13.57 2 3 2 187801 7.50 1.00 13.57 2 3 2 187802 1.31 0.28 2 3 5 187802 1.34 0.34 2 3 5 187803 10.63 1.06 15.36 2 3 2 187803 10.64 1.06 15.22 2 3 2 187804 10.62 1.06 15.57 2 3 2 187804 10.52 1.08 15.43 2 3 2 187805 11.97 1.10 16.26 2 3 2 187805 11.88 1.10 16.12 2 3 2 187806 12.59 1.12 16.47 2 3 2 187806 12.71 1.12 16.28 2 3 2 187807 11.06 1.12 16.31 2 3 2 187807 11.17 1.11 16.24 2 3 2 187808 11.31 1.14 16.81 2 3 2 187808 11.22 1.13 16.77 2 3 2 187810 10.84 1.14 17.07 2 3 2 187810 10.88 1.16 17.09 2 3 2 187811 10.01 1.15 17.23 2 3 2 187811 10.09 1.17 16.77 2 3 2 187812 9.61 1.15 17.05 2 3 2 187812 9.62 1.16 16.86 2 3 2 187813 9.83 1.17 17.23 2 3 2 187813 9.77 1.15 17.21 2 3 2 187814 9.82 1.17 17.21 2 3 2 187814 9.81 1.15 16.93 2 3 2 187815 9.61 1.15 17.33 2 3 2 187815 9.61 1.15 17.21 2 3 2 187816 9.31 1.14 17.33 2 3 2 187816 9.40 1.16 17.07 2 3 2 187817 9.06 1.13 16.66 2 3 2 187817 8.99 1.13 16.56 2 3 2 187818 8.91 1.14 17.03 2 3 2 187818 8.95 1.12 16.54 2 3 2 187819 9.16 1.20 16.98 2 3 2 187819 9.27 1.15 17.07 2 3 2 187820 9.09 1.12 16.77 2 3 2 187820 9.16 1.15 16.70 2 3 2 187821 8.63 1.09 16.13 2 3 2 187821 8.59 1.08 16.38 2 3 2 187822 8.32 1.09 15.92 2 3 2 187822 8.31 1.07 15.64 2 3 2 187823 7.94 1.04 15.00 2 3 2 187823 7.95 1.05 15.37 2 3 2 187824 7.12 0.89 12.08 2 3 2 187824 7.13 0.90 12.24 2 3 2 187825 3.00 0.38 3.10 2 3 2 187825 3.00 0.40 3.01 2 3 2 187827 10.18 1.05 14.59 2 3 2 187827 10.40 1.04 14.65 2 3 2 187828 10.65 1.05 14.79 2 3 2 187828 10.69 1.04 14.79 2 3 2 187829 10.87 1.06 15.25 2 3 2 187829 11.30 1.08 15.18 2 3 2 187830 11.18 1.12 16.31 2 3 2 187830 10.96 1.10 15.99 2 3 2 187831 11.04 1.16 16.73 2 3 2 187831 11.00 1.15 16.91 2 3 2 187832 10.05 1.12 16.43 2 3 2 187832 10.09 1.12 15.97 2 3 2 187833 9.91 1.13 16.87 2 3 2 187833 10.04 1.14 16.71 2 3 2 187834 9.70 1.14 16.57 2 3 2 187834 9.74 1.14 16.64 2 3 2 187835 9.72 1.14 16.64 2 3 2 187835 9.89 1.14 16.57 2 3 2 187836 9.74 1.15 17.01 2 3 2 187836 9.77 1.15 16.89 2 3 2 187837 9.41 1.14 16.52 2 3 2 187837 9.47 1.15 16.62 2 3 2 187838 9.00 1.13 16.16 2 3 2 187838 9.01 1.12 16.18 2 3 2 187839 8.99 1.12 16.02 2 3 2 187839 9.02 1.11 15.81 2 3 2 187840 8.75 1.12 16.09 2 3 2 187840 8.88 1.11 16.18 2 3 2 187841 8.60 1.09 15.56 2 3 2 187841 8.74 1.10 15.81 2 3 2 187842 8.14 1.09 15.51 2 3 2 187842 8.18 1.06 15.37 2 3 2 187843 7.77 1.00 13.81 2 3 2 187843 7.74 1.00 13.72 2 3 2 187844 7.37 0.93 12.57 2 3 2 187844 7.37 0.94 12.22 2 3 2 187845 6.10 0.86 10.90 2 3 2 187845 6.11 0.86 10.76 2 3 2 187846 1.68 0.37 2.41 2 3 2 187846 1.77 0.40 2.53 2 3 2 187847 1.28 0.36 1.30 2 3 2 187847 1.31 0.34 1.09 2 3 2 187851 9.78 1.09 16.00 2 3 2 187851 9.84 1.10 16.07 2 3 2 187852 9.84 1.08 16.00 2 3 2 187852 9.86 1.10 16.09 2 3 2 187853 9.78 1.11 15.98 2 3 2 187853 9.89 1.08 16.14 2 3 2 187854 9.84 1.12 16.55 2 3 2 187854 9.51 1.12 16.67 2 3 2 187855 9.11 1.09 16.14 2 3 2 187855 9.15 1.08 16.39 2 3 2 187856 8.84 1.08 16.14 2 3 2 187856 8.91 1.08 15.86 2 3 2 187857 8.41 1.04 15.84 2 3 2 187857 8.48 1.05 15.42 2 3 2 187858 8.02 1.04 15.38 2 3 2 187858 8.07 1.04 15.40 2 3 2 187859 7.74 0.98 14.48 2 3 2 187859 7.84 0.99 14.46 2 3 2 187860 7.21 0.94 13.35 2 3 2 187860 7.25 0.93 13.17 2 3 2 187861 6.85 0.90 12.64 2 3 2 187861 6.91 0.89 12.87 2 3 2 187862 5.36 0.72 9.18 2 3 2 187862 5.03 0.72 9.13 2 3 2 187867 1.74 0.35 2.79 9 9 9 187867 1.77 0.36 2.49 9 9 9 187872 1.67 0.35 2.12 2 3 3 187872 1.70 0.35 1.98 2 3 3 187875 8.19 0.88 15.06 2 3 2 187875 8.47 0.90 15.29 2 3 2 187876 8.14 0.91 15.38 2 3 2 187876 8.20 0.90 15.38 2 3 2 187877 7.99 0.88 15.06 2 3 2 187877 8.06 0.91 15.11 2 3 2 187878 7.79 0.89 15.15 2 3 2 187878 7.82 0.88 14.71 2 3 2 187879 7.33 0.84 13.82 2 3 2 187879 7.35 0.81 13.80 2 3 2 187880 6.58 0.75 11.75 2 3 2 187880 6.54 0.73 11.98 2 3 2 187881 5.15 0.65 9.23 2 3 2 187881 5.21 0.65 9.23 2 3 2 187886 1.58 0.31 3.12 2 3 3 187886 1.61 0.31 2.06 2 3 3 187891 1.41 0.28 1.21 2 3 2 187891 1.47 0.27 1.37 2 3 2 187893 5.25 0.56 8.72 2 3 2 187893 5.37 0.55 8.77 2 3 2 187898 5.04 0.58 8.10 2 3 2 187898 5.04 0.53 8.12 2 3 2 187902 0.37 0.20 0.15 2 3 3 187902 0.41 0.19 0.29 2 3 3 187908 10.41 1.06 16.00 2 2 2 187908 10.47 1.16 15.99 2 2 2 187909 9.89 1.10 16.53 2 2 2 187909 9.86 1.10 16.39 2 2 2 187910 9.73 1.00 16.16 2 3 2 187910 9.86 1.09 16.37 2 3 2 187911 10.01 1.11 16.65 2 2 2 187911 10.04 1.08 16.55 2 2 2 187912 9.62 1.09 16.16 2 2 2 187912 9.69 1.08 16.46 2 2 2 187913 9.52 1.10 16.64 2 2 2 187913 9.58 1.11 16.60 2 2 2 187914 8.58 1.08 15.48 2 2 2 187914 8.68 1.05 15.81 2 2 2 187915 8.35 1.05 15.64 2 2 2 187915 8.35 1.08 15.58 2 2 2 187916 8.11 1.04 14.97 2 2 2 187916 8.11 1.10 14.92 2 2 2 187917 7.85 1.05 15.00 2 2 2 187917 7.82 1.05 15.20 2 2 2 187918 7.39 1.00 14.27 2 2 2 187918 7.68 1.02 14.18 2 2 2 187919 5.81 0.96 12.12 2 2 2 187919 5.87 0.96 12.20 2 2 2 187920 1.35 0.57 3.86 2 2 2 187920 1.36 0.47 3.97 2 2 2 187921 0.22 0.21 0.00 2 2 2 187921 0.32 0.23 0.00 2 2 2 187922 10.92 1.04 15.56 2 3 2 187922 11.14 0.87 15.82 2 3 2 187923 10.42 1.04 16.13 2 2 2 187923 10.54 1.02 16.06 2 2 2 187924 10.13 1.04 15.79 2 2 2 187924 10.20 1.04 16.13 2 2 2 187925 9.86 0.94 16.32 2 3 2 187925 9.85 1.04 16.44 2 3 2 187926 9.64 1.03 16.22 2 2 2 187926 9.71 1.03 16.48 2 2 2 187927 9.53 0.87 16.26 2 3 2 187927 9.60 1.05 16.29 2 3 2 187928 9.54 1.01 16.55 2 2 2 187928 9.55 1.06 16.31 2 2 2 187929 9.69 1.05 16.52 2 2 2 187929 10.19 1.05 16.62 2 2 2 187930 9.62 0.96 16.37 2 3 2 187930 9.64 1.02 16.44 2 3 2 187931 9.36 1.04 16.29 2 2 2 187931 9.44 1.04 16.39 2 2 2 187932 8.79 1.05 16.15 2 2 2 187932 8.87 1.02 16.22 2 2 2 187933 8.13 1.03 15.62 2 2 2 187933 8.29 1.01 15.59 2 2 2 187934 8.34 1.01 15.47 2 2 2 187934 10.40 1.00 15.50 3 2 2 187935 7.94 1.01 15.21 2 2 2 187935 7.90 1.00 14.97 2 2 2 187936 7.56 0.99 15.13 2 2 2 187936 7.53 1.01 15.28 2 2 2 187937 6.87 0.98 14.08 2 2 2 187937 6.92 0.96 13.86 2 2 2 187938 0.00 0.20 0.00 2 2 2 187938 0.00 0.21 0.00 2 2 2 187939 0.00 0.18 0.00 2 2 2 187939 0.00 0.15 0.00 2 2 2 187940 10.65 0.96 14.64 2 2 2 187940 10.81 0.97 14.90 2 2 2 187941 10.86 0.96 14.90 2 2 2 187941 11.12 0.96 14.89 2 2 2 187942 10.78 0.98 15.01 2 2 2 187942 10.81 0.98 14.99 2 2 2 187943 10.96 1.01 15.20 2 2 2 187943 10.92 1.00 15.37 2 2 2 187944 11.07 1.00 15.63 2 2 2 187944 10.85 1.00 15.56 2 2 2 187945 10.77 1.02 15.82 2 2 2 187945 10.89 1.01 15.77 2 2 2 187946 10.55 1.00 15.86 2 2 2 187946 10.61 1.00 15.97 2 2 2 187947 10.28 1.02 16.21 2 2 2 187947 10.14 1.03 16.23 2 2 2 187948 9.60 1.04 16.16 2 2 2 187948 9.64 1.04 16.07 2 2 2 187949 9.42 1.04 16.54 2 2 2 187949 9.50 1.05 16.37 2 2 2 187950 9.55 1.04 16.76 2 2 2 187950 9.60 1.09 16.61 2 2 2 187951 9.56 1.06 16.78 2 2 2 187951 9.52 1.05 16.65 2 2 2 187952 10.00 1.06 16.46 2 2 2 187952 9.34 1.06 16.44 2 2 2 187953 8.78 1.03 16.24 2 2 2 187953 8.94 1.03 16.24 2 2 2 187954 8.27 1.00 15.68 2 2 2 187954 8.28 0.99 15.47 2 2 2 187955 8.07 0.97 15.37 2 2 2 187955 8.03 0.99 15.42 2 2 2 187956 7.85 0.98 15.17 2 2 2 187956 7.89 0.99 15.20 2 2 2 187957 7.74 0.97 14.69 2 2 2 187957 7.80 0.98 14.74 2 2 2 187958 6.89 0.93 12.50 2 2 2 187958 7.10 0.93 12.56 2 2 2 187959 3.38 0.63 5.47 2 2 2 187959 3.21 0.63 5.47 2 2 2 187960 1.09 0.34 1.15 2 2 2 187960 1.06 0.35 1.16 2 2 2 187964 10.27 0.97 14.35 2 2 2 187964 10.36 0.96 14.97 2 2 2 187965 10.74 0.97 14.82 2 2 2 187965 10.93 0.97 15.08 2 2 2 187966 11.01 1.01 15.63 2 2 2 187966 11.05 1.00 15.70 2 2 2 187967 10.90 1.01 15.86 2 2 2 187967 10.93 1.01 15.48 2 2 2 187968 10.68 1.02 15.91 2 2 2 187968 10.69 1.02 15.76 2 2 2 187969 10.54 1.02 16.15 2 2 2 187969 10.57 1.04 16.17 2 2 2 187970 10.16 1.05 16.17 2 2 2 187970 10.27 1.05 16.26 2 2 2 187971 9.79 1.05 16.38 2 2 2 187971 9.83 1.04 16.40 2 2 2 187972 9.46 1.06 16.69 2 2 2 187972 9.48 1.04 16.71 2 2 2 187973 9.47 1.05 16.42 2 2 2 187973 9.53 1.04 16.58 2 2 2 187974 9.45 1.04 16.65 2 2 2 187974 9.46 1.06 16.80 2 2 2 187975 9.31 1.05 16.53 2 2 2 187975 9.27 1.07 16.60 2 2 2 187976 9.33 1.06 16.74 2 2 2 187976 9.38 1.06 16.67 2 2 2 187977 9.08 1.06 16.55 2 2 2 187977 9.17 1.04 16.47 2 2 2 187978 8.83 1.04 15.99 2 2 2 187978 9.17 1.02 16.11 2 2 2 187980 8.49 1.00 15.73 2 2 2 187980 8.50 1.01 15.78 2 2 2 187982 7.67 0.98 14.86 2 2 2 187982 7.74 0.97 15.20 2 2 2 187983 8.18 0.99 14.93 2 2 2 187983 8.24 0.98 15.02 2 2 2 187984 7.45 0.96 13.47 2 2 2 187984 7.48 0.96 13.89 2 2 2 187985 5.98 0.82 10.06 2 2 2 187985 5.91 0.81 9.97 2 2 2 187986 1.74 0.34 1.77 2 2 2 187986 1.75 0.34 1.84 2 2 2 187988 10.21 0.97 14.58 2 2 2 187988 10.27 0.97 14.84 2 2 2 187989 10.36 0.96 14.89 2 2 2 187989 10.38 0.97 14.79 2 2 2 187990 10.99 0.99 15.12 2 2 2 187990 11.18 1.01 14.91 2 2 2 187991 11.23 1.00 15.70 2 2 2 187991 11.29 1.00 15.65 2 2 2 187992 10.75 1.01 15.54 2 2 2 187992 10.79 1.01 15.59 2 2 2 187993 10.41 1.03 15.51 2 2 2 187993 10.45 1.02 15.66 2 2 2 187994 10.53 1.05 15.78 2 2 2 187994 10.46 1.05 16.13 2 2 2 187995 10.16 1.05 16.25 2 2 2 187995 10.26 1.05 16.33 2 2 2 187996 9.59 1.06 16.20 2 2 2 187996 9.66 1.06 16.18 2 2 2 187997 9.45 1.07 16.30 2 2 2 187997 9.54 1.06 16.17 2 2 2 187998 9.53 1.07 16.32 2 2 2 187998 9.62 1.07 16.63 2 2 2 187999 9.41 1.08 16.53 2 2 2 187999 9.42 1.07 16.60 2 2 2 188000 9.27 1.05 16.35 2 2 2 188000 9.27 1.06 16.28 2 2 2 188001 8.93 1.06 15.85 2 2 2 188001 8.93 1.04 16.21 2 2 2 188002 8.68 1.05 16.20 2 2 2 188002 8.73 1.05 16.04 2 2 2 188003 8.32 1.02 15.79 2 2 2 188003 8.35 1.04 15.50 2 2 2 188004 8.07 1.03 15.14 2 2 2 188004 8.05 1.04 15.05 2 2 2 188005 8.00 1.02 15.16 2 2 2 188005 7.99 1.02 15.16 2 2 2 188006 7.62 1.01 13.99 2 2 2 188006 7.69 1.01 14.06 2 2 2 188007 7.48 0.99 13.87 2 2 2 188007 8.10 0.99 13.41 2 2 2 188008 6.02 0.84 10.20 2 2 2 188008 5.98 0.82 10.25 2 2 2 188009 2.18 0.58 5.46 2 2 2 188009 2.18 0.58 5.49 2 2 2 188010 0.27 0.18 0.00 2 2 2 188010 0.31 0.14 0.00 2 2 2 188011 10.12 0.98 14.11 2 2 2 188011 10.12 0.97 14.06 2 2 2 188012 11.23 1.01 14.87 2 2 2 188012 11.04 1.01 14.75 2 2 2 188013 10.19 1.06 15.81 2 2 2 188013 10.15 1.04 15.78 2 2 2 188014 11.42 1.04 15.35 2 2 2 188014 11.46 1.04 15.66 2 2 2 188015 11.15 1.05 15.94 2 2 2 188015 11.18 1.06 15.89 2 2 2 188016 10.65 1.05 15.65 2 2 2 188016 10.65 1.04 15.77 2 2 2 188017 10.38 1.07 15.76 2 2 2 188017 10.53 1.05 15.79 2 2 2 188018 10.13 1.06 16.22 2 2 2 188018 10.20 1.07 16.10 2 2 2 188019 9.64 1.09 16.19 2 2 2 188019 9.73 1.07 16.00 2 2 2 188020 9.65 1.06 16.55 2 2 2 188020 9.65 1.07 16.47 2 2 2 188021 10.60 1.09 16.16 3 2 2 188021 9.51 1.08 16.42 2 2 2 188022 9.59 1.08 16.42 2 2 2 188022 9.65 1.08 16.54 2 2 2 188023 9.24 1.08 16.15 2 2 2 188023 9.28 1.05 16.32 2 2 2 188024 8.78 1.04 15.79 2 2 2 188024 8.74 1.04 16.00 2 2 2 188025 8.89 1.05 15.88 2 2 2 188025 8.90 1.04 16.12 2 2 2 188026 8.65 1.05 15.78 2 2 2 188026 8.69 1.04 15.80 2 2 2 188027 8.60 1.04 15.78 2 2 2 188027 8.61 1.10 15.35 2 2 2 188028 8.33 1.02 15.53 2 2 2 188028 8.26 1.01 15.63 2 2 2 188029 8.09 1.01 15.10 2 2 2 188029 8.06 1.01 15.15 2 2 2 188030 7.72 1.01 14.72 2 2 2 188030 7.91 1.00 14.69 2 2 2 188031 7.42 0.98 14.45 2 2 2 188031 7.44 0.97 14.43 2 2 2 188032 3.78 0.76 8.80 2 2 2 188032 3.72 0.76 8.80 2 2 2 188033 0.47 0.15 0.16 2 2 2 188033 0.48 0.15 0.23 2 2 2 188034 10.49 1.02 14.35 2 2 2 188034 10.50 1.03 14.26 2 2 2 188035 10.29 1.00 14.30 2 2 2 188035 10.46 1.04 14.37 2 2 2 188036 10.44 1.02 14.55 2 2 2 188036 10.32 1.06 14.27 2 2 2 188037 11.49 1.05 15.24 2 2 2 188037 11.42 1.04 15.36 2 2 2 188038 11.60 1.07 15.40 2 2 2 188038 11.64 1.05 15.35 2 2 2 188039 11.21 1.08 15.66 2 2 2 188039 11.30 1.07 15.32 2 2 2 188040 11.04 1.10 15.93 2 2 2 188040 10.95 1.09 15.82 2 2 2 188041 10.62 1.12 16.07 2 2 2 188041 10.64 1.09 15.88 2 2 2 188042 10.19 1.05 16.22 2 2 2 188042 10.29 1.07 16.10 2 2 2 188043 9.77 1.06 16.10 2 2 2 188043 9.77 1.07 16.38 2 2 2 188044 10.08 1.07 16.14 3 2 2 188044 9.53 1.10 16.26 3 2 2 188045 11.82 1.10 16.42 2 2 2 188045 9.65 1.07 15.87 2 2 2 188046 9.77 1.09 16.55 2 2 2 188046 9.80 1.07 16.46 2 2 2 188047 9.56 1.12 16.29 2 2 2 188047 10.75 1.10 16.24 2 2 2 188048 9.42 1.08 16.00 2 2 2 188048 9.27 1.13 16.05 2 2 2 188049 9.26 1.11 16.37 2 2 2 188049 9.32 1.10 16.35 2 2 2 188050 8.93 1.08 16.00 2 2 2 188050 8.97 1.06 15.95 2 2 2 188051 8.61 1.06 15.71 2 2 2 188051 8.67 1.07 15.62 2 2 2 188052 8.69 1.04 15.40 2 2 2 188052 8.69 1.03 15.35 2 2 2 188053 8.46 1.05 15.49 2 2 2 188053 8.39 1.05 15.40 2 2 2 188054 8.23 1.04 15.16 2 2 2 188054 8.25 1.05 15.16 2 2 2 188055 8.15 1.03 15.11 2 2 2 188055 8.18 1.03 15.13 2 2 2 188056 7.47 0.97 12.57 2 2 2 188056 7.31 0.96 12.45 2 2 2 188064 10.43 0.97 13.88 2 2 2 188064 10.48 0.95 13.97 2 2 2 188065 10.14 1.00 13.72 2 2 2 188065 10.20 0.99 13.86 2 2 2 188066 10.61 1.00 14.30 2 2 2 188066 10.76 0.99 14.35 2 2 2 188067 11.68 1.01 15.00 2 2 2 188067 11.61 1.02 14.97 2 2 2 188068 11.28 1.03 15.20 2 2 2 188068 11.25 1.08 15.02 2 2 2 188069 11.14 1.10 15.29 2 2 2 188069 11.15 1.07 15.29 2 2 2 188070 10.75 1.07 15.66 2 2 2 188070 10.85 1.06 15.47 2 2 2 188071 10.49 1.07 15.70 2 2 2 188071 10.64 1.10 15.77 2 2 2 188072 9.93 1.07 15.65 2 2 2 188072 9.93 1.06 15.84 2 2 2 188073 9.42 1.09 16.03 2 2 2 188073 9.52 1.09 15.87 2 2 2 188074 9.41 1.08 15.86 2 2 2 188074 9.41 1.08 15.91 2 2 2 188075 9.43 1.08 15.90 2 2 2 188075 9.62 1.07 15.95 2 2 2 188076 9.52 1.08 16.04 2 2 2 188076 9.64 1.10 16.17 2 2 2 188077 9.25 1.12 16.13 2 2 2 188077 9.28 1.07 15.87 2 2 2 188078 9.01 1.06 15.68 2 2 2 188078 9.08 1.08 15.66 2 2 2 188079 9.01 1.05 15.67 2 2 2 188079 9.04 1.12 15.44 2 2 2 188080 8.77 1.08 15.25 2 2 2 188080 8.71 1.05 15.20 2 2 2 188081 8.74 1.04 15.39 2 2 2 188081 9.32 1.07 15.30 2 2 2 188082 8.38 1.02 15.02 2 2 2 188082 8.38 1.03 15.00 2 2 2 188083 8.49 1.04 15.13 2 2 2 188083 8.53 1.08 14.76 2 2 2 188084 8.71 1.07 15.38 2 2 2 188084 10.87 1.06 15.29 3 2 2 188085 8.79 1.05 15.05 2 2 2 188085 8.80 1.09 15.07 2 2 2 188086 7.61 0.96 12.49 2 2 2 188086 7.99 1.02 12.23 2 2 2 188087 1.71 0.28 0.00 2 2 2 188087 2.02 0.23 0.00 2 2 2 188088 10.51 0.98 13.79 2 2 2 188088 10.38 0.97 14.02 2 2 2 188089 10.54 0.99 14.41 2 2 2 188089 10.66 1.00 14.63 2 2 2 188090 11.75 1.05 14.74 2 2 2 188090 11.80 1.00 15.00 2 2 2 188091 12.35 1.05 15.39 2 2 2 188091 12.36 1.04 15.43 2 2 2 188092 11.64 1.05 15.59 2 2 2 188092 11.69 1.12 15.57 2 2 2 188093 11.10 1.07 15.50 2 2 2 188093 11.21 1.13 15.68 2 2 2 188094 10.66 1.05 15.79 2 2 2 188094 10.68 1.07 15.63 2 2 2 188095 10.10 1.05 15.51 2 2 2 188095 10.34 1.05 15.79 2 2 2 188096 10.42 1.04 16.67 2 2 2 188096 10.18 1.16 16.47 2 2 2 188097 9.70 1.05 16.70 2 2 2 188097 9.71 1.06 16.27 2 2 2 188098 9.55 1.05 16.70 2 2 2 188098 9.69 1.03 16.27 2 2 2 188099 9.60 1.04 16.13 2 2 2 188099 9.65 1.07 16.57 2 2 2 188100 9.65 1.05 16.53 2 2 2 188100 9.70 1.03 16.02 2 2 2 188101 9.07 1.00 15.84 2 2 2 188101 9.31 1.05 16.35 2 2 2 188102 8.90 1.04 16.44 2 2 2 188102 9.03 1.08 15.86 2 2 2 188103 8.88 1.02 16.19 2 2 2 188103 8.88 1.07 15.54 2 2 2 188104 8.74 1.04 16.12 2 2 2 188104 8.90 1.04 16.15 2 2 2 188105 8.50 1.04 15.79 2 2 2 188105 8.54 1.11 15.80 2 2 2 188106 8.18 1.04 15.47 2 2 2 188106 8.18 1.04 15.31 2 2 2 188107 8.36 1.09 15.79 2 2 2 188107 8.32 1.06 15.71 2 2 2 188108 8.28 1.04 15.16 2 2 2 188108 9.02 1.04 15.44 2 2 2 188109 8.15 1.04 14.84 2 2 2 188109 8.21 1.04 14.98 2 2 2 188110 7.76 1.09 13.81 2 2 2 188110 7.66 1.01 13.83 2 2 2 188111 4.53 0.57 3.98 2 2 2 188111 4.56 0.57 3.84 2 2 2 188112 10.46 0.97 14.28 2 2 2 188112 10.52 0.96 14.33 2 2 2 188113 10.28 0.97 14.65 2 2 2 188113 10.32 0.96 14.78 2 2 2 188114 11.07 0.99 15.30 2 2 2 188114 10.98 0.98 14.90 2 2 2 188115 11.92 1.00 15.68 2 2 2 188115 11.85 1.00 15.68 2 2 2 188116 11.53 1.03 15.56 2 2 2 188116 11.55 1.01 16.13 2 2 2 188117 10.91 1.02 16.03 2 2 2 188117 11.07 1.02 16.08 2 2 2 188118 10.74 1.04 15.94 2 2 2 188118 10.67 1.02 16.56 2 2 2 188119 10.06 1.01 16.29 2 2 2 188119 10.19 1.03 16.51 2 2 2 188120 9.30 1.01 16.40 2 2 2 188120 9.30 1.01 16.25 2 2 2 188121 9.39 1.01 16.58 2 2 2 188121 9.45 1.00 16.48 2 2 2 188122 9.53 1.00 16.38 2 2 2 188122 9.47 1.02 16.46 2 2 2 188123 9.43 1.01 16.53 2 2 2 188123 9.21 1.00 16.36 2 2 2 188124 9.16 1.00 16.39 2 2 2 188124 9.20 1.00 16.46 2 2 2 188125 8.90 1.00 16.34 2 2 2 188125 8.94 0.98 16.12 2 2 2 188126 9.05 1.00 16.54 2 2 2 188126 8.98 1.03 16.45 2 2 2 188127 8.75 1.02 16.17 2 2 2 188127 8.82 1.04 16.35 2 2 2 188128 8.53 0.99 15.86 2 2 2 188128 8.54 0.99 15.71 2 2 2 188129 8.39 0.99 15.94 2 2 2 188129 8.40 0.98 15.84 2 2 2 188130 8.29 0.99 15.77 2 2 2 188130 8.26 0.98 15.72 2 2 2 188131 8.32 0.98 15.80 2 2 2 188131 8.21 0.98 15.87 2 2 2 188132 8.08 0.98 15.63 2 2 2 188132 8.17 0.97 15.36 2 2 2 188133 7.51 0.93 14.30 2 2 2 188133 7.56 0.93 14.40 2 2 2 188134 5.42 0.79 11.87 2 2 2 188134 5.48 0.79 11.85 2 2 2 188136 9.75 0.92 14.44 2 2 2 188136 9.75 0.92 14.04 2 2 2 188137 10.08 0.95 14.86 2 2 2 188137 10.15 0.94 14.91 2 2 2 188138 11.81 0.99 15.16 2 2 2 188138 11.85 0.99 15.18 2 2 2 188139 12.62 1.00 15.73 2 2 2 188139 12.71 0.99 15.91 2 2 2 188140 13.14 1.03 15.83 2 2 2 188140 13.15 1.03 16.03 2 2 2 188141 13.51 1.04 16.36 2 2 2 188141 13.60 1.04 16.61 2 2 2 188142 12.65 1.05 16.01 2 2 2 188142 12.65 1.04 16.19 2 2 2 188143 11.63 1.02 16.46 2 2 2 188143 11.66 1.04 16.44 2 2 2 188144 11.40 1.06 16.37 2 2 2 188144 11.38 1.03 16.32 2 2 2 188145 10.57 1.04 16.58 2 2 2 188145 10.61 1.04 16.38 2 2 2 188146 9.72 1.04 16.65 2 2 2 188146 9.78 1.05 16.63 2 2 2 188147 9.70 1.06 16.88 2 2 2 188147 9.83 1.06 16.61 2 2 2 188148 9.72 1.07 16.78 2 2 2 188148 9.73 1.05 16.86 2 2 2 188149 9.72 1.07 16.49 2 2 2 188149 9.75 1.07 16.64 2 2 2 188150 9.64 1.07 16.94 2 2 2 188150 9.80 1.06 17.04 2 2 2 188151 9.86 1.08 16.87 2 2 2 188151 9.88 1.08 17.19 2 2 2 188152 9.25 1.03 16.60 2 2 2 188152 9.07 1.03 16.50 2 2 2 188153 8.72 1.04 15.91 2 2 2 188153 8.74 1.04 15.77 2 2 2 188154 8.64 1.04 15.97 2 2 2 188154 8.83 1.03 15.94 2 2 2 188155 8.60 1.03 15.85 2 2 2 188155 8.63 1.02 15.90 2 2 2 188156 8.46 1.03 15.53 2 2 2 188156 8.47 1.03 15.51 2 2 2 188157 8.29 1.00 15.31 2 2 2 188157 8.30 1.01 15.46 2 2 2 188158 2.24 0.59 8.48 2 2 2 188158 2.24 0.60 8.74 2 2 2 188159 1.58 0.45 6.59 2 2 2 188159 1.64 0.45 6.54 2 2 2 188160 7.99 0.98 15.05 2 2 2 188160 7.96 0.99 14.99 2 2 2 188161 8.15 0.97 14.72 2 2 2 188161 8.21 0.98 15.16 2 2 2 188162 8.14 0.99 15.24 2 2 2 188162 8.14 0.99 15.33 2 2 2 188163 8.04 0.99 14.82 2 2 2 188163 8.07 1.00 14.77 2 2 2 188164 7.84 0.99 14.58 2 2 2 188164 7.99 0.99 14.75 2 2 2 188165 7.86 0.97 13.70 2 2 2 188165 8.11 0.97 13.85 2 2 2 188166 7.85 0.92 12.54 2 2 2 188166 7.94 0.91 12.52 2 2 2 188167 4.17 0.72 9.96 2 2 2 188167 4.20 0.69 9.85 2 2 2 188168 3.45 0.61 8.78 2 2 2 188168 3.42 0.61 8.68 2 2 2 188169 3.93 0.63 8.95 2 2 2 188169 3.94 0.63 8.80 2 2 2 188170 3.86 0.62 8.76 2 2 2 188170 3.90 0.63 8.88 2 2 2 188171 10.16 0.97 14.30 2 2 2 188171 10.17 0.99 14.33 2 2 2 188172 9.80 0.97 14.33 2 2 2 188172 9.83 0.98 14.23 2 2 2 188173 11.99 1.02 14.94 2 2 2 188173 12.02 1.03 15.34 2 2 2 188174 12.74 1.05 15.88 2 2 2 188174 12.87 1.05 15.83 2 2 2 188175 11.99 1.05 15.65 2 2 2 188175 12.06 1.04 15.75 2 2 2 188176 11.88 1.07 15.86 2 2 2 188176 11.85 1.08 15.96 2 2 2 188177 11.13 1.06 16.32 2 2 2 188177 11.20 1.07 15.78 2 2 2 188178 10.63 1.07 16.32 2 2 2 188178 10.74 1.06 16.27 2 2 2 188179 10.34 1.07 16.02 2 2 2 188179 10.37 1.06 16.20 2 2 2 188180 9.62 1.06 16.23 2 2 2 188180 9.66 1.06 16.38 2 2 2 188181 9.29 1.07 16.41 2 2 2 188181 9.33 1.06 16.38 2 2 2 188182 9.40 1.08 16.13 2 2 2 188182 9.44 1.07 16.41 2 2 2 188183 9.52 1.08 16.39 2 2 2 188183 9.55 1.08 16.54 2 2 2 188184 9.13 1.07 16.52 2 2 2 188184 9.09 1.07 16.49 2 2 2 188185 8.91 1.08 16.47 2 2 2 188185 8.98 1.07 16.39 2 2 2 188186 9.03 1.06 16.09 2 2 2 188186 9.06 1.06 16.24 2 2 2 188187 8.67 1.05 15.97 2 2 2 188187 8.86 1.04 16.15 2 2 2 188188 8.85 1.04 15.95 2 2 2 188188 8.87 1.05 15.95 2 2 2 188189 8.48 1.04 15.90 2 2 2 188189 8.49 1.05 15.72 2 2 2 188190 8.47 1.04 16.05 2 2 2 188190 8.50 1.04 16.05 2 2 2 188191 8.52 1.04 15.95 2 2 2 188191 8.67 1.03 15.75 2 2 2 188192 8.47 1.02 15.07 2 2 2 188192 8.38 1.01 15.10 2 2 2 188195 10.39 0.97 14.92 2 2 2 188195 10.40 0.97 14.49 2 2 2 188196 10.57 1.00 15.18 2 2 2 188196 10.67 1.01 15.15 2 2 2 188197 10.79 1.01 14.68 2 2 2 188197 10.81 0.99 15.38 2 2 2 188198 10.93 1.00 15.46 2 2 2 188198 11.03 0.99 15.56 2 2 2 188199 11.17 1.03 15.49 2 2 2 188199 11.20 1.02 15.39 2 2 2 188200 12.11 1.04 15.82 2 2 2 188200 12.14 1.04 15.90 2 2 2 188201 12.63 1.06 16.41 2 2 2 188201 12.70 1.06 16.43 2 2 2 188202 11.47 1.06 16.46 2 2 2 188202 11.48 1.04 16.51 2 2 2 188203 11.28 1.08 16.64 2 2 2 188203 11.43 1.08 16.62 2 2 2 188204 10.37 1.07 16.47 2 2 2 188204 10.36 1.07 16.31 2 2 2 188205 9.50 1.05 16.53 2 2 2 188205 9.34 1.06 16.25 2 2 2 188206 9.46 1.06 16.35 2 2 2 188206 9.51 1.06 16.66 2 2 2 188207 9.50 1.06 17.04 2 2 2 188207 9.60 1.06 16.94 2 2 2 188208 9.42 1.07 16.76 2 2 2 188208 9.40 1.07 16.79 2 2 2 188209 9.16 1.07 16.51 2 2 2 188209 9.19 1.06 16.51 2 2 2 188210 9.14 1.07 16.82 2 2 2 188210 9.24 1.06 16.69 2 2 2 188211 9.80 1.10 17.41 2 2 2 188211 10.01 1.10 17.10 2 2 2 188212 9.08 1.07 16.21 2 2 2 188212 9.06 1.06 16.39 2 2 2 188213 8.76 1.04 15.92 2 2 2 188213 8.57 1.03 16.04 2 2 2 188214 8.68 1.04 15.77 2 2 2 188214 8.69 1.04 15.77 2 2 2 188215 8.67 1.04 16.10 2 2 2 188215 8.71 1.07 15.54 2 2 2 188216 8.47 1.02 15.75 2 2 2 188216 8.37 1.03 15.77 2 2 2 188217 8.80 1.00 14.66 2 2 2 188217 8.83 0.99 14.54 2 2 2 188218 5.97 0.66 8.41 2 2 2 188218 6.07 0.65 8.53 2 2 2 188219 10.39 0.98 14.56 2 2 2 188219 10.45 0.98 14.61 2 2 2 188220 10.31 0.97 14.56 2 2 2 188220 10.27 0.98 14.34 2 2 2 188221 10.80 0.98 14.77 2 2 2 188221 10.65 0.99 14.62 2 2 2 188222 12.57 1.01 15.43 2 2 2 188222 12.59 1.01 15.18 2 2 2 188223 11.56 1.02 15.72 2 2 2 188223 11.60 1.02 15.59 2 2 2 188224 12.69 1.05 15.97 2 2 2 188224 12.00 1.05 16.18 2 2 2 188225 12.17 1.07 16.18 2 2 2 188225 12.24 1.06 16.15 2 2 2 188226 11.90 1.07 16.59 2 2 2 188226 11.94 1.06 16.05 2 2 2 188227 11.16 1.08 16.64 2 2 2 188227 11.28 1.09 16.74 2 2 2 188228 11.02 1.08 16.59 2 2 2 188228 10.99 1.09 16.59 2 2 2 188229 9.96 1.07 16.50 2 2 2 188229 9.72 1.08 16.47 2 2 2 188230 9.85 1.08 16.48 2 2 2 188230 9.86 1.07 16.53 2 2 2 188231 9.78 1.07 17.01 2 2 2 188231 9.84 1.10 16.94 2 2 2 188232 10.02 1.11 17.09 2 2 2 188232 10.14 1.10 17.04 2 2 2 188233 9.40 1.07 16.66 2 2 2 188233 9.41 1.09 16.61 2 2 2 188234 9.45 1.10 17.05 2 2 2 188234 9.58 1.10 17.07 2 2 2 188235 9.63 1.09 16.74 2 2 2 188235 9.66 1.09 17.07 2 2 2 188236 8.98 1.07 16.31 2 2 2 188236 9.08 1.09 16.18 2 2 2 188237 9.01 1.08 16.24 2 2 2 188237 9.06 1.06 16.55 2 2 2 188238 8.99 1.05 16.09 2 2 2 188238 9.03 1.06 16.32 2 2 2 188239 8.34 1.04 15.71 2 2 2 188239 8.45 1.03 15.66 2 2 2 188240 8.15 1.03 15.28 2 2 2 188240 8.36 1.02 15.08 2 2 2 188241 7.82 0.98 13.67 2 2 2 188241 7.78 0.97 13.87 2 2 2 188242 1.67 0.45 6.72 2 2 2 188242 1.69 0.46 6.50 2 2 2 188243 11.08 0.93 14.28 2 2 2 188243 11.33 0.93 14.42 2 2 2 188244 10.69 0.95 14.49 2 2 2 188244 10.72 0.96 14.57 2 2 2 188245 13.23 1.00 15.39 2 2 2 188245 13.30 1.01 15.29 2 2 2 188246 14.07 1.04 15.97 2 2 2 188246 14.24 1.04 15.90 2 2 2 188247 14.45 1.04 16.14 2 2 2 188247 14.47 1.05 16.14 2 2 2 188248 14.08 1.06 16.23 2 2 2 188248 14.18 1.07 16.28 2 2 2 188249 13.54 1.06 16.01 2 2 2 188249 13.50 1.06 16.45 2 2 2 188250 12.77 1.06 16.50 2 2 2 188250 12.89 1.08 16.60 2 2 2 188251 12.10 1.07 16.23 2 2 2 188251 12.13 1.07 16.54 2 2 2 188252 11.27 1.06 16.74 2 2 2 188252 11.52 1.07 16.57 2 2 2 188253 10.54 1.07 16.54 2 2 2 188253 10.59 1.08 16.56 2 2 2 188254 9.89 1.08 16.32 2 2 2 188254 9.89 1.08 16.54 2 2 2 188255 9.78 1.08 16.75 2 2 2 188255 9.88 1.08 16.63 2 2 2 188256 10.09 1.08 16.88 2 2 2 188256 10.12 1.09 16.90 2 2 2 188257 10.14 1.11 17.00 2 2 2 188257 10.11 1.10 16.90 2 2 2 188258 10.09 1.10 16.94 2 2 2 188258 10.10 1.10 16.82 2 2 2 188259 10.00 1.11 17.13 2 2 2 188259 10.00 1.12 16.89 2 2 2 188260 10.02 1.13 17.38 2 2 2 188260 10.02 1.13 17.23 2 2 2 188261 9.26 1.10 16.91 2 2 2 188261 9.41 1.10 16.91 2 2 2 188262 8.93 1.09 16.23 2 2 2 188262 8.96 1.10 16.16 2 2 2 188263 9.20 1.11 16.20 2 2 2 188263 9.20 1.10 16.45 2 2 2 188264 8.02 1.05 15.06 2 2 2 188264 8.03 1.04 15.11 2 2 2 188265 7.95 1.15 14.52 2 2 2 188265 7.98 1.17 14.54 2 2 2 188266 0.00 0.58 6.79 2 2 2 188266 0.00 0.56 6.89 2 2 2 188267 12.41 1.01 15.24 2 2 2 188267 12.35 1.03 15.07 2 2 2 188268 12.43 1.02 15.04 2 2 2 188268 12.36 1.02 15.14 2 2 2 188269 14.53 1.06 15.55 2 2 2 188269 14.62 1.06 16.02 2 2 2 188270 15.46 1.09 16.40 2 2 2 188270 15.53 1.08 16.48 2 2 2 188271 14.98 1.09 16.28 2 2 2 188271 14.97 1.09 16.21 2 2 2 188272 14.08 1.08 16.25 2 2 2 188272 14.12 1.10 16.23 2 2 2 188273 13.29 1.10 16.86 2 2 2 188273 13.37 1.10 16.76 2 2 2 188274 12.48 1.09 16.49 2 2 2 188274 12.55 1.11 16.86 2 2 2 188275 11.63 1.09 16.59 2 2 2 188275 11.60 1.09 16.86 2 2 2 188276 10.87 1.09 16.66 2 2 2 188276 10.83 1.10 16.59 2 2 2 188277 9.97 1.08 16.46 2 2 2 188277 10.01 1.10 16.51 2 2 2 188278 9.93 1.08 16.53 2 2 2 188278 10.05 1.09 16.97 2 2 2 188279 10.05 1.10 17.07 2 2 2 188279 10.01 1.10 17.00 2 2 2 188280 10.03 1.11 16.82 2 2 2 188280 10.04 1.11 16.92 2 2 2 188281 9.93 1.11 16.85 2 2 2 188281 10.11 1.11 16.80 2 2 2 188282 10.16 1.12 17.48 2 2 2 188282 10.20 1.13 17.60 2 2 2 188283 10.13 1.11 17.01 2 2 2 188283 10.04 1.12 17.08 2 2 2 188284 9.97 1.12 17.47 2 2 2 188284 9.96 1.11 17.55 2 2 2 188285 9.20 1.08 16.81 2 2 2 188285 9.23 1.10 16.69 2 2 2 188286 8.12 1.03 15.32 2 2 2 188286 8.34 1.03 15.30 2 2 2 188287 8.01 1.01 15.00 2 2 2 188287 7.99 1.01 14.71 2 2 2 188288 7.50 0.95 13.68 2 2 2 188288 7.50 0.97 13.73 2 2 2 188291 11.61 1.01 14.95 2 2 2 188291 11.76 1.01 14.97 2 2 2 188292 12.75 1.03 15.41 2 2 2 188292 12.82 1.04 15.41 2 2 2 188293 14.20 1.04 16.01 2 2 2 188293 14.11 1.03 15.62 2 2 2 188294 15.45 1.08 16.21 2 2 2 188294 15.42 1.08 16.38 2 2 2 188295 14.96 1.09 16.30 2 2 2 188295 14.97 1.10 16.50 2 2 2 188296 14.01 1.08 16.33 2 2 2 188296 14.16 1.10 16.60 2 2 2 188297 13.06 1.08 16.62 2 2 2 188297 12.99 1.08 16.64 2 2 2 188298 12.22 1.10 16.64 2 2 2 188298 12.23 1.10 16.69 2 2 2 188299 11.05 1.09 16.69 2 2 2 188299 11.09 1.10 16.74 2 2 2 188300 9.82 1.08 16.37 2 2 2 188300 9.84 1.09 16.57 2 2 2 188301 9.47 1.08 16.41 2 2 2 188301 9.47 1.08 16.63 2 2 2 188302 9.62 1.10 16.51 2 2 2 188302 9.52 1.08 16.48 2 2 2 188303 9.61 1.08 16.66 2 2 2 188303 9.76 1.09 16.75 2 2 2 188304 9.75 1.09 17.00 2 2 2 188304 9.78 1.10 16.95 2 2 2 188305 9.77 1.11 17.14 2 2 2 188305 9.73 1.11 16.72 2 2 2 188306 9.97 1.11 16.92 2 2 2 188306 10.01 1.11 16.92 2 2 2 188307 10.06 1.11 16.99 2 2 2 188307 10.09 1.12 17.41 2 2 2 188308 10.11 1.14 17.67 2 2 2 188308 10.11 1.15 17.77 2 2 2 188309 10.14 1.12 17.72 2 2 2 188309 10.11 1.12 16.98 2 2 2 188310 8.81 1.07 16.08 2 2 2 188310 8.71 1.07 16.03 2 2 2 188311 7.80 1.00 14.53 2 2 2 188311 7.86 1.00 14.46 2 2 2 188312 7.81 1.00 14.41 2 2 2 188312 7.82 0.99 14.26 2 2 2 188313 6.24 0.94 13.13 2 2 2 188313 6.20 0.93 13.13 2 2 2 188315 11.09 1.01 14.57 2 2 2 188315 11.18 0.99 14.33 2 2 2 188316 11.02 0.99 14.67 2 2 2 188316 11.07 1.02 14.74 2 2 2 188317 12.07 1.02 15.30 2 2 2 188317 12.10 1.04 15.23 2 2 2 188318 14.20 1.06 16.03 2 2 2 188318 14.17 1.06 15.84 2 2 2 188319 14.32 1.07 16.06 2 2 2 188319 14.28 1.07 15.96 2 2 2 188320 14.30 1.07 15.96 2 2 2 188320 14.49 1.09 16.13 2 2 2 188321 14.07 1.09 16.52 2 2 2 188321 14.07 1.09 16.10 2 2 2 188322 13.40 1.09 16.57 2 2 2 188322 13.30 1.09 16.54 2 2 2 188323 12.63 1.09 16.39 2 2 2 188323 12.67 1.10 16.42 2 2 2 188324 11.94 1.08 16.37 2 2 2 188324 12.12 1.11 16.49 2 2 2 188325 11.23 1.10 16.71 2 2 2 188325 11.24 1.10 16.81 2 2 2 188326 10.32 1.09 16.61 2 2 2 188326 10.26 1.09 16.29 2 2 2 188327 10.22 1.09 16.75 2 2 2 188327 10.15 1.10 16.73 2 2 2 188328 10.33 1.09 16.50 2 2 2 188328 10.36 1.12 16.87 2 2 2 188329 10.32 1.12 17.12 2 2 2 188329 10.35 1.12 17.07 2 2 2 188330 10.27 1.11 16.82 2 2 2 188330 10.31 1.11 16.97 2 2 2 188331 10.14 1.11 16.92 2 2 2 188331 10.20 1.10 16.79 2 2 2 188332 9.97 1.12 17.28 2 2 2 188332 10.10 1.12 16.87 2 2 2 188333 9.96 1.13 17.38 2 2 2 188333 10.02 1.11 17.28 2 2 2 188334 9.37 1.08 16.42 2 2 2 188334 9.52 1.08 16.61 2 2 2 188335 8.60 1.03 15.31 2 2 2 188335 8.63 1.05 15.24 2 2 2 188336 8.40 1.04 15.21 2 2 2 188336 8.44 1.04 15.33 2 2 2 188337 8.65 1.02 14.23 2 2 2 188337 8.83 1.03 14.35 2 2 2 188338 0.52 0.31 2.54 2 2 2 188338 0.56 0.29 2.57 2 2 2 188339 11.14 0.92 14.41 2 2 2 188339 10.99 0.92 13.97 2 2 2 188340 10.69 0.91 14.41 2 2 2 188340 10.71 0.92 14.36 2 2 2 188341 10.32 0.92 14.52 2 2 2 188341 10.39 0.93 14.29 2 2 2 188342 11.25 0.94 14.91 2 2 2 188342 11.36 0.95 14.96 2 2 2 188343 12.00 0.98 15.52 2 2 2 188343 12.01 0.98 15.15 2 2 2 188344 12.40 1.00 15.70 2 2 2 188344 12.53 0.99 15.80 2 2 2 188345 11.88 0.99 16.07 2 2 2 188345 11.92 1.00 15.28 2 2 2 188346 11.45 1.00 15.86 2 2 2 188346 11.49 1.02 16.02 2 2 2 188347 11.38 1.04 16.13 2 2 2 188347 11.29 1.03 15.94 2 2 2 188348 10.87 1.06 16.07 2 2 2 188348 10.99 1.04 16.13 2 2 2 188349 9.96 1.06 16.13 2 2 2 188349 10.03 1.04 16.29 2 2 2 188350 9.57 1.05 15.95 2 2 2 188350 9.63 1.04 16.05 2 2 2 188351 9.62 1.06 16.03 2 2 2 188351 9.66 1.05 16.26 2 2 2 188352 9.41 1.05 16.16 2 2 2 188352 9.48 1.04 16.00 2 2 2 188353 9.22 1.05 15.93 2 2 2 188353 9.30 1.04 15.80 2 2 2 188354 9.26 1.04 16.06 2 2 2 188354 9.36 1.05 16.48 2 2 2 188355 9.13 1.02 16.06 2 2 2 188355 9.03 1.03 16.30 2 2 2 188356 8.93 1.04 15.88 2 2 2 188356 9.01 1.04 16.09 2 2 2 188357 8.94 1.04 16.38 2 2 2 188357 9.01 1.04 16.44 2 2 2 188358 8.89 1.02 16.28 2 2 2 188358 8.93 1.04 15.68 2 2 2 188359 8.25 1.02 15.73 2 2 2 188359 8.59 1.02 15.63 2 2 2 188360 8.33 1.01 15.47 2 2 2 188360 8.36 1.00 15.37 2 2 2 188361 7.93 0.97 14.53 2 2 2 188361 8.03 0.98 14.61 2 2 2 188362 0.00 0.16 0.00 2 2 2 188362 0.00 0.14 0.16 2 2 3 188363 10.28 0.94 14.30 2 2 2 188363 10.24 0.94 14.51 2 2 2 188364 10.17 0.94 14.57 2 2 2 188364 10.33 0.94 14.54 2 2 2 188365 10.60 0.97 14.52 2 2 2 188365 10.63 0.96 14.70 2 2 2 188366 11.47 0.98 15.07 2 2 2 188366 11.48 1.00 15.38 2 2 2 188367 11.34 1.01 15.25 2 2 2 188367 11.56 1.02 15.44 2 2 2 188368 11.35 1.02 15.80 2 2 2 188368 11.36 1.03 15.67 2 2 2 188369 10.61 1.03 15.60 2 2 2 188369 10.68 1.03 15.78 2 2 2 188370 10.34 1.04 16.04 2 2 2 188370 10.41 1.03 15.81 2 2 2 188371 9.79 1.02 16.18 2 2 2 188371 9.79 1.03 16.15 2 2 2 188372 9.52 1.04 16.16 2 2 2 188372 9.56 1.04 15.94 2 2 2 188373 9.35 1.03 16.37 2 2 2 188373 9.45 1.05 16.47 2 2 2 188374 9.44 1.06 16.13 2 2 2 188374 9.59 1.06 16.24 2 2 2 188375 9.16 1.04 16.11 2 2 2 188375 9.23 1.05 15.90 2 2 2 188376 8.93 1.04 16.21 2 2 2 188376 9.05 1.05 16.06 2 2 2 188377 9.20 1.05 16.27 2 2 2 188377 9.33 1.06 16.24 2 2 2 188378 9.16 1.05 16.48 2 2 2 188378 9.18 1.06 16.43 2 2 2 188379 8.66 1.02 15.57 2 2 2 188379 8.41 0.99 15.54 2 2 2 188380 8.81 1.04 16.02 2 2 2 188380 8.85 1.04 15.78 2 2 2 188381 8.61 1.03 15.91 2 2 2 188381 8.63 1.04 15.83 2 2 2 188382 8.46 1.03 15.36 2 2 2 188382 8.56 1.03 15.36 2 2 2 188383 7.94 0.98 14.92 2 2 2 188383 8.01 0.99 14.76 2 2 2 188384 6.95 0.83 11.22 2 2 2 188384 7.03 0.84 11.04 2 2 2 188387 11.16 1.01 15.55 2 2 2 188387 11.20 1.01 15.03 2 2 2 188388 11.12 1.02 15.53 2 2 2 188388 11.27 1.01 15.47 2 2 2 188389 11.10 1.02 15.29 2 2 2 188389 11.01 1.01 15.22 2 2 2 188390 11.03 1.02 15.59 2 2 2 188390 11.03 1.02 15.30 2 2 2 188391 11.24 1.04 16.01 2 2 2 188391 11.24 1.03 15.90 2 2 2 188392 10.77 1.03 15.69 2 2 2 188392 10.81 1.04 15.90 2 2 2 188393 10.22 1.04 16.33 2 2 2 188393 10.26 1.04 16.43 2 2 2 188394 9.72 1.05 16.04 2 2 2 188394 9.76 1.04 16.17 2 2 2 188395 9.26 1.04 16.44 2 2 2 188395 9.40 1.05 16.57 2 2 2 188396 9.42 1.06 16.70 2 2 2 188396 9.47 1.06 16.33 2 2 2 188397 9.66 1.06 16.21 2 2 2 188397 9.75 1.06 16.34 2 2 2 188398 9.48 1.05 16.79 2 2 2 188398 9.62 1.05 16.10 2 2 2 188399 9.37 1.05 16.34 2 2 2 188399 9.25 1.05 16.42 2 2 2 188400 9.08 1.04 16.16 2 2 2 188400 9.07 1.04 16.29 2 2 2 188401 8.70 1.04 15.90 2 2 2 188401 8.71 1.03 16.16 2 2 2 188402 8.63 1.02 15.48 2 2 2 188402 8.70 1.04 15.58 2 2 2 188403 8.59 1.02 16.01 2 2 2 188403 8.51 1.04 15.90 2 2 2 188404 8.64 1.05 15.93 2 2 2 188404 8.76 1.04 15.90 2 2 2 188405 8.55 1.01 15.70 2 2 2 188405 8.66 1.01 15.28 2 2 2 188406 8.38 1.00 15.33 2 2 2 188406 8.48 1.00 15.73 2 2 2 188407 8.24 0.96 13.86 2 2 2 188407 8.21 0.96 13.65 2 2 2 188408 0.71 0.29 1.89 2 2 3 188408 0.64 0.25 1.58 2 2 2 188419 9.85 1.05 16.02 2 2 2 188419 10.03 1.06 16.13 2 2 2 188420 9.83 1.05 16.31 2 2 2 188420 9.93 1.06 16.18 2 2 2 188421 9.75 1.07 16.29 2 2 2 188421 9.63 1.07 16.52 2 2 2 188423 9.45 1.06 16.13 2 2 2 188423 9.58 1.06 16.16 2 2 2 188424 9.41 1.05 16.16 2 2 2 188424 9.50 1.05 16.14 2 2 2 188425 9.11 1.04 15.98 2 2 2 188425 9.13 1.05 15.82 2 2 2 188426 8.90 1.04 15.53 2 2 2 188426 8.87 1.04 15.53 2 2 2 188427 8.79 1.02 15.30 2 2 2 188427 8.69 1.04 15.11 2 2 2 188428 8.61 1.02 14.98 2 2 2 188428 8.68 1.03 15.11 2 2 2 188429 8.53 1.01 14.70 2 2 2 188429 8.64 1.01 14.62 2 2 2 188430 7.34 0.92 11.47 2 2 2 188430 7.27 0.91 11.42 2 2 2 188431 0.46 0.17 0.00 2 2 2 188431 0.49 0.19 0.00 2 2 2 188435 9.77 1.05 15.01 2 2 2 188435 9.79 1.06 15.43 2 2 2 188436 9.54 1.07 15.72 2 2 2 188436 9.58 1.06 15.80 2 2 2 188438 8.88 1.05 15.04 2 2 2 188438 8.57 1.03 15.52 2 2 2 188439 8.68 1.05 15.12 2 2 2 188439 8.68 1.05 15.09 2 2 2 188440 8.57 1.04 14.88 2 2 2 188440 8.63 1.04 14.94 2 2 2 188441 8.58 1.03 15.15 2 2 2 188441 8.62 1.03 15.12 2 2 2 188442 8.67 1.04 14.91 2 2 2 188442 8.70 1.03 14.65 2 2 2 188443 8.69 1.00 14.64 2 2 2 188443 8.74 1.00 14.64 2 2 2 188444 8.51 1.01 13.84 2 2 2 188444 8.50 1.00 14.27 2 2 2 188450 6.88 0.84 10.02 2 2 2 188450 6.92 0.85 9.96 2 2 2 188455 0.48 0.19 0.00 2 2 2 188455 0.41 0.18 0.00 2 2 2 188457 10.22 1.06 15.10 2 2 2 188457 10.22 1.05 15.16 2 2 2 188457 8.89 1.04 15.35 2 2 2 188457 8.91 1.04 15.17 2 2 2 188458 9.72 1.05 14.68 2 2 2 188458 9.72 1.04 14.89 2 2 2 188459 9.89 1.01 14.26 2 2 2 188459 9.93 1.01 14.23 2 2 2 188460 10.14 0.98 12.61 2 2 2 188460 10.17 0.98 12.55 2 2 2 188461 9.63 0.95 10.53 2 2 2 188461 9.67 0.98 10.27 2 2 2 188467 11.34 1.02 9.10 2 2 2 188467 11.46 1.03 9.49 2 2 2 188473 1.18 0.57 1.48 2 2 2 188473 1.18 0.57 1.36 2 2 2 188474 13.10 1.11 14.93 2 2 2 188474 12.91 1.09 14.71 2 2 2 188475 11.31 1.07 14.24 2 2 2 188475 11.35 1.07 14.43 2 2 2 188476 9.81 1.00 13.19 2 2 2 188476 9.91 1.01 13.19 2 2 2 188477 10.90 1.01 10.20 2 2 2 188477 10.71 0.99 10.51 2 2 2 188482 10.08 0.97 8.71 2 2 2 188482 10.12 0.98 8.76 2 2 2 188488 14.61 1.40 20.11 2 2 2 188488 14.75 1.38 20.08 2 2 2 188490 14.07 1.09 15.12 2 2 2 188490 14.10 1.08 15.36 2 2 2 188491 14.36 1.09 15.16 2 2 2 188491 14.29 1.08 15.16 2 2 2 188492 12.70 1.13 14.16 2 2 2 188492 12.47 1.04 14.33 2 2 2 188493 11.41 1.01 11.54 2 2 2 188493 11.55 1.01 11.45 2 2 2 188498 5.19 0.76 5.73 2 2 3 188498 5.41 0.77 4.81 2 2 3 188507 2.51 0.45 0.00 2 2 2 188507 1.81 0.42 0.00 2 2 2 188509 10.91 1.02 13.38 2 2 2 188509 10.94 0.99 13.59 2 2 2 188510 11.03 0.97 11.70 2 2 2 188510 11.16 0.99 11.68 2 2 2 188515 11.48 0.99 8.54 2 2 2 188515 11.52 0.98 8.32 2 2 2 188521 0.83 0.38 0.00 2 2 2 188521 0.75 0.38 0.00 2 2 2 5. Dissolved Inorganic Carbon in Seawater (Bob Gershey) a. Description of Equipment and Technique The total dissolved inorganic carbon content of seawater is defined as the total concentration of carbonate ion, bicarbonate ion and unionized species of carbon dioxide. Before analysis, the sample is treated with acid to convert all ionized species to the unionized form, which is then separated from the liquid phase and subsequently measured using a coulometric titration technique. This involves the reaction of carbon dioxide gas with a dimethylsulfoxide solution of ethanolamine to produce hydroxyethylcarbamic acid. The acidic solution is titrated with hydroxide ion formed by the electrolytic decomposition of water. The progress of the titration is followed through colorimetric measurement of the absorbance of a pH indicator dye (thymolphthalein) in the ethanolamine solution. A known volume of seawater is dispensed into a stripping chamber from a pipet of known volume and temperature controlled to within 0.4 °C. It is then acidified with ten percent its volume of a 10% solution of carbon dioxide-free phosphoric acid. The solution in stripped of carbon dioxide gas by bubbling with a stream of nitrogen gas directed through a glass frit. The carrier gas exiting the stripper passes through a magnesium perchlorate trap to remove water vapour and acidic water droplets. The gas stream is then directed into the coulometric titrator where the total amount of carbon dioxide gas is quantified. b. Sampling Procedure and Data Processing Technique Samples are drawn from the rosette immediately following the drawing of the oxygen samples in order to minimize exchange of carbon dioxide gas with the head space in the sampler. This exchange will typically result in a loss of carbon dioxide. It is desirable that the samples be drawn before half the sampler is emptied and within ten minutes of recovery. Clean borosilicate glass bottles are rinsed twice with 30 - 50 ml of the sample. The bottle is then filled from the bottom using a length of vinyl tubing attached to the spigot of the sampler. The sample is overflowed by at least a half of the volume of the bottle (typically 250 ml). A head space of 1% is left to allow for expansion without leakage. If samples are not to be analyzed within four to five hours, the sample is poisoned with 100 (l/250 ml of 50% saturated mercuric chloride solution. The bottle is tightly sealed and stored preferably at the temperature of collection in the dark. Theoretically, the coulometer should give a direct measurement of the amount of carbon titrated based on calculations using the Nernst equation. In practice, the coulometer's calibration is checked using Certified Reference Materials obtained from the Scripps Institute of Oceanography, LaJolla, California. These samples are treated in the same manner as a seawater sample. Values are reported in units of µmol/kg. The overall precision of the analysis should be at least 1.5 µmol/kg for samples with concentrations in the range of 1800-2300 µmol/kg. c. Replicate Analysis The precision of this data was estimated as 4.2 µmol/kg. In total, 216 replicate carbonate measurements were obtained for 107 sample id numbers: 105 sample id numbers had one replicate and 2 sample id numbers had three replicates. The following is a statistical summary of the absolute value of the replicate differences; only acceptable values were used in calculating the statistics. Table C.5 lists all replicate measurements. Number of Replicate Differences = 2 id had two replicates * 3 possible Differences + 105 ids had one replicate * 1 possible difference = 6 + 105 = 111 Statistic Value ----------------------------------- Number of Acceptable Replicate Differences 102 Minimum (µmoles/kg) 0.0 Maximum (µmoles/kg) 9.2 Mean (µmoles/kg) 1.6 Median (µmoles/kg) 1.2 Standard Deviation (µmoles/kg) 1.6 Table C.5 Replicate water sample total carbon values in µmoles/kg. Sample ID Total WOCE Number Carbon QF --------------------------------------- 186220 2139.9 2 186220 2139.9 2 186230 2106.1 2 186230 2106.6 2 186248 2131.9 2 186248 2133.9 2 186266 2138.4 2 186266 2139.2 2 186298 2148.2 2 186298 2148.7 2 186322 2151.1 2 186322 2152.6 2 186343 2148.2 2 186343 2148.5 2 186373 2146.6 2 186373 2126.0 3 186382 2154.4 2 186382 2155.2 2 186387 954.6 4 186387 2150.6 2 186406 2152.6 2 186406 2152.8 2 186446 2146.9 2 186446 2147.9 2 186461 2150.7 2 186461 2152.7 2 186495 2157.0 2 186495 2157.0 2 186537 2104.1 2 186537 2104.1 2 186582 2155.1 2 186582 2156.4 2 186611 2150.3 2 186611 2152.3 2 186662 2150.7 2 186662 2151.5 2 186691 2157.2 2 186691 2160.4 2 186722 2150.4 2 186722 2153.2 2 186722 2149.5 3 186729 2151.2 2 186729 2148.6 2 186750 2150.5 2 186750 2153.0 2 186777 2148.3 2 186777 2149.5 2 186802 2152.9 2 186802 2155.9 2 186823 27.8 4 186823 134.7 4 186844 2152.6 2 186844 2154.4 2 186852 2124.8 2 186852 2129.0 2 186859 2114.9 2 186859 2117.2 2 186866 2021.2 3 186866 2021.4 3 186874 2148.8 2 186874 2150.8 2 186903 2150.7 2 186903 2154.8 2 186933 2151.4 2 186933 2153.5 2 186941 2129.4 2 186941 2124.4 2 186956 2152.4 2 186956 2154.8 2 186968 2154.3 2 186968 2154.9 2 187007 2153.7 2 187007 2156.9 2 187037 2151.9 2 187037 2156.1 2 187039 2148.6 2 187039 2156.8 2 187040 2148.2 2 187040 2149.0 2 187055 408.7 4 187055 265.8 4 187061 2154.0 2 187061 2150.6 2 187068 153.0 3 187068 170.7 3 187093 2150.0 2 187093 2156.4 2 187117 2159.5 2 187117 2160.8 2 187170 2152.9 2 187170 2153.2 2 187205 2154.0 2 187205 2156.5 2 187220 2150.3 2 187220 2151.9 2 187234 2155.0 2 187234 2151.3 2 187280 2151.5 2 187280 2152.3 2 187307 2151.7 2 187307 2153.1 2 187336 2152.1 2 187336 2153.1 2 187360 2150.5 2 187360 2153.0 2 187404 2149.9 2 187404 2150.4 2 187414 2143.2 2 187414 2142.5 2 187434 2136.2 2 187434 2136.5 2 187448 2119.0 2 187448 2120.7 2 187459 2130.1 2 187459 2130.5 2 187470 2110.1 2 187470 2110.4 2 187486 2152.4 2 187486 2153.5 2 187514 2152.8 2 187514 2149.5 2 187529 2152.0 2 187529 2154.3 2 187561 2149.3 2 187561 2150.6 2 187579 2150.9 2 187579 2152.1 2 187636 2151.8 2 187636 2153.7 2 187667 2149.4 2 187667 2150.7 2 187688 2156.7 2 187688 2156.8 2 187699 2151.8 2 187699 2150.6 2 187708 2154.0 2 187708 2153.5 2 187734 2154.9 2 187734 2155.2 2 187762 2151.7 2 187762 2151.9 2 187807 2153.4 2 187807 2154.1 2 187829 2151.9 2 187829 2153.2 2 187855 2150.1 2 187855 2155.9 2 187872 2040.2 2 187872 2042.5 2 187886 2041.6 2 187886 2040.8 2 187893 2084.5 2 187893 2085.8 2 187910 2153.2 2 187910 2154.2 2 187929 2154.7 2 187929 2154.8 2 187943 2154.8 2 187943 2155.2 2 187968 2153.8 2 187968 2153.9 2 187993 2153.9 2 187993 2154.7 2 188015 2154.5 2 188015 2156.0 2 188040 2153.1 2 188040 2154.4 2 188065 2153.1 2 188065 2155.7 2 188092 2154.1 2 188092 2154.6 2 188113 2154.8 2 188113 2155.9 2 188142 2155.5 2 188142 2154.3 2 188154 2149.5 2 188154 2150.2 2 188179 2151.9 2 188179 2152.7 2 188182 2150.1 2 188182 2151.4 2 188197 2154.2 2 188197 2154.3 2 188222 2153.3 2 188222 2154.0 2 188250 2154.6 2 188250 2155.2 2 188269 2157.9 2 188269 2157.2 2 188292 2157.5 2 188292 2155.5 2 188323 2151.2 2 188323 2152.4 2 188345 2151.0 2 188345 2151.6 2 188345 2152.0 2 188363 2149.8 2 188363 2153.1 2 188389 2145.6 2 188389 2154.8 2 188391 2157.2 2 188391 2154.5 2 188425 2140.2 2 188425 2164.2 3 188439 2150.6 2 188439 2150.7 2 188460 2136.3 2 188460 2137.2 2 188475 2148.5 2 188475 2149.0 2 188491 2155.7 2 188491 2158.1 2 188498 2098.5 2 188498 2100.2 2 188515 2131.4 2 188515 2130.3 2 6. Alkalinity (Bob Gershey) a. Description of Equipment and Technique The total alkalinity of seawater is defined as the number of moles of hydrogen ion equivalent to the excess of proton acceptors (bases formed from weak acids with dissociation constants of less than K=10-4.5) over proton donors (acids with K>10-4.5) in a one kilogram sample. An automated potentiometric titration system is used to determine this quantity. During the course of the titration the pH is measured using a Ross combination electrode standardized using a Hansson seawater buffer. A known volume (~25ml) of sample is measured in a calibrated, thermostated pipette and dispensed in to an open cup. The alkalinity of the sample is estimated from its salinity and acid equivalent to 0.7 of this amount is added and the pH measured. A further three aliquots of acids are added to bring the titration to 90% completion. The Gran Function F3 (Stumm and Morgan) is then applied to these points to obtain a more refined estimate of the alkalinity. Five additional aliquots are then added to complete the titration. b. Sampling Procedure and Data Processing Technique Samples are collected using the same procedure as for Dissolved Inorganic Carbon (see Section 5b). The pH values for the last five points of the titration are used to evaluate the Gran Function F1 from which the final estimate of the equivalence point is obtained. Hydrochloric acid used in the titrations is calibrated is two ways: against a standard solution of sodium borate using an acid base titration and against potassium iodate using an iodometric titration with sodium thiosulphate. In addition, the calibration is checked using Certified Reference Materials obtained from the Scripps Institute of Oceanography, LaJolla, California. Values are reported in units of µmol/kg. The overall precision of the analysis is 1.5 µmol/kg for samples with concentrations in the range of 1900-2400 µmol/kg. c. Replicate Analysis The precision of the alkalinity data was 9.5 µmol/kg. The alkalinity replicates consisted of 93 duplicate measurements, 1 triplicate measurement and 1 quadruplicate measurement. A statistical summary of the absolute value of the replicate differences is given below. Only acceptable sample values were used when calculating replicate differences. All replicates and their quality flags are given in Table C.6. Statistic Value ----------------------------------- Number of Acceptable Replicate Differences 79 Minimum (µmoles/kg) 0.1 Maximum (µmoles/kg) 13.1 Mean (µmoles/kg) 2.7 Median (µmoles/kg) 1.8 Standard Deviation (µmoles/kg) 2.6 Sample ID Total WOCE Number Alkalinity QF ----------------------------------------- 186219 2267.8 3 186219 2264.4 2 186224 2213.2 2 186224 2214.5 2 186238 2298.0 2 186238 1008138 4 186239 2276.7 2 186239 2278.2 2 186254 2232.8 2 186254 2235.2 2 186267 2265.5 2 186267 2258.6 2 186297 2275.1 2 186297 2277.0 2 186301 2280.8 2 186301 1008138 4 186315 2279.3 2 186315 2281.6 2 186321 2271.5 3 186321 2284.1 2 186330 2265.7 2 186330 2299.5 3 186344 2274.6 2 186344 2271.2 2 186370 2294.7 2 186370 2293.2 2 186407 2294.4 2 186407 2294.5 2 186440 2297.2 2 186440 2298.6 2 186474 2297.0 2 186474 2304.7 2 186494 2298.0 2 186494 2300.9 2 186521 2297.0 2 186521 2296.6 2 186545 2293.5 2 186545 2296.2 2 186580 2303.3 2 186580 2305.4 2 186596 2284.6 2 186596 2288.1 2 186617 2079.3 2 186617 1008138 4 186618 2279.9 2 186618 2280.1 2 186630 2293.3 2 186630 2290.3 2 186637 2287.9 2 186637 2286.3 2 186672 2278.9 2 186672 1008138 4 186692 2298.7 2 186692 2301.2 2 186695 2280.6 3 186695 2293.2 2 186728 2285.0 2 186728 2285.1 2 186759 2285.7 2 186759 2283.1 2 186778 2295.8 2 186778 2295.8 2 186821 2223.7 2 186821 2225.0 2 186823 2214.3 2 186823 2214.3 3 186843 2286.6 2 186843 2287.1 2 186859 2287.7 3 186859 2263.9 2 186859 2264.6 2 186859 2284.1 3 186873 2369.2 3 186873 2288.8 2 186902 2285.4 2 186902 2319.3 3 186914 2290.1 2 186914 2290.8 2 186927 2296.8 2 186927 2300.2 2 186946 2296.6 2 186946 2299.9 2 186967 2300.0 2 186967 2291.0 2 187006 2295.7 2 187006 2348.5 3 187036 2291.6 2 187036 2292.0 2 187070 2289.4 2 187070 2290.4 2 187103 2292.1 2 187103 2294.1 2 187118 2302.8 3 187118 2307.3 3 187183 2287.1 2 187183 2284.6 2 187204 2290.9 2 187204 2304.0 2 187237 2288.2 2 187237 2291.0 2 187244 2287.1 2 187244 2288.4 2 187272 2292.1 2 187272 2293.6 2 187306 2290.3 2 187306 2300.2 2 187332 2288.4 2 187332 2286.7 2 187362 2282.7 2 187362 2284.4 2 187378 2278.6 2 187378 2281.8 2 187402 2280.3 2 187402 2283.7 2 187415 2269.9 2 187415 2271.6 2 187436 2221.5 2 187436 2222.7 2 187441 2223.6 2 187441 2218.7 2 187453 2248.1 2 187453 2247.0 2 187469 2270.9 2 187469 2277.1 2 187485 2285.2 2 187485 2286.3 2 187487 2227.8 3 187487 2290.5 2 187513 2288.9 2 187513 2356.5 3 187521 2290.4 2 187521 2289.2 2 187530 2291.6 2 187530 2291.7 2 187550 2290.1 2 187550 2291.0 2 187576 2290.6 2 187576 2291.8 2 187597 2290.9 2 187597 2296.5 2 187637 2285.7 2 187637 2292.1 2 187653 2291.3 2 187653 2286.6 2 187661 2294.4 2 187661 2290.3 2 187693 2289.9 2 187693 2290.5 2 187707 2300.7 2 187707 2316.1 3 187733 2298.5 2 187733 2299.1 2 188141 2305.9 2 188141 2306.6 2 188158 2294.5 2 188158 2290.3 2 188176 2298.6 2 188176 2300.3 2 188180 2291.8 2 188180 2294.1 2 188196 2297.1 2 188196 2299.0 2 188225 2300.2 2 188225 2300.9 2 188243 2297.2 2 188243 2298.7 2 188272 2313.0 2 188272 2306.5 2 188291 2304.8 2 188291 2315.3 3 188324 2305.8 2 188324 2306.4 2 188326 2301.2 2 188326 2302.1 2 188342 2301.7 2 188342 2306.5 2 188365 2302.1 2 188365 2304.3 2 188387 2298.8 2 188387 2297.0 2 188391 2306.4 2 188391 2298.7 2 188391 2300.5 2 188423 2290.7 2 188423 2291.7 2 188444 2279.7 2 188444 2284.2 2 188457 2274.9 2 188457 2283.7 2 188482 2224.1 2 188482 2224.8 2 188509 1008138 4 188509 2268.9 2 7. Halocarbons (Michael Hingston) a. Description of Equipment and Technique The suite of halocarbon compounds analyzed included the chlorofluorocarbons CFC- 12, CFC-11, CFC-113 and the halocarbons carbon tetrachloride and methyl chloroform. The analyses were carried out on two purge and trap systems developed at the Bedford Institute of Oceanography. The water samples were injected into the systems directly from the syringes used to collect the samples. A minimum of two volumes of water were used to rinse the sample pipette. The samples were purged for four minutes with ultra high purity nitrogen at a flow rate of 80 ml/min. The components were trapped in Porapak-N trap which was cooled to a temperature of less than 10°C. They were then desorbed by heating the trap up to 170°C. The contents of the trap were then passed through a 75m DB-624 megabore column. The resolved components exiting the column were quantified using electron capture detection. b. Sampling Procedure and Data Processing Technique Samples are collected directly from the rosette using 100 ml syringes to avoid contact of the sample with the atmosphere. The syringes are rinsed three times before they are filled. To prevent contamination, the CFC samples are the first samples which are collected from the bottles. The samples are then stored in a water bath of continuously flowing surface sea water until analysis. Air samples are taken in the winch room at the start of the cruise to ensure that it is not contaminated. The analysis of the samples is always completed within 24 hours after they have been drawn. Duplicates are taken at each station, with some of these being run on each system to ensure that the results are comparable. Chromatograms are analyzed using a commercial software package. Concentrations of the various components are evaluated from baseline-corrected peak areas. Calibration is carried out using working gas standards made up at Brookhaven National Laboratories. These standards have been calibrated in turn against a standard air sample ALM-64975 provided by CMDL/NOAA, Boulder Colorado. Standard volumes are corrected for lab temperature and pressure. Results are reported in units of pmol/kg of sea water. Clean air samples are also analyzed with each station, as a check on the standardization. c. Replicate analysis A total of 6 unique sample id numbers had duplicate CFC water samples drawn and a total of 81 unique sample id numbers had triplicate CFC water samples drawn. Replicates were taken at most stations, with some of these being run on each system to ensure that the results were comparable. A statistical summary of the absolute value of the replicate differences is below. Only acceptable sample values were used when calculating replicate differences. All replicates and their quality flags are given in Table C.7. Statistic CFC11 CFC12 CFC113 Carbon Tet. Methyl Chl. ------------------------------------------------------------------------------- Number of Acceptable Replicate Differences 225 226 91 156 33 Minimum (pmoles/kg) 0.000 0.000 0.000 0.000 0.010 Maximum (pmoles/kg) 0.681 0.749 0.185 1.421 13.902 Mean (pmoles/kg) 0.087 0.090 0.024 0.171 1.974 Median (pmoles/kg) 0.058 0.068 0.010 0.126 1.002 Standard Deviation (pmoles/kg) 0.105 0.090 0.035 0.195 2.782 Detection Limits (pmoles/kg) 0.15 0.10 0.12 0.30 0.13 Sample ID Freon Freon Freon Carbon Methyl WOCE Number 11 12 113 Tet. Chl. QF ------------------------------------------------------------------- 186225 5.990 3.140 1007.760 2 2 5 5 4 186225 5.911 3.077 0.312 8.394 780.578 2 2 2 2 4 186225 5.804 2.980 0.292 8.559 686.619 2 2 2 2 4 186245 5.129 2.579 0.311 7.475 743.850 2 2 2 2 4 186245 4.662 2.667 0.341 7.475 27.252 2 2 2 2 2 186245 5.100 2.820 7.740 534.840 2 2 5 2 4 186263 4.379 2.326 0.341 6.432 108.585 2 2 2 2 4 186263 4.389 2.326 0.292 6.432 171.834 2 2 2 2 4 186263 4.427 2.277 0.350 6.578 119.172 2 2 2 2 4 186303 4.106 2.218 0.234 7.074 77.451 2 2 2 3 4 186303 4.126 2.296 0.214 6.928 52.581 2 2 2 2 4 186303 4.116 2.189 0.156 5.838 230.952 2 2 2 3 3 186320 3.425 1.761 0.175 5.877 26.698 2 2 2 2 3 186320 3.464 1.781 0.224 5.877 93.472 2 2 2 2 3 186320 3.396 1.810 0.292 5.877 49.582 2 2 2 2 3 186347 4.213 2.238 0.253 6.869 55.160 2 2 3 2 4 186347 4.194 2.257 0.214 6.869 1179.989 2 2 2 2 3 186347 4.390 2.420 0.260 7.060 2 2 3 2 5 186372 4.270 2.240 307.930 2 2 5 5 4 186372 4.135 2.228 0.214 6.655 159.487 2 2 2 2 3 186372 4.190 2.460 0.000 2 2 5 5 4 186395 3.510 1.880 5.980 32.630 2 2 5 2 2 186395 3.410 6.060 0.000 2 5 5 2 4 186395 3.405 1.751 0.175 5.819 272.634 2 2 3 2 4 186433 1.673 1.099 0.117 3.794 0.000 2 2 3 2 3 186433 1.790 0.866 0.146 3.804 24.575 2 2 3 2 2 186433 1.800 0.953 0.136 3.784 22.328 2 2 3 2 3 186465 3.259 1.605 0.234 4.807 42.208 2 2 2 2 4 186465 3.289 1.742 0.146 4.865 0.000 2 2 3 2 4 186465 3.308 1.800 0.263 4.466 0.000 2 2 2 3 4 186500 3.026 1.537 0.126 4.943 142.198 2 2 3 2 3 186500 3.060 1.510 6.020 805.440 2 2 5 3 3 186500 3.016 1.411 0.117 4.913 0.000 2 2 3 2 3 186524 2.958 1.605 0.272 4.777 0.000 2 2 3 2 3 186524 2.977 1.605 0.146 4.680 0.000 2 2 2 2 3 186524 2.977 1.528 0.185 4.729 540.818 2 2 2 2 4 186541 1.703 0.827 0.000 3.405 128.564 2 2 2 2 3 186541 1.703 0.827 0.000 3.405 128.564 2 2 2 2 3 186542 1.508 0.700 0.000 3.172 8.911 2 2 2 2 3 186542 1.508 0.700 0.000 3.172 8.911 2 2 2 2 3 186543 1.518 0.720 0.000 2.909 84.436 2 2 2 2 3 186543 1.518 0.720 0.000 2.909 84.436 2 2 2 2 3 186553 3.114 1.567 0.204 5.196 98.009 2 2 2 2 3 186553 3.114 1.596 0.195 5.575 89.446 2 2 2 2 3 186553 3.160 1.680 5.530 -1.000 2 2 5 2 4 186599 4.590 2.680 8.010 -1.000 2 2 5 2 4 186599 4.457 2.482 0.311 7.815 13.158 2 2 2 2 3 186599 4.660 2.610 8.050 -1.000 2 2 5 2 4 186607 1.557 0.808 0.000 3.113 0.000 2 2 2 2 3 186607 1.469 0.671 0.000 3.152 -0.973 2 2 2 2 3 186607 1.498 0.720 0.000 3.191 44.442 2 2 2 2 4 186629 1.510 0.780 3.120 0.000 2 2 5 2 3 186629 1.470 0.800 3.310 12.720 2 2 5 2 2 186629 1.508 0.905 0.000 2.753 35.179 2 2 2 3 3 186660 3.629 1.761 0.243 6.120 56.948 2 2 2 3 3 186660 3.668 1.771 0.243 5.935 99.729 2 2 2 3 4 186660 3.760 1.940 6.200 21.680 2 2 5 3 3 186710 5.167 2.696 0.341 8.894 160.193 2 2 2 3 4 186710 5.187 2.803 0.311 7.551 -0.973 2 2 2 3 4 186710 5.157 2.900 0.360 6.987 0.000 2 2 2 3 3 186722 3.804 1.995 0.214 5.059 116.776 2 2 2 2 4 186722 3.688 1.790 0.292 5.176 -0.973 2 2 2 2 4 186722 3.824 1.917 0.243 5.526 80.367 2 2 2 3 3 186751 3.619 2.150 0.224 5.351 645.419 2 2 2 3 3 186751 3.551 2.072 0.204 4.690 0.000 2 2 2 3 3 186751 3.600 1.888 0.243 5.848 245.270 2 2 2 3 3 186785 5.150 5 5 5 2 5 186785 3.830 2.090 5.150 -1.000 2 2 5 2 4 186785 3.911 2.199 0.204 5.439 69.587 2 2 2 2 3 186810 295.820 5 5 5 5 4 186810 3.892 2.102 0.311 4.894 -0.973 2 2 2 3 4 186810 4.070 2.300 4.630 -1.000 2 2 5 3 4 186825 6.623 3.165 0.214 8.269 323.855 2 2 2 2 3 186825 6.450 3.400 8.340 0.000 2 2 5 2 3 186825 6.555 3.311 0.263 7.986 94.404 2 2 2 2 3 186850 4.282 1.761 0.165 5.479 310.336 2 2 2 3 3 186850 4.438 2.287 0.165 6.559 299.466 2 2 2 3 3 186850 4.380 2.510 7.090 0.000 2 2 5 2 3 186861 5.100 2.657 0.311 6.862 0.000 2 2 2 2 3 186861 5.159 2.657 0.302 6.960 187.226 2 2 2 2 4 186861 5.188 2.813 0.311 7.057 0.000 2 2 2 2 3 186881 4.408 2.258 0.282 5.625 211.338 2 2 2 2 4 186881 4.068 2.413 0.321 5.625 -0.973 2 2 2 2 4 186881 4.510 2.560 9.600 0.000 2 2 5 3 3 186909 3.512 1.722 0.195 4.612 331.187 2 2 2 3 3 186909 3.600 1.730 4.880 0.000 2 2 5 3 3 186909 3.454 1.703 0.195 4.884 1118.867 2 2 2 2 3 186930 2.960 1.570 4.370 -1.000 2 2 5 2 4 186930 3.090 4.240 1250.590 2 5 5 2 4 186930 2.870 1.540 4.200 -1.000 2 2 5 2 4 186949 1.839 0.905 0.175 2.899 0.000 2 2 3 2 3 186949 1.868 0.924 0.000 2.899 62.168 2 2 2 2 3 186949 1.907 0.963 0.000 2.899 45.794 2 2 2 2 3 186971 2.630 1.250 4.260 145.480 2 2 5 2 4 186971 2.640 1.370 4.460 0.000 2 2 5 2 3 186971 2.680 4.260 -1.000 2 5 5 2 4 187012 2.773 1.352 0.000 5.040 57.032 2 2 2 3 3 187012 2.714 1.411 0.000 3.717 57.032 2 2 2 2 3 187012 2.530 1.304 0.000 3.911 132.842 2 2 2 2 4 187043 3.800 1.940 7.910 1001.400 2 2 5 3 4 187043 4.080 2.100 8.050 128.370 2 2 5 3 3 187043 3.970 2.160 8.050 279.560 2 2 5 3 4 187062 2.549 1.177 0.088 4.291 85.833 2 2 3 3 3 187062 2.432 1.206 0.000 4.690 254.502 2 2 2 3 3 187062 2.670 1.350 0.000 4.640 2 2 2 3 5 187101 2.850 1.390 4.930 302.830 2 2 5 2 4 187101 2.790 1.400 3.500 0.000 2 2 5 3 3 187101 2.820 1.460 3.870 0.000 2 2 5 3 3 187123 2.520 1.284 0.000 3.999 24.936 2 2 2 3 2 187123 2.520 1.206 0.136 3.833 25.607 2 2 2 3 2 187123 2.600 1.240 3.830 0.000 2 2 5 3 3 187181 4.349 2.656 0.311 6.101 51.365 2 2 2 3 4 187181 4.291 2.248 0.331 6.101 42.287 2 2 2 3 3 187181 4.310 2.452 0.234 5.867 50.353 2 2 3 3 4 187207 2.422 1.197 0.000 5.146 23.037 2 2 2 2 2 187207 2.422 1.333 0.136 5.253 23.991 2 2 2 2 2 187207 2.384 1.372 0.000 5.127 34.595 2 2 2 2 3 187233 1.926 0.856 0.185 4.135 21.900 2 2 2 3 2 187233 1.850 0.900 3.590 19.200 2 2 5 3 3 187233 1.868 1.012 0.146 5.049 35.802 2 2 3 3 2 187274 2.090 1.080 5.420 24.870 2 2 5 2 3 187274 2.072 1.099 0.078 5.147 21.064 2 2 3 2 2 187274 2.092 1.109 0.088 5.390 21.394 2 2 3 2 2 187314 3.470 1.760 6.450 38.150 2 2 5 3 2 187314 3.510 1.840 5.880 15.350 2 2 5 3 3 187314 3.520 1.850 5.940 30.970 2 2 5 3 2 187335 2.670 1.430 5.070 32.900 2 2 5 3 2 187335 2.646 1.313 0.068 5.234 24.829 2 2 3 3 2 187359 3.259 1.781 0.282 4.894 97.024 2 2 2 3 4 187359 3.830 2.070 7.070 87.330 2 2 5 3 4 187359 3.880 2.070 6.360 36.650 2 2 5 3 3 187374 3.690 1.780 6.990 82.460 2 2 5 2 4 187374 3.590 1.790 0.175 6.713 32.935 2 2 2 2 2 187374 3.600 1.839 0.175 6.889 33.343 2 2 2 3 2 187410 4.652 2.443 0.253 7.620 40.084 2 2 3 2 4 187410 4.652 2.618 0.224 7.630 51.908 2 2 2 2 4 187410 4.710 2.744 0.185 7.688 65.231 2 2 3 2 3 187416 4.632 2.462 0.331 7.133 38.984 2 2 2 2 2 187416 4.496 2.540 0.389 7.299 49.572 2 2 3 2 3 187416 4.652 2.559 0.331 7.464 40.298 2 2 2 2 4 187453 5.569 2.901 0.263 10.427 49.672 2 2 2 3 4 187453 5.569 2.823 0.292 11.264 51.035 2 2 3 3 4 187453 5.403 2.853 0.263 10.846 61.968 2 2 2 3 3 187473 5.812 2.891 0.282 8.548 58.423 2 2 2 2 4 187473 5.617 2.823 0.292 8.723 50.187 2 2 2 2 4 187473 5.617 2.843 0.243 8.635 77.018 2 2 3 2 4 187489 4.437 2.384 0.214 5.838 38.065 2 2 2 2 2 187489 4.427 2.452 0.214 6.266 40.439 2 2 2 2 3 187489 4.379 2.471 0.165 6.052 58.021 2 2 3 2 3 187520 3.775 2.014 0.136 5.624 35.232 2 2 3 2 2 187520 3.717 2.034 0.165 5.536 36.847 2 2 3 2 2 187520 3.727 2.053 0.097 5.711 49.107 2 2 3 2 4 187532 2.675 1.333 0.000 5.536 26.113 2 2 2 2 2 187532 2.753 1.382 0.000 5.730 27.115 2 2 2 2 2 187532 2.598 1.401 0.029 5.633 33.147 2 2 3 2 3 187557 3.688 1.790 0.000 5.643 30.045 2 2 2 2 3 187557 3.795 1.888 0.000 5.692 35.864 2 2 2 2 3 187557 3.726 1.917 0.000 5.731 36.525 2 2 2 2 3 187581 3.619 1.839 0.156 6.013 31.115 2 2 2 3 2 187581 3.649 1.888 0.126 5.838 30.181 2 2 2 2 2 187581 3.590 1.917 0.146 5.682 31.028 2 2 2 2 2 187615 4.427 2.306 0.185 7.541 54.615 2 2 2 2 4 187615 4.486 2.501 0.195 7.852 60.433 2 2 2 2 4 187615 4.486 2.520 0.175 7.687 37.315 2 2 2 2 3 187654 4.758 2.676 0.243 7.307 42.744 2 2 2 3 4 187654 4.739 2.598 0.224 8.144 39.193 2 2 2 3 2 187654 4.476 2.608 0.214 7.706 62.905 2 2 2 3 3 187672 4.160 2.200 7.070 50.850 2 2 5 2 4 187672 4.252 2.325 0.195 6.879 35.241 2 2 2 2 3 187706 5.353 2.823 0.311 6.998 50.387 2 2 3 2 3 187706 5.334 2.852 0.360 7.017 51.954 2 2 2 2 3 187706 5.295 2.900 0.331 7.008 70.700 2 2 2 2 3 187739 2.929 1.508 0.117 4.369 26.717 3 2 3 2 3 187739 3.327 1.421 0.000 4.417 46.974 2 2 2 2 4 187739 3.347 1.489 0.000 4.320 53.259 2 2 2 2 3 187768 4.408 2.316 0.165 5.351 39.591 2 2 2 2 2 187768 4.670 2.179 0.156 5.332 58.272 3 2 2 2 3 187768 4.447 2.209 0.195 5.312 37.820 2 2 2 2 2 187815 3.960 2.082 0.126 4.904 35.134 2 2 3 2 3 187815 3.970 2.082 0.204 4.982 61.463 2 2 2 2 4 187815 4.038 2.121 0.234 4.943 61.590 2 2 3 2 4 187835 3.756 1.868 0.136 5.040 33.626 2 2 3 2 2 187835 3.707 1.907 0.185 5.040 57.298 2 2 3 2 3 187835 3.765 1.936 0.156 5.050 34.998 2 2 2 2 187860 4.418 2.491 0.204 5.712 38.858 2 2 2 2 2 187860 4.476 2.598 0.185 6.121 53.192 2 2 2 2 3 187860 4.486 2.618 0.195 5.907 40.045 2 2 3 2 4 187878 4.204 2.355 0.204 5.440 35.761 2 2 2 2 2 187878 4.311 2.365 0.224 5.858 35.752 2 2 3 2 2 187878 4.223 2.394 0.165 5.644 36.530 2 2 3 2 2 187911 3.376 1.829 0.117 7.015 52.133 3 2 3 3 3 187911 3.843 1.927 0.000 6.665 34.998 2 2 2 3 2 187911 3.980 2.004 0.136 7.239 38.452 2 2 3 3 2 187931 3.493 1.975 0.165 7.366 50.781 2 2 2 3 4 187931 3.269 1.995 0.107 6.188 63.342 3 2 3 3 4 187931 3.697 2.014 0.204 6.792 34.717 2 2 2 2 3 187945 2.792 1.420 0.000 6.266 27.008 2 2 2 3 2 187945 1.400 0.000 6.610 43.230 5 2 2 3 3 187945 2.851 1.362 0.000 6.596 25.870 2 2 2 3 2 187980 4.583 2.520 0.243 8.086 38.863 3 3 2 2 2 187980 4.272 2.228 0.204 7.950 43.933 2 2 2 2 4 187980 4.223 2.257 0.234 8.222 46.541 2 2 2 2 4 187997 3.760 1.870 6.870 38.440 2 2 5 3 2 187997 3.561 1.849 0.185 6.246 36.136 2 2 2 3 2 187997 3.678 1.917 0.204 7.180 38.277 2 2 3 3 2 188022 3.746 2.063 0.282 7.638 58.826 2 2 3 3 4 188022 3.795 2.043 0.165 7.307 60.694 2 2 2 3 4 188022 3.746 1.917 0.204 7.472 38.316 2 2 2 2 2 188050 4.281 2.287 0.175 7.190 37.110 2 2 3 2 2 188050 4.340 2.335 0.195 7.054 41.041 2 2 2 2 3 188050 4.250 2.310 7.320 61.240 2 2 5 2 3 188069 2.442 1.158 0.000 6.752 24.692 2 2 2 2 2 188069 2.354 1.206 0.000 6.625 21.365 2 2 2 2 2 188069 2.296 1.275 0.000 6.694 37.943 2 2 2 2 3 188095 2.920 1.490 6.240 23.230 2 3 5 2 3 188095 2.851 1.518 0.185 6.198 28.507 2 2 2 2 2 188095 2.987 1.673 0.000 6.130 28.196 2 2 2 2 2 188118 2.520 1.380 6.160 25.930 3 2 5 2 2 188118 2.520 1.372 0.000 5.964 24.975 2 2 2 2 2 188118 2.617 1.411 0.000 6.013 27.281 2 2 2 2 2 188143 2.130 1.150 5.490 21.560 2 2 5 2 2 188143 2.080 0.960 5.120 22.210 2 3 5 2 2 188143 2.160 1.060 5.910 56.770 2 2 5 2 3 188175 2.218 1.070 0.000 5.507 22.026 2 2 2 2 2 188175 2.111 1.070 0.097 5.302 22.746 3 2 3 2 2 188175 2.063 1.031 0.136 5.400 23.787 2 2 3 2 2 188200 2.170 1.030 5.770 32.110 2 2 5 2 3 188200 2.150 1.080 5.220 15.530 2 3 5 2 3 188200 2.100 1.190 5.480 24.760 2 2 5 2 3 188238 4.145 2.316 0.175 8.543 51.853 3 2 3 2 3 188238 4.388 2.335 0.224 9.331 37.121 2 2 2 2 2 188238 4.447 2.442 0.214 8.728 37.579 2 2 3 2 2 188258 3.260 1.693 0.146 6.490 46.917 2 2 2 2 4 188258 3.279 1.761 0.146 6.743 43.784 2 2 2 2 4 188258 3.230 1.771 0.146 6.607 31.243 2 2 2 2 3 188275 2.024 0.992 0.000 4.184 15.898 2 2 2 2 2 188275 2.004 1.002 0.019 4.184 13.553 2 2 3 3 2 188322 1.480 0.710 3.370 12.700 2 2 5 2 3 188322 1.700 0.830 3.470 82.960 3 2 5 2 3 188322 1.660 0.700 3.280 45.320 2 2 5 2 3 188358 4.280 2.210 8.080 124.950 2 3 5 2 3 188358 4.174 2.150 0.195 7.765 58.265 2 3 3 2 3 188358 4.184 2.296 0.165 7.969 99.862 2 2 2 2 3 188384 4.905 2.813 0.273 8.069 1497.751 2 2 2 2 3 188384 5.149 2.813 0.243 8.614 134.062 2 2 2 2 3 188384 5.100 2.900 0.380 9.237 870.976 2 2 3 3 3 188430 4.876 2.618 0.243 9.596 190.165 2 2 2 2 3 188430 4.896 2.618 0.273 9.664 1199.466 2 2 3 2 4 188430 4.905 2.638 0.243 9.733 375.786 2 2 2 3 3 188441 3.629 1.888 0.175 6.636 336.455 2 2 2 2 3 188441 4.311 2.131 0.214 8.057 354.505 2 2 3 2 3 188441 4.272 2.364 0.156 7.629 458.659 2 3 2 2 3 188461 5.208 2.658 0.253 8.314 411.665 2 2 2 2 3 188461 5.092 2.638 0.253 8.041 276.851 2 2 2 2 3 188461 5.150 2.638 0.292 7.574 235.359 2 2 3 2 3 8. Reversing Thermometers Reversing thermometers were not used since the dual temperature sensors on the Seabird CTD provide a better in-the-field temperature calibration. 9. Helium / Tritium (Rochelle Ugstad) A total of 180 He and 177 Tr samples were collected by Rochelle Ugstad for Peter Schlosser of Lamont-Doherty Earth Observatory, Columbia University. a. Description of Equipment and Technique He samples were collected through tygon tubing into copper tubes (40 g capacity) bolted into aluminium channels for support and protection. Tr samples were collected into 250 ml brown glass bottles, directly from the Niskin spigot. b. Sampling Procedure and Data Processing Technique He samples were taken after CFCs and occasionally after DOC (WOCE parameter 43). Samples were drawn through tygon tubing that was cured in seawater to reduce bubbles. After all detected bubbles were worked out of the line, the metal channel holding the copper sample tube was lowered to allow a gravity feed of water through the tube. The channel was then struck several times on one side with a ratchet beginning at the intake end in order to pass any air bubbles out of the copper tube. Flushing of the copper tube took place during both parts of the bubble-removing procedure. When air removal and flushing were complete, both ends of the copper tube were sealed, starting at the outflow end, by tightening the two bolts at each end with a ratchet wrench. GMT time of sampling was noted on each sample. These samples will be shipped to Lamont for analysis. Tritium samples were collected into bottles without rinsing or flushing; after all other samples were collected from the rosette. The bottle caps were secured with electrical tape after each station. These samples will be shipped to Lamont for analysis. Occasionally the water supply in the Niskin bottles was exhausted before the sample bottles could be filled completely. This was not a common problem and was avoided by monitoring the amount of water used to rinse sample bottles. Replacement watches were handed out to all persons in the scientific party and the winch operators who normally wore luminous-dial watches. Signs were posted on each winch room door warning personnel to avoid wearing luminous-dial watches inside the room. 10. Oxygen Isotopes (Rochelle Ugstad) a. Sampling Procedure Water samples were initially collected using a 10 litre rosette bottle. Samples for oxygen isotope analysis were collected last in the sampling. A total of about 450 isotope samples were drawn into 30 ml bottles. The bottles were sealed with electrical tape after each station. Samples are being sent to Peter Schlosser and Bob Houghton at Lamont-Doherty Earth Observatory, Columbia University, Palisades, NY. D. MOORED MEASUREMENTS - DESCRIPTIONS, TECHNIQUES AND CALIBRATIONS 1. Current Meter Moorings (Allyn Clarke) a. Description of the Equipment and Technique The standard BIO deep sea mooring consists of a large streamlined subsurface buoyancy package supporting one or more Aanderaa Current Meters, back up buoyancy packages and an acoustic release. The subsurface buoyancy packages are either constructed using 9" glass balls supported in a fibreglass structure or using deep-sea syntactic foam formed in the same streamlined shape as the older glass floats. All of the moorings deployed on 97009 were constructed using jacketed 3/16" wire. Stainless steel shackles and swivels were used to connect the instruments and backup buoyancy packages to the wire lengths. All shackles were secured with a piece of jacketed seizing wire as the mooring was assembled and deployed. The acoustic releases were EG&G DAC model releases. Since these releases were rather old, we placed two releases on all of the moorings. The moorings have been designed for a 20 month deployment. Our traditional back-up buoyancy packages consist of two 17 inch glass balls contained in plastic hard hats and fastened to a stainless steel tension bar one metre in length. These backup buoyancy packages are shackled together to form doubles and triples before they are shackled into the mooring line. During the recovery of M1094 during 96006, the shackles joining backup buoyancy packages came apart as the mooring was worked by relatively heavy sea conditions. We believe that the sea conditions caused a great deal of relative motion between packages. This caused the seizing wire to fail and then the shackles unscrewed themselves. For the moorings set on 97009, two modifications were implemented. First, the shackles on the backup buoyancy packages were secured by being pinned rather than seized. Second, a safety wire was stretched across the double and triple buoyancy packages to provide an additional tension element should one of the shackles fail. Bathymetric surveys are conducted before beginning a mooring deployment in order to determine the depth of water at the intended mooring site. On some occasions, the mooring location needed to be moved several miles in order to find the appropriate depth. The raw soundings for all of these surveys were corrected using Matthews tables for area 12. The data for these sounding surveys is included with the deployment logs. b. Sampling Procedure and Data Processing Techniques The Aanderaa current meters are set with a sampling interval of two hours; the SEACAT temperature / salinity recorders to one hour. On recovery, the data is processed using standard software packages within the BIO Oceans suite of programs. c. Calibration Data The temperature, pressure, conductivity and direction sensors of the Aanderaa current meters are calibrated in the laboratory prior to deployment. The SEACAT instruments are calibrated before and after deployment. These calibrations will not be included in this cruise report. d. Deployment and Recovery Logs Placement Mooring No. 1244 Geographic Area: Labrador Sea Intended Duration: 20 months Ship: Hudson Cruise No: 96026 Date: 21/10/1996 Sea State: 1-2 m swell Weather Conditions: 15 knots @ 310 T Mooring Technician: Scotney/Hartling Navigation Inst: GPS Latitude: 55o 28.715 N Longitude: 53o 39.300 W Time of Fix: 13:51 Z Raw Depth: 1502 fathoms Corrected Depth: 2801 m Main Float Type: Braincon 4 disc Main Float Markings: Nose 222, 223, 224 Radio Beacon Type: Nil Radio Beacon Freq. Light Type: Nil Color/Rate: Mooring Line Type: Jacketed wire Mooring Line Color: Yellow Release Type: EGG/DAC Release S/N: 502901 Release Code: 0126/2367/2345 (release/enable/disable) Release Type: EGG/DAC Release S/N: 701163 Release Code: 0345/4567/2456 (release/enable/disable) Placement Log Time (Z) Instrument Remarks -------------------------------------------------------------------------------- 1043 Braincon Float Lifted off deck 1045 ACM 4342 in water, rotor ok 1046 Braincon Float in water, released from hook 1056 3 bb/backup wire in water/added second wire to lengthen backup wire across bb package 1104 100 m/3bb in water/142 m length 1109 ACM 2663 In water 1119 3bb/backup wire in water/45 m 1221 ACM 3300 In water 1230 ACM 4406 In water 1235 2bb/1076 m In water 1250 3bb/25 m In water ACM 4998 36 m length replaced by two shorter shots for second release 1256 ACM 4998 in water/18 m length 1258 502901 In water 1304 2bb/701163 In water, begin tow to suitable depth. Note: strong easterly set during mooring. Ship did not advance on mooring site during entire deployment 1351 Anchor away 1428 Anchor on bottom 1457 closest approach 55 28.6233 N 1533 701163 Interrogate (1/2 sec for 1 min) and disabled 1534 502911 Interrogate (1/2 sec for 1 min) and disabled 1536 checked transponders, all silent Sounding Survey - M1244 Date: October 21, 1996 Time Latitude Longitude Sounder Value Corrected Depth (z) (fathoms) (metres) -------------------------------------------------------- 0900 1470 2740 0905 1472 2744 0910 1479 2757 0915 1479 2757 0920 1458 2718 0925 1439 2682 0930 1440 2684 0935 1440 2684 0940 1440 2684 0945 1439 2682 0950 1438 2680 0955 1437 2678 1000 1435 2675 Note: The Sounder Value was obtained from the winch room sounder, which was connected to a transducer on the ram. It was assumed that the sounding was based on a sound velocity of 800 fathoms/sec. This was then converted to a raw sounder value in metres based on a sound velocity of 1500 m/s by multiplying by 1.875 (1500/800). Six metres were added to account for the depth and two metres for the depth of the ram below the keel. The resulting raw depth was then corrected using Matthews Tables for area 12. Placement Mooring No. 1245 Geographic Area: Labrador Sea Intended Duration: 20 months Ship: Hudson Cruise No: 96026 Date: 22/10/1996 Sea State: 1-2 m swell, .5 m waves Weather Conditions: 20-25 knots @ 320 Mooring Technician: Scotney/Hartling Navigation Inst: GPS Latitude: 55o 44.827 N Longitude: 53o 29.0772 W Time of Fix: 14:44 Z Raw Depth: 1640 fathoms Corrected Depth: 3061 m Main Float Type: Braincon glass Main Float Markings: 78, 68, 62, 64 Radio Beacon Type: Nil Radio Beacon Freq. Light Type: Nil Light Color/Rate: Mooring Line Type: Jacketed wire Mooring Line Color: Yellow Release Type: EGG/DAC Release S/N: 205004 Release Code: 0347/1357/1356 (release/enable/disable) Release Type: EGG/DAC Release S/N: 308606 Release Code: 0247/2356/2347 (release/enable/disable) Placement Log Time (Z) Instrument Remarks ------------------------------------------------------------------------------ 1049 Float/5m/ACM 1902/50 m in water 1053 3bb/100 m in water 1056 3bb/142 m in water 1103 ACM 5358/450 m in water 1112 2 bb/45 m in water 1114 ACM 828/498 m in water 1123 ACM 4201/140 m in water 1127 2bb/1326 m in water 1153 3bb/25 m 1 ball casing broken and repaired in chute, in water 1157 ACM 4202/18 m adding two 18 m lengths on drum 1158 308606/18 m in water 1203 2bb/205004 1205 anchor away 55o 44.988 N, 53o 29.4862 W 1244 anchor on bottom, 4.5 cables from drop site, range on release 1740 fathoms 1444 best estimated position 55o 44.827 N, 53o 29.0772 W, 2.3 cables SE of anchor drop site 1450 205004 Interrogated and disabled 1452 308606 Interrogated (1/2 sec for 65 sec) and disabled Sounding Survey - M1245 Date: October 22, 1996 Time Latitude Longitude Sounder Value Corrected Depth (z) (fathoms) (metres) ---------------------------------------------------------------- 55 41.67 53 32.12 1600 2986 55 42.72 53 31.78 1610 3005 55 42.79 53 31.29 1610 3005 55 43.38 53 30.79 1620 3024 55 43.94 53 30.35 1622 3027 55 44.48 53 29.85 1620 3024 55 45.06 53 29.38 1640 3062 A/C 55 45.61 53 28.96 1632 3047 55 46.19 53 28.46 1640 3062 A/C 55 46.04 53 27.54 1638 3058 55 45.39 53 26.75 1640 3062 55 44.55 53 26.75 1628 3039 55 43.96 53 26.23 1629 3041 1133 55 44.77 53 28.67 1638 3058 Note: The Sounder Value was obtained from the winch room sounder, which was connected to a transducer on the ram. It was assumed that the sounding was based on a sound velocity of 800 fathoms/sec. This was then converted to a raw sounder value in metres based on a sound velocity of 1500 m/s by multiplying by 1.875 (1500/800). Six metres were added to account for the keel depth and two metres for the depth of the ram below the keel. The resulting raw depth was then corrected using Matthews Tables for area 12. Placement Mooring No. 1246 Geographic Area: Labrador Sea Intended Duration: 20 months Ship: Hudson Cruise No: 96026 Date: 22/10/1996 Sea State: 2-3 m swell, 0.5 m waves Weather Conditions: 25-30 knots @ 320 Mooring Technician: Scotney/Hartling Navigation Inst: GPS Latitude: 56o 09.82 N Longitude: 52o 58.43 W Time of Fix: 2200Z Raw Depth: 1816 fathoms Corrected Depth: 3397 m Main Float Type: Synt. Foam Main Float Markings: 001 Radio Beacon Type: Nil Radio Beacon Freq. Light Type: Nil Light Color/Rate: Mooring Line Type: Jacketed wire Mooring Line Color: Yellow Release Type: EGG/DAC Release S/N: 503301 Release Code: 0256/1257/1256 (release/enable/disable) Release Type: EGG/DAC Release S/N: 100406 Release Code: 0157/3456/2567 (release/enable/disable) Placement Log Time Instrument Remarks (Z) ------------------------------------------------------------------------------- 1931 Float 001/5 m/ACM 7013/398 m in water, the mooring wire got looped over the top of the buoy as it was being swung out but was quickly freed 1941 ACM 5001/450 m in water 1950 2bb/46 m in water, grease on 46 m segment 1952 ACM 5359/498 m in water 2001 ACM 5568/190 m in water 2006 3bb/1624 m in water 2030 3bb/25 m in water 2033 ACM 6401/18 36 m length on drum replaced by two 18 m lengths 2035 503501/18 m in water 2038 2bb/100406 Weight being transferred to anchor, kevlar slip line caught up on release, pulling gear back in board to correct problem 2045 Weight transferred to anchor and slip line clear 2047 Anchor away 56o 10.036 N 52o 58.254W 2131 Anchor on bottom 2200 Closest approach 2215 100406 Interrogated, upright and disabled 2215 503301 Interrogated, upright and disabled Sounding Survey - M1246 Date: October 22, 1996 Time Latitude Longitude Sounder Value Corrected Depth (z) (fathoms) (metres) --------------------------------------------------------- 1735 56 07.15 53 04.82 1788 3343 1740 56 07.87 53 04.15 1800 3365 1745 56 08.62 53 03.36 1803 3371 1750 56 10.40 53 02.63 1806 3377 1755 56 10.14 53 01.76 1810 3385 1800 56 10.89 53 00.99 1820 3404 1805 56 11.00 54 00.00 1820 3404 1810 56 10.73 53 59.53 1815 3394 2007 56 09.88 53 58.13 1816 3396 56 00.12 53 58.81 1820 3404 Note: The Sounder Value was obtained from the winch room sounder, which was connected to a transducer on the ram. It was assumed that the sounding was based on a sound velocity of 800 fathoms/sec. This was then converted to a raw sounder value in metres based on a sound velocity of 1500 m/s by multiplying by 1.875 (1500/800). Six metres were added to account for the keel depth and two metres for the depth of the ram below the keel. The resulting raw depth was then corrected using Matthews Tables for area 12. Recovery Mooring No. 1194 Ship: Hudson Cruise No: 96026 Date: 23/10/1996 Mooring Technician: Scotney/Hartling Sea State: 2-3 m swell/.5 m waves Weather Conditions: 20 knots @ 325 Recovery Log Time (Z) Instrument Remarks 0955 Interrogate release/release responded 1041 Closest approach 5.5 cables to west of last spring's position. New position 56o 44.4032 N 52o28.7239 W 1145 3.5 miles NW of site, grapnel, chain, hooks deployed 1155 at join in the wire, nicol pressing in an eye, joining in main weight and the release 1212 Weight and release in water 1516 Bridge believes we are hooked on, insisting on recovering wire. We are 1.9 km from site, drag was 400 m from the mooring release. Drag release 3 km from vessel at closest approach 1536 Yellow object sighted on surface/wrong floats 1840 Caught mooring/begin hauling 1947 Yellow double at surface/2 grapnels hooked into balls 1957 2 bb on deck - two wires leading into the water 2026 Recovered the rest of the drag line/lost all grappling equipment 2030 Started hauling yellow wire, much damage on jacket of wire 2044 Seacat and ACM on board/rest of wire broken 2052 Release on board Placement Mooring No. 1226 Geographic Area: Labrador Sea Intended Duration: 20 months Ship: Hudson Cruise No: 96026 Date: 24/10/1996 Sea State: 2-3 m swell, 0.5 m waves Weather Conditions: 10-15 knots @ 310 T Mooring Technician: Scotney/Hartling Navigation Inst: GPS Latitude: 56o 44.62 N Longitude: 52o26.61 W Time of Fix:: 1526 Z Raw Depth: 1778 fathoms Corrected Depth: 3513 m Main Float Type: Synthetic Foam Main Float Markings: 002 Radio Beacon Type: Nil Radio Beacon Freq.: Light Type: Nil Light Color/Rate: Mooring Line Type: Jacketed wire Mooring Line Color: yellow Release Type: EGG/DAC Release S/N: 107102 Release Code: A0134 Release Type: EGG/DAC Release S/N: 307405 Release Code: A0457 Placement Log Time (Z) Instrument Remarks 1122 Float 002, IOS CTD, Seacat 1628 lifted off flight deck and over the stern and into the water. No tangles or snags. Two lines from buoy to IOS CTD 1125 ACM 2037/20 m in water 1128 WOTAN 02/43 m in water 1132 2 streamline bb/73 m extra safety wire across pair of floats 1137 Seacat 1623/216 m in water 1144 RDI 236/30 m in water 1147 Seacat 1626/249 m in water 1152 ACM 3198/122 m (ACM 3196 in records) 1157 2 streamline bb/124 m extra safety wire 1200 Seacat 1625/249 m 1205 ACM 6403/122 m in water 1209 3 bb/124 m 1213 Seacat 1624/248 m 1218 ACM 7651/122 m 1221 2 bb/124 m 1225 Seacat 1627/499 m 1235 ACM 8695/442 m 1243 2 bb/134 m 1248 107002/125 m 1251 2 bb/134 m 1255 ACM 8696/21 m 1300 2 bb/307405/chain 1302 anchor away 56o 44.8801 N 52o 26.7721 W - 1778 fathoms corrected to 3513 m 1343 anchor on bottom 1512 closest approach 56o 44.94 N 52 o 26.74 W on SW to NE course 1528 307405 Interrogated and disabled 1526 closest approach 56o 44.62 N 52 o 26.61 W on NW to SE course (Best position for M1226) 1529 107002 Interrogated and disabled 1531 releases Checked transponders, all silent Recovery Mooring No. 1230 Ship: Hudson Cruise No: 96026 Date: 26/10/96 Mooring Technician: Scotney/Hartling Sea State: 0.5 m swell Weather Conditions: 10-12 knots @ 310 Recovery Log Time (Z) Instrument Remarks 1645 107402 3.2 nm range, release enabled, transponding on release, acoustic range 3850 fathoms 742 ship stopped 2996 metres from site. Send enable and transpond commands; no reply 1715 742 ship stopped 2 miles from site. No response through ships transducers 1724 742 over the side transducer/send enable command, return ping 4 times and transpond. Acoustic range 5255 m 1740 742 0.4 miles, transponding on Benthos through EGG deck unit and sounder 1750 742 At site, disable, enable then release commands. Benthos released. On its way up, transpond 4 times mode. 1835 107402 enabled, 1/2 sec for 60 sec, release, 1./sec for 1844 742 on surface and sighted by bridge 1856 742 Finally hooked. Hard hat broken by a hook. WHOI lost a hook. 1858 742 on board 1917 107402 on surface off starboard bow 1920 hooked on 1923 on board 2. Sound Source Moorings Four sound source moorings were set around the periphery of the Labrador Sea. Sound Source North Launch Date 26 October, 1996 Time 1243 UTC Latitude 58o 15.6551 N Longitude 50o 49.1543 W Position Source GPS Deployed by: John/Paul Recorder Mark Prater Ship and Cruise No Hudson 97009 Corrected Water Depth 3551 metres Anchor Position Lat. 58o15.655N Anchor Position Long. 50o 49.1543 W Argos Platform ID No. 10778/SN23104 Flasher ID No. 6435 Acoustic Release Information Release No. 016780 EG&G Tested to 1000metres Receiver No. Release Command 542430 Interrogate Freq. 11.0 Reply Freq. 12.0 Sound Source South Launch Date 06 November 1996 Time 1829 UTC Latitude 54o 58.76 N Longitude 48o 43.03 W Position Source GPS Deployed by: John/Paul Recorder Mark Prater Ship and Cruise No Hudson 97009 Corrected Water Depth 3792 metres Anchor Position Lat 54o 58.76 N Anchor Position Longitude 48o 43.03 W Argos Platform ID No. 10775 SN 52265 Flasher ID No. 6425 Acoustic Release Information Release No. 016779 EG&G Tested to 1000 metres Receiver No. Release Command 542413 Interrogate Freq. 11.0 Reply Freq. 12.0 Sound Source East Launch Date 08 November 1996 Time 1603 UTC Latitude 56o 47.055 N Longitude 43o 59.522 W Position Source GPS Deployed by: John/Paul Recorder Mark Prater Ship and Cruise No Hudson 97009 Corrected Water Depth 3422 metres Anchor Position Lat 56o 47.055 N Anchor Position Longitude 43o 59.522 W Argos Platform ID No. 10779 Flasher ID No. 1611 Acoustic Release Information Release No. 016777 EG&G Tested to 1000 metres Receiver No. Release Command 542357 Interrogate Freq. 11.0 Reply Freq. 12.0 Sounding Survey - Sound Source East Date: November 08, 1996 Time(z) Latitude Longitude Sounder Value Corrected Depth Note (fathoms) (metres) ------------------------------------------------------------------------------- 1040 56 43.97 44 07.66 1840 3442 1045 56 43.62 44 06.30 1805 3374 1050 56 43.22 44 04.46 1755 3279 1055 56 42.74 44 02.77 1710 3194 1100 56 42.20 44 01.99 1665 3109 1105 56 42.44 43 59.82 1675 3129 A/C to 000 1110 56 43.43 44 00.01 1660 3099 1115 56 44.35 43 59.97 1575 2938 1120 56 45.36 43 59.98 1785 3337 1125 56 46.54 43 59.99 1790 3346 1130 56 47.44 43 59.99 1835 3432 New mooring site 1135 56 48.19 43 59.96 1850 3461 1140 56 48.86 43 59.86 1880 3517 A/C to 145 1145 56 49.04 43 59.37 1890 3537 1150 56 48.47 43 58.55 1890 3537 1155 56 47.90 43 58.31 1865 3489 A/C to 207 1200 56 47.36 43 58.51 1860 3480 1205 56 47.41 43 57.95 1885 3527 1210 56 47.46 43 57.76 Light and pump 1245 56 47.38 43 57.94 1885 3527 1250 56 47.38 43 58.02 1885 3527 1300 56 47.44 43 57.88 1885 3527 1305 56 47.47 43 57.65 1885 3527 1315 56 47.59 43 57.34 1885 3527 1335 56 47.53 43 56.82 1890 3537 A/C to 250 1340 56 47.36 43 57.77 1885 3527 1345 56 47.18 43 58.88 1835 3432 1350 56 47.00 43 59.96 1825 3413 1355 56 46.94 44 00.09 1795 3356 1400 56 47.26 44 00.58 1820 3403 A/C to 070 1405 56 47.57 43 59.28 1845 3450 1410 56 47.84 43 57.92 1865 3489 1415 56 47.84 43 56.82 1885 3527 Begin deployment Note: The Sounder Value was obtained from the winch room sounder, which was connected to a transducer on the ram. It was assumed that the sounding was based on a sound velocity of 800 fathoms/sec. This was then converted to a raw sounder value in metres based on a sound velocity of 1500 m/s by multiplying by 1.875 (1500/800). Six metres were added to account for the keel depth and two metres for the depth of the ram below the keel. The resulting raw depth was then corrected using Matthews Tables for area 12. Sounding Survey - Sound Source South Date: November 06, 1996 Time(z) Latitude Longitude Sounder Value Corrected Depth Note (fathoms) (metres) ------------------------------------------------------------------------------- 1230 54 57.65 48 37.65 2092 3922 1235 54 57.71 48 37.86 2092 3922 1240 54 57.83 48 38.13 2092 3921 1245 54 57.95 48 38.48 2091 3920 1250 54 58.20 48 38.95 2090 3919 1255 54 58.37 48 39.26 2090 3918 1300 54 58.63 48 39.71 2083 3904 1305 54 58.90 48 40.14 2078 3895 1310 54 59.10 48 40.50 2076 3892 1315 54 59.31 48 40.87 2073 3885 1320 54 59.47 48 41.17 2072 3884 1325 54 59.73 48 41.58 2070 3880 1230 54 59.95 48 41.92 2067 3874 1335 55 00.15 48 42.35 2061 3862 1340 55 00.48 48 43.96 2058 3857 1345 55 00.77 48 43.33 2050 3842 begin turn to 225 1350 55 00.40 48 43.96 2032 3807 1355 54 59.88 48 44.56 2020 3785 begin turn to 135 1400 54 59.88 48 43.83 2022 3788 1405 54 58.97 48 42.92 2026 3796 new mooring site 1410 54 58.47 48 42.08 2030 3803 1415 54 58.04 48 41.37 2033 3809 1420 54 57.71 48 40.75 2036 3816 1425 54 57.40 48 40.31 2038 3820 1430 54 57.18 48 39.87 2040 3823 1435 54 56.91 48 39.44 2042 3827 1829 54 58.92 48 43.22 2024 3792 anchor drop Best estimated mooring position: Latitude: 54 58.78: Longitude: 48 43.04 Note: The Sounder Value was obtained from the winch room sounder, which was connected to a transducer on the ram. It was assumed that the sounding was based on a sound velocity of 800 fathoms/sec. This was then converted to a raw sounder value in metres based on a sound velocity of 1500 m/s by multiplying by 1.875 (1500/800). Six metres were added to account for the keel depth and two metres for the depth of the ram below the keel. The resulting raw depth was then corrected using Matthews Tables for area 12. Sound Source West Launch Date 21 October, 1996 Time 2257 UTC Latitude 55o 40.90 N Longitude 53o 29.63 W Position Source GPS Deployed by: John / Paul Recorder Mark Prater Ship and Cruise No Hudson 97009 Corrected Water Depth 2987 metres Anchor Position Latitude 55o 40.660 N Anchor Position Longitude 53o 28.9549 W 1 cable to the west Argos Platform ID No. 23668 sub-buoy Flasher ID No. 6436 sub-buoy Acoustic Release Information Release No. 246 Benthos Tested to 1000 metres Receiver No. Release Command D Interrogate Freq. 10.0 Reply Freq. 12.0 3. CTD Profiler Mooring Launch Date 21 October, 1996 Time 2257 UTC Latitude 55o 40.90 N Longitude 53o 29.63 W Position Source GPS Deployed by: John/Paul Recorder Mark Prater Ship and Cruise No Hudson 97009 Corrected Water Depth 2987 metres Anchor Position Latitude 55o 40.660 N Anchor Position Longitude 53o 28.9549 W 1 cable to the west Argos Platform ID No. 23668 sub-buoy Flasher ID No. 6436 sub-buoy Acoustic Release Information Release No. 246 Benthos Tested to 1000 metres Receiver No. Release Command D Interrogate Freq. 10.0 Reply Freq. 12.0 Sounding Survey - CTD Profiler Date: October 21, 1996 Time(z) Latitude Longitude Sounder Value Corrected Depth (fathoms) (metres) -------------------------------------------------------------- 1605 55 30.66 53 42.17 1521 2837 1610 55 31.40 53 42.54 1525 2844 1612 55 31.83 53 42.11 1534 2861 1615 55 32.29 53 41.76 1530 2853 1620 55 33.00 53 40.92 1539 2871 1625 55 33.79 53 40.08 1545 2881 1630 55 34.56 53 39.16 1545 2881 1635 55 35.32 53 38.36 1549 2889 1640 55 36.10 53 37.44 1559 2908 1645 55 36.85 53 36.52 1562 2914 1650 55 37.57 53 35.61 1570 2929 1655 55 38.34 53 34.77 1580 2949 1700 55 39.06 53 34.00 1584 2956 1705 55 39.82 53 33.19 1590 2967 1710 55 40.56 53 32.34 1598 2982 1715 55 41.25 53 31.50 1605 2995 1720 55 42.06 53 30.55 1612 3008 1725 55 42.79 53 29.73 1612 3009 1730 55 43.42 53 28.77 1620 3024 1735 55 43.12 53 27.16 1618 3020 1740 55 42.36 53 26.80 1616 3016 1745 55 41.40 53 27.49 1606 2997 1750 55 40.46 53 28.42 1596 2979 1755 55 39.61 53 29.31 1588 2964 2027 55 39.26 53 29.03 1582 2952 2103 55 40.38 53 29.61 1592 2971 Note: The Sounder Value was obtained from the winch room sounder, which was connected to a transducer on the ram. It was assumed that the sounding was based on a sound velocity of 800 fathoms/sec. This was then converted to a raw sounder value in metres based on a sound velocity of 1500 m/s by multiplying by 1.875 (1500/800). Six metres were added to account for the keel depth and two metres for the depth of the ram below the keel. The resulting raw depth was then corrected using Matthews Tables for area 12. 4. Meteorological Mooring 5. Tomography Mooring 6. Inverted Echo Sounders A. Labrador Sea Deployment Three Inverted Echo Sounders (IES) were deployed to serve as a water-column calorimeter along the western end of WOCE repeat section AR7W. These will join the IES set near the OWS Bravo location during 96006. The vertically integrated acoustic travel time, which the IES measures round-trip from the ocean bottom to the surface, determines the vertically integrated heat content (relative to one or more calibration CTDs during its moored measurement period). The instrument also measures the bottom pressure field. Deployment details: * 14-Jun-1995 06:22Z. Deployed IES076 at Location 16 (Station 27) along WOCE line. * 57° 22.65'N, 51° 47.07'W (by GPS), depth(corr) 3463m. * CTD= site#16, event#28. Down time: 08:02Z @ 57°23.08'N 51°46.42'W. * RADIO/FLASHER # 25 @ 156.875MHz * Backup timed release is 800d from final reset @ 18:00Z 13-Jun-1995 * = (better double check this) 21-Aug-1997. IES is pinging exactly on the hour; we tracked it in beacon mode to the bottom. It hit bottom in 38-39 minutes, after the first few pings of sample. It couldn't have drifted more than 0.3NM or 0.5km. I reconfirmed this position against what the bridge recorded (57° 22.72'N 51° 47.19'W), which coincided more exactly with the launch time. (Ours was 4 minutes after launch). They were still getting ready to take the calibration CTD while the IES sank, and didn't begin until a few minutes after the IES was on the bottom; so the time is coincident. E. ACKNOWLEDGEMENTS F. APPENDICES Appendix 1: Along Track CTD Calibration Information BSB SEABIRD Model 25-03 Serial Number 258917-0116 Temperature Sensor (031548) T = 1/{a + b[ln(fo/f)] + c[ln2[fo/f] + d[ln3(fo/f)]} - 273.15 Where ln indicates a natural logarithm, f is the frequency a = 3.68120903 E-03 b = 6.05726873 E-04 c = 1.57453931 E-05 d = 2.37605653 E-06 fo = 6145.410 slope = 1, offset = 0(Seabird calibration dated November 2, 1993) Conductivity Sensor (041124) Conductivity = (afm + bf2 + c + dt)/[10(1-9.57(10-8)p)] Where f is the frequency, p is pressure in dbars, t is the temperature m = 4.4 a = 7.91164000 E-06 b = 4.91698742 E-01 c = -4.03526125 E+00 d = 6.64743265 E-05 Slope = 1.00000000 Offset = 0.000 Irradiance Sensor (1567) Where m = -0.7558000 b = -3.4702000 Calibration Constant = 3.34000 Multiplier = 1.000 Fluorometer Sensor (304) Where Scale Factor = 10.000 Offset = 0.000 Appendix 2: 97009 CTD Temperature, Salinity, and Oxygen Calibration (Igor Yashayaev) 1 Comparison of Upcast Discrete CTD Data During the 97009 calibration process, a comparison of different versions of discrete CTD data at the time of bottle trip was conducted. Typically, BIO discrete CTD data are produced based on a three-second average of the raw 24 Hz data immediately following the bottle firing. Previously these discrete CTD data have not been subject to the processing (editing, filtering, temporal alignment of the temperature, conductivity and oxygen data channels or the conductivity thermal mass compensation effect) that has been applied to the profile data. The effects of neglecting this processing were investigated. The procedure compared the standard processing qat CTD salinities from the CTD with what was termed qup files. The qup files contained values similar to the qat files, but with the downcast processing included. All processing steps other than the Seasoft loopedit were included in the qup processing. The qup processing also used a slightly different time window for computing the average parameter values. The qat file used an average of three seconds of data immediately following the bottle trip. The qup file used upcast data that was averaged into 1-second bins. The scan at the time of bottle trip was then compared to the centre scan from the 1-second records. All centre scans within (51 scans of the bottle trip scan were identified. If no records were identified in this interval, the interval was systematically increased by 50 scans until at least one record was found. All records in the interval were averaged (weighted equally) to obtain the qup value. For the comparison, resulting salinities from sensors 9 and 10 were combined to form a larger dataset. Matched pair differences between the qat and qup files were determined and a t-test performed. Considering only points deeper than 180 dbar, and only differences within a range of (0.01, the computed t-statistic was 0.74 with a p_value of 0.94, which indicated strong evidence of a zero difference between the qat and qup salinities. In addition to this analysis, we compared the water sample salinities with the qat and qup salinities. Using a two-sample t-test, again omitting all points shallower than 180 dbar and all differences outside the (0.01 range, we computed 95% confidence intervals of: Difference Lower 95% Upper 95% ------------------------------------- ws - qat9 -0.00556 0.00542 ws - qat10 -0.00554 0.00486 ws - qup9 -0.00522 0.00503 ws - qup10 -0.00578 0.00507 At the 95 percentile, the qat and water sample confidence interval encompassed zero, indicating at the 95% level, a zero difference. Figure 1 shows histograms of the water sample minus qat and qup differences. Considering only the statistical results, one would not proceed with further calibration. However, considering oceanographic and instrumentation details, further calibration will be applied. 2 CTD Temperature Calibration Through cruise 97009 sensor set #09 was used as the primary system and #10 as the secondary system. During Seasoft processing, Tpcor was adjusted via the command line of DATCNV to reflect the Tpcor values indicated by Seabird in a memo dated 26 February 1997. The values were: Sensor Tpcor ------------------ 2298 -2.06e-07 2303 -0.80e-07 Upon completion of the cruise, all CTD casts were reprocessed from the raw data files applying a linear correction to temperature. This correction was based on the March, 1997 laboratory calibrations of sensor sets #09 and #10 shown in Figures 2a,b. Black circles and black lines represent the March 1997 calibration. The slope and offset coefficients (Table 1), used in .con files were obtained from linear regressions of TBath-TCTD on TCTD. 3 CTD Pressure Calibration There were two CTD probes (each with a unique pressure sensor) used during 97009. There was no noticeable change in water sample salinity - CTD salinity differences with the change in pressure sensors. Unless both sensors had a similar bias, both probes seemed to have produced highly accurate pressure readings. No additional treatment was applied to the CTD pressure measurements. 4 CTD Salinity Calibration CTD sensor set #09 was used as the primary system and set #10 was used as the secondary system throughout the 97009 cruise. CTD salinities were calibrated in two stages. First, the slope and offset coefficients were determined from the laboratory calibrations of conductivity sensors and in-situ measurements. These coefficients were applied in the Seabird processing via the .con files. The second stage in the calibration determined what additional correction was needed for CTD salinities to account for pressure dependence and/or station-by-station drift. Prior to each stage a calibration data set was created. 4.0 Calibration Data Set On both of the salinity calibration stages a special data set was created from the CTD data (cpcor, slope and offset coefficients were applied to the data prior to the second stage) and the water sample data. This data set was based on discrete CTD readings of temperature, pressure, salinity, etc.; averaged over three seconds at the depth and time of bottle tripping. Using the qat and qup files as the source, the qat-based and qup-based calibration files were created. The creation process for both files is outlined below: * all qat and qup files were merged into all_qat.dat and all_qup.dat; * all_qat.dat and all_qup.dat were merged with water sample salinity measurements into all_qat&bot.dat and all_qup&bot.dat; if needed, the set was subdivided into homogeneous fragments (unique CTD set#, sensor behavior) from all_qat&bot.dat and all_qup&bot.dat (for 97009, this was skipped); * SBottle - SCTD differences were analyzed versus station number, pressure, temperature and salinity in an attempt to justify exclusion of problematic data. 4.1 Determination of coefficients for conductivity correction applied in Seabird processing. To determine calibration coefficients (slope and offset) for a conductivity sensor in a laboratory, a sufficient number of data points must be collected over a wide range of conductivity values. The March 1997 laboratory calibration data collected for the two sensors used during 97009 are shown in Figures 2c,d. The Bath-CTD differences were linearly regressed on CTD conductivity to calculate the 'laboratory' coefficients (or laboratory slope and offset). The slope and offset regression coefficients can also be independently determined by comparing CTD conductivities with in-situ conductivities derived from water sample salinities (these coefficients are named in-situ slope and offset). To conduct this comparison the CTD data must be reprocessed with temperature corrections (see above) applied and the conductivity slope and offset assumed to be 1.0 and 0.0, respectively. The in-situ water sample conductivity was computed from water sample salinity and in-situ temperature (measured by CTD), thus providing a measurement comparable to the in-situ CTD conductivity. To achieve the best results when calibrating CTD salinities, the samples must be taken within relatively homogeneous1 layers. Since such samples collected during 97009 do not provide measurements that cover a wide enough range of conductivity2 values, the laboratory slope was used as the best available estimate. The CTD data have been reprocessed with the assumptions that the slope of conductivity correction was the same as the laboratory slope and the offset was 0. The recomputed CTD conductivities were then compared with the in-situ water sample conductivities, which permitted the determination of a more accurate offset. The Cpcor coefficient (exponential pressure correction) was varied to minimize the pressure dependent drift of CTD - water sample conductivity differences. The Cpcor and linear coefficients (slope and offset) for conductivity are given in Table 1. These coefficients were applied in the Seabird processing via the .con files. 4.2 Post-Seabird Processing of CTD Salinity The corrections for the CTD salinities determined in this step were required because the Seabird software can only apply corrections to temperature and conductivity measurements that are expressed as exponential pressure dependence. Invariant slope and offset coefficients do not account for the existence of a time drift in the characteristics of a CTD sensor. The drift can be compensated by introducing variation to the offset coefficient or by applying a correction in the "Post-Seabird" stage. To find out what additional corrections were to be applied to the CTD salinities, the following steps were used: Medians of SBottle - SCTD in pressure bins of 180 dbar were determined. These bins were centred at 100 dbar intervals between 300 and 3600 dbar (e.g. intervals were 210-390, 310-490, etc). Only medians supported by 7 or more measurements were used in the evaluation of the polynomial coefficients. By using the medians to determine the pressure dependent calibrations, we hoped to reduce the influence of outliers on the aspects of the salinity calibration. SBottle - SCTD medians in the pressure bins were used to fit a polynomial function (Figure 3) on pressure. Persistence in the shape of the SBottle - SCTD medians versus pressure dictated our choice of a 2nd degree order polynomial function (in the case of a cruise with deeper stations a choice of a 3rd degree polynomial function would probably provide a better fit). The resulting coefficients are presented in Table 3. The 2nd degree polynomial was further justified by a general F-test comparing the 1st and 2nd degree fits. The results of the test for conductivity sensor #10, using data in the 300 to 3600 dbar interval, were an F-statistic of 271.3 and p-value of 0. Note that the results from the F-test for the 1st degree fit for sensor #10 were an F- statistic of 0.1 and P-value of 0.71, i.e. not a good fit. The statistical results comparing the 1st and 2nd degree fits for sensor#9 were less obvious numerically but Figure 3 indicated an obvious 2nd order fit was required. Figure 4 shows the salinity difference plots after the pressure dependent signals have been removed. The station medians of SBottle - SCTD were calculated, using the data deeper than 300 dbar. The station-to-station progression of such medians is presented in Figure 5a (1-2). These values were computed by performing iterative re- evaluations of a time drift and the 2nd degree pressure-dependent polynomial correction. This procedure is similar to that described further in sections 5.2.1-5.2.7. The time drift corresponds to the station medians of the SBottle - SCTD differences deeper than 300 dbar. Each median was calculated from at least 6 values of SBottle - SCTD. If the number of measurements on a station was insufficient to meet this criterion, the neighboring stations were also involved in the computation of a median. Both CTD systems showed a significant station-to-station variation in the SBottle - SCTD station medians. The overall tendency for system #9 was about 0.001 psu, whereas it was 0.002 psu for system #10. In addition to this, the SBottle - SCTD differences for both systems showed similar patterns for groups of stations. The medians between station 45 and 50 were the lowest. Stations 50 to 70 showed a rapid increase of the differences, which resulted in the highest overall median values. Between stations 71 and 81 the medians decreased by 0.001 for system #9 and 0.0005 for system #10. Close to the end of the cruise we collected additional replicates of salinity samples (8-10 for each station). These were then divided into two groups, which were analyzed at different times. The purpose of this experiment was to see if the water sample salinity measurements changed over time3. That is, one group of samples was analyzed in the routine order (within 24 hours after collection), but the other groups of samples were not analyzed until after a few days or weeks had passed. If differences existed between the "regular" (measured at the usual time after water collection) conductivity values and those measured at a later time, the differences should show up in the analysis. From the start of this experiment there was no significant station-to-station change seen in the SBottle - SCTD differences. No systematic differences were evident. Since there was no obvious reason for water sample salinity to change at the mentioned rates we can hardly base an explanation of the time drift in Figure 5a on a drift in the water sample salinities. It is proposed that in the future if this experiment is done throughout the entire cruise, it will greatly aid in identifying whether the water sample or CTD data are responsible for any apparent drift in the SBottle - SCTD differences. For most of the cruise, the CTD sensors were not properly soaked between stations. This could have led to the accumulation of residual material in both sensors' conductivity cell. On the long steams when the systems were flushed the cells could have been partially or completely cleaned. The volume and characteristics of each cell would have responded accordingly to its cleanliness. This served as a motivation to attribute most of the station-to- station change in the SBottle - SCTD differences to the time drift in the CTD salinities. To compensate this time drift, a special correction was constructed and added to 97009 CTD salinities. On the other hand, the difference between primary and secondary salinities changed between stations 20 and 120 by about 0.0015 psu (Figure 5a (3-4), Figure 6). Since the station medians were supported by a relatively small number of measurements, they could experience some noise originated from the CTD readings and the water sample measurements. Consistency in the drifts of SBottle - SCTD1 and SBottle - SCTD2 medians (Figure 5a, (1-2), Figure 6) suggested that there was a common cause in these signals. To determine the corresponding component a unified station-to-station correction was computed on consolidated data (primary joined with "adjusted" secondary). This station-to-station correction was thereafter added to the 97009 primary CTD salinities. The correction for the 97009 secondary CTD salinities in addition to the common correction had a component accounting for inter-sensor time drift (linear on station number). The following outlines the procedure of determination of time (station) dependent correction suggested for the 97009 CTD salinities: * The differences between the station medians of primary and secondary CTD salinity (SCTD2 - SCTD1, (3) in Figure 5a) were computed and linearly regressed on station number (LSCTD2-SCTD1(St#), (4) in Figure 5a). * The SBottle - SCTD2 medians ((2) in Figure 5a) were corrected for LSCTD2- SCTD1(St#) ((4)). This made the time drift in the "adjusted" SBottle - SCTD2 series ((5)) consistent with the time drift in SBottle - SCTD1 ((1)). * The SBottle - SCTD1 and "adjusted" SBottle - SCTD2 medians were merged into a single dataset ((5) combined with (1a) in Figure 5a). * The merged "inter-system" data set ((5)+(1a) in Figure 5a) was subdivided into fragments where the station medians were monotonous. This grouping resulted in seven fragments, which included the stations: 21-41, 45-53, 66-71, 80-91, 95- 114, 117-118 and 120-126 ((6) in Figure 5a). Each fragment was processed as follows: a median of all "inter-system" medians in the fragment was computed and assigned to each station within the fragment as a correction for the time drift. The corrections for the stations between the fragments were computed by linear interpolation (using medians from the fragments closest on either side) and outside the fragments by extrapolation (for stations before 21 the 21-41 correction was used; for stations after 126 the 120-126 correction was used). The combined result was a unified station-to-station correction ((7) in Figure 5a). * The unified station-to-station correction ((7) in Figure 5a,b) was applied to the primary salinity. In addition to the unified correction, the secondary salinity was also corrected for the intersystem time drift: LSCTD2-SCTD1(St#) = 0.0000126 * St# - 0.00132, where St# - station number. The intersystem time drift ((9) in Figure 5b) was computed as a linear regression of the difference ((8)) between the SBottle - SCTD2 medians ((2)) and the unified correction ((7)) on the station number. The overall time correction for the secondary salinities is a sum of the unified and intersystem corrections ((10)). * The station-to-station correction is summarized in Tables 4-5. 5. CTD Oxygen Calibration Generally, calibration of CTD oxygen data involves two steps. In the first step non-linear 'hardware' coefficients are computed and applied to the data in the Seabird processing via the .con files. The second step addresses an additional (secondary) correction that is applied to the oxygen concentrations derived in the Seabird processing. The second step is dictated by time drift in the sensors' characteristics and effects of pressure, temperature and oxygen unaccounted for in Seabird processing. The calibration parameters for the CTD oxygen data were based on down trace CTD data and measurements of water sample oxygen concentration from bottles tripped on the up trace. Though these datasets are inconsistent (to some degree) in time and spatial location, they were considered the only reliable source of information for calibration of CTD oxygen. 5.0 Calibration data set On both stages of processing a calibration data set is created from the CTD data and the water sample data. The calibration data file (set) is used for finding and testing calibrations (coefficients in 5.1) later applied to the CTD data via the .con files or in the secondary correction (5.2). This file is based on discrete CTD temperature, pressure, salinity, etc.; averaged over three seconds at the depth and time of bottle tripping and is created as outlined below: Since the oxygen sensors installed on the CTD package work more reliably on the down trace part of a CTD cast, all oxygen calibrations were based on down traces. Therefore, the down trace measurements were matched with the data from the calibration file in an attempt to locate a point or a group of points representative of a water type at the depth and time of bottle tripping. The match search was performed for each record of the calibration file and was designed as follows: The data from a down trace profile were restricted to a certain pressure (or/and) density (or/and) temperature (or/and) salinity in the vicinity of the values in the calibration file. Typical criteria (definition of vicinity): differences between up trace and down trace pressure 25 dbar, potential temperature 0.5K, salinity 0.02; This defines a 'group'. Search the 'group' for the point(s), which are (proved to be) "closest" to the bottle trip point (from the calibration file). If more than one point was found, the points were averaged. The measure of "closeness" was a distance, defined in multidimensional space, where dimensions are normalized (weighted or rescaled) pressure, potential temperature, salinity and density. Normalization for each axis was done according to expected variability within a water type. In ultimate cases only one or two dimensions were chosen. The found point was identified as a match to the up trace CTD data point at the time of bottle trip and its properties were added to the calibration file. Water sample (ws) salinity and oxygen concentration determined onboard were added to the calibration file. For initial 'indirect' check of quality, the differences between water sample and calibrated CTD salinity were computed. If the absolute difference exceeded 0.004 the point (record) containing this data was considered unreliable and discarded from further analysis. Next the data set was split into "sets" based on distinct changes in the sensors behavior. The "set" represented quasi-steady periods of oxygen sensor behavior. This avoided extreme temporal drifts in any of the "sets" and allowed the use of the same non-linear coefficients for each "set". Determination of 'Hardware' Coefficients A nonlinear multiparametric least square or least median absolute deviation technique was used to determine the oxygen sensor processing coefficients (soc, boc, tcor, and pcor) using oxygenws vs. downcast temperaturectd, salinityctd, pressurectd, oxygen currentctd and oxygen temperaturectd (where the ws/ctd subscripts represents water sample/CTD data). Applying the results of step 5.1.1, the oxygenctd was derived. Computation of the difference oxygenws - oxygenctd. Statistics of the difference were computed and the records that produced outliers (whether caused by oxygenws or oxygenctd) were marked or deleted from the calibration file. Repeat 5.1.1 - 5.1.2 until all obvious outliers are deleted from the data. Checking the oxygenws - oxygenctd distributions: if the differences (oxygenws - oxygenctd) are randomly distributed versus all parameters (temperature, pressure, oxygen current, and oxygen temperature) and there are no evident outliers, proceed to stage described in 5.2,otherwise, using the calibration file cleaned according to 5.1.3, repeat all the steps of stage 5.1 until the first part of the check 5.1.4 is satisfied (typically, 10 to 15 iterations are required to clean the calibration file and determine the oxygen sensor processing coefficients soc, boc, tcor, and pcor). In the case of notable time drift the scheme 5.1.1 - 5.1.4 is transformed to the following (for simplicity assume that all records producing outliers in oxygenws - oxygenctd differences were removed): * Search for the best values of soc, boc, tcor, and pcor, using least square or least median absolute deviation technique (similar to 5.1.1). * Applying the results of step 5.1.1* (on the first pass) or 5.1.5* (subsequent iteration), the oxygenctd was derived. * Computation of the difference oxygenws - oxygenctd. Determination of medians of oxygenws - oxygenctd from a moving window. The window size is expressed either in a number of stations or in a number of samples. In both cases the search of oxygenws - oxygenctd is conducted in a window of stations. In the last case the search starts with one station and continues by adding one station to either side of the window, until the total number of samples in the window is equal or greater than the required number of samples.Hereafter, the oxygenws - oxygenctd medians are named medws-ctd. * Adding medws-ctd to oxygenws forms oxygenws# with a time drift similar to that in oxygenctd. * Analogous to 5.1.1* (search for the best values of soc, boc, tcor, and pcor via least square or least median absolute deviation technique), except oxygenws#, is used instead of oxygenws. * Checking the oxygenws# - oxygenctd distributions: * if the differences (oxygenws# - oxygenctd) are randomly distributed versus the variables used in regression (temperature, pressure, oxygen current, and oxygen temperature) and the variance of the differences (or median absolute deviation) is not getting smaller with any subsequent iteration, proceed to the next stage of the calibration process (section 5.2), * otherwise, repeat all instructions from 5.1.1* to 5.1.5* until the first part of 5.1.6* is satisfied. The number of sufficient iterations varies depending on the method (least square or least median absolute deviation), noise to time drift ratio, etc. 5.2 Computing corrections of time drift and residual effects of pressure, temperature and oxygen After the coefficients soc, boc, tcor, and pcor have been updated and the .con files and the CTD data have been reprocessed, the calibration file is reconstructed. However, instead of computation of CTD oxygen from downcast parameters (as in section 5.1) all corrections found on this stage are applied directly to the oxygen values (ml/l) derived in the Seabird processing (ignored on stage 5.1). Compute the differences oxygenws - oxygenctd. Using the differences from 5.2.1 (in the first iteration on this stage) or 5.2.5 (in any subsequent iteration), compute the median oxygenws - oxygenctd for each station. The series of station-by-station medians represents the time drift of the sensor. * Subtract the individual station median (time drift, 5.2.2) from the differences oxygenws - oxygenctd for that station, which must be taken from 5.2.1. * For each "set" of stations (as defined in 5.0.4) compute a polynomial fit of the residuals from 5.2.3 on pressure, temperature and oxygen. * Subtract the polynomial correction, derived in 5.2.4, from the differences computed in 5.2.1 (before subtraction of the time drift). Check for the outliers, remove or flag if there are any. * Subtract the time drift (station median) from the results of 5.2.5. * If these (new 5.2.6) residuals don't depend on pressure, temperature, oxygen or time and their statistics are not improving with any subsequent iteration (in other words, the distributions are not getting tighter) advance to 5.2.7. * Otherwise, use the results of step 5.2.5 and repeat all the steps of stage 5.2 until the first bulleted condition of 5.2.6 is satisfied. The search of the best CTD oxygen corrections (on time, pressure, etc.) typically requires 7 to 15 repetitions. * Finalize calibration coefficients. 5.3 Application of 5.0 - 5.2 to 97009 CTD oxygen data The CTD Set #09 was used as a primary and #10 as a secondary system through the 97009 cruise. Oxygen measurements from the primary CTD set were available through the whole cruise, whereas the secondary oxygen was successfully recorded only starting from the station #80 (due to failure of the first installation of the oxygen sensor on the secondary system). The first step of calibration of the CTD oxygen data was based on the adjustment of the soc, boc, tcor, and pcor coefficients as described in 5.1. This was done by iterative reevaluations of these coefficients and time drift in the CTD oxygen. The optimal soc, boc, tcor, and pcor coefficients are given in Table 2. These coefficients were entered into the corresponding .con files used in the reprocessing of the CTD data. The differences between the water sample and CTD oxygen values after the CTD data reprocessing are presented in Figures 7 and 8. Below 500 dbar the distribution of the differences is relatively uniform on pressure. Examination of the station-by-station evolution of the water sample vs. CTD oxygen differences (Figure 8) revealed their persistent station-to- station variation. The time drift in the oxygen current readings evidently caused this signal. The time drift identified in both primary and secondary CTD oxygen is shown as a solid line in Figure 8. Removal of the drift from the CTD oxygen4 reduced the variance of the differences between the water sample and CTD oxygen values. There is no noticeable residual pressure and temperature dependence of the differences. Therefore, the second step of CTD oxygen calibration (described in 5.2) resulted in a simple station-by-station correction of the CTD oxygen. The corresponding values that were added to the CTD oxygen on each station are summarized in Table 5. The water sample oxygen, shown in Figure 9a, shows considerable noise to signal ratio. However, there does appear to be a fluctuation at ~1000 dbar. The CTD oxygen, Figure 9b,c, does show the general features of the water sample data, including the noted fluctuation at ~1000 dbar that was evident in the water samples. 6. Summary Usage of the same sets of temperature and conductivity sensors in all Labrador Sea cruises starting from 1997 allowed us to track a similar pattern in behavior of the sensors from cruise to cruise. In the case of insufficient information, such knowledge can provide a framework for a limited data set, providing a better solution for the calibration problem. 7. Acknowledgements A hard work and help of my friends and colleagues from BIO, involved in the acquisition and verification of deep ocean data granted that the strategy of the CTD data processing and quality control outlined in this document has some rational grains in it. Allyn Clarke coordinated and supervised laboratory calibrations, cruise preparations and operations. Anthony Isenor is responsible for the data management. He also generously helped me to edit this document and to conduct statistical testing of some results. Jeff Jackson made a number of useful comments on the text. Rick Boyce repeatedly and most accurately performs the laboratory calibrations and helps in conducting experiments aimed to provide better measurements of water sample salinities. Table 1. Offset, slope and pressure coefficients for temperature and conductivity CTD Set Sensor PCOR Offset Slope --------------------------------------------------------- 09 (primary) Temperature -2.06e-7 0.0 0.99998 Conductivity -1.0e-7 -0.00005 1.000115 10 (secondary) Temperature -0.8e-7 -0.0005 1.0 Conductivity -1.0e-7 0.00011 1.000113 Table 2. Temperature, conductivity and oxygen coefficients used in .con files Temperature Primary Tpcor: -2.060E-7 As recommended by Seabird (note of Feb. 26, 1997) Slope: 0.99998 Based on regressions using lab. temperature (March, Offset: 0.0 1997) and conductivity calibrations (March, 1997) Temperature Secondary Tpcor: -0.800E-7 As recommended by Seabird (note of Feb. 26, 1997) Slope: 1.0 Based on regressions using lab. temperature (March, Offset: -0.0005 1997) and conductivity calibrations (March, 1997) Conductivity Primary Cpcor: -1.00000E-007 The limit of Seasoft Cpcor's (I would use -1.1) to account for pressure influence on conductivity Slope: 1.000115 Based on regressions using lab. conductivity calibrations (March, 1997) Offset: -0.00005 As revealed by fitting of CTD conductivities against those derived from the Bottle data (97009) Conductivity Secondary Cpcor: -1.00000E-007 The limit of Seasoft Cpcor's (I would use -1.1) to account for pressure influence on conductivity Slope: 1.000113 Based on regressions using lab. conductivity calibrations (March, 1997) Offset: 0.00011 As revealed by fitting of CTD conductivities against those derived from the Bottle data (97009) Oxygen Primary SOC: 3.2020 All oxygen coefficients are based BOC: -0.0080 on fitting the CTD oxygen values TCOR: -0.0360 to those from the water samples PCOR: 1.390E-004 Oxygen Secondary SOC: 2.8330 All oxygen coefficients are based BOC: 0.0480 on fitting the CTD oxygen values TCOR: -0.0410 to those from the water samples PCOR: 1.270E-004 Table 3. Coefficients for pressure polynomial for salinity correction CTD Set Degree of polynomial term 0 1 2 -------------------------------------------------------- 09 (primary) -0.00125 1.2168E-006 -2.459E-010 10 (secondary) -0.00050 6.0973E-007 -1.606E-010 Table 4. Inflection points for the station based correction of CTD salinity Station CTD System Primary + ý Secondary ------------------------------------------ 21 -0.00048 -0.00106 -0.00154 41 -0.00048 -0.00080 -0.00128 45 -0.00093 -0.00075 -0.00168 53 -0.00093 -0.00065 -0.00158 66 0.0012 -0.00049 0.00071 71 0.0012 -0.00043 0.00077 80 0.00037 -0.00031 0.00006 91 0.00037 -0.00017 0.00019 95 0.0006 -0.00012 0.00047 114 0.0006 0.00012 0.00071 117 0.00047 0.00015 0.00062 118 0.00047 0.00017 0.00063 120 0.00022 0.00019 0.00041 126 0.00022 0.00027 0.00048 Table 4a. Station-by-station correction of CTD salinity Station Primary Secondary Correction Correction -------------------------------- 1 -0.00048 -0.00179 2 -0.00048 -0.00178 3 -0.00048 -0.00176 4 -0.00048 -0.00175 5 -0.00048 -0.00174 6 -0.00048 -0.00173 7 -0.00048 -0.00171 8 -0.00048 -0.00170 9 -0.00048 -0.00169 10 -0.00048 -0.00168 11 -0.00048 -0.00166 12 -0.00048 -0.00165 13 -0.00048 -0.00164 14 -0.00048 -0.00163 15 -0.00048 -0.00161 16 -0.00048 -0.00160 17 -0.00048 -0.00159 18 -0.00048 -0.00158 19 -0.00048 -0.00156 20 -0.00048 -0.00155 21 -0.00048 -0.00154 22 -0.00048 -0.00153 23 -0.00048 -0.00151 24 -0.00048 -0.00150 25 -0.00048 -0.00149 26 -0.00048 -0.00147 27 -0.00048 -0.00146 28 -0.00048 -0.00145 29 -0.00048 -0.00144 30 -0.00048 -0.00142 31 -0.00048 -0.00141 32 -0.00048 -0.00140 33 -0.00048 -0.00139 34 -0.00048 -0.00137 35 -0.00048 -0.00136 36 -0.00048 -0.00135 37 -0.00048 -0.00134 38 -0.00048 -0.00132 39 -0.00048 -0.00131 40 -0.00048 -0.00130 41 -0.00048 -0.00129 42 -0.00059 -0.00139 43 -0.000705 -0.00149 44 -0.00082 -0.00159 45 -0.00093 -0.00169 46 -0.00093 -0.00167 47 -0.00093 -0.00166 48 -0.00093 -0.00165 49 -0.00093 -0.00164 50 -0.00093 -0.00162 51 -0.00093 -0.00161 52 -0.00093 -0.00160 53 -0.00093 -0.00158 54 -0.00077 -0.00141 55 -0.00060 -0.00123 56 -0.00044 -0.00106 57 -0.00028 -0.00088 58 -0.00011 -0.00070 59 0.00005 -0.00053 60 0.00022 -0.00035 61 0.00038 -0.00017 62 0.00054 0.00000 63 0.00071 0.00018 64 0.00087 0.00036 65 0.00104 0.00053 66 0.0012 0.00071 67 0.0012 0.00072 68 0.0012 0.00073 69 0.0012 0.00075 70 0.0012 0.00076 71 0.0012 0.00077 72 0.00111 0.00069 73 0.00102 0.00061 74 0.00092 0.00053 75 0.00083 0.00045 76 0.00074 0.00037 77 0.00065 0.00029 78 0.00055 0.00021 79 0.00046 0.00013 80 0.00037 0.00006 81 0.00037 0.00007 82 0.00037 0.00008 83 0.00037 0.00009 84 0.00037 0.00011 85 0.00037 0.00012 86 0.00037 0.00013 87 0.00037 0.00014 88 0.00037 0.00016 89 0.00037 0.00017 90 0.00037 0.00018 91 0.00037 0.00019 92 0.00043 0.00026 93 0.00049 0.00033 94 0.00054 0.00040 95 0.0006 0.00047 96 0.0006 0.00049 97 0.0006 0.00050 98 0.0006 0.00051 99 0.0006 0.00052 100 0.0006 0.00054 101 0.0006 0.00055 102 0.0006 0.00056 103 0.0006 0.00057 104 0.0006 0.00059 105 0.0006 0.00060 106 0.0006 0.00061 107 0.0006 0.00063 108 0.0006 0.00064 109 0.0006 0.00065 110 0.0006 0.00066 111 0.0006 0.00068 112 0.0006 0.00069 113 0.0006 0.00070 114 0.0006 0.00071 115 0.00056 0.00068 116 0.00051 0.00065 117 0.00047 0.00062 118 0.00047 0.00063 119 0.00034 0.00052 120 0.00022 0.00041 121 0.00022 0.00042 122 0.00022 0.00043 123 0.00022 0.00045 124 0.00022 0.00046 125 0.00022 0.00047 126 0.00022 0.00048 Table 5. Station-by-station correction of CTD oxygen Station Primary Secondary Correction Correction -------------------------------- 4 0.14656 5 0.14656 6 0.08893 7 0.14656 8 0.14656 9 0.14656 10 0.08893 11 0.08893 12 0.37909 13 0.38709 14 0.38709 15 0.63614 16 0.91223 17 1.16680 18 1.67354 19 1.86041 20 1.09925 21 0.92633 22 0.00053 23 -0.14928 24 -0.33287 25 -0.22102 26 -0.27352 27 -0.07800 28 -0.18329 29 -0.22311 30 -0.23491 31 -0.34488 32 -0.32606 33 -0.16202 34 -0.19000 35 -0.23961 36 -0.27330 37 -0.23203 38 -0.28577 39 -0.27323 40 -0.24855 41 -0.39190 42 -0.38128 43 -0.33115 44 -0.30455 45 -0.29813 46 -0.38940 47 -0.32237 48 -0.16451 49 -0.27895 50 -0.32778 51 -0.17744 52 -0.22333 53 -0.18131 54 -0.13614 55 -0.19250 56 -0.19250 57 -0.19250 58 -0.28092 59 -0.28092 60 -0.28092 61 -0.13790 62 -0.13790 63 -0.13790 64 -0.22951 65 -0.22951 66 -0.22951 67 -0.13382 68 -0.13632 69 -0.20198 70 -0.06792 71 -0.05891 72 -0.07746 73 -0.19449 74 -0.21932 75 -0.21932 76 -0.21932 77 -0.02738 78 -0.01576 79 -0.01576 80 -0.01576 -0.16065 81 -0.07211 -0.03772 82 -0.12580 0.00036 83 -0.07979 -0.12234 84 0.12664 -0.08355 85 0.06170 -0.19972 86 0.05089 -0.16053 87 -0.00139 -0.10376 88 -0.02363 -0.10122 89 -0.02449 -0.07486 90 0.09417 -0.04149 91 0.03667 -0.01307 92 0.10144 0.00040 93 0.09230 -0.01139 94 0.03601 0.01147 95 0.01571 0.00721 96 -0.06298 -0.00932 97 0.18420 0.01003 98 0.15833 0.07562 99 0.15391 0.07319 100 0.16167 0.04023 101 0.23833 0.00496 102 0.18487 -0.06575 103 0.20528 -0.01895 104 0.22359 0.00328 105 0.22359 0.04992 106 0.35498 0.08364 107 0.43669 0.12467 108 0.43669 0.12981 109 0.21928 -0.01272 110 0.27262 0.01300 111 0.35636 0.04261 112 0.34090 0.03297 113 0.33597 0.02476 114 0.46924 0.08885 115 0.44528 0.08163 116 0.40725 0.05971 117 0.43984 0.08439 118 0.47175 0.07383 119 0.44866 0.07237 120 0.50829 0.10281 121 0.46205 0.05662 122 0.48253 0.07003 123 0.45970 0.06838 124 0.54977 0.09142 125 0.57681 0.10992 126 0.59439 0.07903 127 0.57958 0.04703 128 0.55214 -0.04207 129 0.55214 -0.04207 G. REFERENCES Carritt, D.E. and J.H. Carpenter. 1966. Comparison and Evaluation of Currently Employed Modifications of the Winkler Method for Determining Dissolved Oxygen in Seawater. A NASCO Report, Jour. Mar. Res., 24, 268-318. Clarke, R. Allyn, Jean-Guy Dessureault and Geoff Lebans. 1995. Upper Ocean Profiling from Vessels Underway, Sea Technology, February 1995. Jones, E.P., F. Zemlyak and P. Stewart. 1992. Operating Manual for the Bedford Institute of Oceanography Automated Dissolved Oxygen Titration System. Can. Tech. Rep. of Hydrography and Ocean Sci. 138: iv+51p. Levy, E.M., C.C. Cunningham, C.D.W. Conrad and J.D. Moffatt. 1977. The Determination of Dissolved Oxygen in Sea Water, Bedford Institute of Oceanography Report Series, BI-R-77-9, August 1977. FOOTNOTES 1 Characterized by small vertical gradients 2 If a cruise provides enough samples to cover a wide range of conductivity values, the in-situ slope is usually used instead of the slope estimated from the laboratory calibrations. During long cruises the in-situ coefficients may be subject to variation in time (i.e. time drift), in which case the computations involve intermediate steps of estimation and subtraction of the drift and revaluation of the slope and offset. These operations are conducted in iterations similarly to 5.1.1*-5.1.6*. The time drift is presented as a series of medians determined from an n-point moving window of stations. 3 This experiment was also aimed to determine the cause of the station-to- station drift of the SBottle - SCTD differences. The time variation of the sample salinity measurements would result in a change of the SBottle - SCTD differences between the groups 4 The time drift was greater in the primary CTD oxygen. WHPO DATA PROCESSING NOTES Date Contact Data Type Data Status Summary 4/7/98 Schott Cruise ID Data Update North Atlantic cruise list Enclosed please find a list of cruises (since 1990) we use as references for our work or are aware of in the North Atlantic. HU97009 Hudson 09.05.-12.06.1997 R.A. Clarke BIO 1/11/00 Clarke DOC Data Requested by jlk figures missing 1/20/00 Huynh DOC Website Updated pdf, txt versions online 3/24/00 Schlosser He/Tr Data are Public See note: as mentioned in my recent message, we will release our data with a flag that indicates that they are not yet final. We started the process of transferring the data and we will continue with the transfer during the next weeks. I had listed the expected order of delivery in my last message. 10/25/00 Clarke CTD/BTL No Data Submitted See Note: The spring 1997 cruise was also an extended cruise. On this cruise, we used two different oxygen titration systems in parallel and in spite of using the same standards got systematic offsets between the two systems. We have decided on a course of action and plan to submit this data set by the end of this year. 12/28/00 Buck SUM Website Updated Unformattted SUM online Added SUM to website. Data is unformatted and has errors. Expocode is 18HU97009_1. 4/19/01 Bartolacci CTD/BTL/SUM Clarification Request Are Data Public? Regarding the 97007 data submission: Are these data public? Is the newly submitted sumfile to replace the current online sumfile? And finally, the *.mgd file is not utilized by this office, is there some reason it was included? New data are encrypted until word from Isenor. 4/19/01 Isenor CTD/BTL/SUM Submitted Also Doc file, See note: Email from Anthony Isenor states that sumfile is to replace current online file, and that data are Non-public until further notice from his lab. Please see email below: Date: Thu, 19 Apr 2001 16:07:07 -0300 From: "Isenor, Anthony" Subject: RE: AR7W Data for 1997 Delivered To: "'Danie Bartolacci'" MIME-version: 1.0 Hi Danie: Sorry about the upload. I will go to the web site and follow the current instructions next time. At this moment, you should consider the data non-public. When we send our submission to our national data centre, they will be public. At that time, I will let you know of the status change. Yes, the delivered SUM file should replace your current SUM file. The mgd file is included as per instructions in the WOCE reporting manual. I will also send a copy to National Geophysical Data Centre, so you can ignore that particular file. As for the other cruises: 91007 - This is an ongoing saga. It is difficult to predict what exactly will happen. 96026 - This is a problem dataset because of multiple CTD systems. It is second on my list. 98023 - This is next on my list. However, it shouldn't be as complicated as 97009. You should have initial cruise reports and SUM files for all three of these. However, no data yet. Regards, Anthony SUM, CTD, Bottle: (ctdraw, ctdprs, ctdtmp, ctdsal, ctdoxy, theta, salnty, oxygen, silcat, no2 no3, phspht, cfc-11, cfc-12, cfc113, ccl4, tcarbn, alkali, qualt1), DOC, bottle, sum, ctd and doc files were submitted by A. Isenor on 2001.04.19. In addition to the above bottle parameters, the bottle file also contains methyl chloroform. It was not indicated whether the new sumfile should replace the current online version, or if all data are to be public. Email confirmation on these matters was sent out on 2001.04.19 by DMB. Files were put online, but no diagnostic checks can be performed until a sumfile is designated and reformatted if necessary. Files will be in AS-IS condition until reply from Isenor. 4/24/01 Bartolacci CTD/BTL/SUM Data Reformatted/OnLine New BTL, CTD, and SUM files reformatted I have reformatted the new bottle sum and ctd files for this cruise. As per Isenor the new sumfile is to be a replacement of the version currently online, and bottle and ctd files should be encrypted until further word from his lab. Notes on reformatting are located in the directory: ar07wh/original/ 2001.04.19 _AR07W_SUM _BOT_CTD _ISENOR and will be documented thru email as well. File BIO97009.zip obtained from ftp-incoming, sent by A. Isenor. (See email below) zip file contains: 97009.mgd unknown file format and data (GPS navigation file?) 97009.sum summary station file, differs from original version sent as per Isenor is to replace current online file. c97009.doc cruise documentation word document format 97009.sea bottle file, needs minor reformatting file contains: CTDPRS, CTDTMP, CTDSAL, CTDOXY, THETA, SALNTY, OXYGEN, SILCAT, PHSPHT, NO2+NO3, CFC- 11, CFC-12, CFC113, TCARBN, CCL4, MCHFRM, ALKALI and QUALT1 *.wct 132 station ctd files BOT: bottle file header was edited to now contain the WHP-ID of AR07W, AR13 and AR27. Dates and Expocode were included in header and a time/date stamp added. Hard carriage returns were removed. Pressure sorted all stations. Several stations contained value columns filled with "******" specifically Alkalinity column (columns 169-176). These characters corresponded to a Q1 byte of 3 or 4. Since no values were given, the *'s were edited to -9.0. occurrances of this edit were: lines 2154, 2124, 2118, 2096, 1767, 1721, 1392, 1102, 1062, 982, 685, 395, 388, 2076-2081, 2445, 2446 Several stations also conatained columns of 7*'s in the MCHFRM column, these corresponded to a Q1 byte of 3 or 4 and were edited to -9.000. occurrances of this edit were: lines 247, 248, 250, 252, 255, 359-368, 763, 765, 767, 768, 922, 927, 932, 2379, 2380, 2381, 2383, 2384, 2386, 2388 Several stations contained entire lines of -9 missing values except for bottle number. These appeared to be bottle numbering place holders and contained no data. These lines were deleted. Following lines were removed for this reason: 264, 359, 382, 405, 842, 864, 907, 908, 962 Edited station 43's cast from 23 to 3 corresponding to the ROSette cast 3. Edited all decimal-leading spaces to a zero (i.e. .790 to 0.790 and -.259 to - 0.259) File was renamed ar07whhy.txt Ran wocecvt with errors pertaining to sumfile missing lat/lons and truncated parameter lists. CTD: Removed hard carriage returns. Edited expocode from 18HU97009/1 to 18HU97009_1 Ran wctcvt with errors pertaining to sumfile missing lat/lons and truncated parameter lists. 132 station files. Zipped file name ar07whct.zip. SUM: Removed hard carriage returns. changed expocode from 18HU97009/1 to 18HU97009_1 changed line numbers to correspond to all WOCE line numbers designated in current online version: stations 1-34 and 117-131 correspond to region AR13 stations 35-44 and 77-116 correspond to region AR27 stations 47-76 corresponds to AR07W (line) Added date/name stamp. Ran sumchk. Errors produced were related to missing lat/lon values and parameter list length, no other formatting errors existed. 11/1/2001 Isenor Final Cruise Report Submitted