Please cite this data set as: Rios, A., M. Alvarez, and H. Bryden. 2002. Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Charles Darwin Cruise in the Indian Ocean on CLIVAR Repeat Hydrography Sections I05_2002 (Mar. 01 - Apr. 15, 2002). http://cdiac.ornl.gov/ftp/oceans/CLIVAR/I05_2002.data/. Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, US Department of Energy, Oak Ridge, Tennessee. doi: 10.3334/CDIAC/otg.CLIVAR_I05_2002 # 4/17/07 Initialized README file # Data from CCHDO and Alvarez # Ship: Charles Darwin # Cruise: CD139 74AB200203 # Dates: 3/1-4/15/2002 # EXPOCODE: 74AB20020301 # Region: I5 repeat section at 32S, Indian Ocean # Chief Scientist - H. Bryden # 146 stations with 24 place Rosette # Hydro: Who - M. Palmer; Status - final # Notes: See McDonagh et al., 2008 # Nuts/O2: Who - R. Sanders; Status - final # Notes:Nitrate is really NO2+NO3 # TCO2: Who - R. Wanninkhof; Status - final # Notes: Stored for analysis on shore # Only 4 profiles in data set. Made for QA/QC. Values agreed # very well with those calculated from pH and Alk. # TA: Who - A. Rios;M. Alvarez; Status - final # Notes: Potentiometric titration (Perez et al, 2000) # Precision 1sd 0.73umol/kg # In addition to measured values, Alvarez, 2007. Calculated corrected values based on MLR analysis # All measurements made in duplicate # Problem on sta 46,104,106,132,138 # pH: Who - A. Rios;M. Alvarez; Status - final # Notes: Spectrophotometric method of Clayton and Byrne (1993) @ 25C # Reported onTotal hydrogen scale; converted to SWS@25 # CRM Batch 55; Mean analyzed value of 7.909+/-0.003 # Precision of replicates estimated as +/-0.0007 # CFC: Who - D. Wisegarver; Status - final # Notes: includes CFC-113 and CCl4 # H-3/He-3: Who - C. Postlewaite,W.Jenkins; Status - final # Notes: ~7 profiles (many more samples collected), includes neon # References: # Alvarez, M., Corrections on the CD139 data base, Unpublished report, 11pp., 2007 # Alvarez, M., C. Lo Monaco, T. Tanhua, A. Yool, A. Oschlies, J.L. Bullister, C. Goyet, N. Metzl, F. Touratier, E. McDonagh and H.L. Bryden, Estimating the storage of anthropogenic carbon in the subtropical Indian Ocean: A comparison of the different approaches, Biogeosciences, submitted Nov. 2008. # Clayton and Byrne, Spectrophotometric seawater pH measurements: total hydrogen ion concentration scale concentration scale calibration of m-cresol purple and at-sea results. Deep-sea Research I, Vol. 40, 10, 2115-2129, 1993. # McDonagh, E. L., H. L. Bryden, B. A. King and R. J. Sanders The circulation of the Indian Ocean at 32�S, Prog. Oceanogr., 79, 20-36, 2008.