CRUISE REPORT HUDSON 93039 NEWFOUNDLAND BASIN WOCE CONTROL VOLUME AR13 5 NOVEMBER - 16 DECEMBER, 1993 A. CRUISE NARRATIVE 1. Highlights a. WOCE Designation: Control Volume 4, Atlantic Repeat Hydrographic Section 13 (AR13) b. Expedition Designation: Hudson 93039 c. Chief Scientist: R. Allyn Clarke Ocean Circulation Division Physical and Chemical Sciences Branch Department of Fisheries and Oceans Bedford Institute of Oceanography P.O. Box 1006 Dartmouth, NS, Canada B2Y 2A4 FAX 902 426 7827 Omnet R.Allyn.Clarke Internet a_clarke@bionet.bio.dfo.ca d. Ship: CSS Hudson e. Ports of Call: November 8-15 BIO, Dartmouth, NS, Canada December 17 BIO, Dartmouth, NS, Canada f. Cruise Dates: November 15, 1993 to December 17, 1993 2. Cruise Summary Information a. Cruise Track A cruise track is included in Figure 1. The jogs in the track were the result of various storms which passed through the region interrupting the program. This map also shows the locations of the North Atlantic Current Meter Mooring Array (ACM6) set from Oceanus in August 1993. The station positions are shown in Figure 2. Some station numbers are indicated for clarity. The various types of stations (float deployment - X, CTD with bottles - ( or CTD - () are indicated. The boundaries of the station occupation region are defined by 38-47 N and 38-50 W. Figure 1. The study area and cruise track. The 200m and 4000m isobaths are also shown. The following symbols are used: _ - midnight ship positions for each day in the study area. Symbol at the Tail of the Bank is on Nov. 17/93. ( - the North Atlantic Current Meter Mooring Array (ACM6) deployed in August/93. + - acoustic sound sources used by the RAFOS floats. Figure 2. Detailed station locations. The 200m, 1000m and 3000m isobaths are also shown. The coastline of Newfoundland is shown in the upper left corner. The following symbols are used to identify station locations: ( - CTD casts with bottles X - RAFOS float deployments ( - CTD casts with no bottles b. Total Number of Stations Occupied 104 full depth CTD stations with up to 20 rosette samples analyzed for CFC's, carbon tetrachloride, methyl chloroform, total carbonate, alkalinity, oxygen, salinity and nutrients 3 2000 metre CTD stations without water sampling 41 RAFOS floats released 600 hours of Acoustic Doppler Current Profiler record 4400 kilometres of deep sea bathymetric sounding c. Floats and Drifters deployed A total of 41 RAFOS floats were released as planned on each of the four full transects of the North Atlantic Current and on a repeat transect on our homeward voyage from the eastern side of our working area. One float lost its weight on launch and failed to descend to its assigned density surface. d. Moorings deployed or recovered No moorings were deployed or recovered. 3. List of Principal Investigators Name Affiliation Responsibility Allyn Clarke Physical and Chemical Sciences CTD, salinity, Bedford Institute of Oceanography shipboard ADCP a_clarke@bionet.bio.dfo.ca Peter Jones Physical and Chemical Sciences oxygen, alkalinity, Bedford Institute of Oceanography carbonate, nutrients, p_jones@bionet.bio.dfo.ca CFCs and halocarbons Tom Rossby Physical Oceanography RAFOS floats University of Rhode Island tom@rafos.gso.uri.edu 4. Scientific Programme and Methods a. Narrative This was primarily a hydrographic survey involving a series of full depth CTD/Tracer stations spaced at 20 miles or less apart. The sections were selected to be either historical sections for which there were a number of earlier occupations or what we thought were TOPEX/POSEIDON ground paths. Unfortunately the program that we were using to predict the ground paths was in error and the actual sections occupied diverge markedly from the orbits, particularly in the north and east of the pattern. The sections enclose four volumes of water. It is hoped that we can use the section data and the boxes to determine the splitting of the Gulf Stream, North Atlantic Current, Labrador Current and Deep Western Undercurrent within this topographically and dynamically complex region. Initial results indicate that this goal is achievable, at least in the three southernmost boxes. It was originally intended to split the southernmost box into two parts with a section crossing the Southeast Newfoundland ridge normally at a location at which the shallowest depth crossing the ridge would have been about 3100 metres. It was hoped that this section would reveal the Gulf Stream flowing eastward south of the ridge and the NA Current flowing to the west on the north side. Time lost due to weather prevented this final section, instead we reoccupied the central part of the mooring section in order to locate the core of the North Atlantic Current to set the final RAFOS floats. The RAFOS float program is lead by Tom Rossby of the University of Rhode Island. The floats were set in and near the North Atlantic Current in order to map the lagrangian velocity fields on isopycnal surfaces in the upper pycnocline throughout the Newfoundland Basin. 5. Major Problems and Goals Not Achieved An unexpected and long term design flaw in the rosette package itself allowed the bottles to be lifted from their pins as the package entered the water. The bottles would then fall onto their spigots, breaking them and were not repairable. This was corrected by strapping the bottles onto their bottom pins using cable ties but not before we had damaged many of our best bottles. Many of the remaining bottles leaked; some consistently (these were replaced) and some intermittently. On many, the tops and bottoms failed to close properly and increasing the strength of the elastics or replacing the seals did not always help. We need to look critically at our bottle design over the winter. There were problems with the firing of bottles when using Rosette #1 (model 1015-24, serial number 400). Subsequent laboratory testing revealed that the rosette would not fire properly in cold water. This rosette was used on stations 1 to 29 inclusive. The mechanical problem with the rosette was not repairable. 6. Other Incidents of Note The hydraulics to open and close the hatch for the boom in the winch room have been destroyed. On several occasions when moving between stations, considerable spray and water entered this hatch when samples were being collected. This is a possible source of contamination of the samples as well as a discomfort to the sampling crew. 7. List of Cruise Participants Name Responsibility Affiliation Larry Bellefontaine Watchkeeper BIO Gerry Boudreau Computers/watchkeeper BIO Rick Boyce Watchkeeper BIO Bruce Carson CTD tech./salts BIO Allyn Clarke Chief Scientist BIO Pierre Clement Nutrients BIO Bob Gershey CFC/Alkalinity/Carbonate BDR Research Mike Hingston CFC/Alkalinity/Carbonate BDR Research Anthony Isenor Data quality/watchkeeper BIO Peter Jones Assistant Scientist BIO Francis Jordan Watchkeeper BIO John Moffatt Oxygens BIO Liam Petrie Watchkeeper BIO Tom Rossby RAFOS URI Clark Rowley RAFOS/watchkeeper URI Ed Verge Watchkeeper BIO Frank Zemlyak CFC/Alkalinity/Carbonate BIO BIO Bedford Institute of Oceanography P.O. Box 1006 Dartmouth, NS, CANADA B2Y 2A4 BDR BDR Research Ltd. Box 652, Station 'M' Halifax, N.S., Canada, B3J 2T3 URI University of Rhode Island Graduate School of Oceanography South Ferry Road Narragansett, RI 02882 B. UNDERWAY MEASUREMENTS 1. Navigation and Bathymetry (Anthony W. Isenor) The navigation system onboard CSS Hudson consists of a Trimble Navigation Loran- GPS 10X decoder and AGCNAV. The decoder receives the satellite fixes and decodes the signals to obtain latitude, longitude and time. The decoder signals are about 1 Hz. All navigation data are logged directly to a Micro VAX II. AGCNAV is a PC based display, and way-point setting software package developed at the Atlantic Geoscience Centre at BIO. The software runs on a PC and graphically indicates ship position, way-points, course, speed, etc. The echo sounder system used for collecting bathymetric data consisted of a Universal Graphic Recorder model UGR-196C-11 connected to a hull mounted 12kHz transducer. The transducer beam width is 15 degrees. The sweep rate of the record was adjusted throughout the course of data collection to aid in identifying the bottom signal. The recorder was also linked to a clock, and thus could indicate 5 minute intervals on the sounder paper. The system was used to collect 10 minute bathymetric soundings during the occupation of AR13. 2. Acoustic Doppler Current Profiler (Murray Scotney) The Hudson was equipped with a hull mounted RDI acoustic doppler current profiler. The transducer (serial number 177) had SC ADCP electronics (serial number 172) converted for ship board use. Logging, using Transect software, was started on November 15, 1993 at 1830Z in Halifax Harbour (Bedford Basin). The configuration of the equipment results in a bin length of 8 metres and a total of 49 bins. The raw data are stored to disk and backed up every two days. Two days of logging creates about 30 Mbytes of data. The data are also averaged in real-time over 10 minute intervals and vertically over 8m bins. The first bin is centred at 18m, while the last is centred at 402m. ADCP logging was stopped on December 14, 1993 at 1817Z. 3. Thermosalinograph No instrument was used. 4. XBT and XCTD No XBT or XCTD probes were dropped. 5. Meteorological observations Routine reporting of meteorological variables was carried out by the ship's crew. 6. Atmospheric Chemistry There was no atmospheric chemistry programme. C. HYDROGRAPHIC MEASUREMENTS - DESCRIPTIONS, TECHNIQUES AND CALIBRATIONS 1. CTD Measurements (Allyn Clarke and Anthony Isenor) a. Description of the Equipment and technique The CTD measurements are made with a standard SEABIRD model 9Plus CTD (serial number 9P 5676-0249, BIO System #2) that is equipped with model 3-02/F temperature sensor (S/N 031376), model 4-02/0 conductivity sensor (S/N 041076), a paroscientific digiquartz model 410K-105 pressure sensor (S/N 49258) and model 13-02 dissolved oxygen sensor (S/N 130284). All but the pressure sensor are mounted in a duct through which a pump pulls sea water. Hence the water flow past the actual sensors is independent of the lowering rate; this simplifies the data processing considerably. The Seabird CTD is mounted vertically within the BIO designed and built CTD/Rosette platform. This platform consists of a central 10 inch diameter aluminum tube which contains at its upper end a space to contain the sea unit for a General Oceanics Model 1015-24 bottle rosette unit and at its bottom end a smaller well that contains a General Oceanics model 6000 12 Khz pinger unit. The space between the central 6 inch diameter pinger well and the 10 inch outer tube is filled with lead and the bottom end of the tube is covered with a fibreglass nose cone that is acoustically transparent. Two rosettes were used during this cruise. For stations 1 to 29 inclusive, BIO Rosette #1 (model 1015-24, serial number 400) was used. For station 30 to end, BIO Rosette #3 (model 1015-24, serial number 1348) was used. The rosette units were changed due to problems with mis-tripped bottles. Subsequent laboratory cold water tests of Rosette #1 indicated inconsistent firing of the bottle trip mechanism. The rosette was considered to be unrepairable and consequently discarded. The CTD sea unit is held in a 6 inch diameter aluminum tube that is welded to the central tube. The CTD sensors are held in a heavy aluminum cage of approximately 6 inches in diameter which is welded to the opposite side. Around the mid point and the top of the central column are attached aluminum rings on which 20, 8 litre sampling bottles are attached. The number of bottles was set by the maximum diameter that we felt comfortable handling through the doors of our enclosed winch room on Hudson. The bottles are somewhat protected from damage by a metal band with a diameter a bit larger than the outer diameter of the bottles when they are mounted. This band is situated just below the bottom of the bottles. The rosette bottles are of a BIO design that are now being made and manufactured by Brooke Ocean Technology, a local ocean engineering company. They differ from standard rosette bottles in that their tops and bottoms rotate about a horizontal axis to close. The energy to close the bottles is provided by stretching rubber tubing between the outside edges of the two lids along the outside surface of the bottle. This design has two advantages. First, the tubing is not inside the bottle either before or after the water sample has been captured. Second, the tubing is applied after the bottle is cocked in the rosette tripping mechanism and hence one doesn't have to fight the pull of the tubing when cocking the rosette. b. Sampling Procedure and data processing techniques The CTD is deployed with a lowering rate of 60 metres/min (40 metres/min in the upper 200 metres or deeper if the conditions are rough). It is recovered at a rate of 90 metres/min (40 metres/min when deeper than 4000 metres or when conditions are rough) The CTD data is recorded onto disk by a 486 computer using SEABIRD SEASOFT Version 4.018 software. A screen display of temperature, oxygen and salinity profiles vs pressure are used to decide the depths at which bottles are to be tripped on the up cast. The bottles are tripped using the enable and fire buttons on the SEABIRD deck unit. During post-processing, the SEASAVE software stores 35 scans at each bottle trip within a separate file. At the end of the station, all the data and header files associated with the station are transferred immediately via ethernet to a second 486 computer. The SEASAVE software is used on this second machine to create 1 and 2 dbar processed data files, an IGOSS TESAC message and a processed rosette trip file. All the raw and processed data files associated with the station are then transferred to the ship's MicroVax computer for archive and subsequent access and distribution to various users on the vessel. All TESAC messages are placed on the GTS after cruise completion. The data processing takes the following steps: DATCNV Converts the raw data to physical parameters. SPLIT Splits the data into DOWN and UP cast. WILDEDIT For every block of 12 scans, flags all scans whose pressure, temperature, conductivity and oxygen values differ from the mean by more than 2 standard deviations. Recomputes mean and standard deviation from unflagged data then marks as bad all scans exceeding 4 standard deviations from these new values. FILTER Low pass filter pressure and conductivity channels to time match parameters for salinity computation. Time constant used for conductivity is 0.045 seconds, for pressure 0.150 seconds. LOOPEDIT Marks as bad, all cycles on the down trace for which the vertical velocity of the CTD unit is less than 0.1 metres/sec. ALIGNCTD Aligns the temperature, conductivity and oxygen values relative to the pressure values accounting for the time delays in the system. Time offsets of 0.010 secs for conductivity, 0.000 secs for temperature and 3.000 secs for oxygen are used. CELLTM A recursive filter used to remove the thermal mass effects from the conductivity data. Thermal anomaly amplitude and time constants of 0.0300 and 9.0000 were used. DERIVE Computes oxygen values. BINAVG Averages the down cast into 1 or 2 dbar pressure bins. (Note: The procedure to produce the 2 dbar averages takes about 5% of the total processing time). DERIVE Computes salinity, potential temperature and sigmatheta. c. Calibration data The CTD calibrations used during this cruise were supplied by Seabird Electronics and are as follows: Conductivity Sensor 041076 (All stations) Conductivity = (afm + bf2 + c + dt)/[10(1-9.57(10-8)p)] where f is the frequency m = 4.1 p is pressure in dbars t is the temperature a = 2.21442246e-5 b = 5.67193159e-1 c = -4.19781901 d = -1.23661793e-4 Temperature Sensor 031376 (All stations) T = 1/{a + b[ln(fo/f)] + c[ln2[fo/f] + d[ln3(fo/f)]} - 273.15 where ln indicates a natural logarithm f is the frequency a = 3.68093833e-3 b = 6.00726775e-4 c = 1.51819564e-5 d = 2.19535579e-6 fo = 6482.31 Pressure Sensor 49258 (All stations) pressure = c (1 - To2/T2) (1 - d[1 - To2/T2]) where T is the pressure period c = c1 + c2 U + c3 U2 d = d1 + d2 U To = T1 + T2 U + T3 U2 + T4 U3 + T5 U4 U is the temperature c1 = -26446.08 psia c2 = -5.19681e-1 psia/deg C c3 = 8.16840e-3 psia/deg C2 d1 = 0.033189 d2 = 0 T1 = 30.78782 micro sec T2 = -5.31736e-4 micro sec/deg C T3 = 4.68447e-6 micro sec/deg C2 T4 = -4.55823e-10 micro sec/deg C3 T5 = 0 Oxygen Sensor 130284 (All Stations) oxygen = A B C where A = {Soc [oc + Tau d(oc)/dt] + Boc} oc is the current from the oxygen sensor d(oc)/dt is the time derivative of oc Soc = 2.5328 Tau = 2.0 Boc = -0.0322 oc = Mv + b m = 2.4528e-7 b = -3.9245e-9 B = OXYSAT(t,s) t is temperature s is salinity C = e{tcor [T + wt (To-T)] + pcor p} e is natural log base tcor = -0.033 pcor = 1.5e-4 p is the pressure wt = 0.670 To oxygen sensor internal temperature T is the water temperature, where T = kv + c k = 8.9625 c = -6.9161 v is the oxygen temperature sensor voltage signal d. Final Post-Cruise CTD Calibrations d.1 Temperature Calibration Temperature Sensor 031376 Thermometer racks containing two protected digital deep sea thermometers and one unprotected mercury in glass thermometer were mounted on the deepest and the fourth from the deepest rosette bottle. The CTD watches were instructed to allow these bottles to sit at the selected depth for five minutes to allow the thermometers to equilibrate to the in-situ temperature. This practice was always followed with the deepest bottle; however, because of the rosette misfiring, the upper thermometers were frequently not provided with equilibration time. However, most readings were obtained from deep within the North Atlantic Deep Water where the temperature change over the previous five minutes would be only a few tenths of a degree. Nearly all of the thermometer values are between 2.3 and 2.8°C. Results from comparision with digital thermometers are as follows: Serial Number Number of Values Thermometer - CTD Median 000T345 97 -0.0101 (C1 000T347 95 -0.0047 (C 000T348 82 -0.0050 (C2 000T354 90 -0.0054 (C Notes: 1. Thermometers 000T345 and 000T347 were paired. The median of the difference T345-T347 was -0.0043 °C. 2. Thermometers 000T348 and 000T354 were paired. The median of the difference T348-T354 was 0.0001 °C. Both the CTD and the digital thermometers were recalibrated during the winter of 93/94. The newer calibrations were used in correcting the thermometers. The CTD temperatures were based on the pre-cruise calibration. The precruise (17/5/93) CTD calibration shows that the CTD is reading 0.0007°C low in the temperature range -2 to 5, no offset in the range 10 to 15. The post cruise CTD calibration (18/1/94) has the CTD temperature low by 0.0009°C in the temperature range -2 to 5, increasing to be low by 0.0017°C in the range 20-25. The comparison with the digital thermometers indicates that the CTD is reading high by 0.006°C. The results from the digital thermometers are inconsistent with the pre and post cruise calibration. Final CTD temperature correction: CTD T no correction applied d.2 Pressure Calibration Pressure Sensor 49258 The median differences between the thermometric pressure and the CTD pressure are as follows: Serial Number Number of Values Thermometer P - CTD Median 0011745 56 -6.4 dbars 0011749 23 -2.6 dbars Given the precision of reading an unprotected thermometer (0.02°C) and the accuracy of its calibration compared with the magnitude of the reading, we are not certain whether either difference is significantly different from zero. All of these values were obtained for pressures between 4000 and 5400 dbars. Our calibration of the CTD pressure sensor in winter 93/94 indicates that at room temperature the pressure error is less than 0.84 dbars. Final CTD pressure correction: CTD P no correction applied d.3 Salinity Calibration Conductivity Sensor 041076 The pre-cruise laboratory calibration (17/05/93) shows that the CTD salinities are low by 0.0025, 0.0045 and 0.0048 for bath temperatures of 2, 10 and 20°C respectively. The post-cruise calibration (18/01/94) shows the CTD salinities are low by 0.0047, 0.0083 and 0.0087 for bath temperatures again of 2, 10 and 20°C respectively. The median value from an analysis of the water sample - CTD salinity differences suggests that the CTD salinities are low by 0.0076. Because of leaking and mis-tripped rosette bottles, the scatter about this median is quite large. On completion of the 1994 and 1995 cruises in the same area (18HU94030 and 18HU95003), we began looking at cruise to cruise differences in the deep water temperatures and salinities. By 1995 we had replaced our rosette bottles and were no longer plagued with problems with leaking and mis-tripped rosette bottles. Our 1995 CTD data set was well constrained by the rosette samples. We wished to use this data set as a guide to the calibration of the 1993 and 1994 cruises. In the southwest corner of our station array, the deep water T/S distributions are very tight within a given cruise. The deep water (>2500 dbars) T/S distribution (as measured by the CTD's) in the southwest corner of our array was 0.0051 less saline in 1993 than in 1995. If we assume that this part of the ocean did not change over the 17 months separating the cruises, this suggests the CTD was reading 0.0051 low during this part of 93039. We then restricted ourselves to the same group of stations in the southwest corner and did a modal analysis of the rosette sample - CTD salinities for the samples deeper than 2500 dbars. This analysis suggested that the CTD salinity was 0.0056 low. We then analyzed both the 1993 - 1995 CTD and the 1993 rosette samples - CTD differences as functions of station number or location, again restricting our attention to samples deeper than 2500 dbars. These analysis showed that the 1993 CTD was reading lower in salinity as time progressed; however, the scatter in the results from the individual stations were such that the changes could either be interpreted as a steady change over time or a couple of step changes followed by periods where the sensor remained steady. We ultimately decided to treat the change as steady as a function of station number. For any given station, the difference between a correction that would be estimated assuming this linear relation with station number and one assuming that the correction makes step changes and then stays constant for 30-40 stations is less than 0.001. The CTD laboratory calibrations and the comparisons with the 1995 T/S distributions both suggest somewhat smaller corrections than the comparisons with the rosette samples. Virtually all the deep rosette samples will have been hauled through saltier upper waters and hence one might expect our leaking problems to result in the rosette samples being biassed high. Consequently we have chosen our final CTD salinity correction more consistent with the 1995 T/S distributions than the rosette samples. The final CTD calibration is: corrected CTD salinity =uncorrected CTD salinity + 0.0049 + X * 0.000017 where X is the station number. d.4 Oxygen Calibrations We have no method of calibrating the oxygen sensors in the laboratory, therefore, we have to rely on fitting the CTD oxygen values to those obtained from the rosette samples. This exercise is made difficult because of the malfunctioning of the rosette itself and also because many of the bottles were not closing properly. In addition, the CTD oxygen values exhibit considerable hysteris between down and up cast. As a first step in the calibration process, we scanned the 1 dbar down tracers to choose the appropriate level to match the level at which the rosette bottles were tripped on the up cast. The matching was done on the basis of locating the same in-situ temperature within 50 dbars of the pressure of the rosette trip. This procedure does add an additional uncertainty into the process since the CTD can be sampling different water masses on the up cast as were sampled on the down. The resulting data set was scanned and all levels in which the difference between the rosette salinity sample and the corresponding CTD salinity from the down were removed. The 1 dbar down traces also contained levels near the surface for which the oxygen sensor had not yet stabilized. We removed all levels for which the down trace was at 25 dbars or less to remove this problem. The data was then examined using linear regressions. Bottle oxygen - CTD oxygen (down trace) vs CTD Oxygen (down trace) Oxygen (bot-down) = 0.5950 - (0.20269*oxygen down) r = 0.77 Bottle oxygen - CTD oxygen (down trace) vs pressure (down trace) Oxygen (bot-down) = -0.5054 - (.000067*pressure) r = 0.35 Bottle oxygen - CTD oxygen (down trace) vs CTD Temperature (down trace) Oxygen (bot-down) = -1.0365 + (0.04283*temperature down) r = 0.70 When the regression against Oxygen is applied to the data, then 50% of the residual bottle - corrected oxygen lie between ±0.06. These residual differences were then further regressed against temperature to give: Bottle oxygen - corrected CTD oxygen (down trace) vs CTD Temperature (down trace) Oxygen (bot-corrected down) = -0.0321 + (0.00638*temperature) r = 0.16 This regression has such a small r value that it does not seem wise to apply it. We will therefore correct oxygen by applying only the correction against itself. Final CTD oxygen corrections: CTD O2 = 0.79731 * CTD O2 + 0.5950 (NOTE: calibration expressed as ml/l) 2. Salinity (Bruce Carson) a. Description of Equipment and Technique Salinity samples are analyzed on one of two Guildline Autosal model 8400 salinometers. Samples are drawn in 150 ml medicine bottles. New caps, equipped with plastic liners, are placed on the sample bottles for each use. The salinometer cell is filled and rinsed three times with sample water before readings are recorded. Two salinometer readings are recorded for every sample and standardization. If the values are fluctuating, more readings are taken. b. Sampling Procedure and Data Processing Technique Salinity samples are drawn into 150 ml medicine bottles after three rinses. The bottles are filled up to the shoulders and then capped with new caps with plastic liners. Files for each separate run are prepared. These files consist of various metadata (date, cruise, lab temperature, geographic location, operator, etc.) and sample specific data such as the bath temperature, sample ID number, and average conductivity ratio. A PC based program computes the salinity using average conductivity ratio of the runs and the standard IAPSO formula. Any changes in the salinometer readings between successive standardizations is assumed to have occurred as a linear drift of the instrument. Thus, the program applies a correction to the ratios, which varies linearly with the samples analyzed. The salinity data is then placed in the water sample database. c. Laboratory and Sample Temperatures Full cases of samples are taken from the winch room to the GP lab where they are left for a period of at least 10 hours to equilibrate to laboratory temperature before being analyzed. The baths in the two salinometers were kept at 21°C and 24°C. The salinometer which was just above the current laboratory temperature would be the one that was used for any given run of samples. d. Replicate analysis A duplicate salinity sample is drawn from one of the rosette bottles on every cast. Statistics of the duplicates are as follows. Statistics related to the difference in duplicate values was determined using the absolute value of the difference. The duplicate values are given in Table C.1. Statistic Value Number of Duplicates 103 Minimum 0 Maximum 0.5821 Mean 0.0072 Median 0.0004 Standard Deviation 0.0576 Table C.1 Duplicate water sample salinity values. Sample ID Number Salinity ---------------- -------- 130501 34.9554 130501 34.9559 130502 34.9564 130502 34.9571 130521 33.0892 130521 33.0894 130526 34.8654 130526 34.8656 130541 35.0071 130541 35.0073 130549 34.9185 130549 34.9207 130575 34.9034 130575 34.9062 130609 34.9077 130609 34.9101 130644 36.0734 130644 36.0734 130676 34.9431 130676 34.9437 130703 35.4246 130703 35.4259 130709 34.8886 130709 34.8887 130740 34.9694 130740 34.9698 130753 34.9422 130753 34.9424 130788 36.4813 130788 36.4814 130789 34.8844 130789 34.8847 130812 34.9524 130812 34.9542 130844 35.0774 130844 35.0776 130850 34.8897 130850 34.8900 130871 34.8995 130871 34.8996 130889 34.8816 130889 34.8816 130911 34.8854 130911 34.9011 130940 34.9499 130940 34.9503 130951 34.9102 130951 34.9107 130990 34.8915 130990 34.8916 131015 34.9366 131015 34.9368 131031 34.9048 131031 34.9050 131060 34.9523 131060 34.9523 131070 34.8995 131070 34.9006 131091 34.9089 131091 34.9093 131114 34.9509 131114 35.0222 131133 34.9546 131133 34.9552 131149 34.9078 131149 34.9079 131169 35.0347 131169 35.0365 131191 34.9143 131191 34.9165 131213 34.9371 131213 34.9375 131229 34.9160 131229 34.9162 131249 34.8761 131249 34.8764 131271 34.5481 131271 34.5495 131277 34.8056 131277 34.8061 131286 33.9684 131286 33.9687 131290 33.2231 131290 33.2232 131299 34.4532 131299 34.4538 131307 34.8539 131307 34.8541 131320 34.8569 131320 34.8573 131336 34.9053 131336 34.9055 131352 34.8662 131352 34.8664 131377 34.9224 131377 34.9225 131382 34.9034 131382 34.9041 131404 34.9051 131404 34.9058 131422 34.9052 131422 34.9077 131447 34.9186 131447 34.9197 131465 34.9556 131465 34.9596 131482 34.9162 131482 34.9162 131507 34.9091 131507 34.9147 131522 34.8960 131522 34.8966 131543 34.8993 131543 34.8996 131562 35.2404 131562 35.2409 131582 35.2050 131582 35.2085 131602 34.8988 131602 34.8994 131623 34.8969 131623 34.8969 131642 34.9054 131642 34.9055 131662 34.8982 131662 34.8986 131683 34.8968 131683 34.9004 131702 34.8964 131702 34.8964 131722 34.8974 131722 34.8974 131747 34.9217 131747 34.9221 131766 34.9249 131766 34.9250 131786 34.8715 131786 34.8727 131798 34.8525 131798 34.8525 131805 34.8721 131805 34.8721 131812 33.6998 131812 34.2819 131816 33.6846 131816 33.6846 131818 34.2560 131818 34.2566 131822 34.2690 131822 34.2692 131826 34.4869 131826 34.4871 131833 33.3330 131833 33.3332 131837 33.3054 131837 33.3056 131838 34.8368 131838 34.8372 131842 33.9604 131842 33.9612 131846 34.8726 131846 34.8730 131853 34.8843 131853 34.8856 131859 34.8065 131859 34.8083 131869 33.3700 131869 33.3706 131875 34.0194 131875 34.0214 131877 34.8487 131877 34.8491 131888 34.9134 131888 34.9138 131921 34.8945 131921 34.8946 131941 34.8949 131941 34.8950 131961 34.8929 131961 34.8931 131987 34.9346 131987 34.9348 132003 34.9115 132003 34.9119 132021 34.9000 132021 34.9004 132044 34.9253 132044 34.9256 132061 34.9020 132061 34.9026 132084 34.9535 132084 34.9537 132101 34.9340 132101 34.9344 132123 34.9045 132123 34.9045 132144 34.9203 132144 34.9231 132161 34.8951 132161 34.8955 e. Standards Used The salinometer was standardized using IAPSO standard water, Batch P120, prepared on April 6, 1992. Standardization with a new ampoule was carried out at the beginning, middle and end of every 32 bottle case and at intermediate points during a case if instrument drift was suspected. 3. Oxygen (Pierre Clement) a. Description of Equipment and Technique The automated procedure to follow is based on the method developed by the Physical and Chemical Services Branch (PCS) of the Bedford Institute of Oceanography (BIO) (Levy et al. 1977). The PCS procedure is a modified Winkler titration from Carritt and Carpenter (1966), using a whole bottle titration. In this method there is no starch indicator and a wetting agent (Wetting Agent A, BDR) is introduced to reduce bubble formation. The full description of the system and method can be found in Jones, et al. (1992). In summary the automated titration system consists of an IBM PC linked to a Brinkmann PC800 colorimeter and a Metrohm 655 Multi-Dosimat Automatic Titrator. The PC talks to the peripherals through a Data Translation, DT2806 and three Data Translation DTX350s. b. Sampling Procedure and Data Processing Technique The sampling bottles are 125ml Iodine flasks with custom ground stoppers (Levy et al. 1977). The flasks volumes are determined gravimetrically. The matched flasks and stoppers are etched with Identification numbers and entered into the Oxygen program database. For this cruise 8 litre Niskin bottles were used to obtain the original sample. Then, the oxygen subsamples are drawn through the bottles spigot with a latex or silicone tube attached so as to introduce the water to the bottom of the flask. Once the flow is started the flask is inverted to ensure that there is no air trapped in the tube, then the tube partially pinched to reduce the flow rate and the flask reoriented and filled to overflowing. The flow is allowed to continue until at least two to three volumes have run through then the flask slowly retracted with continuous low flow to ensure that no air gets trapped in the flask. The flask is then brought to the reagent station and one ml of the Alkaline Iodide and Manganous Chloride Reagents are added and the stoppers carefully inserted, again ensuring that no air gets into the flasks. The flasks are shaken then carried to the lab for analysis. c. Replicate analysis A duplicate oxygen sample is drawn from one of the rosette bottles on every cast. Statistics of the duplicates are as follows. Statistics related to the difference in duplicate values was determined using the absolute value of the difference. In total, 155 duplicate samples were drawn. Of these samples five (sample numbers 130711, 130733, 130743, 130754 and 130849) did not have a duplicate because one or both values were missing or bad. The valid duplicate sample values are given in Table C.2. Number of valid duplicates = 150 Median of [(absolute difference/sample mean concentration) * 100%] = 0.28 % Statistic Value (ml/l) Value ((moles/kg) Minimum 0 0 Maximum 0.469 20.4 Mean 0.032 1.4 Median 0.018 0.8 Standard Deviation 0.062 2.7 Table C.2 Duplicate water sample oxygen values in (moles/kg. Sample ID Number Oxygen ((moles/kg) ((moles/kg) ---------------- ----------------- 130503 180.8 130503 180.8 130522 317.5 130522 318.4 130525 291.6 130525 292.0 130538 291.7 130538 292.3 130557 257.6 130557 259.4 130574 269.5 130574 270.1 130599 268.0 130599 268.5 130611 272.2 130611 272.4 130644 170.7 130644 170.7 130659 248.4 130659 248.5 130673 273.4 130673 273.6 130689 265.8 130689 265.9 130786 208.8 130786 208.8 130792 273.7 130792 273.9 130813 272.2 130813 272.3 130841 259.5 130841 261.4 130880 245.3 130880 246.0 130890 267.1 130890 268.4 130909 267.4 130909 268.9 130935 273.0 130935 274.5 130949 268.6 130949 268.8 130988 230.5 130988 230.8 130989 268.4 130989 269.6 131019 255.9 131019 256.3 131029 271.4 131029 273.9 131061 259.2 131061 260.5 131071 278.8 131071 279.8 131092 271.1 131092 271.8 131106 225.2 131106 227.1 131109 272.0 131109 272.9 131127 227.0 131127 229.1 131133 274.1 131133 275.6 131141 248.9 131141 249.5 131152 272.2 131152 273.3 131165 144.4 131165 145.4 131170 288.0 131170 289.4 131180 268.1 131180 268.5 131189 262.6 131189 264.0 131199 276.9 131199 278.1 131211 283.9 131211 284.5 131226 190.2 131226 190.7 131232 287.3 131232 287.3 131234 295.5 131234 297.2 131250 296.7 131250 297.0 131263 311.5 131263 312.0 131269 292.6 131269 292.8 131279 298.0 131279 299.6 131284 292.0 131284 294.1 131291 324.7 131291 324.7 131296 318.5 131296 319.0 131297 351.9 131297 353.0 131299 286.3 131299 287.3 131306 290.3 131306 291.6 131311 315.8 131311 316.7 131319 292.3 131319 292.4 131325 283.3 131325 284.8 131332 298.7 131332 299.1 131348 292.4 131348 292.7 131358 235.8 131358 236.4 131371 287.4 131371 287.5 131373 291.3 131373 293.0 131384 288.6 131384 289.1 131385 280.9 131385 282.3 131406 277.6 131406 284.3 131412 300.0 131412 300.8 131423 288.0 131423 288.3 131425 279.7 131425 279.8 131452 296.5 131452 297.0 131460 183.3 131460 183.7 131462 280.1 131462 281.7 131464 280.2 131464 297.8 131485 269.0 131485 269.0 131487 281.8 131487 282.4 131506 275.5 131506 279.1 131516 272.1 131516 273.5 131523 282.2 131523 283.9 131524 282.1 131524 283.5 131525 270.1 131525 270.6 131553 283.1 131553 284.6 131556 213.6 131556 214.0 131563 281.5 131563 281.5 131564 222.1 131564 222.8 131588 280.4 131588 281.6 131594 225.6 131594 226.2 131605 282.8 131605 284.5 131607 279.0 131607 279.1 131623 283.0 131623 301.8 131633 286.7 131633 286.8 131643 280.5 131643 283.2 131644 200.4 131644 201.7 131663 280.1 131663 282.5 131673 281.2 131673 281.3 131686 267.3 131686 271.2 131696 238.1 131696 239.2 131703 280.7 131703 280.8 131704 279.5 131704 280.2 131723 290.5 131723 290.9 131725 286.0 131725 286.3 131742 293.3 131742 294.6 131743 289.0 131743 289.1 131762 283.3 131762 283.5 131763 280.1 131763 281.6 131789 305.2 131789 306.5 131795 250.1 131795 252.4 131802 280.9 131802 281.5 131806 272.0 131806 272.9 131810 241.8 131810 244.0 131815 288.8 131815 288.8 131820 318.7 131820 319.8 131824 303.1 131824 323.5 131828 317.7 131828 320.1 131831 268.8 131831 270.9 131835 271.9 131835 273.0 131840 292.0 131840 292.7 131843 301.6 131843 303.7 131847 286.9 131847 287.9 131852 297.7 131852 298.2 131864 289.2 131864 292.8 131868 282.3 131868 282.6 131874 287.3 131874 287.7 131882 292.1 131882 292.6 131885 290.6 131885 293.2 131901 293.4 131901 294.1 131902 287.1 131902 287.4 131924 283.5 131924 284.8 131934 290.5 131934 292.4 131943 282.9 131943 284.8 131944 282.7 131944 283.0 131965 282.2 131965 282.8 131970 294.5 131970 295.7 131984 281.0 131984 282.1 131989 284.0 131989 284.3 132001 285.5 132001 286.5 132002 285.1 132002 285.8 132026 279.9 132026 281.2 132036 239.0 132036 240.4 132041 287.8 132041 289.8 132042 285.1 132042 286.4 132065 280.6 132065 282.6 132076 204.3 132076 205.1 132081 284.6 132081 285.1 132082 283.9 132082 284.0 132106 289.4 132106 289.4 132112 217.9 132112 219.4 132121 273.5 132121 279.0 132121 1602.6 132122 278.0 132122 278.5 132141 282.3 132141 284.7 132142 280.2 132142 280.5 132165 280.1 132165 280.6 132175 184.0 132175 184.5 4. Nutrients (Pierre Clement) a. Description of Equipment and Technique Nutrient concentrations are determined using a Technicon Autoanalyser II. The chemistries are standard Technicon (Silicate 186-72W, Phosphate 155-71W, Nitrate/Nitrite 158-71W) except for Phosphate which is modified by separating the Ascorbic Acid (4.0 gms/L) from the Mixed Reagent. This alteration is achieved by introducing the modified Mixed Reagent instead of water at the start of the sample stream at 0.23 ml/min. and the Ascorbic Acid is pumped into the stream between the two mixing coils at 0.32 ml/min.. b. Sampling Procedure and Data Processing Technique Duplicate nutrient subsamples are drawn into 30 ml HDPE (Nalge) wide mouth sample bottles from 8 L Niskins. The bottles are 10% Hcl washed, rinsed once with tap water, three times with Super-Q and oven dried at >100 Degrees F. A sample run includes six Working Standards run at the beginning and end. Duplicate Check Standards are run every 16 samples followed by blanks as a Baseline Check. These Standards are made up in 33 ppt NaCl (VWR,Analar grade) as is the wash water. The Standards are tested against CSK Solution Standards (Sagami Chemical Center, Japan). Analog data is converted to digital, processed and statistics calculated by a Pascal 6.0 in house program (Logger) on a PC. Chart recordings, hard copy and disk copies of the data are kept for reference. c. Replicate analysis Duplicate samples are drawn from each rosette bottle on every cast. Statistics of the duplicates are as follows. All values are given in ( moles/kg. Statistics related to the difference in duplicate values was determined using the absolute value of the difference. Precision is determined based on the (standard deviation/mean concentration) * 100%. Duplicate values are given in Table C.3. Statistic Silicate Phosphate NO2+NO3 mean concentration 12.279 1.057 15.533 mean difference 0.146 0.016 0.150 median difference 0.066 0.010 0.111 standard deviation of difference 0.283 0.044 0.152 precision 2.30 % 4.163 % 0.978 % Table C.3 Duplicate water sample values for silicate, phosphate and NO2+NO3, in (moles/kg. Sample ID Number Silcate Phosphate NO2+NO3 --------- ------- --------- ------- 130521 8.54 .95 7.09 130521 8.63 .95 7.26 130522 8.57 .93 6.86 130522 8.63 .96 6.99 130523 6.11 .79 4.96 130523 6.12 .84 4.92 130524 2.60 .50 1.34 130524 2.66 .54 1.36 130525 9.94 1.11 16.98 130525 10.02 1.13 16.69 130526 9.92 1.12 16.89 130526 9.94 1.12 17.07 130527 9.83 1.09 16.83 130527 9.86 1.10 16.89 130528 10.25 1.10 16.62 130528 10.33 1.13 16.91 130529 10.50 1.07 16.59 130529 10.73 1.08 16.27 130530 11.41 1.10 16.08 130530 11.45 1.12 16.17 130531 10.10 1.03 11.74 130531 10.12 1.03 11.78 130532 10.16 1.02 11.74 130532 10.55 1.04 11.53 130533 8.89 .98 8.39 130533 9.01 .97 8.28 130534 4.53 .63 3.18 130534 4.55 .64 3.11 130535 12.61 1.12 17.06 130535 13.01 1.12 16.72 130536 10.89 1.12 17.09 130536 10.93 1.12 16.89 130537 10.36 1.12 16.53 130537 10.56 1.09 16.51 130538 10.28 1.12 16.63 130538 10.28 1.10 16.70 130539 9.88 1.11 16.60 130539 9.97 1.11 16.93 130540 11.53 1.19 18.02 130540 11.68 1.18 18.28 130541 11.93 1.23 18.71 130541 11.97 1.20 18.61 130542 12.75 1.28 19.53 130542 12.79 1.31 19.31 130543 11.04 1.21 16.53 130543 11.05 1.16 16.59 130544 9.62 1.08 13.02 130544 9.69 1.08 13.01 130545 6.68 .85 10.31 130545 6.78 .88 10.49 130546 1.74 .38 1.06 130546 1.95 .37 1.14 130547 1.57 .30 0.00 130547 1.62 .31 0.00 130549 15.94 1.12 16.65 130549 16.06 1.07 16.47 130550 16.25 1.20 17.46 130550 16.50 1.20 17.20 130551 16.87 1.21 17.98 130551 17.01 1.23 18.12 130552 16.09 1.20 18.26 130552 16.11 1.25 18.13 130553 16.00 1.18 18.07 130553 16.02 1.20 17.80 130554 12.64 1.15 17.36 130554 12.91 1.15 17.96 130555 11.95 1.16 17.61 130555 12.20 1.16 17.79 130556 11.74 1.18 17.95 130556 11.86 1.16 18.12 130557 11.77 1.19 18.15 130557 11.90 1.18 18.39 130558 11.80 1.19 18.27 130558 11.89 1.19 18.25 130559 12.19 1.23 18.77 130559 12.27 1.24 18.88 130560 12.59 1.28 19.31 130560 12.73 1.29 19.94 130561 13.15 1.32 20.53 130561 13.32 1.32 20.42 130562 12.00 1.22 18.58 130562 12.05 1.20 18.45 130563 12.03 1.23 18.48 130563 12.14 1.24 18.55 130564 13.69 1.43 21.65 130564 13.90 1.41 22.32 130565 11.34 1.21 17.02 130565 11.54 1.23 17.13 130566 9.83 1.09 15.09 130566 9.84 1.10 15.09 130567 1.37 .30 0.00 130567 1.42 .28 0.00 130569 23.31 1.20 17.28 130569 23.38 1.17 17.34 130570 17.17 1.14 16.52 130570 17.30 1.13 16.45 130571 16.54 1.08 17.07 130571 16.68 1.09 17.19 130572 18.00 1.15 17.92 130572 18.11 1.15 18.12 130573 17.71 1.19 17.94 130573 17.91 1.17 18.04 130574 14.29 1.17 17.72 130574 14.47 1.19 17.72 130575 11.44 1.13 16.87 130575 11.45 1.11 17.31 130576 10.88 1.12 17.07 130576 11.06 1.14 17.27 130577 11.13 1.14 17.92 130577 11.25 1.15 17.99 130578 11.02 1.14 17.80 130578 11.04 1.17 18.03 130579 10.52 1.14 17.13 130579 10.54 1.12 17.49 130580 10.84 1.15 17.61 130580 10.95 1.15 17.56 130581 12.26 1.25 19.44 130581 12.62 1.24 19.36 130582 10.56 1.16 17.17 130582 10.65 1.16 17.29 130583 13.09 1.37 21.16 130583 13.16 1.37 21.21 130584 13.31 1.40 21.26 130584 13.38 1.38 21.05 130585 7.19 .97 15.50 130585 7.19 .98 15.55 130586 6.60 .90 9.41 130586 6.62 .90 9.44 130587 1.16 .33 0.00 130587 1.22 .30 0.00 130588 1.19 .30 0.00 130588 1.27 .30 0.00 130589 21.55 1.24 18.64 130589 21.71 1.25 18.45 130590 19.19 1.24 19.07 130590 19.25 1.22 19.03 130591 17.01 1.24 18.85 130591 17.07 1.22 19.04 130593 18.37 1.31 20.17 130593 18.49 1.30 20.00 130594 13.92 1.25 19.45 130594 13.96 1.25 19.63 130595 13.50 1.25 19.56 130595 13.55 1.25 19.58 130596 12.08 1.21 19.61 130596 12.11 1.25 19.29 130598 2.31 .28 2.63 130598 2.42 .26 2.65 130599 10.71 1.19 17.88 130599 10.88 1.20 17.99 130600 10.68 1.20 17.77 130600 10.84 1.19 17.67 130602 14.10 1.54 23.02 130602 14.31 1.53 23.09 130603 14.11 1.55 22.95 130603 14.22 1.53 22.80 130604 11.26 1.44 21.90 130604 11.32 1.43 22.23 130605 4.44 .72 11.68 130605 4.53 .70 11.80 130606 1.00 .16 .25 130606 1.08 .15 .36 130609 19.71 1.18 17.12 130609 19.75 1.18 17.42 130610 16.63 1.15 16.80 130610 17.26 1.15 16.92 130611 18.99 1.23 18.09 130611 19.19 1.23 18.01 130612 19.70 1.24 18.26 130612 19.85 1.29 18.31 130613 19.74 1.27 18.30 130613 19.77 1.28 18.63 130614 14.40 1.20 17.25 130614 14.65 1.20 17.40 130615 13.25 1.23 17.64 130615 13.46 1.23 17.57 130616 12.28 1.22 17.84 130616 12.32 1.21 18.08 130617 11.86 1.24 18.38 130617 12.04 1.23 18.21 130618 11.66 1.22 17.60 130618 11.68 1.19 17.80 130619 12.01 1.23 18.78 130619 12.14 1.22 18.85 130620 12.26 1.27 19.05 130620 12.35 1.27 19.38 130621 12.50 1.31 19.47 130621 12.51 1.33 19.50 130622 13.25 1.42 21.15 130622 13.32 1.42 21.36 130623 14.52 1.54 23.72 130623 14.61 1.57 23.57 130624 14.70 1.57 23.67 130624 14.71 1.59 23.85 130625 6.63 .98 15.43 130625 6.64 .96 15.40 130626 2.55 .38 6.59 130626 2.59 .36 6.67 130627 1.18 0.00 .31 130627 1.19 0.00 .25 130628 1.19 .09 .25 130628 1.24 .09 .28 130629 20.28 1.14 16.83 130629 20.29 1.12 16.81 130630 16.84 1.11 16.43 130630 16.95 1.12 16.22 130631 16.68 1.16 16.92 130631 16.70 1.15 16.95 130632 17.39 1.18 18.04 130632 17.48 1.19 18.07 130633 15.64 1.22 17.81 130633 15.79 1.22 18.05 130634 12.46 1.12 17.16 130634 12.75 1.14 16.63 130635 11.80 1.14 17.34 130635 11.86 1.17 17.54 130636 11.73 1.19 17.78 130636 11.88 1.16 17.91 130639 12.47 1.34 19.39 130639 12.52 1.30 19.63 130640 12.91 1.35 20.48 130640 13.00 1.38 20.21 130641 14.58 1.62 24.24 130641 14.58 1.60 24.09 130642 7.64 1.06 17.24 130642 7.77 1.07 17.30 130643 4.42 .68 11.58 130643 4.44 .70 11.58 130644 4.26 .69 11.07 130644 4.27 .67 11.19 130645 3.33 .47 7.41 130645 3.35 .46 7.43 130646 1.15 .09 .34 130646 1.28 0.00 .36 130647 1.12 0.00 .35 130647 1.13 0.00 .33 130649 19.79 1.13 16.41 130649 19.87 1.13 16.62 130650 23.28 1.19 17.32 130650 23.34 1.19 17.18 130651 21.34 1.19 17.11 130651 21.45 1.17 17.25 130652 15.80 1.12 16.47 130652 15.83 1.13 16.44 130653 15.27 1.13 16.06 130653 15.32 1.12 16.32 130654 8.74 .87 13.26 130654 8.78 .89 13.26 130655 14.46 1.20 17.60 130655 14.55 1.18 17.61 130656 13.39 1.20 18.09 130656 13.40 1.20 17.95 130657 11.81 1.17 18.02 130657 11.83 1.21 17.84 130658 11.62 1.17 17.72 130658 11.68 1.20 17.63 130659 11.86 1.25 18.59 130659 11.90 1.25 18.73 130660 12.26 1.31 19.34 130660 12.45 1.32 19.23 130661 14.92 1.57 24.35 130661 14.99 1.57 24.34 130662 12.50 1.48 23.02 130662 12.60 1.44 23.15 130663 12.71 1.48 22.90 130663 12.77 1.48 23.00 130664 8.10 1.13 17.85 130664 8.14 1.14 18.03 130665 1.36 .19 3.40 130665 1.38 .20 3.27 130666 1.45 .20 3.23 130666 1.51 .20 3.26 130667 1.11 .10 .62 130667 1.13 .09 .63 130668 1.20 .09 .64 130668 1.21 .10 .64 130669 35.71 1.43 20.01 130669 35.95 1.42 19.98 130670 34.01 1.43 19.97 130670 34.12 1.44 19.97 130671 16.77 1.20 17.62 130671 16.95 1.19 17.54 130672 15.90 1.22 17.85 130672 15.96 1.22 18.05 130673 18.43 1.20 17.65 130673 18.58 1.21 17.77 130674 2.18 .20 4.29 130674 2.30 .23 4.61 130676 11.93 1.19 18.34 130676 11.97 1.19 18.26 130678 10.86 1.21 19.18 130678 10.87 1.20 19.17 130679 12.94 1.33 20.82 130679 13.09 1.36 21.02 130680 14.64 1.61 25.02 130680 14.66 1.62 24.63 130681 10.73 1.38 22.33 130681 10.81 1.36 21.89 130682 4.78 .72 12.99 130682 4.88 .73 12.82 130683 2.75 .39 8.03 130683 2.75 .41 8.28 130684 2.73 .37 8.05 130684 2.74 .37 8.08 130685 1.32 0.00 2.85 130685 1.47 0.00 2.82 130686 1.52 .09 3.11 130686 1.55 .10 3.08 130687 1.10 0.00 .26 130687 1.10 0.00 .36 130688 1.09 0.00 .26 130688 1.17 0.00 .28 130689 33.89 1.33 20.69 130689 33.97 1.31 20.55 130690 33.84 1.34 20.45 130690 34.03 1.35 20.46 130691 16.70 1.17 18.24 130691 16.76 1.19 18.05 130692 18.23 1.20 18.42 130692 18.28 1.21 18.37 130693 20.10 1.22 18.40 130693 20.27 1.20 18.51 130694 1.31 0.00 1.62 130694 1.40 0.00 1.76 130695 15.00 1.19 18.06 130695 15.15 1.15 17.96 130696 12.97 1.16 17.93 130696 13.09 1.16 17.93 130697 12.07 1.19 18.25 130697 12.74 1.19 18.01 130698 12.10 1.29 20.23 130698 12.71 1.30 19.86 130699 11.04 1.18 18.20 130699 11.36 1.16 18.13 130700 12.08 1.31 20.08 130700 12.11 1.30 19.53 130701 13.81 1.52 23.11 130701 14.05 1.50 23.54 130702 10.67 1.39 21.34 130702 10.80 1.33 21.58 130703 11.05 1.33 21.85 130703 11.14 1.36 22.09 130704 4.51 .66 11.90 130704 4.63 .66 11.94 130705 1.78 .20 4.02 130705 1.80 .17 4.06 130706 1.46 .14 3.06 130706 1.50 .14 3.03 130707 1.04 0.00 0.00 130707 1.06 0.00 0.00 130708 1.05 0.00 0.00 130708 1.06 0.00 0.00 130709 39.26 1.36 20.62 130709 39.57 1.41 20.91 130710 34.88 1.36 20.09 130710 34.96 1.35 19.94 130711 11.29 1.00 15.71 130711 11.30 1.00 16.02 130712 27.49 1.29 18.77 130712 27.55 1.30 18.81 130713 22.54 1.24 18.37 130713 22.62 1.27 18.46 130714 3.00 .34 5.70 130714 3.05 .32 5.78 130715 22.24 1.23 18.10 130715 22.36 1.21 18.44 130716 20.75 1.23 18.33 130716 20.81 1.22 18.23 130717 18.24 1.21 18.08 130717 18.38 1.20 18.52 130718 10.58 1.11 17.36 130718 10.62 1.13 17.86 130719 11.94 1.13 18.06 130719 12.02 1.13 18.06 130720 12.56 1.17 18.28 130720 12.74 1.16 18.24 130721 11.83 1.16 18.16 130721 12.34 1.18 18.22 130722 11.58 1.21 18.61 130722 11.66 1.20 18.76 130723 12.69 1.32 20.49 130723 12.70 1.31 20.81 130724 11.52 1.38 21.68 130724 11.69 1.42 21.84 130725 3.44 .55 9.30 130725 3.51 .54 9.49 130726 1.47 .17 3.47 130726 1.50 .17 3.56 130727 .85 0.00 0.00 130727 .86 0.00 0.00 130728 .86 0.00 0.00 130728 .96 0.00 0.00 130729 38.65 1.35 20.33 130729 38.80 1.37 20.22 130730 33.82 1.41 19.63 130730 33.83 1.36 19.66 130731 18.98 1.15 16.69 130731 19.26 1.13 16.67 130732 27.74 1.28 18.52 130732 28.15 1.27 18.65 130733 26.19 1.25 18.11 130733 26.37 1.25 18.14 130734 9.79 1.02 15.39 130734 9.84 1.03 15.76 130735 20.54 1.22 17.98 130735 20.56 1.18 17.95 130736 19.17 1.21 18.21 130736 19.26 1.21 18.15 130737 17.43 1.22 18.25 130737 17.45 1.22 18.25 130738 12.06 1.23 18.68 130738 12.27 1.24 18.76 130739 12.88 1.21 18.00 130739 12.97 1.22 18.20 130740 12.64 1.21 17.89 130740 12.66 1.19 17.94 130741 11.77 1.22 17.77 130741 11.84 1.21 17.79 130742 11.57 1.23 18.16 130742 11.70 1.22 18.07 130751 29.65 1.27 18.22 130751 29.78 1.28 18.60 130752 29.43 1.30 18.61 130752 29.50 1.33 18.69 130753 26.87 1.29 18.25 130753 27.24 1.27 18.34 130754 4.16 .56 8.79 130754 4.16 .57 8.83 130755 23.05 1.27 18.07 130755 23.12 1.29 18.20 130756 21.61 1.28 18.14 130756 21.80 1.27 18.36 130757 19.74 1.28 18.50 130757 19.82 1.27 18.17 130758 10.97 1.26 18.83 130758 11.12 1.31 18.60 130759 13.24 1.20 17.92 130759 13.38 1.20 17.94 130760 12.44 1.20 17.88 130760 12.60 1.21 17.95 130761 11.79 1.20 17.74 130761 11.84 1.21 17.96 130762 11.56 1.25 18.46 130762 11.59 1.24 18.42 130763 12.30 1.33 20.09 130763 12.33 1.35 19.92 130764 12.45 1.37 20.73 130764 12.63 1.39 20.30 130765 2.41 .34 6.72 130765 2.47 .34 6.59 130766 1.41 .12 3.41 130766 1.42 .13 3.43 130767 .77 0.00 0.00 130767 .77 0.00 0.00 130768 .77 0.00 0.00 130768 .80 0.00 0.00 130769 38.92 1.39 20.44 130769 39.10 1.39 20.63 130770 32.96 1.32 19.43 130770 33.34 1.34 19.66 130771 31.40 1.30 19.11 130771 31.43 1.32 18.99 130772 22.63 1.25 18.08 130772 22.68 1.25 18.57 130773 28.15 1.26 18.52 130773 28.18 1.28 18.96 130774 1.97 .18 3.68 130774 2.10 .19 3.60 130775 21.89 1.22 18.14 130775 21.92 1.22 17.96 130776 21.56 1.27 18.33 130776 21.59 1.26 18.42 130777 18.36 1.22 18.43 130777 18.39 1.23 18.45 130778 18.52 1.23 18.45 130778 18.59 1.24 18.44 130779 10.45 1.00 15.63 130779 10.51 1.00 15.43 130780 12.22 1.20 17.68 130780 12.25 1.19 18.12 130781 11.77 1.19 18.23 130781 11.84 1.21 17.84 130782 11.68 1.26 18.78 130782 11.68 1.23 18.38 130783 11.61 1.18 18.07 130783 11.71 1.20 18.24 130784 9.86 1.24 19.18 130784 9.92 1.25 19.49 130785 4.07 .59 10.35 130785 4.11 .59 10.27 130786 1.40 .15 3.57 130786 2.35 .14 3.56 130788 .84 0.00 0.00 130788 .87 0.00 0.00 130789 36.68 1.33 19.98 130789 36.72 1.34 19.85 130790 33.57 1.33 19.35 130790 34.17 1.34 19.30 130791 28.34 1.29 18.53 130791 28.45 1.28 18.55 130792 27.68 1.23 18.58 130792 27.92 1.24 18.70 130793 24.29 1.20 18.24 130793 24.44 1.24 18.07 130794 7.43 .92 14.75 130794 7.47 .91 14.72 130795 20.02 1.21 17.78 130795 20.13 1.21 17.80 130796 18.18 1.20 17.71 130796 18.22 1.19 18.12 130797 16.30 1.20 18.08 130797 16.33 1.19 17.86 130798 11.42 1.25 18.81 130798 11.49 1.25 18.75 130799 11.59 1.15 17.52 130799 11.72 1.17 17.64 130800 11.58 1.15 17.57 130800 11.60 1.16 17.95 130801 11.50 1.19 18.08 130801 11.63 1.24 18.17 130802 12.17 1.29 19.13 130802 12.21 1.29 19.28 130803 12.65 1.37 20.62 130803 12.66 1.37 20.43 130804 12.90 1.41 20.55 130804 12.94 1.40 20.49 130805 13.69 1.53 22.95 130805 13.71 1.52 23.31 130806 4.14 .66 11.00 130806 4.14 .64 11.05 130807 1.33 .19 3.57 130807 1.38 .17 3.59 130809 36.31 1.34 19.65 130809 36.33 1.35 20.25 130810 28.84 1.25 18.86 130810 28.87 1.26 18.62 130811 29.72 1.28 19.08 130811 31.04 1.30 19.03 130812 24.56 1.24 18.18 130812 24.89 1.24 18.11 130813 25.03 1.24 18.01 130813 25.07 1.24 18.05 130814 6.47 .76 12.03 130814 6.60 .75 12.05 130815 21.32 1.21 17.79 130815 21.36 1.23 18.08 130816 19.08 1.21 18.20 130816 19.09 1.22 18.08 130817 16.70 1.18 17.66 130817 16.76 1.19 17.83 130818 11.44 1.20 18.30 130818 11.48 1.21 18.34 130819 12.37 1.17 17.68 130819 12.41 1.17 17.54 130820 11.90 1.18 17.91 130820 11.94 1.17 17.72 130821 11.31 1.19 17.91 130821 11.40 1.19 17.86 130822 11.47 1.21 18.48 130822 11.56 1.22 18.41 130823 12.94 1.36 20.50 130823 13.01 1.38 20.61 130824 8.54 1.16 18.00 130824 8.56 1.14 18.17 130825 1.92 .27 5.55 130825 2.03 .28 5.44 130826 .97 .09 1.79 130826 .99 .08 1.78 130827 1.07 0.00 .64 130827 1.08 0.00 .63 130828 1.07 0.00 .62 130828 1.08 0.00 .67 130829 37.57 1.39 19.97 130829 37.83 1.38 19.90 130830 31.54 1.29 18.87 130830 31.62 1.31 18.95 130831 15.95 1.14 17.43 130831 16.01 1.14 17.23 130833 22.15 1.21 17.51 130833 22.18 1.20 17.20 130834 10.08 .89 13.33 130834 10.40 .91 13.64 130835 18.29 1.19 17.54 130835 18.31 1.20 17.71 130836 17.13 1.20 17.80 130836 17.18 1.20 17.75 130837 16.03 1.20 17.70 130837 16.10 1.20 17.83 130838 11.94 1.17 17.43 130838 11.97 1.17 17.31 130839 11.63 1.16 17.24 130839 11.64 1.16 17.11 130840 11.85 1.18 17.47 130840 11.88 1.19 17.56 130841 11.48 1.22 18.11 130841 11.52 1.21 17.83 130842 11.55 1.25 18.83 130842 11.61 1.23 18.91 130843 13.04 1.41 21.44 130843 13.29 1.42 21.25 130844 13.50 1.51 22.73 130844 13.55 1.51 22.54 130845 4.00 .67 11.00 130845 4.03 .66 11.05 130846 1.24 .17 2.95 130846 1.27 .18 3.02 130847 1.01 0.00 .58 130847 1.03 0.00 .55 130848 1.04 0.00 .54 130848 1.04 0.00 .55 130849 38.22 1.41 20.28 130849 38.30 1.39 19.86 130850 35.00 1.36 19.92 130850 35.12 1.36 19.84 130851 30.62 1.33 19.08 130851 30.75 1.33 19.19 130852 29.14 1.31 18.63 130852 29.44 1.30 19.08 130853 28.47 1.27 18.87 130853 28.50 1.30 18.88 130854 15.27 .98 14.56 130854 15.44 .99 14.75 130855 22.12 1.25 18.14 130855 22.40 1.26 18.18 130856 19.70 1.25 18.27 130856 19.89 1.26 18.38 130857 17.97 1.19 17.97 130857 18.13 1.23 18.13 130858 12.37 1.27 19.17 130858 12.47 1.28 19.17 130859 13.14 1.19 17.59 130859 13.29 1.20 17.58 130860 12.37 1.20 17.95 130860 12.49 1.21 17.68 130861 11.70 1.20 17.87 130861 11.74 1.20 18.15 130862 11.93 1.25 18.74 130862 12.18 1.25 18.55 130863 11.88 1.23 18.68 130863 12.03 1.23 18.95 130865 3.35 .52 9.34 130865 3.43 .54 9.31 130866 2.15 .29 5.84 130866 2.16 .30 5.81 130867 2.17 .29 5.82 130867 2.19 .30 5.89 130868 1.15 0.00 .45 130868 1.76 0.00 .47 130869 37.73 1.33 20.46 130869 37.75 1.37 20.32 130870 34.93 1.32 20.01 130870 34.98 1.34 19.95 130871 32.06 1.32 19.43 130871 32.80 1.32 19.51 130872 27.16 1.28 18.72 130872 27.37 1.29 18.81 130873 27.25 1.27 18.89 130873 27.81 1.28 18.88 130874 15.99 1.18 17.76 130874 16.04 1.16 17.56 130875 17.39 1.21 17.90 130875 17.39 1.21 17.86 130876 14.88 1.20 17.79 130876 15.02 1.19 17.77 130877 12.79 1.19 17.60 130877 12.80 1.18 17.57 130878 11.01 1.20 18.15 130878 11.17 1.19 18.21 130879 10.85 1.12 16.86 130879 11.04 1.11 17.19 130880 11.82 1.23 18.94 130880 11.86 1.23 18.63 130881 12.51 1.35 20.65 130881 12.55 1.33 20.44 130882 9.52 1.18 19.07 130882 9.70 1.19 19.23 130883 9.45 1.20 19.21 130883 9.52 1.19 19.30 130884 3.51 .55 9.31 130884 3.51 .57 9.31 130885 1.68 .24 4.42 130885 1.72 .24 4.40 130886 1.64 .22 4.36 130886 1.67 .23 4.40 130887 1.29 .16 3.14 130887 1.32 .16 3.18 130888 1.09 0.00 .50 130888 1.09 0.00 .51 130889 39.94 1.38 20.93 130889 39.96 1.36 20.98 130890 37.11 1.36 20.21 130890 37.22 1.34 20.18 130891 32.54 1.32 19.63 130891 32.66 1.32 19.60 130892 31.22 1.31 19.41 130892 31.30 1.29 19.25 130893 28.31 1.27 18.82 130893 28.31 1.28 18.97 130894 22.43 1.24 18.47 130894 22.46 1.24 18.50 130895 22.22 1.24 18.31 130895 22.49 1.23 18.37 130896 19.69 1.23 18.20 130896 20.10 1.21 18.47 130897 18.13 1.21 18.17 130897 18.27 1.24 18.11 130898 10.11 1.09 17.78 130898 10.12 1.07 17.68 130899 11.22 1.04 16.23 130899 11.29 1.03 16.33 130900 12.53 1.19 18.16 130900 12.55 1.16 18.24 130901 11.97 1.17 18.31 130901 11.98 1.17 18.46 130902 11.68 1.22 18.73 130902 11.70 1.22 18.82 130903 11.91 1.23 19.57 130903 11.94 1.27 19.40 130904 11.89 1.25 19.64 130904 11.92 1.25 19.62 130905 12.96 1.40 21.60 130905 13.01 1.39 21.41 130906 10.53 1.30 20.03 130906 10.81 1.31 20.31 130907 .59 .09 .35 130907 .61 .09 .44 130908 3.54 .55 9.34 130908 3.62 .55 9.47 130909 35.58 1.41 19.78 130909 35.84 1.38 19.77 130910 35.39 1.39 19.89 130910 35.41 1.39 19.98 130911 29.39 1.32 19.00 130911 29.51 1.33 19.05 130912 17.04 1.24 17.99 130912 17.24 1.24 18.00 130913 25.83 1.27 18.30 130913 25.92 1.28 18.42 130914 20.95 1.24 18.07 130914 21.05 1.27 18.05 130915 18.95 1.27 17.97 130915 19.25 1.27 18.51 130916 17.03 1.25 17.90 130916 17.16 1.23 17.78 130917 14.76 1.23 17.36 130917 15.13 1.19 17.75 130918 12.73 1.19 17.73 130918 12.84 1.20 17.51 130919 11.18 1.14 17.23 130919 11.53 1.15 17.01 130920 11.47 1.20 18.04 130920 11.57 1.21 18.08 130921 11.43 1.22 18.62 130921 11.52 1.23 18.51 130922 11.73 1.27 19.56 130922 11.79 1.28 19.73 130923 11.74 1.38 20.97 130923 11.78 1.38 20.68 130924 11.72 1.38 20.82 130924 11.74 1.38 20.85 130925 4.42 .70 11.69 130925 4.46 .68 11.12 130926 2.70 .45 7.94 130926 2.70 .44 7.93 130927 .58 0.00 .55 130927 .58 0.00 .60 130929 35.42 1.40 19.56 130929 35.69 1.34 19.74 130930 33.71 1.34 19.60 130930 33.77 1.33 19.85 130931 31.15 1.31 19.31 130931 31.18 1.31 19.34 130932 25.68 1.26 18.98 130932 25.91 1.25 18.49 130933 24.90 1.26 18.51 130933 25.18 1.26 18.45 130934 22.90 1.24 18.23 130934 23.01 1.26 17.98 130935 20.08 1.23 17.83 130935 20.13 1.22 18.04 130936 18.00 1.21 17.96 130936 18.04 1.22 17.95 130937 15.93 1.21 17.88 130937 16.05 1.22 17.94 130938 12.73 1.15 17.28 130938 12.76 1.15 17.19 130939 11.06 1.11 16.59 130939 11.24 1.17 16.51 130940 11.65 1.18 18.04 130940 11.71 1.18 17.65 130941 11.61 1.21 18.47 130941 11.72 1.20 18.03 130942 11.71 1.27 19.18 130942 11.80 1.22 19.36 130943 12.37 1.31 20.50 130943 12.38 1.33 20.48 130944 11.76 1.26 19.67 130944 11.99 1.28 19.59 130945 6.35 .91 14.81 130945 6.35 .89 14.88 130946 6.27 .91 14.80 130946 6.42 .92 14.95 130947 .66 0.00 .52 130947 .80 0.00 .42 130948 .62 0.00 .39 130948 .65 0.00 .41 130949 35.52 1.31 19.59 130949 35.59 1.36 19.56 130950 21.42 1.14 17.00 130950 21.42 1.17 16.92 130951 21.25 1.16 17.78 130951 21.30 1.16 17.53 130952 18.37 1.15 17.64 130952 19.26 1.15 17.56 130953 18.90 1.13 17.46 130953 18.97 1.15 17.36 130954 16.27 1.13 17.53 130954 16.60 1.15 17.41 130955 15.87 1.17 17.71 130955 16.10 1.17 17.56 130956 14.33 1.17 17.69 130956 14.41 1.18 17.62 130957 12.91 1.15 17.56 130957 13.01 1.14 17.45 130958 12.71 1.12 17.14 130958 12.71 1.16 17.12 130959 11.58 1.13 17.24 130959 11.61 1.12 17.30 130960 11.29 1.16 17.76 130960 11.29 1.15 17.71 130961 11.37 1.19 18.58 130961 11.42 1.19 18.07 130962 11.58 1.22 19.15 130962 11.64 1.24 18.81 130963 11.55 1.22 19.02 130963 11.61 1.23 19.25 130964 12.69 1.38 21.16 130964 12.72 1.38 21.02 130965 5.86 .83 13.67 130965 5.92 .82 13.82 130966 2.71 .44 7.81 130966 2.74 .46 7.81 130967 2.73 .44 7.86 130967 2.73 .44 7.88 130968 .62 0.00 .58 130968 .67 0.00 .63 130969 22.66 1.13 17.38 130969 23.01 1.17 17.28 130970 23.60 1.15 17.39 130970 23.69 1.17 17.45 130971 21.98 1.17 17.31 130971 22.04 1.18 17.85 130972 14.63 1.16 17.72 130972 14.89 1.13 17.42 130973 17.71 1.16 17.21 130973 17.75 1.15 17.52 130974 16.24 1.16 17.29 130974 16.62 1.13 17.47 130975 16.59 1.16 18.29 130975 16.76 1.16 17.83 130976 14.78 1.16 17.62 130976 14.90 1.15 17.81 130977 12.86 1.13 17.55 130977 12.89 1.13 17.61 130978 9.46 1.01 15.90 130978 9.51 .99 15.75 130979 10.41 1.03 16.31 130979 10.44 1.05 16.57 130980 11.39 1.17 18.15 130980 11.40 1.17 18.00 130981 11.98 1.23 19.43 130981 12.00 1.23 19.38 130982 12.97 1.41 21.17 130982 13.07 1.37 21.37 130983 9.97 1.23 19.57 130983 10.12 1.26 20.01 130985 3.21 .53 8.70 130985 3.27 .50 8.81 130987 .64 .09 .51 130987 .68 0.00 .59 130988 .62 .12 1.19 130988 .63 .11 1.21 130989 30.70 1.31 18.83 130989 30.92 1.33 18.74 130990 32.58 1.34 19.18 130990 32.69 1.33 19.16 130991 29.85 1.32 19.38 130991 29.93 1.32 18.65 130992 24.82 1.25 18.04 130992 25.02 1.24 18.40 130993 26.31 1.27 18.69 130993 26.62 1.27 18.62 130994 19.66 1.20 18.01 130994 20.37 1.21 17.97 130995 19.23 1.23 18.10 130995 19.23 1.27 18.23 130996 14.44 1.17 17.33 130996 14.53 1.17 17.39 130997 13.10 1.13 17.38 130997 13.16 1.13 17.56 130998 6.08 .73 12.10 130998 6.10 .73 12.05 130999 10.13 1.00 15.63 130999 10.32 1.02 15.45 131000 11.49 1.19 17.82 131000 11.52 1.18 17.83 131001 11.47 1.21 18.25 131001 11.60 1.20 18.29 131002 12.25 1.30 20.10 131002 12.29 1.32 19.67 131003 7.76 1.05 16.69 131003 7.94 1.03 16.55 131004 2.74 .43 7.46 131004 3.29 .41 7.47 131005 1.81 .25 5.31 131005 1.82 .25 5.21 131006 1.82 .25 5.42 131006 1.82 .25 5.27 131007 .75 0.00 1.12 131007 .77 0.00 1.13 131008 .75 0.00 1.12 131008 .75 0.00 1.12 131009 23.27 1.17 17.67 131009 23.31 1.17 17.65 131010 23.08 1.19 17.70 131010 23.27 1.18 17.72 131011 22.45 1.18 17.52 131011 22.59 1.18 17.37 131012 18.32 1.15 17.35 131012 18.46 1.15 16.95 131013 17.90 1.14 16.96 131013 18.09 1.16 17.08 131014 14.69 1.15 17.29 131014 14.69 1.15 17.30 131015 14.69 1.15 17.07 131015 14.94 1.15 17.04 131016 13.35 1.14 17.12 131016 13.35 1.14 17.10 131017 11.73 1.13 16.87 131017 11.73 1.13 16.85 131018 8.08 1.00 15.75 131018 8.14 1.02 15.97 131019 8.97 1.00 15.41 131019 9.04 1.00 15.49 131020 10.83 1.17 17.93 131020 10.92 1.18 17.97 131021 11.53 1.21 18.33 131021 11.53 1.21 18.20 131022 12.04 1.29 19.77 131022 12.09 1.28 19.26 131023 11.86 1.27 19.12 131023 11.88 1.28 19.51 131024 6.29 .91 14.56 131024 6.32 .87 14.42 131025 3.77 .60 10.10 131025 3.78 .60 10.07 131026 2.35 .37 6.83 131026 2.37 .38 6.92 131027 .77 .08 1.20 131027 .77 .09 1.26 131028 .77 0.00 1.19 131028 .77 0.00 1.19 131029 19.35 1.14 16.92 131029 19.41 1.13 17.50 131030 23.71 1.21 17.76 131030 24.12 1.20 17.67 131031 24.47 1.22 17.94 131031 24.85 1.22 17.87 131032 17.93 1.15 16.92 131032 17.93 1.14 16.92 131033 20.92 1.18 17.33 131033 20.92 1.17 17.29 131034 17.26 1.21 17.31 131034 17.32 1.17 17.31 131035 15.62 1.17 17.58 131035 15.65 1.17 17.49 131036 13.76 1.15 17.28 131036 13.79 1.15 17.45 131037 12.70 1.15 17.22 131037 12.71 1.13 17.29 131038 10.13 1.17 18.05 131038 10.14 1.17 18.12 131039 9.89 1.07 16.66 131039 9.98 1.07 16.23 131040 10.91 1.20 17.83 131040 11.01 1.18 17.93 131041 11.11 1.22 18.39 131041 11.13 1.21 18.46 131042 12.91 1.40 21.30 131042 13.00 1.40 21.08 131043 12.95 1.38 20.63 131043 12.95 1.38 20.94 131044 8.51 1.15 17.58 131044 8.53 1.12 17.58 131045 1.93 .32 5.87 131045 1.97 .32 5.94 131046 1.95 .33 5.90 131046 1.96 .32 5.93 131047 .76 .11 1.16 131047 .77 .10 1.21 131048 .75 .10 1.17 131048 .76 .10 1.16 131049 21.87 1.22 16.94 131049 21.97 1.22 17.19 131050 22.85 1.27 17.50 131050 23.04 1.24 17.36 131051 22.99 1.25 17.77 131051 23.02 1.29 17.41 131052 19.18 1.39 17.10 131052 19.19 1.27 17.26 131053 19.53 1.28 17.21 131053 19.59 1.27 17.20 131054 18.02 1.30 17.22 131054 18.07 1.29 17.22 131055 15.99 1.28 17.11 131055 16.08 1.27 17.24 131056 14.69 1.29 17.18 131056 14.81 1.29 17.57 131057 13.17 1.24 17.55 131057 13.24 1.24 17.39 131058 8.96 1.20 17.70 131058 8.97 1.19 17.56 131059 8.31 .99 14.40 131059 8.42 1.00 14.39 131060 11.37 1.26 17.94 131060 11.45 1.26 17.83 131061 11.30 1.29 18.37 131061 11.32 1.29 18.33 131062 12.22 1.36 19.44 131062 12.28 1.37 19.73 131063 12.46 1.49 21.47 131063 12.48 1.50 21.64 131064 6.94 1.11 15.61 131064 7.03 1.02 15.67 131065 2.87 .49 7.75 131065 2.88 .49 7.61 131066 1.96 .34 5.65 131066 1.99 .34 5.66 131067 1.16 .18 2.60 131067 1.16 .18 2.65 131068 .85 .11 1.20 131068 .86 .12 1.22 131069 19.06 1.21 17.16 131069 19.10 1.18 17.20 131070 23.73 1.26 17.84 131070 23.75 1.27 17.85 131071 20.57 1.24 17.58 131071 20.80 1.24 17.61 131072 13.17 1.23 17.68 131072 13.18 1.25 17.50 131073 15.72 1.19 17.02 131073 15.78 1.20 17.51 131074 14.46 1.24 17.49 131074 14.52 1.23 17.56 131075 15.57 1.24 17.21 131075 15.65 1.21 17.31 131076 14.10 1.26 17.40 131076 14.20 1.23 17.13 131077 12.24 1.21 16.98 131077 12.36 1.22 17.25 131078 12.17 1.35 19.63 131078 12.85 1.36 19.35 131079 11.41 1.27 18.17 131079 11.70 1.26 18.43 131080 11.35 1.23 17.72 131080 11.39 1.25 18.09 131081 11.48 1.25 18.28 131081 11.51 1.24 18.21 131082 11.88 1.32 19.32 131082 11.95 1.31 19.24 131083 12.35 1.42 20.63 131083 12.37 1.40 20.82 131084 8.78 1.17 17.68 131084 8.79 1.19 17.52 131085 2.14 .38 5.79 131085 2.18 .38 5.85 131086 1.85 .32 5.33 131086 1.85 .32 5.27 131087 1.59 .25 4.40 131087 1.61 .26 4.38 131088 .81 .10 1.25 131088 .83 .12 1.28 131089 24.21 1.23 17.77 131089 24.26 1.23 17.85 131090 27.13 1.28 18.32 131090 27.13 1.28 18.54 131091 23.94 1.25 17.98 131091 24.01 1.24 18.13 131092 19.39 1.16 17.03 131092 19.62 1.18 17.09 131093 19.86 1.21 17.35 131093 19.91 1.21 17.44 131094 16.42 1.20 17.15 131094 16.46 1.18 17.22 131095 13.89 1.19 17.16 131095 14.01 1.19 17.04 131096 14.51 1.20 17.54 131096 14.59 1.20 17.42 131097 12.40 1.17 17.20 131097 12.46 1.16 16.96 131098 9.95 1.17 17.61 131098 10.01 1.17 17.48 131099 8.99 1.05 15.48 131099 9.00 1.04 15.46 131100 11.33 1.21 17.80 131100 11.38 1.22 17.69 131101 11.49 1.25 18.59 131101 11.56 1.25 18.27 131102 12.16 1.34 20.03 131102 12.19 1.33 19.79 131103 9.87 1.28 18.76 131103 9.89 1.28 18.88 131104 4.75 .74 11.68 131104 4.78 .76 11.84 131105 1.85 .31 4.89 131105 2.45 .31 4.85 131106 1.93 .32 5.18 131106 1.97 .31 5.21 131107 1.21 .20 3.12 131107 1.36 .20 3.14 131108 .74 .12 1.59 131108 1.04 .12 1.60 131109 16.19 1.24 17.06 131109 16.54 1.24 17.48 131110 22.56 1.28 17.47 131110 22.66 1.26 17.47 131111 20.89 1.25 17.54 131111 21.12 1.27 17.41 131112 12.95 1.21 16.98 131112 14.29 1.20 17.45 131113 15.78 1.22 16.99 131113 16.86 1.22 17.10 131114 15.99 1.32 17.41 131114 16.06 1.33 17.43 131115 14.37 1.31 17.38 131115 15.13 1.34 17.45 131116 13.07 1.31 17.29 131116 13.15 1.28 17.36 131117 11.49 1.24 17.14 131117 11.55 1.24 17.20 131118 10.99 1.28 17.45 131118 12.75 1.27 18.52 131119 11.30 1.33 18.15 131119 11.31 1.31 17.91 131120 12.14 1.40 19.24 131120 12.22 1.39 19.37 131121 12.25 1.46 20.43 131121 13.24 1.47 20.43 131122 7.87 1.15 16.30 131122 7.92 1.16 16.20 131123 4.12 .71 10.17 131123 4.17 .73 10.30 131124 1.93 .36 5.02 131124 1.94 .35 4.98 131125 1.89 .32 4.93 131125 1.93 .32 5.08 131126 1.70 .28 4.77 131126 1.82 .29 4.77 131127 .92 .16 2.20 131127 .97 .16 2.29 131128 .92 .14 2.16 131128 .93 .15 2.21 131129 17.96 1.19 17.26 131129 17.98 1.19 17.11 131130 22.83 1.23 17.79 131130 23.26 1.24 17.57 131131 1.95 .32 5.71 131131 2.70 .33 5.73 131132 12.16 1.18 17.79 131132 12.74 1.16 17.56 131133 13.17 1.19 18.08 131133 13.20 1.22 18.05 131134 15.96 1.22 18.08 131134 16.02 1.21 17.81 131135 14.40 1.18 17.68 131135 14.74 1.18 17.95 131136 14.02 1.21 17.83 131136 14.05 1.21 18.10 131137 12.28 1.13 17.78 131137 12.55 1.16 17.62 131138 11.59 1.17 17.80 131138 11.71 1.19 17.69 131139 11.29 1.22 17.55 131139 11.49 1.20 17.68 131140 11.34 1.23 18.13 131140 11.51 1.21 18.12 131141 11.52 1.24 18.43 131141 12.14 1.25 18.61 131142 12.12 1.31 18.90 131142 12.33 1.32 18.93 131143 12.28 1.41 20.01 131143 12.71 1.40 20.30 131144 10.08 1.28 19.24 131144 10.15 1.29 18.94 131145 5.10 .77 12.57 131145 5.13 .77 12.52 131146 2.34 .39 6.96 131146 2.53 .40 6.87 131147 1.50 .23 4.38 131147 1.57 .24 4.35 131148 .75 .11 1.57 131148 .81 .11 1.54 131149 22.44 1.19 18.07 131149 22.84 1.22 17.89 131150 23.88 1.22 17.88 131150 24.31 1.23 18.12 131151 19.59 1.20 17.67 131151 19.61 1.22 17.67 131152 16.72 1.25 17.66 131152 16.80 1.20 18.55 131153 17.31 1.15 17.47 131153 17.80 1.16 17.81 131154 16.62 1.17 17.27 131154 17.10 1.20 17.40 131155 16.35 1.19 17.42 131155 17.17 1.19 17.71 131156 14.46 1.22 17.87 131156 14.51 1.21 17.82 131157 13.54 1.23 17.79 131157 14.37 1.20 17.96 131158 11.74 1.20 17.63 131158 11.86 1.22 17.75 131159 11.11 1.21 17.78 131159 11.24 1.19 18.09 131160 11.14 1.22 18.32 131160 11.24 1.23 18.51 131161 11.62 1.19 18.76 131161 11.63 1.22 18.89 131162 11.33 1.24 18.53 131162 11.40 1.23 19.03 131163 12.39 1.35 19.83 131163 12.41 1.33 19.83 131164 11.06 1.23 17.64 131164 11.79 1.22 17.86 131165 13.33 1.57 24.23 131165 13.38 1.57 23.77 131166 5.45 .87 13.57 131166 5.47 .87 13.67 131167 1.07 .14 1.28 131167 1.11 .15 1.34 131168 1.01 .13 1.29 131168 1.05 .12 1.28 131169 11.92 1.54 18.63 131169 13.36 1.53 18.48 131170 18.55 1.48 16.83 131170 18.55 1.43 16.75 131171 17.73 1.45 16.87 131171 17.99 1.44 16.82 131172 13.85 1.43 17.31 131172 13.90 1.47 17.16 131173 15.38 1.54 17.44 131173 15.48 1.50 17.40 131174 17.76 1.49 17.59 131174 17.92 1.51 17.52 131175 16.04 1.49 17.50 131175 16.22 1.50 17.64 131176 14.86 1.52 17.80 131176 14.99 1.52 17.91 131177 12.77 1.40 17.56 131177 12.88 1.42 17.73 131178 11.47 1.44 17.18 131178 11.65 1.40 17.69 131179 11.94 1.46 17.74 131179 12.02 1.46 18.14 131180 11.87 1.52 18.24 131180 13.49 1.49 18.14 131181 11.65 1.50 18.46 131181 11.87 1.49 18.27 131182 12.33 1.57 19.42 131182 12.41 1.59 19.45 131183 12.57 1.59 19.41 131183 13.34 1.59 19.39 131184 13.13 1.68 20.95 131184 13.18 1.69 21.11 131185 14.80 1.90 24.04 131185 14.95 1.86 24.31 131186 5.44 .93 12.42 131186 5.46 .92 12.54 131187 3.60 .68 8.97 131187 3.63 .67 8.97 131188 1.45 .21 1.19 131188 1.78 .22 1.30 131189 13.22 1.40 17.77 131189 13.28 1.39 17.93 131190 19.57 1.35 16.96 131190 19.59 1.33 16.67 131191 21.12 1.38 17.48 131191 21.14 1.38 17.50 131192 11.87 1.41 17.91 131192 12.01 1.44 18.18 131193 19.08 1.33 17.09 131193 19.17 1.31 17.05 131194 16.24 1.29 16.71 131194 17.50 1.30 16.78 131195 16.23 1.34 16.91 131195 16.42 1.34 17.12 131196 16.50 1.38 17.60 131196 16.51 1.36 17.63 131197 15.15 1.34 17.43 131197 15.42 1.32 17.08 131198 14.17 1.34 17.96 131198 14.24 1.35 17.77 131199 13.24 1.33 17.80 131199 13.51 1.34 18.05 131200 11.47 1.30 17.46 131200 11.48 1.31 17.45 131201 11.86 1.37 18.29 131201 12.04 1.37 18.29 131202 11.88 1.43 18.34 131202 11.97 1.40 18.79 131203 11.88 1.40 18.06 131203 11.90 1.42 18.12 131204 12.81 1.53 20.33 131204 12.98 1.54 20.31 131205 14.52 1.76 23.08 131205 14.55 1.77 23.22 131206 13.47 1.75 23.47 131206 13.68 1.72 23.72 131207 4.41 .77 11.22 131207 4.42 .79 11.18 131209 11.58 1.39 17.95 131209 11.59 1.41 17.81 131210 18.20 1.29 16.75 131210 18.20 1.31 16.45 131211 15.49 1.30 16.24 131211 15.56 1.24 16.48 131212 12.06 1.34 17.17 131212 12.10 1.31 17.05 131213 15.54 1.42 17.43 131213 15.55 1.36 17.59 131214 14.62 1.31 17.36 131214 14.62 1.34 17.66 131215 12.19 1.29 17.15 131215 12.28 1.29 17.08 131216 11.50 1.29 17.14 131216 11.99 1.30 16.87 131217 11.31 1.28 17.31 131217 11.42 1.31 17.26 131218 11.17 1.25 17.43 131218 11.21 1.26 16.94 131219 13.04 1.28 17.79 131219 13.51 1.31 17.84 131220 10.79 1.28 17.54 131220 10.85 1.26 17.43 131221 11.29 1.31 17.65 131221 11.43 1.30 17.90 131222 11.97 1.36 18.43 131222 12.02 1.37 18.68 131223 13.36 1.56 20.99 131223 13.51 1.52 21.05 131224 12.38 1.49 19.87 131224 12.64 1.47 20.18 131225 11.64 1.49 20.04 131225 11.80 1.51 20.10 131226 6.53 .97 14.37 131226 6.54 .96 14.23 131227 4.55 .77 11.52 131227 4.57 .77 11.49 131228 1.46 .23 1.56 131228 1.50 .23 1.62 131229 14.26 1.21 16.62 131229 14.46 1.20 16.92 131230 14.45 1.19 16.63 131230 14.46 1.21 16.69 131231 13.21 1.22 16.56 131231 13.27 1.19 16.62 131232 12.03 1.23 16.79 131232 12.12 1.24 16.80 131233 11.70 1.20 17.10 131233 11.73 1.21 17.07 131234 10.83 1.19 16.86 131234 10.90 1.19 16.76 131235 10.53 1.18 16.89 131235 10.55 1.20 16.93 131236 10.54 1.21 17.18 131236 10.58 1.20 16.96 131237 11.43 1.20 16.99 131237 12.87 1.20 17.12 131238 10.72 1.22 17.26 131238 10.83 1.21 17.18 131239 11.12 1.26 17.43 131239 11.16 1.26 17.71 131240 11.11 1.24 17.84 131240 11.30 1.24 17.72 131241 11.35 1.26 17.94 131241 11.49 1.28 18.13 131242 11.82 1.40 18.04 131242 11.87 1.26 18.54 131243 11.91 1.26 18.12 131243 12.12 1.28 18.51 131244 10.70 1.21 17.31 131244 11.15 1.22 17.58 131245 11.99 1.31 18.76 131245 12.29 1.35 18.63 131246 11.83 1.32 18.37 131246 11.92 1.35 17.99 131247 12.69 1.46 20.19 131247 12.69 1.45 20.19 131248 5.46 .76 9.35 131248 5.47 .83 9.27 131249 11.11 1.22 16.97 131249 11.39 1.17 17.05 131250 11.18 1.27 16.73 131250 11.32 1.15 16.72 131251 10.86 1.16 16.69 131251 10.92 1.15 16.72 131252 10.83 1.17 16.88 131252 10.87 1.15 16.84 131253 11.00 1.17 16.94 131253 11.01 1.17 17.17 131254 10.44 1.16 16.80 131254 10.48 1.14 16.78 131255 10.21 1.15 16.78 131255 10.21 1.18 17.18 131256 10.11 1.16 17.32 131256 10.26 1.18 17.04 131257 10.01 1.17 17.39 131257 10.09 1.17 17.00 131258 9.89 1.28 17.12 131258 9.94 1.16 18.01 131259 9.43 1.16 17.14 131259 9.47 1.14 17.02 131260 9.65 1.17 16.83 131260 9.67 1.18 16.76 131261 6.67 .97 12.54 131261 7.09 .99 12.52 131262 1.51 .35 1.46 131262 1.63 .26 1.52 131263 1.40 .33 1.30 131263 1.48 .33 1.33 131264 10.08 1.23 16.98 131264 10.22 1.14 17.03 131265 9.97 1.12 16.92 131265 10.01 1.14 17.08 131266 9.77 1.25 16.56 131266 9.98 1.12 16.79 131267 10.03 1.13 16.76 131267 10.11 1.13 16.75 131268 9.70 1.14 16.86 131268 9.75 1.13 16.77 131269 9.28 1.11 16.50 131269 9.32 1.11 16.63 131270 9.13 1.10 16.13 131270 9.16 1.11 16.37 131271 9.05 1.08 15.22 131271 9.08 1.09 15.32 131272 4.66 .72 8.34 131272 4.73 .74 8.02 131273 1.80 .38 2.22 131273 1.81 .43 2.22 131274 9.98 1.19 14.81 131274 10.03 1.07 14.90 131275 10.04 1.13 16.67 131275 10.10 1.12 16.63 131276 10.15 1.10 16.81 131276 10.22 1.12 16.61 131277 10.54 1.12 16.74 131277 10.59 1.12 16.73 131278 10.67 1.11 15.88 131278 10.74 1.11 15.82 131279 11.20 1.07 13.62 131279 11.49 1.09 13.64 131280 10.92 1.06 12.42 131280 10.92 1.05 12.41 131281 10.94 1.05 11.70 131281 11.01 1.05 11.77 131282 10.55 1.14 11.03 131282 10.59 1.04 10.92 131283 2.19 .50 2.74 131283 2.24 .43 2.77 131284 10.43 1.11 12.74 131284 10.46 1.05 12.72 131285 11.15 1.10 14.30 131285 11.23 1.09 14.13 131286 10.79 1.06 12.81 131286 10.87 1.07 12.90 131287 10.62 1.04 12.11 131287 10.70 1.09 12.02 131288 10.09 1.04 10.77 131288 10.16 1.05 10.84 131289 2.37 .53 2.55 131289 2.43 .47 2.65 131290 8.20 1.04 7.87 131290 8.51 .96 8.08 131291 7.61 .93 7.24 131291 7.63 .92 7.27 131292 6.49 .82 5.88 131292 6.50 .83 5.95 131293 4.24 .67 3.82 131293 4.30 .64 3.92 131294 10.84 1.14 10.19 131294 10.85 1.08 10.32 131295 10.92 1.10 10.36 131295 10.95 1.10 10.16 131296 10.48 1.08 10.00 131296 10.53 1.09 10.04 131297 2.77 .62 3.37 131297 2.80 .55 3.36 131298 11.77 1.12 15.53 131298 11.82 1.22 15.38 131299 11.86 1.13 14.81 131299 11.87 1.12 14.79 131300 11.11 1.07 13.52 131300 11.16 1.09 13.37 131301 9.99 1.04 10.73 131301 10.00 1.04 10.76 131302 2.89 .60 2.91 131302 2.92 .58 2.99 131303 9.81 1.12 16.66 131303 9.89 1.18 16.40 131304 9.81 1.14 16.76 131304 10.02 1.14 16.79 131305 9.79 1.14 16.54 131305 9.87 1.14 16.62 131306 9.97 1.23 16.22 131306 10.06 1.13 16.49 131307 10.34 1.14 16.52 131307 10.43 1.13 16.60 131308 10.53 1.13 16.29 131308 10.70 1.11 16.26 [AWI1] 131309 10.75 1.10 16.23 131309 10.80 1.12 15.99 131310 9.60 1.09 15.04 131310 9.62 1.09 14.96 131311 8.36 .98 11.30 131311 8.48 .96 11.11 131312 2.38 .50 4.25 131312 2.39 .54 4.18 131313 11.18 1.16 17.09 131313 11.24 1.17 17.07 131314 11.21 1.20 17.22 131314 11.22 1.18 17.27 131315 10.09 1.15 17.23 131315 10.29 1.18 17.17 131316 9.55 1.16 16.79 131316 9.63 1.17 16.81 131317 10.12 1.18 17.31 131317 10.30 1.19 17.29 131318 9.99 1.18 17.47 131318 10.10 1.20 17.25 131319 9.66 1.20 17.63 131319 9.70 1.20 17.68 131320 9.40 1.19 17.28 131320 9.45 1.19 17.47 131321 9.05 1.18 16.88 131321 9.10 1.18 17.23 131322 8.28 1.15 16.16 131322 8.44 1.14 16.18 131323 6.45 1.01 13.10 131323 6.50 1.00 13.10 131324 1.61 .46 3.27 131324 1.65 .48 3.35 131325 13.34 1.17 16.87 131325 13.36 1.17 16.82 131326 13.46 1.18 17.19 131326 13.50 1.18 17.02 131327 12.76 1.19 17.42 131327 12.87 1.17 17.20 131328 12.52 1.18 17.30 131328 12.56 1.16 17.20 131329 11.95 1.14 17.00 131329 11.97 1.15 17.37 131330 11.08 1.16 17.18 131330 11.10 1.15 17.27 131331 10.41 1.16 16.93 131331 10.70 1.15 17.13 131332 10.24 1.15 17.04 131332 10.37 1.14 16.96 131333 10.35 1.16 17.28 131333 10.40 1.18 17.34 131334 10.72 1.18 17.64 131334 10.79 1.19 17.50 131335 10.70 1.17 17.61 131335 10.77 1.16 18.47 131336 11.08 1.21 17.71 131336 11.10 1.20 17.71 131337 10.91 1.17 18.08 131337 10.94 1.17 17.87 131338 11.12 1.19 18.32 131338 11.18 1.20 18.49 131339 11.40 1.21 18.60 131339 11.42 1.22 18.76 131340 11.40 1.26 18.73 131340 11.43 1.25 18.57 131341 11.67 1.29 18.79 131341 11.77 1.28 19.15 131342 8.05 1.05 13.72 131342 8.13 1.06 13.79 131343 1.93 .40 2.56 131343 2.18 .42 2.50 131344 1.68 .36 2.10 131344 1.72 .36 2.08 131345 15.47 1.13 17.20 131345 15.52 1.12 17.05 131346 14.85 1.11 17.12 131346 14.91 1.11 17.20 131347 13.85 1.11 17.10 131347 13.91 1.12 17.23 131348 11.53 1.13 17.52 131348 11.62 1.14 17.49 131349 11.12 1.12 17.20 131349 11.27 1.12 17.42 131350 10.65 1.12 17.58 131350 10.68 1.12 17.56 131351 10.48 1.15 17.39 131351 10.56 1.12 17.67 131352 10.55 1.25 17.65 131352 10.61 1.27 17.80 131353 10.83 1.12 17.85 131353 10.89 1.13 18.16 131354 11.40 1.17 18.56 131354 11.46 1.18 18.70 131355 11.10 1.18 18.44 131355 11.12 1.19 18.76 131356 11.58 1.21 18.88 131356 11.58 1.21 18.95 131357 11.74 1.23 18.96 131357 11.84 1.25 19.10 131358 11.80 1.27 18.89 131358 11.86 1.28 19.08 131359 8.81 1.09 15.59 131359 8.84 1.09 15.55 131360 2.12 .42 3.06 131360 2.14 .41 2.98 131361 1.74 .34 1.97 131361 1.75 .34 1.87 131362 15.30 1.10 17.88 131362 15.38 1.10 17.72 131363 20.49 1.11 17.75 131363 20.57 1.12 17.84 131364 16.09 1.09 17.04 131364 16.43 1.15 17.17 131365 11.64 1.14 18.18 131365 11.65 1.17 18.35 131366 15.05 1.13 17.28 131366 15.08 1.12 17.19 131367 14.44 1.12 17.54 131367 14.45 1.14 17.50 131368 13.84 1.14 17.34 131368 14.03 1.15 17.54 131369 13.07 1.08 17.06 131369 13.22 1.09 17.61 131370 12.43 1.10 17.71 131370 12.48 1.11 17.59 131371 12.51 1.13 17.67 131371 12.54 1.11 17.58 131372 11.06 1.09 17.40 131372 11.13 1.10 17.42 131373 11.20 1.10 17.39 131373 11.25 1.11 17.48 131374 10.57 1.11 17.61 131374 10.82 1.11 17.68 131375 10.98 1.14 17.79 131375 11.06 1.13 18.02 131376 11.23 1.17 18.07 131376 11.32 1.16 18.16 131377 11.13 1.14 18.07 131377 11.15 1.15 18.20 131378 11.18 1.18 18.47 131378 11.29 1.18 18.58 131379 11.43 1.22 18.69 131379 11.64 1.24 18.94 131380 9.43 1.13 16.15 131380 9.46 1.15 16.11 131381 2.41 .46 3.86 131381 2.44 .46 3.97 131382 16.30 1.12 16.96 131382 16.30 1.11 17.24 131383 20.98 1.15 17.68 131383 20.99 1.17 17.63 131384 14.17 1.09 16.67 131384 14.22 1.08 16.65 131385 11.32 1.12 17.29 131385 11.34 1.11 17.21 131386 12.84 1.09 16.89 131386 12.93 1.08 16.53 131387 12.71 1.09 16.68 131387 12.76 1.09 16.90 131388 12.73 1.10 17.19 131388 12.81 1.10 17.15 131389 12.49 1.11 17.08 131389 12.61 1.11 17.37 131390 11.19 1.10 17.11 131390 11.23 1.10 17.17 131391 10.57 1.12 16.93 131391 10.59 1.09 17.10 131392 10.47 1.09 17.09 131392 10.67 1.11 16.95 131393 10.60 1.09 17.37 131393 10.66 1.10 17.02 131394 10.96 1.13 17.70 131394 11.01 1.13 17.77 131395 10.96 1.14 17.91 131395 11.01 1.14 17.98 131396 11.18 1.15 18.05 131396 11.23 1.17 18.22 131397 11.45 1.18 18.36 131397 11.57 1.18 18.40 131398 10.78 1.19 18.23 131398 10.80 1.18 18.01 131399 11.28 1.21 18.55 131399 11.34 1.22 18.26 131400 9.62 1.13 16.27 131400 9.67 1.13 16.09 131401 1.52 .30 1.49 131401 1.53 .30 1.59 131402 15.21 1.08 16.87 131402 15.23 1.05 16.63 131403 16.95 1.08 16.66 131403 17.26 1.08 16.48 131404 15.97 1.08 16.81 131404 16.16 1.11 16.71 131405 11.71 1.14 17.86 131405 11.73 1.13 17.58 131406 10.80 1.16 17.17 131406 10.93 1.17 17.21 131407 13.35 1.15 17.32 131407 13.47 1.13 17.09 131408 12.73 1.15 17.39 131408 12.74 1.13 17.40 131409 11.08 1.08 16.32 131409 11.23 1.07 16.32 131410 10.94 1.09 16.44 131410 11.00 1.09 16.52 131411 10.75 1.09 16.53 131411 11.11 1.10 16.46 131412 9.64 1.15 16.02 131412 9.65 1.11 16.13 131413 9.61 1.11 16.08 131413 9.65 1.10 16.22 131414 9.66 1.10 16.18 131414 9.90 1.10 16.35 131415 9.98 1.20 16.82 131415 10.29 1.12 16.81 131416 10.03 1.14 17.09 131416 10.08 1.14 16.91 131418 10.24 1.17 17.45 131418 10.40 1.16 17.40 131419 10.19 1.19 17.46 131419 10.28 1.19 17.45 131420 .96 .34 .74 131420 .96 .34 .91 131421 .91 .32 .75 131421 .97 .32 .77 131422 15.34 1.10 16.16 131422 15.35 1.11 16.29 131423 17.40 1.10 16.06 131423 17.42 1.13 15.97 131424 16.92 1.13 16.46 131424 17.05 1.15 16.43 131425 10.73 1.18 16.86 131425 10.88 1.14 16.62 131426 13.19 1.11 16.38 131426 13.27 1.12 16.37 131427 14.01 1.11 15.89 131427 14.06 1.11 15.97 131428 11.75 1.08 15.55 131428 11.76 1.09 15.60 131429 11.96 1.11 15.84 131429 12.00 1.10 15.83 131430 10.81 1.09 16.26 131430 10.85 1.11 16.05 131431 10.28 1.10 16.36 131431 10.38 1.12 16.37 131432 9.86 1.13 16.35 131432 10.13 1.12 16.34 131433 10.04 1.12 16.42 131433 10.11 1.16 16.53 131434 9.74 1.11 16.72 131434 9.83 1.12 16.42 131435 9.79 1.13 16.90 131435 9.99 1.16 17.00 131436 10.32 1.23 17.41 131436 10.46 1.19 17.42 131437 10.10 1.19 17.19 131437 10.12 1.21 17.06 131438 11.37 1.30 18.57 131438 11.41 1.33 18.37 131439 11.83 1.39 19.86 131439 11.88 1.40 19.85 131440 10.65 1.36 19.40 131440 10.83 1.37 19.70 131441 4.80 .82 11.87 131441 4.80 .82 11.70 131442 17.49 1.09 15.54 131442 17.49 1.10 15.54 131443 19.30 1.13 15.87 131443 19.38 1.13 15.84 131444 17.78 1.13 15.99 131444 17.87 1.14 15.99 131445 10.74 1.15 16.56 131445 10.78 1.18 16.83 131446 15.41 1.16 16.61 131446 15.52 1.18 16.79 131447 17.25 1.16 16.20 131447 17.39 1.16 16.27 131448 16.56 1.15 16.03 131448 16.62 1.15 16.14 131449 14.50 1.15 15.95 131449 14.61 1.15 15.96 131450 13.44 1.10 16.19 131450 13.56 1.10 16.45 131451 11.39 1.08 16.06 131451 11.47 1.08 16.17 131452 10.41 1.07 16.08 131452 10.42 1.08 15.82 131453 10.29 1.08 16.13 131453 10.31 1.09 16.15 131454 10.80 1.14 16.51 131454 10.90 1.13 16.57 131455 10.94 1.14 16.90 131455 10.97 1.14 17.11 131456 10.65 1.14 16.97 131456 10.77 1.13 17.04 131457 10.49 1.14 16.90 131457 10.53 1.14 16.83 131458 11.98 1.25 19.21 131458 12.07 1.24 18.69 131459 13.07 1.40 20.64 131459 13.11 1.40 19.51 131460 6.46 .89 14.26 131460 6.48 .90 14.09 131461 3.88 .63 10.24 131461 3.89 .63 10.31 131462 19.66 1.14 16.47 131462 19.78 1.13 16.31 131463 22.43 1.16 16.68 131463 22.49 1.16 16.96 131464 18.48 1.16 16.87 131464 18.51 1.15 16.85 131465 11.75 1.15 16.83 131465 11.75 1.16 17.45 131466 14.69 1.24 17.95 131466 14.72 1.24 18.00 131467 17.29 1.16 16.51 131467 17.35 1.14 16.53 131468 18.00 1.16 16.94 131468 18.06 1.14 16.55 131469 16.01 1.15 16.99 131469 16.11 1.15 16.60 131470 14.73 1.11 16.78 131470 14.81 1.12 16.92 131471 13.46 1.12 16.73 131471 13.51 1.15 17.41 131472 12.14 1.14 17.00 131472 12.17 1.15 16.78 131473 11.60 1.15 16.99 131473 11.71 1.15 17.15 131474 11.26 1.15 17.16 131474 11.48 1.15 17.11 131475 11.19 1.16 17.44 131475 11.26 1.18 17.34 131476 11.37 1.19 17.49 131476 11.39 1.19 17.62 131477 11.43 1.21 18.32 131477 11.46 1.21 18.07 131478 12.25 1.27 19.20 131478 12.31 1.27 19.42 131479 10.97 1.28 18.41 131479 10.99 1.29 18.62 131480 6.49 .93 14.82 131480 6.54 .94 14.17 131481 1.44 .27 1.94 131481 1.45 .27 2.02 131482 16.87 1.15 17.37 131482 17.28 1.15 17.32 131483 22.68 1.16 17.24 131483 22.79 1.17 17.01 131484 21.53 1.17 16.82 131484 21.80 1.17 16.91 131485 11.23 1.15 17.26 131485 11.30 1.16 17.30 131486 16.94 1.16 17.80 131486 17.22 1.19 17.67 131487 20.95 1.15 17.20 131487 21.03 1.18 17.16 131488 18.79 1.16 17.00 131488 19.00 1.16 17.17 131489 16.77 1.15 16.97 131489 17.30 1.15 17.31 131490 15.16 1.14 16.93 131490 15.35 1.14 17.12 131491 13.96 1.16 16.81 131491 14.01 1.15 16.75 131492 11.94 1.11 16.71 131492 12.03 1.12 16.53 131493 11.58 1.13 16.85 131493 11.64 1.14 17.08 131494 11.10 1.11 16.86 131494 11.15 1.12 17.03 131495 11.09 1.15 17.19 131495 11.12 1.15 17.42 131496 11.04 1.16 17.70 131496 12.48 1.18 17.74 131497 11.26 1.18 17.92 131497 11.27 1.20 17.90 131498 12.07 1.27 18.74 131498 12.08 1.27 18.79 131499 11.77 1.32 19.18 131499 11.83 1.31 19.57 131500 1.27 .25 1.45 131500 1.30 .26 1.53 131501 1.25 .24 1.47 131501 1.26 .23 1.46 131502 22.69 1.13 17.28 131502 22.70 1.15 17.11 131503 23.33 1.17 17.11 131503 23.76 1.17 17.60 131504 22.50 1.18 17.73 131504 25.37 1.17 17.69 131505 11.57 1.17 17.47 131505 11.63 1.18 17.59 131506 16.72 1.21 17.58 131506 16.86 1.20 17.55 131507 20.67 1.16 17.73 131507 20.73 1.18 17.18 131508 18.58 1.16 17.18 131508 18.60 1.17 17.29 131509 15.65 1.12 16.80 131509 15.72 1.14 16.91 131510 14.62 1.10 16.51 131510 14.94 1.11 16.99 131511 12.32 1.09 16.45 131511 12.36 1.12 16.76 131512 11.27 1.12 16.59 131512 11.97 1.11 16.63 131513 10.66 1.13 16.61 131513 10.69 1.12 16.49 131514 11.39 1.14 16.86 131514 11.44 1.13 16.88 131515 11.32 1.14 17.25 131515 11.46 1.14 16.96 131516 11.20 1.17 17.74 131516 11.23 1.16 17.26 131517 8.54 .96 13.66 131517 8.85 .97 13.56 131518 11.38 1.19 18.03 131518 11.51 1.19 18.00 131519 12.54 1.31 19.37 131519 12.65 1.32 19.46 131520 3.67 .69 7.22 131520 3.71 .67 7.04 131521 1.37 .26 1.14 131521 1.38 .24 1.09 131522 22.50 1.16 17.13 131522 22.59 1.15 16.93 131523 23.62 1.17 17.30 131523 24.68 1.18 17.53 131524 17.89 1.18 17.42 131524 18.42 1.18 17.54 131525 11.35 1.17 17.03 131525 11.48 1.17 16.96 131526 18.04 1.15 17.48 131526 18.20 1.18 17.45 131527 17.21 1.16 16.60 131527 17.27 1.16 16.87 131528 17.49 1.15 16.87 131528 18.83 1.15 16.67 131529 15.40 1.14 16.53 131529 15.51 1.13 16.48 131530 14.69 1.15 16.67 131530 15.17 1.17 16.62 131531 12.33 1.12 16.36 131531 12.42 1.11 16.23 131532 12.15 1.15 16.84 131532 12.31 1.14 16.56 131533 11.39 1.13 16.72 131533 11.57 1.15 16.74 131534 11.16 1.13 16.71 131534 11.87 1.11 16.71 131535 11.19 1.15 17.13 131535 11.20 1.17 16.97 131536 11.70 1.23 17.52 131536 12.15 1.22 17.87 131537 12.04 1.32 19.21 131537 12.49 1.33 19.00 131538 12.41 1.34 19.44 131538 13.12 1.34 19.37 131539 10.38 1.24 17.85 131539 10.57 1.24 17.85 131540 2.38 .42 4.46 131540 2.40 .41 4.60 131541 1.58 .26 2.12 131541 1.63 .27 2.15 131542 19.41 1.12 16.68 131542 19.57 1.12 16.78 131543 23.34 1.16 16.93 131543 23.52 1.18 17.03 131544 19.13 1.13 17.06 131544 19.43 1.13 16.48 131545 11.31 1.19 17.97 131545 11.57 1.19 17.83 131546 11.85 1.16 16.63 131546 11.94 1.16 16.62 131547 12.14 1.18 17.12 131547 12.21 1.17 17.36 131548 15.86 1.15 16.48 131548 15.91 1.14 16.74 131549 14.37 1.16 16.66 131549 14.62 1.15 16.70 131550 13.39 1.13 16.39 131550 13.46 1.13 16.54 131551 11.70 1.12 16.74 131551 12.98 1.14 16.47 131552 10.57 1.12 16.59 131552 10.59 1.11 16.40 131553 10.92 1.14 16.80 131553 11.41 1.13 16.76 131554 11.60 1.19 17.22 131554 11.73 1.18 17.49 131555 12.05 1.25 18.27 131555 12.43 1.25 18.13 131556 12.48 1.32 18.88 131556 14.30 1.32 18.98 131557 12.24 1.34 19.76 131557 12.27 1.38 19.43 131558 9.05 1.15 18.39 131558 9.06 1.12 18.55 131559 6.34 .88 14.21 131559 6.45 .87 14.36 131560 2.96 .43 7.31 131560 4.46 .43 7.41 131561 1.14 .12 1.17 131561 2.32 .12 1.20 131562 9.66 1.05 16.77 131562 9.68 1.04 16.84 131563 23.33 1.16 17.55 131563 26.44 1.16 17.59 131564 1.62 .19 2.94 131564 1.70 .18 3.20 131565 22.19 1.15 17.71 131565 22.22 1.16 17.16 131566 15.48 1.11 17.15 131566 15.75 1.09 17.15 131567 18.77 1.11 17.07 131567 18.81 1.15 17.18 131568 16.47 1.13 17.06 131568 16.77 1.11 16.86 131569 15.81 1.15 17.39 131569 15.93 1.14 17.51 131570 14.10 1.13 17.48 131570 14.30 1.14 17.37 131571 12.29 1.10 16.95 131571 12.46 1.10 17.11 131572 11.42 1.12 17.10 131572 12.07 1.12 17.06 131573 11.21 1.13 17.22 131573 11.36 1.11 17.45 131574 11.41 1.10 17.34 131574 11.43 1.10 17.38 131575 11.14 1.14 17.52 131575 11.17 1.16 17.69 131576 12.64 1.31 19.72 131576 12.78 1.33 20.00 131577 11.92 1.33 20.62 131577 14.02 1.33 20.96 131578 6.13 .84 13.63 131578 6.21 .83 13.60 131579 2.78 .41 6.96 131579 2.82 .41 7.17 131580 1.67 .22 3.94 131580 1.76 .21 3.90 131581 .99 .09 1.26 131581 1.01 .10 1.28 131582 10.20 1.07 17.18 131582 10.22 1.10 16.95 131583 23.92 1.16 17.17 131583 24.00 1.14 17.21 131584 7.23 .84 13.40 131584 7.30 .83 13.45 131585 23.73 1.18 17.28 131585 23.77 1.16 17.45 131586 18.00 1.16 17.24 131586 18.02 1.16 17.27 131587 15.53 1.11 16.52 131587 15.68 1.12 16.57 131588 14.50 1.11 16.37 131588 14.56 1.10 16.59 131589 13.38 1.12 16.99 131589 13.42 1.10 16.68 131590 11.93 1.09 16.69 131590 11.96 1.08 16.75 131591 11.21 1.10 17.00 131591 11.22 1.10 16.96 131592 11.10 1.12 17.17 131592 11.18 1.11 17.16 131593 11.09 1.15 17.53 131593 11.17 1.15 17.63 131594 12.27 1.25 19.30 131594 12.29 1.25 19.10 131595 12.31 1.30 19.99 131595 14.49 1.29 19.83 131596 10.69 1.24 18.42 131596 10.72 1.22 18.48 131597 6.30 .85 13.72 131597 6.38 .87 13.74 131598 3.73 .56 9.20 131598 4.43 .56 9.11 131599 2.39 .36 6.39 131599 2.99 .36 6.37 131600 1.40 .19 3.55 131600 3.75 .19 3.54 131601 1.18 .14 1.51 131601 1.20 .15 1.55 131602 22.51 1.10 16.29 131602 22.69 1.11 16.14 131603 22.63 1.11 16.67 131603 22.67 1.12 16.28 131604 19.95 1.11 16.49 131604 20.16 1.11 16.40 131605 21.46 1.12 16.26 131605 21.57 1.14 16.49 131606 13.90 1.16 17.60 131606 13.91 1.18 17.70 131607 17.05 1.17 17.54 131607 17.09 1.18 17.39 131608 15.92 1.18 17.36 131608 15.98 1.17 17.30 131609 15.01 1.16 17.44 131609 15.07 1.17 17.33 131610 13.08 1.16 17.29 131610 13.12 1.15 17.30 131611 12.09 1.15 17.60 131611 12.16 1.16 17.37 131612 11.69 1.18 18.05 131612 11.73 1.16 17.45 131613 10.93 1.18 17.51 131613 10.96 1.16 17.75 131614 11.32 1.12 18.23 131614 11.45 1.15 18.40 131615 11.86 1.22 19.11 131615 11.87 1.23 19.08 131616 12.80 1.32 20.23 131616 12.89 1.32 19.73 131617 5.13 .76 11.92 131617 5.39 .72 12.04 131618 5.03 .71 12.03 131618 5.07 .71 12.06 131619 2.70 .36 6.89 131619 2.70 .38 7.02 131620 1.25 0.00 1.57 131620 1.26 .09 1.71 131621 1.15 0.00 1.23 131621 1.23 0.00 1.22 131622 23.38 1.10 17.43 131622 23.45 1.16 17.51 131623 23.44 1.16 17.99 131623 23.46 1.17 17.80 131624 7.87 .85 13.71 131624 7.89 .86 13.89 131625 23.28 1.19 17.93 131625 23.35 1.18 17.83 131626 18.20 1.14 17.85 131626 18.35 1.15 17.35 131627 18.11 1.14 17.52 131627 18.16 1.13 17.79 131628 17.18 1.16 17.87 131628 17.23 1.16 17.82 131629 15.15 1.14 17.54 131629 15.32 1.14 17.64 131630 12.66 1.06 17.27 131630 12.86 1.10 17.30 131631 12.00 1.12 17.44 131631 12.14 1.12 17.39 131632 11.49 1.16 17.33 131632 11.53 1.12 17.29 131633 11.09 1.13 17.90 131633 11.18 1.13 17.54 131634 10.82 1.12 17.88 131634 10.83 1.14 18.10 131635 11.46 1.19 18.49 131635 11.63 1.19 18.65 131636 12.69 1.31 20.68 131636 12.71 1.32 20.91 131637 8.34 1.08 17.67 131637 8.39 1.08 17.82 131638 10.88 1.21 19.91 131638 11.03 1.26 20.11 131639 4.62 .67 11.28 131639 4.63 .68 11.36 131640 4.81 .70 12.63 131640 4.86 .71 12.59 131641 1.23 .08 1.03 131641 1.28 .09 1.06 131642 22.54 1.12 17.87 131642 22.70 1.15 18.05 131643 22.53 1.18 18.21 131643 22.57 1.17 18.09 131644 11.70 1.26 19.93 131644 11.75 1.25 19.77 131645 17.42 1.15 17.52 131645 17.58 1.17 17.80 131646 15.39 1.15 17.41 131646 15.43 1.15 17.62 131647 14.21 1.14 17.64 131647 14.34 1.15 17.87 131648 12.73 1.15 17.55 131648 12.75 1.13 17.70 131649 11.08 1.11 17.22 131649 11.14 1.07 16.94 131650 11.66 1.14 17.57 131650 11.67 1.14 17.56 131651 10.80 1.13 17.30 131651 10.90 1.13 17.35 131652 10.94 1.14 17.52 131652 11.08 1.16 17.42 131653 10.63 1.16 17.38 131653 10.70 1.17 17.68 131654 11.51 1.21 18.59 131654 11.67 1.21 18.69 131655 12.30 1.27 19.58 131655 12.37 1.28 19.39 131656 12.53 1.38 20.67 131656 12.66 1.37 20.55 131657 12.68 1.35 22.23 131657 12.77 1.40 22.40 131658 10.39 1.26 20.16 131658 10.50 1.28 20.09 131659 6.81 .94 15.04 131659 6.88 .96 14.82 131660 4.46 .71 11.15 131660 4.53 .69 11.28 131661 1.56 .23 2.31 131661 1.59 .25 2.34 131662 19.74 1.09 16.73 131662 20.12 1.15 16.70 131663 23.17 1.20 17.45 131663 23.28 1.20 17.42 131664 21.96 1.17 17.84 131664 21.97 1.18 17.64 131665 21.27 1.13 17.02 131665 21.50 1.16 17.15 131666 131666 15.63 1.16 17.68 131666 15.75 1.19 17.39 131667 131667 18.00 1.16 17.45 131667 18.05 1.17 17.34 131668 16.22 1.15 17.77 131668 16.37 1.16 17.17 131669 14.66 1.17 17.13 131669 14.74 1.15 17.08 131670 13.58 1.16 17.00 131670 13.59 1.16 16.90 131671 12.74 1.16 17.54 131671 12.95 1.15 17.51 131672 11.62 1.16 17.37 131672 11.79 1.17 16.97 131673 11.28 1.10 17.57 131673 11.32 1.13 17.48 131674 11.22 1.17 17.75 131674 11.32 1.17 17.82 131675 11.45 1.19 18.04 131675 11.51 1.20 17.97 131676 12.26 1.29 19.77 131676 12.48 1.30 19.27 131677 12.74 1.35 20.52 131677 12.78 1.35 20.83 131678 12.09 1.36 20.53 131678 12.29 1.37 20.48 131679 7.05 .99 15.23 131679 7.11 .99 15.29 131680 2.65 .46 6.88 131680 2.70 .48 7.05 131681 1.43 .24 2.25 131681 1.45 .25 2.29 131682 22.09 1.18 17.44 131682 22.09 1.14 17.56 131683 23.12 1.18 17.85 131683 23.23 1.20 17.88 131684 17.71 1.27 18.12 131684 17.94 1.18 18.04 131685 22.58 1.44 18.31 131685 22.68 1.20 18.25 131686 15.85 1.31 18.42 131686 16.02 1.42 18.12 131687 19.23 1.17 18.02 131687 19.25 1.21 18.05 131688 16.86 1.19 17.97 131688 16.88 1.16 18.29 131689 15.05 1.15 18.28 131689 15.08 1.17 18.20 131690 13.66 1.12 18.28 131690 13.71 1.10 18.30 131691 12.47 1.12 18.17 131691 12.52 1.18 18.23 131692 11.81 1.15 18.66 131692 11.93 1.14 18.25 131693 11.32 1.17 18.80 131693 11.38 1.14 18.48 131694 11.48 1.20 19.16 131694 11.53 1.18 19.32 131695 11.82 1.21 20.01 131695 11.88 1.36 19.83 131696 12.11 1.25 20.42 131696 12.21 1.27 20.42 131697 13.15 1.38 22.27 131697 13.29 1.38 22.39 131698 11.92 1.34 22.16 131698 12.02 1.31 22.33 131699 8.80 1.10 19.37 131699 8.88 1.11 19.29 131700 3.78 .57 10.38 131700 3.83 .58 10.52 131701 1.53 .21 2.64 131701 1.58 .22 2.72 131702 22.35 1.17 18.45 131702 22.44 1.12 19.78 131703 23.37 1.18 18.75 131703 23.39 1.17 18.85 131704 22.78 1.19 18.71 131704 22.90 1.18 18.90 131705 21.98 1.24 18.65 131705 22.03 1.20 19.11 131706 18.98 1.12 18.51 131706 19.06 1.10 18.45 131707 17.70 1.13 18.56 131707 17.75 1.16 18.59 131708 15.79 1.22 18.45 131708 15.87 1.14 18.32 131709 14.65 1.13 18.66 131709 14.73 1.14 18.42 131710 13.34 1.12 18.67 131710 13.36 1.23 18.42 131711 11.81 1.14 18.49 131711 12.01 1.14 18.56 131712 11.71 1.14 18.61 131712 12.20 1.18 18.58 131713 11.27 1.17 18.71 131713 11.41 1.14 18.57 131714 11.45 1.12 19.04 131714 11.59 1.15 19.19 131715 11.79 1.18 19.81 131715 11.79 1.17 20.12 131716 12.13 1.22 20.61 131716 12.20 1.30 20.39 131717 12.90 1.36 22.39 131717 13.10 1.42 22.38 131718 12.86 1.39 23.17 131718 12.89 1.41 23.22 131719 10.72 1.30 21.43 131719 10.78 1.26 21.20 131720 4.71 .71 12.59 131720 4.88 .72 12.70 131721 1.61 .23 3.00 131721 1.61 .25 3.10 131722 15.09 1.01 16.63 131722 15.16 1.05 16.87 131723 16.72 1.06 17.38 131723 16.76 1.06 17.14 131724 18.01 1.11 17.90 131724 18.10 1.11 17.69 131725 17.27 1.12 17.98 131725 17.28 1.12 17.88 131726 14.47 1.12 17.95 131726 14.57 1.12 17.75 131727 16.86 1.15 18.01 131727 16.92 1.17 18.29 131728 12.59 1.09 17.48 131728 12.63 1.09 17.15 131729 11.51 1.10 17.60 131729 11.57 1.10 17.53 131730 10.36 1.06 17.71 131730 10.46 1.04 17.29 131731 10.04 1.08 17.73 131731 10.15 1.07 17.52 131732 11.38 1.13 18.23 131732 11.39 1.12 18.31 131733 11.45 1.13 18.24 131733 11.50 1.17 18.57 131734 11.20 1.14 18.51 131734 11.30 1.15 18.56 131735 11.35 1.18 19.27 131735 11.44 1.18 19.34 131736 11.71 1.27 19.48 131736 11.83 1.31 19.63 131737 11.90 1.25 20.24 131737 11.99 1.23 20.34 131738 11.82 1.18 20.07 131738 11.85 1.20 20.03 131739 12.54 1.34 21.76 131739 12.58 1.34 21.73 131740 6.89 .93 16.06 131740 6.98 .93 15.87 131741 1.76 .30 3.94 131741 1.84 .31 3.94 131742 14.47 1.01 16.51 131742 14.57 1.02 16.54 131743 17.26 1.08 17.07 131743 17.38 1.08 17.31 131744 17.74 1.10 17.39 131744 17.86 1.10 17.48 131745 14.96 1.09 16.79 131745 14.99 1.08 16.93 131746 14.31 1.05 17.46 131746 14.50 1.10 17.18 131747 13.18 1.06 17.29 131747 13.19 1.08 17.04 131748 12.24 1.08 17.02 131748 12.30 1.07 17.14 131749 11.28 1.07 17.14 131749 11.31 1.07 17.46 131750 10.50 1.08 17.74 131750 10.61 1.07 17.23 131751 10.35 1.08 17.25 131751 10.52 1.07 17.14 131752 11.78 1.11 17.79 131752 11.93 1.13 18.30 131753 11.47 1.15 17.80 131753 11.75 1.12 18.30 131754 11.19 1.08 17.86 131754 11.27 1.12 18.56 131755 11.19 1.10 17.80 131755 11.28 1.15 18.34 131756 10.76 1.13 18.42 131756 11.06 1.14 18.64 131757 10.77 1.16 18.38 131757 10.93 1.17 18.61 131758 10.82 1.16 18.52 131758 10.93 1.18 18.52 131759 11.61 1.24 19.34 131759 11.85 1.26 19.54 131760 12.75 1.38 21.39 131760 12.77 1.37 21.40 131761 9.06 1.04 12.73 131761 9.12 1.02 12.74 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2.62 .48 4.42 131804 2.65 .48 4.39 131805 12.92 1.20 18.11 131805 12.98 1.19 18.08 131806 13.23 1.23 18.51 131806 13.23 1.23 18.58 131807 12.69 1.30 19.42 131807 12.71 1.32 19.46 131808 7.76 1.07 14.26 131808 7.76 1.06 14.52 131809 2.57 .49 4.53 131809 2.57 .50 4.51 131810 15.95 1.36 20.02 131810 16.00 1.40 20.04 131811 4.99 .76 8.15 131811 5.03 .75 8.08 131812 8.63 1.14 15.30 131812 8.77 1.19 15.70 131813 1.99 .46 3.03 131813 2.03 .48 3.14 131814 12.71 1.40 18.47 131814 13.02 1.32 18.54 131815 8.31 1.15 15.19 131815 8.32 1.21 15.18 131816 3.76 .77 7.91 131816 3.94 .77 7.86 131817 2.10 .50 3.38 131817 2.13 .48 3.36 131818 10.13 1.22 16.01 131818 10.20 1.20 16.99 131819 7.00 1.07 13.60 131819 7.03 1.07 13.63 131820 2.13 .53 3.60 131820 2.18 .48 3.73 131821 1.88 .44 2.81 131821 1.89 .43 2.79 131822 10.15 1.23 16.02 131822 10.34 1.21 16.01 131823 8.68 1.14 14.52 131823 8.74 1.17 14.67 131824 4.46 2.39 8.92 131824 5.22 .81 9.03 131825 1.89 .46 3.04 131825 1.95 .45 2.91 131826 11.46 1.33 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16.48 131873 9.60 1.09 16.34 131873 9.65 1.09 16.55 131874 9.45 1.10 16.35 131874 9.53 1.11 16.72 131875 6.50 .96 12.62 131875 6.54 .95 12.72 131876 2.65 .50 4.94 131876 2.68 .49 5.01 131877 9.87 1.08 16.16 131877 9.88 1.06 16.13 131878 9.76 1.07 16.47 131878 9.84 1.06 16.16 131879 10.10 1.09 16.73 131879 10.22 1.09 16.71 131880 9.76 1.08 16.46 131880 9.82 1.08 16.56 131881 9.65 1.08 16.42 131881 9.77 1.09 16.65 131882 9.27 1.09 16.24 131882 9.32 1.10 16.35 131883 8.04 1.04 14.70 131883 8.14 1.03 15.00 131884 2.49 .45 4.19 131884 2.51 .44 4.20 131885 12.65 1.03 15.43 131885 12.92 1.00 15.40 131886 4.64 .63 7.49 131886 4.70 .59 7.41 131887 12.49 1.05 15.87 131887 12.57 1.06 16.07 131888 11.62 1.08 16.48 131888 11.64 1.06 16.10 131889 10.65 1.09 16.53 131889 10.68 1.07 16.95 131890 10.05 1.05 16.26 131890 10.71 1.08 16.55 131891 9.83 1.11 16.54 131891 9.96 1.10 16.78 131892 9.66 1.09 16.65 131892 9.72 1.09 16.52 131893 10.01 1.13 16.62 131893 10.14 1.07 16.97 131894 10.08 1.14 17.07 131894 10.13 1.12 17.12 131895 9.57 1.12 16.98 131895 9.67 1.08 17.14 131896 9.43 1.13 17.17 131896 9.76 1.07 16.91 131897 9.44 1.12 16.84 131897 9.49 1.10 16.69 131898 10.57 1.18 17.96 131898 10.65 1.16 17.91 131899 2.13 .39 3.29 131899 2.14 .38 3.36 131901 13.79 1.03 15.51 131901 13.84 1.02 15.40 131902 17.38 1.07 16.43 131902 17.49 1.04 16.51 131903 15.72 1.07 16.71 131903 15.82 1.07 16.40 131904 16.43 1.07 16.90 131904 16.45 1.07 16.62 131905 13.66 1.08 16.75 131905 13.72 1.07 16.75 131906 13.11 1.06 17.09 131906 13.11 1.08 16.76 131907 12.09 1.05 16.75 131907 12.16 1.07 16.91 131909 10.85 1.06 16.77 131909 10.86 1.08 17.50 131910 10.51 1.08 17.10 131910 10.60 1.08 16.76 131911 10.25 1.06 16.66 131911 10.30 1.06 16.79 131912 10.05 1.05 16.80 131912 10.12 1.07 16.73 131913 10.28 1.08 17.12 131913 10.54 1.09 16.79 131914 11.15 1.13 18.23 131914 11.27 1.14 17.65 131915 11.29 1.16 18.33 131915 11.31 1.18 18.16 131916 10.88 1.18 17.85 131916 10.95 1.19 17.98 131919 7.85 .98 12.99 131919 7.91 .96 13.07 131920 1.90 .35 2.33 131920 1.93 .36 2.42 131921 13.86 1.01 15.42 131921 14.09 .99 15.23 131922 13.88 1.01 15.23 131922 13.94 1.02 15.32 131923 17.49 1.08 16.24 131923 17.72 1.07 16.34 131924 18.31 1.12 16.48 131924 18.32 1.11 16.35 131925 16.07 1.09 16.15 131925 16.39 1.09 16.50 131926 15.31 1.08 16.74 131926 15.33 1.09 16.45 131927 14.97 1.10 17.04 131927 15.08 1.10 16.71 131928 12.41 1.09 16.65 131928 12.56 1.10 16.70 131929 12.37 1.07 16.80 131929 12.44 1.10 16.64 131930 11.46 1.09 16.56 131930 11.47 1.07 16.72 131931 11.08 1.10 16.61 131931 11.11 1.09 16.66 131932 11.64 1.11 16.75 131932 11.73 1.10 16.62 131933 10.34 1.09 16.47 131933 10.42 1.09 16.50 131934 10.32 1.10 16.48 131934 10.34 1.09 16.50 131935 10.98 1.12 17.38 131935 11.13 1.12 16.95 131936 7.46 .89 12.43 131936 7.56 .88 12.27 131937 10.88 1.13 17.65 131937 10.93 1.15 17.56 131938 10.51 1.13 17.50 131938 10.58 1.14 17.51 131939 10.17 1.15 16.98 131939 10.21 1.14 16.93 131940 1.84 .38 2.35 131940 1.85 .33 2.46 131941 13.57 1.03 14.87 131941 13.76 1.01 14.84 131942 14.71 1.03 15.21 131942 14.81 1.03 15.08 131943 18.79 1.10 16.30 131943 18.87 1.23 16.22 131944 19.32 1.11 16.28 131944 21.67 1.13 16.17 131945 16.36 1.08 16.10 131945 16.38 1.08 16.26 131946 14.57 1.07 16.14 131946 14.70 1.09 16.16 131947 13.01 1.08 16.08 131947 13.15 1.09 15.79 131948 13.06 1.10 16.21 131948 13.07 1.11 16.15 131949 12.88 1.12 16.18 131949 12.95 1.12 16.32 131950 11.33 1.10 15.83 131950 11.52 1.10 15.95 131951 11.38 1.11 16.15 131951 11.42 1.10 16.15 131952 10.61 1.11 16.04 131952 10.67 1.10 15.91 131953 10.74 1.09 16.28 131953 10.79 1.08 16.23 131954 10.62 1.12 16.50 131954 10.65 1.10 16.59 131955 10.47 1.11 16.74 131955 10.51 1.11 16.66 131956 10.86 1.18 17.26 131956 11.81 1.18 17.20 131957 10.53 1.14 16.38 131957 10.57 1.15 16.59 131958 11.04 1.19 17.24 131958 11.05 1.19 17.42 131959 9.69 1.14 15.76 131959 9.70 1.15 16.03 131960 1.85 .35 2.45 131960 2.10 .36 2.37 131961 13.53 1.03 15.29 131961 13.54 1.07 15.15 131962 15.34 1.07 15.86 131962 15.46 1.06 15.59 131963 17.58 1.12 16.54 131963 17.62 1.14 16.61 131964 11.09 1.19 17.42 131964 11.23 1.17 17.21 131965 16.94 1.13 17.18 131965 17.07 1.14 17.27 131966 15.73 1.12 16.97 131966 16.84 1.15 17.15 131967 13.53 1.10 16.92 131967 13.62 1.11 16.91 131968 12.57 1.12 16.85 131968 12.60 1.11 16.88 131969 11.84 1.14 17.30 131969 11.90 1.08 17.46 131970 10.89 1.08 17.24 131970 11.00 1.08 17.31 131971 10.60 1.08 17.40 131971 10.80 1.10 17.46 131972 10.65 1.12 17.80 131972 10.72 1.12 17.62 131973 10.92 1.13 18.45 131973 10.94 1.14 18.26 131974 11.26 1.16 19.01 131974 11.35 1.16 19.00 131975 11.92 1.23 19.66 131975 11.97 1.21 19.65 131976 10.05 1.11 16.29 131976 10.27 1.09 16.54 131977 11.95 1.24 20.29 131977 11.95 1.28 20.40 131978 9.78 1.08 15.93 131978 9.84 1.06 16.04 131979 2.22 .36 2.94 131979 2.33 .34 2.99 131980 2.02 .33 1.98 131980 2.05 .34 1.93 131981 17.43 1.05 17.21 131981 17.58 1.08 17.06 131982 17.33 1.05 17.45 131982 17.47 1.06 17.47 131983 12.86 1.09 18.06 131983 13.06 1.12 18.37 131984 20.11 1.11 18.13 131984 20.46 1.12 18.17 131985 18.80 1.11 18.34 131985 18.90 1.10 18.42 131986 16.76 1.09 18.25 131986 16.78 1.15 18.29 131987 15.36 1.10 18.19 131987 15.38 1.09 18.13 131988 14.27 1.09 18.03 131988 14.39 1.08 18.32 131989 12.40 1.08 18.30 131989 12.45 1.09 18.29 131990 11.04 1.11 17.60 131990 11.21 1.06 17.89 131991 11.51 1.07 17.95 131991 11.67 1.07 17.98 131992 11.42 1.10 18.66 131992 11.46 1.10 18.68 131993 11.37 1.12 18.86 131993 11.45 1.08 18.78 131994 11.51 1.15 19.24 131994 11.63 1.15 19.51 131995 12.13 1.20 20.13 131995 12.18 1.21 20.29 131996 11.18 1.11 18.89 131996 11.23 1.13 19.08 131997 13.12 1.32 22.96 131997 13.23 23.00 131998 8.67 1.05 18.50 131998 8.69 1.10 18.80 131999 3.84 .54 10.00 131999 3.86 .52 10.12 132000 1.79 .21 3.48 132000 1.83 .22 3.43 132001 17.61 1.04 17.27 132001 17.62 1.04 16.86 132002 20.10 1.08 17.73 132002 20.11 1.11 17.85 132003 19.51 1.08 17.70 132003 19.58 1.09 17.69 132004 16.66 1.03 16.94 132004 16.70 1.18 16.56 132005 17.54 1.07 17.38 132005 17.62 1.09 17.77 132006 15.42 1.07 17.49 132006 15.51 1.11 17.58 132007 13.88 1.06 18.11 132007 13.96 1.08 17.43 132008 12.59 1.07 17.63 132008 12.66 1.08 17.39 132009 11.38 1.06 17.27 132009 11.43 1.07 17.05 132010 11.03 1.07 17.51 132010 11.14 1.07 17.53 132011 10.70 1.07 17.54 132011 10.82 1.06 17.19 132012 11.12 1.12 17.87 132012 11.19 1.11 17.84 132013 11.32 1.15 18.65 132013 11.33 1.15 18.63 132014 11.82 1.21 19.43 132014 11.98 1.21 19.07 132015 11.30 1.23 19.21 132015 11.38 1.21 19.36 132016 6.74 .85 14.40 132016 6.78 .84 14.32 132017 4.92 .68 11.49 132017 4.92 .70 11.58 132018 3.12 .45 7.76 132018 3.14 .46 7.65 132019 3.30 .48 8.35 132019 4.44 .49 8.29 132020 2.04 .28 4.76 132020 2.26 .29 4.71 132021 15.32 1.04 15.90 132021 15.52 1.00 15.79 132022 18.42 1.06 16.48 132022 18.46 1.05 16.35 132024 16.89 1.08 16.33 132024 18.10 1.08 16.48 132025 15.26 1.07 16.49 132025 16.05 1.06 16.36 132026 14.23 1.06 16.69 132026 14.26 1.09 16.43 132027 12.46 1.07 16.67 132027 12.56 1.07 16.54 132028 11.99 1.07 16.45 132028 12.08 1.06 16.46 132029 10.78 1.07 16.55 132029 10.82 1.08 16.25 132030 10.92 1.09 16.85 132030 10.97 1.08 16.80 132031 11.04 1.09 16.88 132031 11.13 1.09 16.86 132032 10.76 1.12 17.20 132032 10.89 1.12 16.97 132033 11.92 1.21 18.32 132033 12.05 1.22 18.76 132034 11.14 1.36 19.18 132034 11.28 1.37 19.42 132035 4.30 .70 10.35 132035 4.54 .71 10.35 132036 3.94 .64 9.84 132036 4.43 .65 9.58 132037 3.85 .67 10.56 132037 3.92 .67 10.29 132038 2.21 .38 5.58 132038 2.24 .40 5.80 132039 2.73 .45 7.17 132039 2.80 .44 7.20 132040 2.03 .32 4.41 132040 2.07 .31 4.41 132041 17.11 1.20 17.09 132041 17.40 1.20 17.00 132042 18.16 1.20 17.00 132042 18.28 1.22 17.26 132044 16.60 1.23 17.68 132044 16.63 1.23 17.61 132045 14.85 1.22 17.35 132045 16.05 1.21 18.95 132046 14.01 1.21 17.71 132046 14.11 1.21 18.03 132047 13.11 1.22 18.06 132047 13.21 1.26 18.06 132048 11.76 1.24 18.11 132048 11.85 1.22 18.10 132049 11.15 1.23 18.14 132049 11.16 1.26 19.45 132050 10.95 1.24 17.85 132050 12.17 1.24 18.21 132051 11.03 1.23 18.58 132051 13.11 1.20 18.69 132052 11.54 1.27 19.17 132052 11.63 1.26 19.04 132053 12.34 1.39 20.41 132053 13.34 1.39 20.60 132054 11.28 1.33 19.32 132054 11.31 1.34 20.94 132055 11.86 1.41 20.88 132055 13.88 1.40 20.69 132056 10.35 1.33 20.34 132056 10.41 1.34 20.60 132057 5.30 .83 12.87 132057 5.36 .82 12.87 132058 3.27 .56 9.07 132058 3.39 .57 9.15 132059 1.78 .31 4.44 132059 2.73 .31 4.40 132060 1.43 .25 3.61 132060 1.43 .25 3.60 132061 18.32 1.15 16.98 132061 18.40 1.15 16.87 132062 19.23 1.17 17.06 132062 19.23 1.17 17.16 132063 11.55 1.31 19.03 132063 11.87 1.28 19.14 132065 14.82 1.15 16.75 132065 14.97 1.15 17.02 132066 13.86 1.16 17.23 132066 13.88 1.16 16.95 132067 12.35 1.16 17.28 132067 12.99 1.17 16.99 132068 11.27 1.13 17.29 132068 11.30 1.14 17.17 132069 11.43 1.16 17.57 132069 11.43 1.18 17.91 132070 10.60 1.16 17.69 132070 10.65 1.18 17.75 132071 10.97 1.21 18.19 132071 11.34 1.32 18.20 132072 11.05 1.24 18.42 132072 11.18 1.22 18.22 132073 11.20 1.26 18.40 132073 11.21 1.27 18.43 132074 11.61 1.31 19.43 132074 11.62 1.31 19.26 132075 11.85 1.39 20.43 132075 11.88 1.38 20.59 132076 8.75 1.11 16.57 132076 8.78 1.14 16.71 132077 5.65 .85 13.07 132077 5.72 .84 12.79 132078 2.61 .47 6.58 132078 2.64 .48 6.55 132079 1.98 .35 4.72 132079 2.01 .35 4.72 132081 18.64 1.16 15.65 132081 18.68 1.17 15.78 132082 19.92 1.13 16.35 132082 19.96 1.12 16.19 132083 20.85 1.24 15.91 132083 20.99 1.21 15.94 132084 16.75 1.10 16.40 132084 17.03 1.11 16.55 132085 17.42 1.23 16.18 132085 17.64 1.22 15.84 132086 14.80 1.20 15.74 132086 14.92 1.19 15.95 132087 13.73 1.18 15.89 132087 13.78 1.21 16.14 132088 12.35 1.20 16.58 132088 12.35 1.21 16.43 132089 11.30 1.16 16.42 132089 12.09 1.15 16.75 132090 11.10 1.16 16.86 132090 11.25 1.15 17.15 132091 11.06 1.17 16.92 132091 11.20 1.18 17.15 132092 11.30 1.20 17.28 132092 12.20 1.21 17.29 132093 11.72 1.24 17.74 132093 12.31 1.24 17.74 132094 12.05 1.32 18.80 132094 12.18 1.34 19.17 132095 11.30 1.30 18.61 132095 11.34 1.31 18.60 132096 9.11 1.17 16.47 132096 9.16 1.15 16.32 132097 6.61 .90 13.86 132097 6.61 .94 13.90 132098 5.66 .81 12.63 132098 8.80 .82 12.53 132099 2.32 .36 5.11 132099 2.65 .35 5.11 132100 2.18 .27 3.43 132100 3.21 .29 3.45 132101 13.47 1.29 16.36 132101 13.48 1.13 16.79 132102 12.93 1.15 15.74 132102 12.99 1.14 15.82 132103 12.07 1.14 16.40 132103 12.56 1.14 16.21 132104 11.20 1.11 16.10 132104 11.20 1.11 16.28 132105 10.70 1.10 15.83 132105 10.73 1.12 16.09 132106 10.65 1.14 16.42 132106 11.22 1.12 16.56 132107 10.83 1.15 16.67 132107 11.47 1.21 16.39 132108 11.35 1.18 16.59 132108 11.39 1.19 16.44 132109 10.98 1.20 16.63 132109 12.46 1.20 16.60 132110 11.51 1.26 17.92 132110 11.53 1.25 17.43 132112 12.33 1.32 19.02 132112 12.40 1.35 19.15 132113 12.21 1.37 19.79 132113 12.38 1.37 19.79 132114 11.06 1.25 19.25 132114 11.39 1.30 19.20 132115 7.40 .99 14.62 132115 8.88 1.00 14.71 132116 6.11 .85 12.83 132116 6.13 .85 12.60 132117 3.56 .57 8.46 132117 3.57 .56 8.59 132118 2.10 .34 4.66 132118 2.10 .34 4.66 132119 2.84 .33 4.66 132119 3.09 .33 4.66 132120 1.91 .28 3.59 132120 4.50 .29 3.53 132121 24.76 1.22 17.03 132121 24.85 1.27 17.03 132122 25.77 1.30 17.31 132122 25.91 1.29 17.33 132123 24.30 1.27 17.16 132123 24.36 1.28 17.19 132124 12.17 1.14 15.70 132124 13.39 1.14 15.79 132125 18.86 1.24 16.76 132125 19.02 1.23 16.75 132126 16.63 1.23 16.80 132126 17.72 1.26 16.69 132127 14.95 1.23 16.51 132127 15.02 1.22 16.32 132128 14.20 1.23 16.59 132128 14.25 1.22 16.68 132129 11.73 1.18 16.41 132129 11.74 1.15 16.38 132130 11.35 1.20 16.60 132130 11.43 1.20 16.44 132131 11.19 1.26 17.26 132131 11.93 1.24 17.74 132132 11.08 1.23 17.43 132132 11.73 1.23 17.46 132133 11.43 1.26 17.86 132133 11.49 1.28 17.87 132134 12.31 1.35 18.53 132134 13.77 1.36 18.78 132135 12.24 1.45 20.56 132135 12.26 1.46 20.31 132136 5.94 .90 13.37 132136 5.96 .92 13.51 132137 3.25 .54 8.34 132137 3.27 .53 8.32 132139 1.11 .19 2.66 132139 1.20 .17 2.68 132140 1.08 .13 1.84 132140 2.02 .13 1.86 132141 22.72 1.17 17.25 132141 22.92 1.22 17.39 132142 22.74 1.21 17.14 132142 22.95 1.23 17.37 132143 22.95 1.23 17.32 132143 23.81 1.23 17.29 132144 22.20 1.23 17.14 132144 22.24 1.23 17.34 132145 22.02 1.26 17.64 132145 22.04 1.24 17.52 132146 17.97 1.18 17.00 132146 18.02 1.15 17.08 132147 18.54 1.20 17.36 132147 18.73 1.19 17.13 132148 16.53 1.18 17.39 132148 16.53 1.20 17.50 132149 14.59 1.20 17.47 132149 15.61 1.20 17.20 132150 12.99 1.18 16.79 132150 13.03 1.19 17.05 132151 10.89 1.18 17.09 132151 10.92 1.19 16.96 132152 11.25 1.19 17.18 132152 11.83 1.18 17.34 132153 11.06 1.20 17.44 132153 11.22 1.20 17.60 132154 11.32 1.20 17.94 132154 11.49 1.16 17.93 132155 11.79 1.28 18.96 132155 12.82 1.29 18.87 132156 11.63 1.36 19.85 132156 11.89 1.37 19.86 132157 5.04 .78 11.95 132157 5.16 .80 11.71 132158 2.67 .46 7.42 132158 2.72 .47 7.46 132159 .96 .17 2.10 132159 2.07 .17 2.09 132160 .99 .15 1.96 132160 1.85 .15 1.93 132161 26.11 1.19 17.65 132161 26.27 1.22 17.69 132162 27.29 1.24 17.78 132162 27.48 1.24 17.74 132163 22.83 1.19 16.96 132163 22.97 1.20 16.67 132164 22.07 1.18 16.64 132164 22.51 1.20 16.77 132165 20.44 1.19 17.02 132165 20.49 1.19 17.03 132166 16.80 1.16 16.56 132166 16.93 1.15 16.75 132167 16.53 1.17 16.61 132167 16.61 1.10 16.41 132168 14.88 1.21 16.63 132168 14.92 1.18 16.84 132169 13.84 1.17 16.98 132169 13.85 1.17 16.90 132170 12.57 1.16 16.84 132170 12.69 1.16 16.64 132171 11.79 1.16 16.53 132171 11.96 1.16 16.51 132172 11.33 1.17 16.81 132172 11.36 1.16 16.74 132173 11.35 1.20 17.45 132173 11.40 1.21 17.37 132174 11.60 1.24 18.16 132174 11.69 1.24 18.06 132175 12.07 1.35 19.78 132175 12.30 1.30 19.62 132176 8.14 1.10 16.47 132176 8.17 1.11 16.64 132177 4.29 .69 10.51 132177 4.36 .70 10.41 132178 2.22 .40 5.87 132178 2.64 .38 5.96 132179 1.59 .26 3.97 132179 1.60 .24 3.91 132180 1.11 .16 1.95 132180 1.13 .16 1.89 5. Dissolved Inorganic Carbon in Seawater (Bob Gershey) a. Description of Equipment and Technique The total dissolved inorganic carbon content of seawater is defined as the total concentration of carbonate ion, bicarbonate ion and unionized species of carbon dioxide. Before analysis, the sample is treated with acid to convert all ionized species to the unionized form, which is then separated from the liquid phase and subsequently measured using a coulometric titration technique. This involves the reaction of carbon dioxide gas with a dimethysulfoxide solution of ethanoline to produce hydroxyethylcarbamic acid. The acidic solution is titrated with hydroxide ion formed by the electrolytic decomposition of water. The progress of the titration is followed through colorimetric measurement of the absorbance of a Ph indicator dye (thymolphthalein) in the ethanolamine solution. A known volume of seawater is dispensed into a stripping chamber from a pipet of known volume and temperature controlled to within 0.4 _C. It is then acidified with ten percent its volume of an 8% solution of carbon dioxide-free phosphoric acid. The solution in stripped of carbon dioxide gas by bubbling with a stream of nitrogen gas directed through a glass frit. The carrier gas exiting the stripper passes through a magnesium perchlorate trap to remove water vapour and acidic water droplets. The gas stream is then directed into the coulometric titrator where the total amount of carbon dioxide gas is quantified. The coulometer is calibrated in two ways. Calibration using gas loops is accomplished by filling stainless steel sample loops (1.5, 2.5 ml) with 99.995% carbon dioxide gas and injecting these into the coulometer. The temperature and pressure of the gas within the loops must be known to within 0.05 _C and 20 Pa respectively. Standard solutions of sodium carbonate are also used to calibrate the system. These samples are treated in the same manner as a seawater sample. Values are reported in units of (mol/kg-1. The overall precision of the analysis should be at least 1.5 (mol/kg-1 for samples with concentrations in the range of 1800-2300 (mol/kg-1. b. Sampling Procedure and Data Processing Technique Water samples are initially collected using a Niskin bottle or similar sampler. Samples for analysis of total inorganic carbon must be taken as soon as possible after recovery of the samples to minimize exchange of carbon dioxide gas with the head space in the sampler which will typically result in a loss of carbon dioxide. It is desirable that the samples be drawn before half the sampler is emptied and within ten minutes of recovery. Clean borosilicate glass bottles are rinsed twice with 30 - 50 ml of the sample. The bottle is then filled from the bottom using a length of vinyl tubing attached to the spigot of the sampler. The sample is overflowed by at least half of the volume of the bottle (typically 250 ml). A head space of 1% is left to allow for expansion without leakage. If samples are not to be analyzed within four to five hours, the samples are poisoned with 100 (l/250 ml of 50% saturated mercuric chloride solution. The bottle is tightly sealed and stored preferably at the temperature of collection. c. Replicate Analysis In total, 120 duplicate carbonate measurements were obtain. The following is a statistical summary of the absolute value of the differences between duplicates. Table C.4 lists all duplicate measurements. Statistic Value Number of Duplicates 120 Minimum 0 (moles/kg Maximum 612.2 (moles/kg Mean 18.2 (moles/kg Median 0.8 (moles/kg Standard Deviation 85.5 (moles/kg Table C.4 Duplicate water sample carbonate values in (moles/kg. Sample Total Carbon ID Number --------- ------------ 130518 2215.3 130518 2216.8 130523 2101.1 130523 2101.8 130524 2059.0 130524 2059.7 130529 2157.6 130529 2157.6 130534 2076.6 130534 2077.3 130543 2157.9 130543 2159.0 130553 2159.4 130553 2160.5 130558 2163.6 130558 2164.9 130595 2156.8 130595 2158.7 130619 2165.9 130619 2166.5 130627 2034.9 130627 2036.7 130632 2161.8 130632 2163.0 130633 2156.7 130633 2156.9 130650 2167.7 130650 2168.1 130659 2164.0 130659 2165.2 130682 2132.5 130682 2156.6 130691 2156.2 130691 2158.7 130718 2156.8 130718 2159.3 130729 2185.8 130729 2186.8 130738 2165.2 130738 2165.2 130752 2171.3 130752 2173.5 130769 2183.9 130769 2185.9 130791 2173.5 130791 2174.2 130809 2183.0 130809 2183.5 130812 2168.8 130812 2169.4 130839 2156.6 130839 2157.7 130866 2110.3 130866 2110.5 130892 2163.7 130892 2182.5 130896 2160.9 130896 2161.9 130911 2174.3 130911 2174.7 130916 2160.6 130916 2161.1 130921 2165.0 130921 2166.2 130977 2156.0 130977 2156.5 131009 2166.6 131009 2170.4 131012 2155.9 131012 2159.2 131022 2172.1 131022 2172.3 131030 1895.6 131030 2167.2 131040 2152.0 131040 2162.6 131049 1876.6 131049 2488.8 131072 1906.6 131072 2481.6 131090 2168.5 131090 2501.1 131112 2158.4 131112 2160.2 131139 2158.1 131139 2160.4 131148 2066.8 131148 2071.6 131154 2158.3 131154 2159.2 131154 2159.8 131171 2162.1 131171 2162.2 131175 2159.0 131175 2159.4 131190 2161.9 131190 2163.7 131228 2040.6 131228 2041.3 131230 2158.2 131230 2158.3 131255 2154.4 131255 2154.6 131268 2152.0 131268 2152.6 131280 2136.3 131280 2138.2 131285 2144.1 131285 2144.4 131292 2101.7 131292 2101.9 131295 2135.7 131295 2136.6 131300 2143.0 131300 2143.8 131304 2154.2 131304 2154.8 131331 2152.8 131331 2153.1 131343 2046.8 131343 2153.7 131389 2155.9 131389 2157.8 131404 2157.5 131404 2158.2 131407 2155.5 131407 2155.6 131452 2154.6 131452 2156.7 131463 2167.6 131463 2168.4 131486 2167.0 131486 2168.4 131491 2163.3 131491 2166.0 131492 2158.7 131492 2165.1 131498 2171.1 131498 2171.4 131526 2163.7 131526 2163.8 131533 2155.8 131533 2156.1 131564 2080.2 131564 2081.2 131572 2154.6 131572 2156.8 131603 2164.5 131603 2165.3 131614 2157.7 131614 2158.3 131624 2132.3 131624 2135.0 131645 2159.7 131645 2160.3 131658 2169.1 131658 2169.6 131683 2165.9 131683 2166.1 131706 2161.3 131706 2161.6 131744 2159.6 131744 2160.9 131764 2159.1 131764 2159.9 131788 2148.4 131788 2150.0 131801 2150.5 131801 2150.9 131809 2070.3 131809 2070.5 131812 2140.4 131812 2141.3 131814 2172.6 131814 2173.7 131819 2126.5 131819 2133.7 131823 2136.8 131823 2141.0 131825 2048.4 131825 2048.4 131829 2043.9 131829 2052.6 131832 2133.7 131832 2133.7 131834 2161.0 131834 2162.0 131839 2153.3 131839 2153.5 131845 2076.8 131845 2077.5 131849 2152.6 131849 2153.3 131854 2152.9 131854 2153.7 131861 2154.4 131861 2155.0 131869 2046.5 131869 2049.8 131872 2153.2 131872 2153.6 131881 2152.5 131881 2152.9 131886 2093.4 131886 2106.3 131901 2154.4 131901 2154.9 131968 2161.1 131968 2164.8 131991 2155.0 131991 2156.4 132001 2160.0 132001 2160.3 132003 2158.9 132003 2160.1 132006 2157.3 132006 2157.8 132044 2159.7 132044 2161.5 132069 2154.2 132069 2154.5 132083 2165.2 132083 2165.6 132111 2169.1 132111 2172.9 132124 2147.4 132124 2148.7 132135 2177.0 132135 2177.2 132143 2167.3 132143 2167.9 132158 2110.1 132158 2110.2 132171 2072.7 132171 2157.1 132178 2104.5 132178 2106.8 6. Alkalinity Frank Zemlyak a. Description of Equipment and Technique Total alkalinity is determined using the Marine Chemistry automated titration system. Total alkalinity is determined using a potentiometric titration of the sea water sample using hydrochloric acid. Once the sample is connected to the system, the operation proceeds automatically, from the glass reaction vessel being rinsed and filled with the sea water sample, to the final calculations at the conclusion of the titration. When the reaction vessel is filled, the semi-micro combination Ross electrode senses when the sample has come to equilibrium, the initial relative mvolt reading is then logged, at the same time, the cell temperature is also recorded. At this point, a rather large quantity of 0.2N hydrochloric acid, is added to the cell via a Metrohm E-655 Dosimat. The increase in volume is accommodated by the withdrawal, by a stepper motor via an Acme lead screw, of an internal glass piston. This large quantity of acid added titrates the sample beyond the carbonate endpoint, at this point, smaller aliquots (0.040mL) of acid are added until the sample has been titrated to and beyond the second inflection point. With each addition of acid the sample is allowed to come to equilibrium, the mvolt reading is logged. Thus, with these relative changes in the voltage in the cell, the endpoint is calculated by using a modified Gran function. Corrections to the final total alkalinity result are made by using the sample salinity, sample temperature and the nutrients, silicate and phosphate. b. Sampling Procedure and Data Processing Technique The 500 ml samples used for alkalinity analysis are collected from 8 L Niskin bottles in much the same fashion as oxygen samples. The samples were stored in a cold water bath whilst awaiting analysis. 6. CFC's (Mike Hingston) a. Description of Equipment and Technique The analyses are carried out on two purge and trap systems developed at the Bedford Institute of Oceanography. The water samples are injected into the systems directly from the syringes. To ensure proper rinsing, at least two volumes of water is passed through the sample pipette before the actual sample volume. The samples are purged for 4 minutes with ultra high purity nitrogen at a flow rate of 60 ml/min. The components are trapped in Porapak-N trap which is cooled to a temperature of less than 10_C. They are then desorbed by heating the trap up to at least 170_C. The contents of the trap are then passed through a 75m DB-624 megabore column. b. Sampling Procedure and Data Processing Technique All samples are collected directly from the Niskin bottles using 100 ml syringes. The syringes are rinsed three times before they are filled. To prevent contamination, the CFC samples are the first samples which are collected from the Niskin bottles. The samples are then stored in a water bath of continuously flowing surface sea water until analysis. Air samples from the winch room are taken periodically to ensure that it has not become contaminated. The analysis of the samples is always completed within 24 hours after they have been drawn. c. Replicate analysis In total, 179 duplicate CFC measurements were obtain. The following is a statistical summary, in pmoles/kg, of the absolute value of the differences between duplicates. Duplicates are taken at each station, with some of these being run on each system to ensure that the results are comparable. Duplicate measurements are given in Table C.5. Statistic CFC11 CFC12 CFC113 Methyl Chl. Carbon Tet. Number 179 179 179 179 179 Mean 0.151 0.161 0.026 0.774 0.225 Minimum 0 0 0 0 0 Maximum 0.991 1.042 0.367 5.481 2.798 Standard Deviation 0.203 0.180 0.053 0.921 0.387 Median 0.062 0.104 0.010 0.464 0.116 Table C.5 Duplicate CFC measurements in pmoles/kg. Sample ID Number Freon 12 Freon 11 Freon 113 Methyl Chl. Carbon Tet. --------- -------- -------- --------- ----------- ----------- 130506 .679 1.212 .071 4.007 1.217 130506 1.438 1.280 .047 5.898 1.676 130519 1.619 .144 5.094 1.407 130519 .952 1.268 .063 5.672 1.657 130523 1.736 5.276 .112 9.594 130523 2.352 4.696 .341 6.796 130523 2.617 4.910 .337 6.972 130528 1.594 3.886 .046 11.479 6.259 130528 2.495 3.498 .204 10.873 4.543 130528 2.637 3.431 .219 10.445 4.251 130537 1.290 3.045 .030 19.513 5.977 130537 1.586 2.798 .154 24.068 4.092 130549 .462 .870 .092 2.443 1.819 130549 .502 1.009 .063 2.433 1.637 130575 1.375 2.349 6.649 3.346 130575 1.449 2.599 .080 6.450 3.029 130575 1.828 2.336 .087 6.471 3.123 130603 .165 .756 .050 2.566 .937 130603 .340 .751 .032 2.817 .921 130603 .342 .766 .038 2.850 .907 130614 .255 1.073 .018 .521 1.120 130614 .323 .583 .023 .980 1.096 130614 .328 .109 .082 1.219 1.214 130643 .727 1.380 .036 1.715 .374 130643 .797 1.368 .044 1.872 .317 130643 .824 1.367 .041 1.934 .314 130658 .613 1.305 .042 3.613 2.160 130658 .667 1.128 .039 3.175 2.003 130672 .285 .584 .052 1.736 1.355 130672 .342 .768 .024 2.334 1.438 130672 .358 .591 .053 1.517 1.217 130695 .239 .477 .065 1.256 1.325 130695 .529 1.137 .041 1.312 1.028 130695 .818 1.245 .039 2.108 1.209 130726 130726 1.206 2.052 .073 4.375 .813 130726 1.234 2.066 .082 4.151 .733 130775 .060 .295 0.000 .282 .887 130775 .088 .359 .023 1.498 .870 130775 .138 .380 .010 .823 .855 130803 .462 1.056 .032 2.871 1.285 130803 .565 1.082 .038 3.137 1.170 130818 .635 1.224 .089 3.665 1.849 130818 .644 1.177 .085 3.547 1.861 130818 .740 1.223 .048 2.914 1.619 130843 .513 1.094 .044 2.861 1.079 130843 .515 1.038 .037 3.148 1.350 130843 .527 1.096 .034 3.061 1.173 130858 .459 1.030 .027 2.758 1.524 130858 .484 1.013 .034 2.731 1.510 130858 .518 .994 .031 3.028 1.500 130906 .621 1.363 .054 3.948 1.095 130906 .640 1.450 .040 3.491 .906 130917 .296 .619 .048 1.518 1.355 130917 .323 1.277 .017 1.807 1.474 130917 .336 .645 .020 1.668 1.267 130938 .578 .989 .035 2.827 1.856 130938 .591 .971 .036 3.223 1.785 130938 .616 .973 .031 2.890 1.875 130961 .627 1.949 4.405 2.353 130961 .633 1.542 .064 3.806 2.317 130961 .703 1.531 .070 4.401 2.333 130975 .187 .487 .016 1.572 1.297 130975 .303 .585 .018 .287 1.057 130975 .330 .515 .173 1.539 1.173 131006 .827 1.799 .055 2.489 .422 131006 .890 1.945 .046 2.323 .340 131006 .921 1.855 .048 3.245 .630 131025 .975 1.851 .086 4.435 .808 131025 1.095 1.936 3.884 .709 131035 .211 1.270 .010 2.050 1.438 131035 .223 1.557 .012 2.203 1.338 131035 .364 .824 .021 1.581 1.354 131063 .472 .970 .028 3.047 .610 131063 .492 1.037 .046 3.512 .989 131063 .509 1.032 .033 3.248 .934 131085 1.243 2.082 .099 4.750 1.022 131085 1.571 2.090 .067 4.620 .808 131085 1.650 2.043 .101 4.822 1.080 131103 .925 1.520 .060 3.832 1.200 131103 1.037 1.494 .081 4.030 1.268 131103 1.089 1.481 .090 4.172 1.260 131115 .322 .574 .016 2.078 1.487 131115 .331 .611 .015 1.421 1.639 131115 .396 .514 .039 1.654 1.292 131138 .735 1.479 .051 4.372 2.698 131138 .764 1.467 .054 4.352 2.734 131138 .858 1.530 .053 4.011 2.783 131156 .688 .672 .018 1.148 1.586 131156 .688 .672 .018 1.148 1.586 131163 .334 .938 .029 2.969 1.371 131163 .514 .934 .027 2.339 1.498 131163 .571 .935 .029 1.793 1.414 131172 .443 1.149 .049 3.406 2.047 131172 .534 1.107 .402 3.541 1.969 131172 .671 1.166 .035 2.589 2.088 131218 1.118 2.339 .116 6.733 3.417 131218 1.146 2.175 .074 6.518 3.476 131242 .634 1.339 .048 3.811 2.230 131242 .847 1.458 .048 2.814 1.965 131261 2.324 4.887 .273 15.865 6.210 131261 2.366 4.893 .302 16.313 6.297 131294 2.520 5.130 .345 17.199 6.944 131294 2.750 4.745 .347 14.863 7.117 131300 2.102 4.263 .304 13.561 6.031 131300 2.235 4.561 .279 15.574 6.000 131307 1.580 3.658 .209 9.481 4.796 131307 1.609 4.125 .250 10.324 4.970 131307 1.835 3.658 .214 12.355 4.857 131342 2.081 4.097 .316 12.006 5.671 131342 2.197 4.418 .348 14.556 5.777 131348 1.063 2.278 .106 7.196 3.577 131348 1.387 2.241 .101 6.008 3.059 131348 1.534 2.230 .121 6.144 3.170 131363 .475 1.101 .035 3.667 2.149 131363 .501 1.266 .034 3.674 2.183 131363 .700 1.150 .050 3.627 1.967 131388 .666 1.276 .038 4.063 2.168 131388 1.091 2.158 .124 7.334 3.352 131394 1.098 1.946 .074 6.222 3.095 131394 1.112 2.300 .090 6.945 3.658 131394 1.438 1.997 .085 5.761 3.104 131431 .941 1.830 .075 6.148 3.122 131431 .963 1.839 .064 5.628 3.091 131431 1.104 1.772 .080 6.834 2.994 131456 1.122 2.492 .086 3.404 2.868 131456 1.153 2.933 .074 3.802 2.930 131476 .652 1.660 .069 5.204 2.436 131476 .918 1.699 .058 5.052 2.606 131476 1.061 1.760 .058 5.392 2.547 131501 1.567 2.970 .162 9.061 3.904 131501 1.580 3.003 .178 8.490 3.884 131519 .582 1.591 .068 4.488 1.801 131519 .633 1.686 5.773 2.062 131519 .754 1.712 .074 5.216 1.828 131548 .302 .682 .183 1.857 1.560 131548 .345 .944 .093 3.113 1.546 131548 .619 .954 .027 1.820 1.318 131581 1.102 2.008 .121 5.525 2.393 131581 1.305 2.089 .143 5.776 2.422 131614 .940 1.879 .073 6.046 3.022 131614 1.240 1.847 .060 5.751 3.158 131614 1.347 1.846 .071 5.504 2.972 131631 .951 1.793 .069 5.297 2.893 131631 1.032 1.742 .120 5.671 2.983 131631 1.123 1.621 .049 4.947 2.867 131659 .838 1.572 .048 3.585 .694 131659 .850 1.697 .076 4.625 .885 131677 .507 1.180 .032 3.866 1.490 131677 .558 1.172 4.223 1.488 131677 .785 1.174 .034 3.172 1.376 131688 .242 .673 0.000 1.570 1.464 131688 .577 .842 .028 2.353 1.443 131688 .708 .981 .011 1.892 1.329 131716 .765 1.821 .070 4.793 2.336 131716 .988 1.932 .093 5.261 2.480 131716 1.287 1.755 .053 4.355 2.172 131754 .789 1.509 .060 4.902 2.556 131754 .813 1.512 .059 4.363 2.409 131754 .909 1.781 .069 4.809 3.003 131765 .323 .902 0.000 5.187 1.737 131765 .562 .966 .021 10.000 1.682 131765 .593 .951 .034 7.009 1.650 131863 1.536 3.356 .185 13.104 4.659 131863 1.576 3.424 .192 13.141 5.052 131863 1.642 3.477 .208 13.774 5.165 131880 1.438 3.161 .167 13.686 5.041 131880 1.491 3.001 .158 10.011 4.227 131880 1.576 2.990 .152 10.725 4.386 131897 1.458 3.644 .215 12.373 5.217 131897 1.559 3.649 .211 11.828 5.157 131897 2.099 3.420 .198 10.235 4.645 131907 .755 1.527 .053 4.511 2.314 131907 .880 1.554 .051 4.919 2.599 131907 .885 1.472 .039 4.081 2.151 131933 1.022 2.614 .101 8.503 4.193 131933 1.420 2.422 .098 7.552 3.514 131984 .431 .935 .020 6.214 1.663 131984 .521 .840 .017 8.197 1.859 131984 .606 .860 .020 11.696 1.887 132015 .777 2.443 .222 5.353 1.579 132015 .940 1.676 .063 7.021 1.822 132026 .430 .885 .014 2.851 1.797 132026 .477 .946 3.161 1.655 132067 .585 1.205 3.674 2.113 132067 .597 1.182 .033 3.118 2.028 132067 .701 1.197 .040 3.433 2.112 132095 .279 .857 .032 2.682 1.079 132095 .740 1.605 .062 5.221 1.789 132095 .906 1.847 .094 5.351 1.887 132107 .801 1.910 .079 6.740 3.202 132107 .876 1.861 6.762 3.182 132107 1.147 1.998 .082 5.276 3.450 132124 .519 1.344 .050 7.196 1.875 132124 .522 1.317 .037 8.951 1.978 132124 .651 1.312 .045 9.415 2.004 132155 .479 1.169 .032 2.832 1.553 132155 .655 1.477 .030 4.168 1.672 132155 .656 1.694 4.614 1.609 132173 .661 1.326 .038 3.706 2.148 132173 .685 1.357 .037 4.819 2.359 132173 .766 1.305 4.788 2.137 d. Standards Used Standardization is carried out using gas standards made up at Brookhaven National Laboratories. Standard volumes are corrected for lab temperature and pressure. Results are reported in units of pmol/kg of sea water. Clean air samples are also analyzed with each station, as a check on the standardization. e. Calibrations The standard values for F12, F11, and F113 were calibrated by Scripps according to their SIO93 scale in March of 1996. The CH3CCl3 was calibrated at BNL in 1995. The CCl4 value is based on numerous air samples taken from 1993 to 1995 and based on the SIO93 atmospheric scale. 8. Reversing Thermometers Anthony W. Isenor a. Description of Equipment and Technique Sensoren-Instrumente-Systeme digital reversing thermometers model RTM 4002 were used to verify CTD thermistor readings on most deep stations. The thermometers have a depth range of up to 10000 m. The pressure housing is made of a glass tube closed at the ends by metal stoppers. One end contains the platinum sensor and the other end is the battery compartment. The thermometers were placed on bottles 1 and 3 of the rosette, thus sampling temperature at the deepest and third deepest bottle trips. The thermometers are placed in standard reversing thermometer racks on the Niskin bottles. Before deployment, a magnet is passed over the thermometers to clear the display and place the thermometer in sample mode. A new temperature will then be recorded upon reversal of the thermometer. On the deepest stations, unprotected mercury in glass thermometers were also attached to the deepest and third deepest bottle trips. The following table lists the number of readings from each thermometer. Digital thermometers are indicated with a 'T' in the serial number. Thermometer Ser. No. Number of Readings -------------------- ------------------ 000T345 103 000T347 101 000T348 100 000T350 1 000T352 1 000T354 102 0011745 59 0011749 29 b. Sampling Procedure and Data Processing Technique The thermometers indicate the temperature reading either via a digital display or column of mercury. The temperature is read and noted on log sheets. The readings are later digitized and calibrations applied using the water sample database system. c. Calibration Data The digital reversing thermometers were calibrated at BIO in February 1991 while the mercury thermometers were last calibrated in March 1968. The digital thermometers were calibrated after the cruise, in March 1994, and were found to have significant drift over this period. The March 1994 calibration also improved the thermometer intercomparison and therefore will be used for calibrations of this temperature dataset. d. Replicate analysis Temperatures between thermometers on the same rosette bottle were analyzed. In total, 213 duplicate temperature readings were obtain. Omitting 5 obvious outliers, we obtain the following statistical summary of the absolute value of the differences between duplicate measurements. Statistic Value Number of Duplicates 208 Minimum 0 (C Maximum 0.133 (C Mean 0.004 (C Median 0.003 (C Standard Deviation 0.010 (C Table C.6 Duplicate temperature measurements from thermometers. Sample ID Number Thermometer Ser. No. Main Corrected Therm. Pressure ---------------- -------------------- -------------- --------------- 130501 000T345 6.490 130501 000T350 6.495 130501 000T354 6.493 130503 000T347 6.507 130503 000T348 6.509 130503 000T352 6.513 130521 000T345 .183 130521 000T354 .185 130523 000T347 1.743 130523 000T348 1.876 130525 000T345 3.612 130525 000T354 3.609 130535 000T345 3.612 130535 000T354 3.609 130537 000T347 3.656 130537 000T348 3.602 130549 000T345 2.651 130549 000T354 2.657 130551 000T347 3.222 130551 000T348 3.220 130569 000T345 2.152 130569 000T354 2.158 130571 000T347 2.731 130571 000T348 2.730 130589 000T345 2.291 130589 000T354 2.294 130591 000T347 2.738 130591 000T348 2.738 130609 000T345 2.251 130609 000T354 2.255 130611 000T347 2.755 130611 000T348 2.756 130629 000T345 2.215 130629 000T354 2.218 130631 000T347 2.858 130631 000T348 2.855 130649 000T345 2.215 130649 000T354 2.218 130651 000T347 2.858 130651 000T348 2.855 130669 000T345 2.293 130669 000T354 2.298 130669 0011745 42.228 5403.0 130669 0011745 42.225 5402.6 130671 000T347 2.459 130671 000T348 18.347 130689 000T345 2.278 130689 000T354 2.281 130689 0011745 41.063 5248.6 130691 000T347 2.330 130691 000T348 2.328 130709 000T345 2.260 130709 000T354 2.265 130709 0011745 42.192 5402.7 130709 0011745 42.189 5402.3 130711 000T347 2.291 130711 000T348 2.289 130711 0011749 37.810 4810.2 130711 0011749 37.806 4809.8 130729 000T345 2.257 130729 000T354 2.261 130729 0011745 41.930 5367.9 130731 000T347 2.289 130731 000T348 2.288 130731 0011749 37.278 4738.9 130749 000T345 2.225 130749 000T354 2.230 130749 0011745 42.079 5392.2 130749 0011745 42.073 5391.3 130751 000T347 2.278 130751 000T348 2.277 130751 0011749 37.760 4805.3 130751 0011749 37.757 4804.9 130769 000T345 2.258 130769 000T354 2.262 130769 0011745 42.183 5401.7 130771 000T347 2.291 130771 000T348 2.290 130771 0011749 37.686 4793.5 130789 000T345 2.264 130789 000T354 2.268 130789 0011745 40.662 5196.5 130789 0011745 40.683 5199.3 130791 000T347 2.283 130791 000T348 2.282 130791 0011749 36.228 4598.3 130791 0011749 36.228 4598.3 130809 000T345 2.268 130809 000T354 2.272 130809 0011745 41.116 5257.0 130809 0011745 41.153 5261.9 130811 000T347 2.287 130811 000T348 2.286 130811 0011749 37.032 4706.0 130829 000T345 2.251 130829 000T354 2.255 130829 0011745 40.600 5189.9 130829 0011745 40.587 5188.1 130831 000T347 2.287 130831 000T348 2.286 130831 0011749 35.371 4482.2 130831 0011749 35.378 4483.2 130849 000T345 2.236 130849 000T354 2.240 130849 0011745 41.102 5259.4 130849 0011745 41.104 5259.7 130851 000T347 2.275 130851 000T348 2.275 130851 0011749 36.137 4587.0 130851 0011749 36.134 4586.6 130869 000T345 2.253 130869 000T354 2.257 130871 000T347 2.269 130871 000T348 2.269 130871 0011749 130889 000T345 2.234 130889 000T354 2.238 130889 0011749 41.155 5267.6 130889 0011749 41.149 5266.9 130891 000T347 2.245 130891 000T348 2.244 130891 0011749 36.216 4601.8 130891 0011749 36.216 4601.8 130909 000T345 2.255 130909 000T354 2.260 130909 0011745 31.790 4002.7 130911 000T347 2.261 130911 000T348 2.260 130911 0011749 130929 000T345 2.241 130929 000T354 2.246 130929 0011745 38.391 4893.9 130929 0011745 38.398 4894.9 130931 000T347 2.242 130931 000T348 2.241 130949 000T345 2.184 130949 000T354 2.188 130949 0011745 36.077 4590.2 130951 000T347 2.315 130951 000T348 2.314 130969 000T345 2.244 130969 000T354 2.248 130969 0011745 36.104 4585.7 130969 0011745 36.109 4586.4 130971 000T347 2.369 130971 000T348 2.368 130989 000T345 2.255 130989 000T354 2.260 130989 0011745 37.633 4790.1 130991 000T347 2.269 130991 000T348 2.268 131009 000T345 2.305 131009 000T354 2.308 131011 000T347 2.367 131011 000T348 2.367 131029 000T345 2.297 131029 000T354 2.302 131029 0011745 38.402 4887.9 131029 0011745 38.388 4886.0 131031 000T347 2.338 131031 000T348 2.337 131049 000T345 2.300 131049 000T354 2.303 131049 0011745 39.231 4999.2 131049 0011745 39.252 5002.0 131051 000T347 2.318 131051 000T348 2.318 131051 0011749 35.394 4481.0 131051 0011749 35.414 4483.8 131069 000T345 2.285 131069 000T354 2.289 131069 0011745 38.918 4959.0 131069 0011745 38.928 4960.4 131071 000T347 2.347 131071 000T348 2.345 131071 0011749 35.399 4477.9 131071 0011749 35.399 4477.9 131089 000T345 2.290 131089 000T354 2.295 131089 0011745 39.068 4978.4 131089 0011745 39.075 4979.4 131091 000T347 2.328 131091 000T348 2.326 131091 0011749 36.375 4612.0 131091 0011749 36.380 4612.7 131109 000T345 2.333 131109 000T354 2.336 131109 0011745 131111 000T347 2.452 131111 000T348 2.451 131129 000T345 2.266 131129 000T354 2.271 131129 0011745 37.438 4762.3 131149 000T345 2.249 131149 000T354 2.253 131149 0011745 36.982 4703.4 131149 0011745 36.982 4703.4 131151 000T347 2.250 131151 000T348 2.250 131169 000T345 2.208 131169 000T354 2.213 131171 000T347 2.283 131171 000T348 2.281 131189 000T345 2.194 131189 000T354 2.199 131191 000T347 2.203 131191 000T348 2.202 131209 000T345 2.153 131209 000T354 2.157 131211 000T347 2.451 131211 000T348 2.450 131229 000T345 2.686 131229 000T354 2.691 131231 000T347 3.012 131231 000T348 3.011 131249 000T345 3.087 131249 000T354 3.092 131251 000T347 3.040 131251 000T348 3.040 131264 000T345 3.179 131264 000T354 3.184 131266 000T347 3.323 131266 000T348 3.322 131274 000T345 3.632 131274 000T354 3.636 131276 000T347 3.844 131276 000T348 3.840 131284 000T345 1.772 131284 000T354 1.778 131286 000T347 .515 131286 000T348 .513 131290 000T345 -.125 131290 000T354 -.117 131292 000T347 .891 131292 000T348 .892 131294 000T345 -1.167 131294 000T354 -1.160 131296 000T347 -1.174 131296 000T348 -1.175 131298 000T345 2.830 131298 000T354 2.835 131300 000T347 1.038 131300 000T348 1.040 131303 000T345 3.380 131303 000T354 3.385 131305 000T347 3.804 131305 000T348 3.803 131313 000T345 2.971 131313 000T354 2.975 131315 000T347 2.983 131315 000T348 2.983 131325 000T345 2.877 131325 000T354 2.882 131327 000T347 2.996 131327 000T348 2.996 131345 000T345 2.510 131345 000T354 2.514 131347 000T347 2.822 131347 000T348 2.822 131362 000T345 2.153 131362 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131524 000T354 2.281 131542 000T345 2.289 131542 000T347 2.293 131542 0011745 37.680 4791.9 131542 0011745 37.680 4791.9 131544 000T348 2.316 131544 000T354 2.314 131562 000T345 2.295 131562 000T347 2.298 131562 0011745 38.307 4875.5 131562 0011745 38.307 4875.5 131564 000T348 2.313 131564 000T354 2.313 131564 0011749 35.325 4472.4 131564 0011749 35.325 4472.4 131582 000T345 2.304 131582 000T347 2.307 131582 0011745 38.321 4876.1 131582 0011745 38.331 4877.5 131584 000T348 2.364 131584 000T354 2.362 131602 000T345 2.292 131602 000T347 2.296 131602 0011745 38.311 4876.4 131604 000T348 2.307 131604 000T354 2.306 131622 000T345 2.286 131622 000T347 2.290 131622 0011745 38.308 4876.7 131624 000T348 2.306 131624 000T354 2.306 131642 000T345 2.392 131642 000T347 2.396 131644 000T348 2.564 131644 000T354 2.563 131662 000T345 2.265 131662 000T347 2.269 131662 0011745 37.069 4712.9 131682 000T345 2.271 131682 000T347 2.275 131682 0011745 37.170 4725.7 131684 000T348 2.290 131684 000T354 2.291 131702 000T345 2.269 131702 000T347 2.274 131702 0011745 37.244 4735.8 131704 000T348 2.294 131704 000T354 2.294 131722 000T345 2.170 131722 000T347 10.860 131724 000T348 2.270 131724 000T354 2.271 131742 000T345 2.102 131742 000T347 2.108 131744 000T348 2.248 131744 000T354 2.249 131762 000T345 2.207 131762 000T347 2.211 131764 000T348 2.282 131764 000T354 2.281 131782 000T345 2.978 131782 000T347 2.983 131784 000T348 3.019 131784 000T354 3.050 131797 000T345 2.876 131797 000T347 2.880 131799 000T348 3.121 131799 000T354 3.122 131805 000T345 3.472 131805 000T347 3.474 131807 000T348 3.626 131807 000T354 3.626 131810 000T345 3.605 131810 000T347 3.609 131812 000T348 2.104 131812 000T354 2.106 131814 000T345 2.751 131814 000T347 2.756 131816 000T348 3.298 131816 000T354 3.302 131818 000T345 2.225 131818 000T347 2.227 131820 000T348 4.905 131820 000T354 4.906 131822 000T345 2.260 131822 000T347 2.265 131824 000T348 8.393 131824 000T354 5.440 131826 000T345 2.733 131826 000T347 2.739 131828 000T348 5.227 131828 000T354 5.220 131830 000T345 3.396 131830 000T347 3.399 131832 000T348 1.804 131832 000T354 1.803 131834 000T345 3.413 131834 000T347 3.417 131836 000T348 2.081 131836 000T354 2.083 131838 000T345 3.491 131838 000T347 3.493 131840 000T348 1.777 131840 000T354 1.764 131842 000T345 .295 131842 000T347 .302 131844 000T348 -1.269 131844 000T354 -1.268 131846 000T345 3.940 131846 000T347 3.945 131848 000T348 3.758 131848 000T354 3.758 131851 000T345 2.953 131851 000T347 2.956 131853 000T348 3.672 131853 000T354 3.673 131859 000T345 2.953 131859 000T347 2.956 131860 000T348 3.672 131860 000T354 3.673 131871 000T345 2.869 131871 000T347 2.874 131873 000T348 3.398 131873 000T354 3.398 131877 000T345 2.882 131877 000T347 2.887 131879 000T348 3.031 131879 000T354 3.033 131885 000T345 2.288 131885 000T347 2.293 131887 000T348 5.517 131887 000T354 2.958 131901 000T345 2.055 131901 000T347 2.061 131903 000T348 2.305 131903 000T354 2.305 131921 000T345 2.094 131921 000T347 2.099 131923 000T348 2.223 131923 000T354 2.223 131941 000T345 2.103 131941 000T347 2.108 131943 000T348 2.224 131943 000T354 2.225 131961 000T345 2.136 131961 000T347 2.141 131961 0011745 35.806 4560.1 131961 0011745 35.803 4559.7 131963 000T348 2.273 131963 000T354 2.271 131981 000T345 2.234 131981 000T347 2.238 131981 0011745 36.008 4574.2 131983 000T348 2.305 131983 000T354 2.301 132001 000T345 2.259 132001 000T347 2.263 132001 0011745 36.743 4669.8 132001 0011745 36.745 4670.1 132003 000T348 2.330 132003 000T354 2.329 132021 000T345 2.221 132021 000T347 2.226 132021 0011745 36.912 4697.6 132023 000T348 2.375 132023 000T354 2.375 132041 000T345 2.232 132041 000T347 2.237 132043 000T348 2.536 132043 000T354 2.535 132061 000T345 2.251 132061 000T347 14.636 132063 000T348 2.395 132063 000T354 2.391 132081 000T345 2.221 132081 000T347 2.227 132083 000T348 2.454 132083 000T354 2.454 132101 000T345 3.238 132101 000T347 3.242 132103 000T348 3.298 132103 000T354 3.298 132121 000T345 2.310 132121 000T347 2.315 132123 000T348 2.360 132123 000T354 2.360 132141 000T345 2.306 132141 000T347 2.310 132143 000T348 2.309 132143 000T354 2.309 132161 000T345 2.284 132161 000T347 2.289 132163 000T348 2.305 132163 000T354 2.304 E. REFERENCES Carritt, D.E. and J.H. Carpenter. 1966. Comparison and Evaluation of Currently Employed Modifications of the Winkler Method for Determining Dissolved Oxygen in Seawater. A NASCO Report, Jour. Mar. Res., 24, 268-318. Jones, E.P., F. Zemlyak and P. Stewart. 1992. Operating Manual for the Bedford Institute of Oceanography Automated Dissolved Oxygen Titration System. Can. Tech. Rep. of Hydrography and Ocean Sci. 138: iv+51p. Levy, E.M., C.C. Cunningham, C.D.W. Conrad and J.D. Moffatt. 1977. The Determination of Dissolved Oxygen in Sea Water, Bedford Institute of Oceanography Report Series, BI-R-77-9, August 1977. [AWI1]