CRUISE REPORT HUDSON 94030 NEWFOUNDLAND BASIN WOCE CONTROL VOLUME AR13 12 OCTOBER - 10 NOVEMBER, 1994 1. Highlights a. WOCE Designation: Control Volume 4, Atlantic Repeat Hydrographic Section 13 b. Expedition Designation: Hudson 94030 c. Chief Scientist: R. Allyn Clarke Ocean Circulation Division Physical and Chemical Sciences Branch Department of Fisheries and Oceans Bedford Institute of Oceanography P.O. Box 1006 Dartmouth, NS, Canada B2Y 2A4 FAX 902 426 7827 Internet clarkea@mar.dfo-mpo.gc.ca d. Ship: CSS Hudson e. Ports of Call: October 12, 1994 Bedford Institute of Oceanography (BIO) Dartmouth, NS, Canada November 10, 1994 BIO, Dartmouth, NS, Canada f. Cruise Dates: October 12, 1994 to November 10, 1994 2. Cruise Summary Information a. Cruise Track A cruise track is included with time information in Figure 1*. This map also shows the locations of the North Atlantic Current Meter Mooring Array (ACM6) set from Oceanus in August 1993. The CTD station positions are shown in Figure 2* while the Moving Vessel CTD (MVCTD) stations are shown in Figure 3. Station numbers are indicated in both figures for clarity. Float deployments are shown in Figure 4. The boundaries of the station occupation region are defined by 38-47N and 38-50W. Figure 1*. The Study Area and Cruise Track. The 200m and 4000m isobaths are shown. The following symbols are used: delta- midnight ship positions for each day in the study area. The symbol closest to the Tail of the Bank is on Oct. 15/94. - the North Atlantic Current Meter Mooring Array (ACM6) deployed in August/93. Figure 2*. CTD Station Numbers and Positions. Figure 3*. MVCTD Station Numbers and Positions. Figure 4*. Float Deployments. The study area is shown along with 200m and 4000m isobaths. The following symbols are used: _ - RAFOS float deployments. - electric field float deployments. b. Total Number of Stations Occupied 97 full depth CTD stations with up to 20 rosette samples analyzed for CFC's, carbon tetrachloride, methyl chloroform, total carbonate, alkalinity, oxygen, salinity and nutrients. 2 CTD stations without water sampling to depths of less than 1000m 10 XBT profiles 19 profiles to 600m using the moving vessel CTD c. Floats and Drifters Deployed A total of 27 RAFOS floats were released as planned on three of the four transects of the North Atlantic Current and on a repeat transect of the mooring section on the homeward voyage from the eastern side of the working area. Five Electric Field Floats (EFF's) were released for the Applied Physics Laboratory, University of Washington, Seattle. The first EFF was released in the core of the Gulf Stream as it crossed 50W. Two were released in the core of the North Atlantic Current (NAC) on the Mooring Section and two more on the Newfoundland Seamount Section. It was originally planned to set four EFF's across the velocity core of the NAC on the mooring section, however, the core was crossed too quickly to permit such a deployment. d. Moorings Deployed or Recovered No moorings were deployed or recovered. 3. List of Principal Investigators Name Affiliation Responsibility Allyn Clarke BIO chief scientist clarkea@mar.dfo- CTD data, oxygens, salts, mpo.gc.ca XBT Peter Jones BIO alkalinity, carbonate, CFCs jonesp@mar.dfo- mpo.gc.ca Tom Rossby URI tom@rafos.gso.uri.edu sound sources, RAFOS floats Tom Sandford University of Washington Electric field floats Jean-Guy Dessurault BIO MVCTD 4. Scientific Program and Methods a. Narrative This was primarily a hydrographic survey involving a series of full depth CTD/Tracer stations spaced at 20 nautical miles or less apart. The sections were selected to be either historical sections for which there were a number of earlier occupations or along TOPEX/POSEIDON ground paths. The sections enclosed four volumes of water; it is hoped that the section data and the boxes may be used to determine the splitting of the Gulf Stream, North Atlantic Current, Labrador Current and Deep Western Undercurrent within this topographically and dynamically complex region. Initial results indicate that this goal is achievable, at least, in the three southern-most boxes. It was originally intended to split the southern-most box into two parts with a section crossing the Southeast Newfoundland ridge (normally at a location at which the shallowest depth crossing the ridge would have been about 4000 metres). It was hoped that this section would reveal the Gulf Stream flowing eastward south of the ridge and the NA Current flowing to the west on the north side. The RAFOS float program was led by Tom Rossby of the University of Rhode Island. The floats were set in and near the North Atlantic Current in order to map the lagrangian velocity fields on isopycnal surfaces in the upper pycnocline throughout the Newfoundland Basin. The floats were positioned by four sound sources moored in the north-west North Atlantic in July, 1993. The floats were programed to return to the surface and report their data in late June, 1995. The Electric Field Floats were Lagrangian isobaric floats which measured the two horizontal components of the electric field as they moved with the current at a preset depth. The electric field allows one to estimate the vertically averaged horizontal velocity field at the float location. One float was released in the velocity core of the Gulf Stream and the remaining four floats were set in the core of the North Atlantic Current. The floats were programed to return to the surface and send back their data in late December 1994. The project leader was Tom Sandford of the University of Washington. The MVCTD (described in Clarke et al., 1995) was an instrument development project led by Jean-Guy Desserault. This device consisted of a special winch, power block, launch, recovery chute, heavy brass body containing a Falmouth Scientific Instruments CTD, Onset Tattletail 8 computer and radio modem. The system is capable of obtaining profiles greater than 1000 metres while steaming at 12 knots. A profile was obtained by first turning on the CTD by sending a signal to the fish via its radio modem. The operator then entered the target depth and the ship's speed into the PC computer that controlled the winch and power block. The PC was then used to initiate the profile. The entire operation of deploying and recovering the fish was performed completely under computer control. The radio modem was then used to download the data from the fish when recovery was complete. Unfortunately, the FSI CTD was equipped with a 600 dbar pressure transducer which restricted the profiles to 600m. This meant that the system was only operational in those areas in which the 10 degree isotherm was believed to be shallower than 600m. 5. Major Problems and Goals Not Achieved Two major problems were encountered during this cruise. The first problem dealt with the plumbing of the CTD unit. All sensors on this unit, except the pressure sensor, should be mounted in a duct through which a pump pulls sea water. However, for stations 1 through 14 inclusive, the pump was installed in reverse. This resulted in the flow direction proceeding first through the pump, then oxygen, conductivity and temperature sensors. A procedure to correct these initial stations has been developed, see Appendix 1 for details. The second problem involved the large number of leaking rosette bottles. This problem was present throughout the entire cruise. 6. Other Incidents of Note The hydraulics used to open and close the hatch for the boom in the winch room were destroyed some time prior to the cruise. On several occasions, while moving between stations, considerable amounts of water entered the hatch during sample collection. This produced a source of possible sample contamination, as well as, discomfort to the sampling crew. 7. List of Cruise Participants Name Responsibility Affiliation Brian Beanlands MVCTD BIO Larry Bellefontaine Watchkeeper BIO Gerry Boudreau Computers/watchkeeper BIO Mary-Elana Carr RAFOS/EFF/watchkeeper URI Bruce Carson CTD tech./salts BIO Allyn Clarke Chief Scientist BIO Pierre Clement Nutrients BIO Jean-Guy Dessureault MVCTD BIO Sandy Fontana RAFOS/EFF/watchkeeper URI Bob Gershey CFC/Alkalinity/Carbonate BDR Research Cathy Griffiths Watchkeeper BIO Mike Hingston CFC/Alkalinity/Carbonate BDR Research John Moffatt Oxygens BIO Liam Petrie Watchkeeper BIO Charlie Ross Data Quality/watchkeeper BIO Ed Verge Watchkeeper BIO Igor Yashayaev Data Quality/watchkeeper Shirshov Frank Zemlyak CFC/Alkalinity/Carbonate BIO BIO Bedford Institute of Oceanography P.O. Box 1006 Dartmouth, NS, CANADA B2Y 2A4 BDR BDR Research Ltd. Box 652, Station 'M' Halifax, N.S., Canada, B3J 2T3 URI University of Rhode Island Graduate School of Oceanography University of Rhode Island South Ferry Road Narragansett, RI 02882 Shirshov P.P. Shirshov Institute of Oceanology Russian Academy of Sciences Krasikova, 23 Moscow, Russia B. UNDERWAY MEASUREMENTS 1. Navigation and Bathymetry Anthony W. Isenor The navigation system onboard CSS Hudson consisted of a Trimble Navigation Loran-GPS 10X decoder and AGCNAV software. The decoder received the satellite fixes and decoded the signals to obtain latitude, longitude and time. The decoder signals were approximately 1 Hz. The AGCNAV software ran on a PC and graphically indicated the ship's position, way-points, course, speed, etc. AGCNAV is a PC based display and way-point setting software package developed at the Atlantic Geoscience Centre at BIO. All navigation data was logged directly to a micro VAX II. The navigation logging was conducted by the shipboard acquisition command procedure, LOGGER. LOGGER produces three files for each successful invocation, the .DATA, .TIME and .HEAD files. These files are then decoded using a PIPE deck, with the primary directive being NMEA_NAV, producing ASCII files containing date, time, position, ships heading, etc. LOGGER was initiated 19 times during the trip, to produce 19 groups of .DATA, .TIME, and .HEAD files. The echo sounder system used for collecting bathymetric data consisted of a Universal Graphic Recorder model UGR-196C-11 connected to a hull mounted 12kHz transducer. The transducer beam width was 15 degrees. The sweep rate of the record was adjusted throughout the course of data collection to aid in identifying the bottom signal. The recorder was also linked to a clock, and thus could indicate five minute intervals on the sounder paper. The system was used to collect bathymetric soundings at five minute intervals while underway between stations. A total of 4100km of deep sea bathymetric sounding data was recorded. During the cruise, the paper take-up mechanism began to fail on the Universal Graphic Recorder and the instrument was replaced by a Raytheon Line Scan Recorder, Model LSR 1811-1. 2. Acoustic Doppler Current Profiler Murray Scotney The Hudson was equipped with a hull mounted RDI acoustic doppler current profiler. The transducer (serial number 177) had SC ADCP electronics (serial number 172) converted for ship board use. Logging, using Transect software, was started on October 12, 1994 at 1830Z in Halifax Harbour (Bedford Basin). The configuration of the equipment resulted in a bin length of eight metres and a total of 50 bins. The raw data was stored to disk and backed up every two days. Two days of logging created approximately 30 Mbytes of data. The data was also averaged in real-time over one minute intervals. ADCP logging was stopped on November 6, 1994. A total of 600 hours of Acoustic Doppler Current Profiler data was recorded. 3. Thermosalinograph No instrument was used. 4. XBT and XCTD 10 XBT probes were dropped between CTD stations in frontal regions. Profiles to 600 metres were obtained using a Falmouth Scientific Instruments model MCTD-DBP-S CTD (serial number 1323) mounted in a special fish that permits semi-automatic upper ocean profiling from a vessel steaming at normal cruising speeds. All XBT and CTD profiles were placed on the GTS via TESAC messages. 5. Meteorological Observations Routine reporting of meteorological variables was carried out by the ship's crew. 6. Atmospheric Chemistry There was no atmospheric chemistry program. C. HYDROGRAPHIC MEASUREMENTS - DESCRIPTIONS, TECHNIQUES AND CALIBRATIONS 1. CTD Measurements Allyn Clarke, Anthony Isenor and Igor Yashayaev a. Description of the Equipment and Technique The CTD measurements were made with a standard SEABIRD model 9Plus CTD (serial number 09P 9984-0370, BIO System #5) that was equipped with a model 3-02/F temperature sensor, a model 4-02/0 conductivity sensor, a paroscientific digiquartz model 410K-105 pressure sensor and a model 13-02 dissolved oxygen sensor. All but the pressure sensor were mounted in a duct through which a pump pulled sea water. Hence, the water flow past the actual sensors was independent of the lowering rate; this simplified the data processing considerably. The Seabird CTD was mounted vertically within the BIO designed and built CTD/Rosette platform. This platform consisted of a central 10 inch diameter aluminum tube, which at its upper end, had a space containing the sea unit for a General Oceanics Model 1015-24 bottle rosette unit (BIO Rosette #3 was used throughout the cruise) and at its bottom end, a smaller well that contained a General Oceanics model 6000 12 Khz pinger unit. The space between the central six inch diameter pinger well and the 10 inch outer tube was filled with lead and the bottom end of the tube was covered with a fibreglass nose cone that was acoustically transparent. The CTD sea unit was placed in a six inch diameter aluminum tube that was welded to the central tube. The CTD sensors were held in a heavy aluminum cage of approximately six inches in diameter which was welded to the opposite side. Around the mid point and the top of the central column were attached aluminum rings on which 20, eight litre sampling bottles were fastened. The number of bottles was set by the maximum diameter that could comfortably be handled through the doors of the enclosed winch room on CSS Hudson. The bottles were somewhat protected from damage by metal bands which had larger diameters than the outer diameters of the bottles when they were mounted. These metal bands were situated just below the bottom of the bottles. The rosette bottles were of a BIO design that were manufactured by Brooke Ocean Technology, a local ocean engineering company. They differed from standard rosette bottles in that their top and bottom caps rotated about a horizontal axis to close. The energy to close the bottles was provided by stretching rubber tubing between the outside edges of the two caps along the outside surface of the bottle. This design had two advantages. First, the tubing was not inside the bottle either before or after the water sample had been captured. Second, the tubing was applied after the bottle was cocked in the rosette tripping mechanism, and hence, eliminated the struggle with the tubing when attempting to cock the General Oceanics Inc. rosette. b. Sampling Procedure and Data Processing Techniques The CTD was deployed with a lowering rate of 60 metres/min (40 metres/min in the upper 200 metres or deeper if the conditions were rough). It was recovered at a rate of 90 metres/min (40 metres/min when deeper than 4000 metres or when conditions were rough) The CTD data was recorded onto disk by a 486 computer using SEABIRD SEASOFT Version 4.201 software. A screen display of temperature, oxygen and salinity profiles vs pressure was used to determine the depths at which bottles were to be tripped on the up cast. The bottles were tripped using the enable and fire buttons on the SEABIRD deck unit. The SEASAVE software stored 73 scans (3 seconds) at each bottle trip within a separate file. At the end of the station, all the data and header files associated with the station were transferred immediately via Ethernet to a second 486 computer. The SEASAVE software was used on this second machine to create one and two dbar processed data files, an IGOSS TESAC message and a processed rosette trip file. All the raw and processed data files associated with the station were then transferred to the ship's micro Vax II computer for archive and subsequent access and distribution to various users on the vessel. The data processing used the following steps: DATCNV Converted the raw data to physical parameters. SPLIT Split the data into DOWN and UP cast. WILDEDIT For every block of 12 scans, flagged all scans whose pressure, temperature, conductivity and oxygen values differed from the mean by more than two standard deviations. Recomputed the mean and standard deviation from unflagged data then marked as bad all scans exceeding four standard deviations from these new values. FILTER Used a low pass filter to time match pressure and conductivity parameters for salinity computation. Time constant used for conductivity is 0.045 seconds, for pressure 0.150 seconds. LOOPEDIT Marked as bad, all cycles on the down trace for which the vertical velocity of the CTD unit was less than 0.1 metres/second. ALIGNCTD Aligned the temperature, conductivity and oxygen values relative to the pressure values accounting for the time delays in the system. Time offsets of 0.010 seconds for conductivity, 0.000 seconds for temperature and 3.000 seconds for oxygen were used. CELLTM A recursive filter used to remove the thermal mass effects from the conductivity data. Thermal anomaly amplitude and time constants of 0.0300 and 9.0000 were used. DERIVE Computed oxygen values. BINAVG Averaged the down cast into one or two dbar pressure bins. (Note: The procedure to produce the two dbar averages took about 5% of the total processing time). DERIVE Computed salinity, potential temperature and sigma-theta. c. Calibration Data A calibration summary is presented in Table 1. The four headings in the Table (Shipboard Processing, First Calibration, ... ) represent sections in the text that follows. In the Oxygen row, the numerals I, II, and III represent procedures that were followed to determine the applied coefficients. The procedures are described in section v. Oxygen Calibration Procedure. The numerics in this table (e.g. 1 - 104) represent station numbers. Parameter 24 Hz Data 1 and 2 dbar data Shipboard First Second Third Processing Calibration Calibration Calibration Conductivity 1-104 1-14(*1) 15-104(*2) Temperature 1-104 1-14(*3) 15-104(*4) Pressure 1-104 1-14(*5) Salinity 1-104 2-14(*8) 15-104(*9) Oxygen 1-104 45-104(*6) 2-44(*7) 2-44(*10) 45-54(*10) 55-84(*10) 85-91(*10) 92-104(*10) I, II -> 45-104 I, II -> 2-44 I, III -> 2-104 (*1) : adjusted by -0.27 seconds (see Appendix 1); see Eqn. 1 section ii; coefficients as per "i. Shipboard Processing" (*2) : see Eqn. 1 section ii; coefficients as per "i. Shipboard Processing" (*3) : adjusted by -0.015 C (see Appendix 1); see Eqn. 2 section ii; coefficients as per "i. Shipboard Processing" (*4) : see Eqn. 2 section ii; coefficients as per "i. Shipboard Processing" (*5) : adjusted by 7 seconds (see Appendix 1) (*6) : see section for expression and coefficients. This calibration was applied to all stations, 1-104. However, the resulting oxygen concentrations from station 1-44 were not used in subsequent analyses, thus only 45-104 are identified in the Table. Concentrations for stations 1-44 were subsequently replaced with results from the Second Calibration. (*7) : see section for expression and coefficients. The Second Calibration used the oxygen sensor mean temperature and current in the 1 or 2 dbar bin and did not use the oxygen concentration computed in the First Calibration. (*8) : see Eqn. 3 section iv (*9) : see Eqn. 4 section iv (*10) : see section; same expression but different coefficients for each group. Table 1. Calibration Summary. i. Shipboard Processing The following calibration coefficients were used during the shipboard processing. Conductivity Sensor (041375) Coefficients Used for Stations 1 to 104 Conductivity = (af^m + bf^2 + c + dt)/[10(1-9.57(10^-8)p)] where f is the frequency m = 4.3 p is pressure in dbars t is the temperature a = 1.18499540E-05 b = 5.13875405E-01 c = -4.13341052E+00 d = 4.56046244E-05 Temperature Sensor (031638) Coefficients Used for Stations 1 to 104 Temperature = 1/{a + b[ln(fo/f)] + c[ln^2[fo/f] + d[ln^3(fo/f)]} - 273.15 where ln indicates a natural logarithm f is the frequency a = 3.68096719E-03 b = 6.0268375E-04 c = 1.55348636E-05 d = 2.30707462E-06 fo = 6034.53 Pressure Sensor (50601) Coefficients Used for Stations 1 to 104 Pressure = C (1 - To^2/T^2) (1 - D[1 - To^2/T^2]) where P is the pressure (psia) T is the pressure period (sec) C = C1 + C2 U + C3 U^2 D = D1 + D2 U To = T1 + T2 U + T3 U^2 + T4 U^3 + T5 U^4 U is the temperature (deg C) U = Mt + B t is the pressure temperature compensation M = 0.01145 B = -8.57985 C1 = -42746.87 psia C2 = 1.06915E+00 psia/deg C C3 = 1.26600E-02 psia/deg C^2 D1 = 0.040873 D2 = 0 T1 = 30.09559 micro sec T2 = -5.61120E-05 micro sec/deg C T3 = 4.34504E-06 micro sec/deg C^2 T4 = 2.42883E-09 micro sec/deg C^3 T5 = 0 Oxygen Sensor (130266 and 130287) Coefficients for Stations 1 to 104 Oxygen = [Soc (oc + tau * doc/dt) + Boc] * OXSAT(T, S) * e^{tcor [T + wt* (To-T)] + pcor * p} where Soc = 2.1015 oc is oxygen sensor current (microamps) oc = mV + b m = 2.4692E-07 V is the oxygen temperature sensor voltage signal b = -4.1977E-10 tau = 2.0 doc/dt is the time derivative of oc Boc = -0.0646 OXSAT is the oxygen saturation value S is salinity (PSU) e is natural log base tcor = -0.033 wt = 0.67 T is the water temperature (C) To is the oxygen sensor internal temperature (C) To = kV + c k = 8.8993 c = -7.0715 pcor = 1.5E-04 p is the pressure (psia) Note: Between stations 44 and 45 there was an exchange of oxygen sensors because sensor 130266 was malfunctioning. Although oxygen sensor 130287 replaced sensor 130266 on the CTD unit; the coefficients for sensor 130266 were never replaced by the coefficients for sensor 130287 in the Seabird software. ii. First Calibration On this cruise, it was found that for stations 1 through 14 inclusive, the pump on the CTD was installed in reverse. This caused water to flow past the CTD sensors opposite to the normal flow direction. The detailed correction procedures are given in Appendix 1. After the Appendix 1 correction was applied, the temperature and conductivity were calibrated using the following linear correction as obtained from the lab calibrations. The First Calibration was applied using SEASOFT modules. Sensor Coefficients for Stations 1 to 104 Conductivity(calibrated) = Conductivity(raw) * 1.00034089 - 0.00061 Eqn. 1 Sensor Coefficients for Stations 1 to 104 Temperature(calibrated) = Temperature(raw) * 1.00013922 + 0.0007 Eqn. 2 The oxygen data was completely (station 1-104) reprocessed. The oxygen coefficients used in the reprocessing were based on the data for stations 45 - 104. These coefficients were applied to the Station 1-44 data in an attempt to improve water sample and CTD comparisons. The oxygen calibration applied in First Calibration used processing stages I and II as described in the following section v. Oxygen Calibration Procedure. The resulting calibration is as follows: Oxygen = [Soc (oc + tau * doc/dt) + Boc] * OXSAT(T, S) * e^{tcor [T + wt* (To-T)] + pcor * p} where Soc = 4.110 oc is oxygen sensor current (microamps) oc = mV + b m = 2.4692E-07 V is the oxygen temperature sensor voltage signal b = -4.1977E-10 tau = 2.0 doc/dt is the time derivative of oc Boc = -0.0574 OXSAT is the oxygen saturation value S is salinity (PSU) e is natural log base tcor = -0.040 wt = 0.67 T is the water temperature (C) To is the oxygen sensor internal temperature (C) To = kV + c k = 8.8993 c = -7.0715 pcor = 1.69E-04 p is the pressure (psia) iii. Second Calibration The Second Calibration used the 1 and 2 dbar mean oxygen temperature and current as input to determine the hardware coefficients for the oxygen sensor used on stations 2 to 44. For the second calibration, new coefficients were found and applied to stations 2 through 44 only. This calibration applied stages I and II as described in section v. Oxygen Calibration Procedure. Oxygen Sensor Coefficients for Stations 2 to 44 Oxygen = (Soc _ oc + Boc) _ OXSAT(T(in situ,) S(in situ)) _ exp(arg); where OXSAT(T(in situ,) S(in situ)) = exp [A1 + A2 _ (100. / (T(in situ) + 273.15)) + A3 _ ln ((T(in situ) + 273.15) / 100.) + A4 _ ((T(in situ) + 273.15) / 100.) + S(in situ) _ (B1 + B2 _ ((T(in situ) + 273.15) / 100.) + B3 _ ((T(in situ) + 273.15) / 100.) _ ((T(in situ) + 273.15) / 100.))]; arg = tcor _ (T(In situ) + wt _ (To - T(in situ))) + pcor _ p(in situ ); Soc = 0.614 oc is the current from the oxygen sensor Boc = 0.72 OXSAT is the oxygen saturation value T(in situ) is the water temperature (C) S(in situ) is salinity (PSU) A1 = -173.4292 A2 = 249.6339 A3 = 143.3483 ln (natural logarithm) A4 = -21.8492 B1 = -0.033096 B2 = 0.014259 B3 = -0.001700 tcor = -0.0164 wt = 0.67 To is the oxygen sensor internal temperature (C), where To = kV + c k = 8.8993 V is the oxygen temperature sensor voltage signal c = -7.0715 pcor = 3.95E-06 p(in situ) is the pressure (psia) iv. Third Calibration The following salinity corrections were made to the 1 and 2 dbar datasets. CTD Salinity(calibrated) = CTD Salinity(raw) + 0.0040 (Stn. 2 - 14) Eqn. 3 CTD Salinity(calibrated) = CTD Salinity(raw) + 0.0018 (Stn. 15 - 104) Eqn. 4 The CTD oxygen Third Calibration used the results of the Second Calibration for the station 2-44 data and the results of the First Calibration for the station 45 to 104 data. The Third Calibration applied stages I and III as described in section v. Oxygen Calibration Procedure. The resulting oxygen corrections were applied to the 1 and 2 dbar datasets. The corrections were of the form: Ox(ctd) = Ox(ctd) + o _ Ox(ctd) + t1 _ T(ctd) + t2 _ T(ctd)^2 + t3 _ T(ctd)^3 + t4 _ T(ctd)^4 + p1 _ P(ctd) + p2 _ P(ctd)^2 + p3 _ P(ctd)^3 + p4 _ P(ctd)^4 + a + Time_cor (Station number), where for Stations 2 to 44: a = -6.1523, o = 0.906663, t1 = 0.25782, t2 = -0.0823562, t3 = 0.00824184, t4 = -0.000222572, p1 = 0.000331526, p2 = -1.20509E-007, p3 = 1.19481E-011, p4 = 0.0, Time_cor (Station number) - see Table 2; where for Stations 45 to 54: a = -0.432137, o = 0.0, t1 = 0.0, t2 = 0.0, t3 = 0.0, t4 = 0.0, p1 = 0.000975191, p2 = -4.89749E-007, p3 = 8.00916E-011, p4 = 0.0, Time_cor (Station number) - see Table 2; where for Stations 55 to 84 and 92 to 104: a = -0.0652795, o = 0.0, t1 = 0.0, t2 = 0.0, t3 = 0.0, t4 = 0.0, p1 = 0.000155021, p2 = -8.31746E-008, p3 = 2.21829E-011, p4 = -2.20387E-015, Time_cor (Station number) - see Table 2; where for Stations 85 to 91: a = 2.139, o = -0.379712, t1 = 0.0, t2 = 0.0, t3 = 0.0, t4 = 0.0, p1 = 0.000976793, p2 = -4.33667E-007, p3 = 0.0, p4 = 0.0, Time_cor (Station number) - see Table 2. Station Correction Station Correction Station Correction number (Time_cor) number (Time_cor) number (Time_cor) 2 -.0564 37 0.2697 72 0.0800 3 -.0564 38 0.2077 73 0.1145 4 -.0568 39 0.2249 74 0.1193 5 -.0411 40 0.1608 75 0.1000 6 -.0069 41 0.1039 76 0.0980 7 .0548 42 0.2419 77 0.0800 8 .1100 43 0.2419 78 0.0624 9 .1848 44 0.2419 79 0.0500 10 .2104 45 -1.2447 80 0.0386 11 .1013 46 -0.5000 81 0.0029 12 .0887 47 0.2970 82 0.0186 13 .0396 48 2.3301 83 -0.0004 14 .0686 49 3.7974 84 -0.0092 15 .1184 50 4.4502 85 0.000 16 -.0276 51 4.4127 86 0.000 17 -.1520 52 3.5728 87 0.000 18 -.0039 53 2.4972 88 0.000 19 -0.0814 54 0.7181 89 0.000 20 -0.2208 55 -0.0108 90 0.000 21 -0.2645 56 -0.0442 91 0.000 22 -0.5040 57 -0.1054 92 0.0147 23 -0.5252 58 0.0078 93 0.0297 24 -0.4459 59 -0.0102 94 -0.0296 25 -0.3255 60 0.0473 95 -0.0156 26 -0.2460 61 0.0441 96 -0.0339 27 -0.0103 62 0.0450 97 -0.0265 28 0.1073 63 0.0468 98 -0.0652 29 0.1305 64 0.0979 99 -0.0025 30 -0.6365 65 0.1039 100 -0.0291 31 0.1767 66 0.0585 101 -0.0170 32 0.3133 67 0.0750 102 -0.0161 33 0.3320 68 0.1029 103 -0.0767 34 0.2505 69 0.0881 104 -0.0767 35 0.2234 70 0.0512 36 0.2774 71 0.0542 v. Oxygen Calibration Procedure The calibration parameters for the CTD oxygen data were based on down trace CTD data and measurements of water sample oxygen concentration from bottles tripped on the uptrace. Although these datasets are inconsistent (to some degree) in time and spatial location, they were considered the only reliable source of information for calibration of CTD oxygen. The procedure for finding the calibrations to be applied to the downcast CTD oxygen was subdivided into three stages (both II and III are iterative procedures): I. Creating a calibration file, II. Computing non-linear 'hardware' coefficients, III. Computing corrections of time drift and residual effects of pressure, temperature and oxygen (secondary correction). I. Creating a Calibration File 1) The calibration file is used for finding and testing calibrations (set of coefficients) later applied to the CTD data, while computing CTD Oxygen. A base for this file consisted of discrete CTD readings of temperature, pressure, salinity, etc. averaged over three seconds at the depth and time of bottle tripping. The calibration file creation steps are outlined below; 2) Water sample salinity and oxygen concentration determined onboard were added to the calibration file; 3) For initial 'indirect' check of quality, the differences between water sample and calibrated CTD salinity were computed. If the absolute difference exceeded 0.004 the point (record) containing this data was considered unreliable and discarded from further analysis; 4) Next, a search and selection was performed for each record of the calibration file. The goal is to find a point in a downtrace profile in the same general water type. - data from a downtrace profile were restricted to a certain pressure (or/and) density (or/and) temperature (or/and) salinity vicinity of the uptrace point (the calibration file). This defines a group. Typical criteria (definition of vicinity): differences between uptrace and downtrace pressure 25 db, potential temperature 0.5K, salinity 0.02. [Note: For some upcast data points, no downcast point was found within the defined criteria. In these cases, the CTD oxygen in the SEA file is indicated with a null value of -9.0 and a quality flag of 9, not sampled.] - find a point in the group which is closest to the uptrace data point (from the calibration file) in multidimensional space, where dimensions are normalized (weighted or rescaled) pressure, potential temperature, salinity and density. Normalization for each axis was done according to expected variability within a water type. In ultimate cases only one or two dimensions were chosen. The found point was identified as being "closest" to the upcast CTD data point at the time of bottle trip. At this point, the downtrace CTD data has been added to the calibration file. 5) Next the dataset was split into sets based on distinct changes in the sensors behavior. The set represented quasi-steady periods of oxygen sensor behavior. This avoided extreme temporal drifts in any of the sets and allowed the use of the same non-linear coefficients for each set. II. Computing Non-linear 'Hardware' Coefficients 1) A nonlinear multiparametric least square technique was used to determine the oxygen sensor processing coefficients (soc, boc, tcor, and bcor) using oxygen(ws) vs. downcast temperature(ctd), salinity(ctd), pressure(ctd), oxygen current(ctd) and oxygen temperature(ctd) (where the ws/ctd subscripts represents water sample/CTD data). 2) Applying the results of step II.1, the oxygen(ctd) was derived. 3) Compute oxygen(ws) - oxygen(ctd). Statistics of the difference were computed and the records that produced outliers (no matter if the outliers were produced by oxygen(ws) or oxygen(ctd)) were marked or deleted from the calibration file. 4) Checking the oxygen(ws) - oxygen(ctd) distributions: - if the differences (oxygen(ws) - oxygen(ctd)) are randomly distributed versus all parameters (temperature, pressure, oxygen current, and oxygen temperature) and there are no evident outliers, proceed to stage III, - otherwise, using the cleaned calibration file (derived in stage I and cleaned according to II.3) repeat all the steps of stage II until the first part of the check II.4 is true (typically, it requires 10 to 15 iterations to clean the calibration file and determine the oxygen sensor processing coefficients soc, boc, tcor, and bcor). III. Computing corrections of time drift and residual effects of pressure, temperature and oxygen 1) Using the differences from II.4 (first iteration on this stage) or III.4 (second and higher iteration), compute the median oxygen(ws) - oxygen(ctd) for each station. The series of station-by-station medians represents the time drift of the sensor. 2) Subtract the individual station median (time drift, III.1) from the differences oxygen(ws) - oxygen(ctd) for that station, which must be taken from II.4. 3) Individually for pressure, temperature and then oxygen, use the set of stations (as defined in I.5) to compute a polynomial fit of the residuals from III.2 in pressure, temperature and oxygen. 4) Subtract the polynomial correction, derived in III.3, from the differences computed in II.4 (before subtraction of the time-drift). Check if there are any outliers. 5) Subtract the time drift (station median) from the results of III.4. - If these (new III.5) residuals don't depend on pressure, temperature, oxygen or time and their statistics is not improving with any sequential iteration (distribution getting tighter) advance to III.6. - Otherwise, use the results of step III.4 and repeat all the steps of stage III until the first bulleted part of III.5 is true. This iteration typically requires 7 to 14 repetitions. 6) Finalize calibration coefficients. vi. CTD Quality Flagging The processed 2 dbar CTD was quality flagged by applying "bad" flags to the near-surface data. This data would have been collected before the system pump was activated, and thus does not represent a measurement from a properly operating system. This typically meant that the temperature, salinity and oxygen data above 10 dbars is flagged using WOCE code "4". 2. Salinity Bruce Carson a. Description of Equipment and Technique Salinity samples were analyzed on one of two Guildline Autosal model 8400 salinometers. Samples were drawn in 150 ml medicine bottles. New caps, equipped with plastic liners, were placed on the sample bottles for each use. The salinometer cell was filled and rinsed three times with sample water before readings were recorded. Two readings of the salinometer were recorded for every sample and standardization. If the values fluctuated, more readings were taken. b. Sampling Procedure and Data Processing Technique Salinity samples were drawn into the medicine bottles after three rinses. The bottles were filled up to the shoulders and then capped with new caps with plastic liners. Data files for each separate run were prepared. These files consisted of various metadata (date, cruise, lab temperature, geographic location, operator, etc.) and sample specific data such as the bath temperature, sample ID number, and average conductivity ratio. A PC based program computed the salinity using average conductivity ratio of the runs and the standard IAPSO formula. Any changes in the salinometer readings between successive standardizations was assumed to have occurred as a linear drift of the instrument. Thus, the program applied a correction to the ratios, which varied linearly with the samples analyzed. The salinity data was then placed in the water sample database. c. Laboratory and Sample Temperatures Full cases of samples were taken from the winch room to the GP lab where they were left for a period of at least 10 hours to equilibrate to laboratory temperature before being analyzed. The baths in these two salinometers were kept at 21C and 24C. The salinometer which was just above the current laboratory temperature would be the one that was used for any given run of samples. d. Replicate Analysis A replicate salinity sample was drawn from one of the rosette bottles on most stations. In total, 93 replicate samples were drawn for 93 sample id numbers. Of these sample id numbers, two (sample numbers 151372 and 151377) had at least one unacceptable sample value. The 186 sample values are given in Table C.1. Statistics of the difference of acceptable replicate values follow. The statistics were determined using the absolute value of the replicate difference. Statistic Value Number of Replicate 91 Differences Minimum 0 Maximum 0.0148 Mean 0.0013 Median 0.0006 Standard Deviation 0.0024 Table C.1 Replicate water sample salinity values. Sample ID Salinity WOCE QF Sample ID Salinity WOCE QF Number Number 150603 34.9270 2 151383 34.4264 2 150603 34.9268 2 151387 34.8448 2 150613 34.9211 2 151387 34.8456 2 150613 34.9252 2 151396 34.8382 2 150627 34.7655 2 151396 34.8382 2 150627 34.7663 2 151404 34.9683 2 150635 34.8647 2 151404 34.9685 2 150635 34.8677 2 151409 34.6100 2 150651 34.9390 2 151409 34.6100 2 150651 34.9390 2 151411 34.8473 2 150679 34.8937 2 151411 34.8500 2 150679 34.8947 2 151425 34.8963 2 150691 34.9061 2 151425 34.8965 2 150691 34.9163 2 151442 34.8721 2 150708 34.8792 2 151442 34.8704 2 150708 34.8784 2 151457 34.9201 2 150726 34.8463 2 151457 34.9202 2 150726 34.8473 2 151473 34.8937 2 150746 34.9479 2 151473 34.8939 2 150746 34.9489 2 151493 34.8950 2 150757 34.8793 2 151493 34.8950 2 150757 34.8803 2 151513 34.8906 2 150790 35.0453 2 151513 34.8932 2 150790 35.0449 2 151535 34.8974 2 150806 34.9559 2 151535 34.8984 2 150806 34.9553 2 151553 34.8942 2 150820 34.8844 2 151553 34.8954 2 150820 34.8869 2 151575 34.9055 2 150837 34.9064 2 151575 34.9059 2 150837 34.9066 2 151597 34.9209 2 150857 34.8729 2 151597 34.9221 2 150857 34.8729 2 151613 34.8910 2 150877 34.8749 2 151613 34.8985 2 150877 34.8751 2 151643 34.9140 2 150908 35.0274 2 151643 34.9148 2 150908 35.0270 2 151657 34.9368 2 150917 34.8876 2 151657 34.9376 2 150917 34.8880 2 151673 34.8936 2 150943 34.9201 2 151673 34.8932 2 150943 34.9213 2 151693 34.8949 2 150963 34.9307 2 151693 34.8961 2 150963 34.9321 2 151714 34.9005 2 150977 34.8818 2 151714 34.9012 2 150977 34.8835 2 151733 34.8980 2 151003 34.9419 2 151733 34.9002 2 151003 34.9431 2 151754 34.9053 2 151017 34.8840 2 151754 34.9036 151017 34.8842 2 151777 35.0018 2 151042 34.9138 2 151777 35.0016 2 151042 34.9142 2 151805 34.9906 2 151060 34.9053 2 151805 34.9906 2 151060 34.9055 2 151818 34.9183 2 151080 34.9099 2 151818 34.9187 2 151080 34.9119 2 151833 34.8934 2 151097 34.9001 2 151833 34.8937 2 151097 34.9006 2 151860 34.8942 2 151121 34.9140 2 151860 34.8987 2 151121 34.9158 2 151873 34.8902 2 151137 34.8900 2 151873 34.8930 2 151137 34.8904 2 151895 34.9048 2 151160 34.9067 2 151895 34.9048 2 151160 34.9061 2 151912 34.8235 2 151177 34.8882 2 151912 34.8226 2 151177 34.8883 2 151917 32.8017 2 151206 34.9134 2 151917 32.8019 2 151206 34.9136 2 151927 34.8389 2 151222 34.9437 2 151927 34.8399 2 151222 34.9441 151932 34.8426 2 151238 34.9024 2 151932 34.8438 2 151238 34.9016 2 151947 34.8739 2 151265 34.9235 2 151947 34.8607 2 151265 34.9235 2 151962 34.8972 2 151284 34.9234 2 151962 34.8969 2 151284 34.9253 2 151985 34.9237 2 151316 35.1849 2 151985 34.9237 2 151316 35.1849 2 152001 34.8949 2 151342 34.9062 2 152001 34.8957 2 151342 34.9062 2 152022 34.8971 2 151355 34.7559 2 152022 34.8981 2 151355 34.7561 2 152046 34.9220 2 151362 34.8224 2 152046 34.9242 2 151362 34.8218 2 152061 34.8993 2 151370 33.2254 2 152061 34.8989 2 151370 33.2258 2 152084 34.9119 2 151372 33.1364 4 152084 34.9119 2 151372 33.5264 2 152101 34.9069 2 151374 33.5739 2 152101 34.9093 2 151374 33.5744 2 152123 34.9053 2 151377 33.7536 4 152123 34.9080 2 151377 33.7551 4 152153 34.9455 2 151382 33.2338 2 152153 34.9456 2 151382 33.2343 2 152167 34.9362 2 151383 34.4263 2 152167 34.9215 2 3. Oxygen Pierre Clement a. Description of Equipment and Technique The automated procedure followed was based on the method developed by the Physical and Chemical Services Branch (PCS) of the Bedford Institute of Oceanography (BIO) (Levy et al. 1977). The PCS procedure was a modified Winkler titration from Carritt and Carpenter (1966), using a whole bottle titration. In this method there was no starch indicator. A wetting agent (Wetting Agent A, BDH) was introduced to reduce bubble formation. The full description of the system and method can be found in Jones, et al. (1992). In summary the automated titration system consisted of an IBM PC linked to a Brinkmann PC800 colorimeter and a Metrohm 655 Multi-Dosimat Automatic Titrator. The PC talked to the peripherals through a Data Translation, DT2806 and three Data Translation DTX350s. b. Sampling Procedure and Data Processing Technique The sampling bottles were 125ml Iodine flasks with custom ground stoppers (Levy et al. 1977). The flasks volumes were determined gravimetrically. The matched flasks and stoppers were etched with identification numbers and entered into the Oxygen program database. For this cruise eight litre Niskin bottles were used to obtain the original sample. Then, the oxygen subsamples were drawn through the bottles spigot with a latex or silicone tube attached so as to introduce the water to the bottom of the flask. Once the flow was started, the flask was inverted to ensure that there was no air trapped in the tube. Next, the tube was partially pinched to reduce the flow rate and the flask reoriented and filled to overflowing. The flow was allowed to continue until at least two to three volumes had run through, then the flask slowly retracted with continuous low flow to ensure that no air got trapped in the flask. The flask was then brought to the reagent station and one millilitre of the Alkaline Iodide and Manganous Chloride Reagents were added and the stoppers carefully inserted, again ensuring that no air got into the flasks. The flasks were then shaken and carried to the lab for analysis. c. Replicate Analysis There were 1580 unique sample id numbers for the cruise. Oxygen samples were intentionally not drawn for 20 sample id numbers. Six sample id numbers did not have enough water in the Rosette bottle to sample for oxygen. While two others had totally unreliable data that was not reported. The remaining 1552 sample id numbers were analyzed for dissolved oxygen; of these sample id numbers, 1455 had one sample value, 10 had two sample values and 87 had three sample values. The replicate samples were taken from a water sample bottle at each station in order to monitor precision, which can be affected by flaws in sampling or titration. Statistics of the replicate differences follow. Only the 233 acceptable values were used in calculating the 229 replicate differences. There were four sample id numbers having acceptable values including one replicate and 75 sample id numbers having acceptable values including two replicates. Number of acceptable replicate differences = 4 sample id numbers having one replicate * 1 possible difference + 75 sample id numbers having two replicates * 3 possible differences = 229 Median of [(absolute difference/sample mean concentration) * 100%] = 0.28 % Statistic Value (moles/kg) Minimum 0.0 Maximum 60.8 Mean 2.3 Median 0.8 Standard Deviation 7.3 Cumulative Frequency Oxygen Difference (moles/kg) 50 % less than or equal to 0.8 68 % less than or equal to 1.5 95 % less than or equal to 5.3 All 281 oxygen replicate sample values with their respective quality flags are given in Table C.2. Table C.2 Replicate water sample oxygen values in moles/kg. Sample ID Oxygen WOCE QF Sample ID Oxygen WOCE QF Number Number 150624 294.9 2 151381 320.6 2 150624 293.9 2 151386 330.7 2 150632 280.0 2 151386 330.8 2 150632 282.9 2 151386 331.8 2 150651 277.4 2 151388 301.8 2 150651 278.0 2 151388 301.9 2 150651 278.2 2 151388 302.2 2 150670 284.9 2 151395 299.4 2 150670 285.2 2 151395 299.7 2 150670 286.4 2 151395 299.8 2 150695 274.9 2 151401 294.2 2 150695 278.6 2 151401 294.3 2 150695 278.6 2 151401 295.6 150715 153.3 2 151408 256.9 2 150715 154.1 2 151408 257.3 2 150715 155.6 2 151408 257.3 2 150729 242.4 2 151414 276.7 2 150729 247.2 2 151414 271.4 2 150729 247.8 2 151414 274.9 2 150751 164.4 2 151427 287.5 2 150751 162.3 2 151427 284.6 2 150751 162.5 2 151427 284.1 2 150758 197.7 2 151436 285.2 2 150758 256.7 2 151436 285.8 2 150758 258.5 2 151436 286.2 2 150785 274.0 2 151442 296.9 4 150785 275.2 2 151442 298.2 4 150785 278.2 2 151454 290.1 2 150800 269.6 2 151454 291.5 2 150800 272.4 2 151454 289.8 2 150800 272.5 2 151476 284.3 2 150826 275.0 2 151476 334.0 2 150826 275.0 2 151476 283.9 2 150826 276.3 2 151502 283.9 2 150838 275.2 2 151502 287.2 2 150838 273.9 2 151502 287.5 2 150838 272.3 2 151526 237.6 2 150870 265.3 2 151526 241.2 2 150870 265.6 2 151526 237.7 2 150870 264.7 2 151536 279.5 2 150878 266.9 2 151536 281.1 2 150878 267.8 2 151536 281.2 2 150878 268.3 2 151571 179.6 2 150907 267.7 2 151571 180.2 2 150907 267.3 2 151571 183.3 2 150907 267.3 2 151576 279.9 2 150932 170.1 2 151576 280.1 2 150932 169.8 2 151576 279.7 2 150932 170.1 2 151595 278.7 2 150944 273.1 2 151595 278.9 2 150944 273.5 2 151595 278.4 2 150944 273.6 2 151619 275.6 2 150974 217.6 4 151619 276.7 2 150974 190.4 4 151619 276.9 2 150975 210.6 2 151637 279.2 2 150975 204.5 2 151637 281.2 2 150975 202.9 2 151637 279.6 2 150993 213.8 2 151663 273.5 2 150993 213.8 2 151663 273.5 2 150993 213.9 2 151663 273.8 2 151001 271.8 2 151681 272.0 4 151001 273.7 2 151681 283.2 4 151001 273.7 2 151682 280.3 2 151023 270.7 2 151682 281.6 2 151023 270.7 2 151682 279.7 2 151023 272.4 2 151694 283.5 2 151041 274.1 2 151694 284.6 2 151041 274.7 2 151694 282.3 2 151041 276.1 2 151717 282.4 4 151058 272.0 2 151717 272.7 4 151058 272.2 2 151717 281.4 4 151058 271.8 2 151752 232.1 2 151080 280.1 4 151752 231.9 2 151080 -3.7 151752 231.7 2 151081 274.6 2 151755 280.3 2 151081 274.7 2 151755 280.8 2 151081 276.4 2 151755 280.8 2 151111 181.6 2 151781 279.9 2 151111 190.5 2 151781 280.3 2 151111 191.3 2 151781 280.3 2 151128 262.9 2 151801 287.7 2 151128 263.8 2 151801 287.8 2 151129 239.6 2 151801 287.4 2 151129 239.6 2 151820 277.9 2 151129 238.2 2 151820 278.4 2 151143 278.4 2 151820 277.1 2 151143 278.6 2 151852 269.2 2 151143 278.6 2 151852 269.7 2 151156 19.6 3 151852 270.0 2 151156 215.6 2 151857 288.3 2 151163 281.6 2 151857 290.6 2 151163 282.7 2 151857 290.1 151163 283.2 2 151879 288.5 2 151180 277.9 2 151879 290.5 2 151180 278.1 2 151879 291.6 2 151180 279.3 2 151896 290.5 2 151201 280.1 2 151896 291.1 2 151201 284.4 2 151896 292.5 2 151201 279.9 2 151916 307.1 2 151226 280.8 2 151916 307.4 2 151226 280.9 2 151931 301.0 2 151226 279.7 2 151931 303.2 2 151240 283.5 2 151931 300.8 2 151240 283.5 2 151941 1.0 4 151240 283.7 2 151941 291.5 4 151257 281.8 2 151947 287.8 2 151257 287.0 2 151947 288.8 2 151257 286.2 2 151947 287.6 2 151286 291.9 2 151964 288.0 3 151286 292.0 2 151964 288.5 3 151286 292.2 2 151964 289.9 3 151297 287.8 2 151984 287.4 3 151297 288.1 2 151984 287.4 3 151297 290.9 2 151984 287.7 3 151330 263.3 2 152005 286.5 3 151330 267.9 2 152005 284.6 3 151330 262.6 2 152005 284.8 3 151341 289.6 2 152026 282.5 3 151341 290.5 2 152026 282.4 3 151341 289.1 2 152026 282.5 3 151354 295.8 2 152048 296.7 4 151354 295.8 2 152048 296.9 3 151354 295.8 2 152048 298.4 3 151364 291.7 2 152063 282.6 3 151364 292.5 2 152063 283.1 3 151364 291.8 2 152063 281.4 3 151368 291.8 2 152086 280.5 3 151368 291.8 2 152086 280.6 3 151368 292.2 2 152086 280.8 3 151372 318.6 2 152103 280.3 3 151372 321.4 2 152103 281.7 3 151372 321.4 2 152103 282.4 3 151376 316.9 2 152121 281.4 3 151376 318.0 2 152121 283.8 3 151376 318.8 2 152121 277.6 3 151377 301.5 2 152144 281.9 3 151377 312.8 2 152144 281.9 3 151377 315.7 2 152144 281.6 3 151381 320.9 2 152162 277.7 3 151381 320.6 2 152162 275.5 3 152162 276.6 3 4. Nutrients Pierre Clement a. Description of Equipment and Technique Nutrient concentrations were determined using a Technicon Autoanalyser II. The chemistries were standard Technicon (Silicate 186-72W, Phosphate 155-71W, Nitrate/Nitrite 158-71W) except for Phosphate which was modified by separating the Ascorbic Acid (4.0 gms/L) from the Mixed Reagent. This alteration was achieved by introducing the modified Mixed Reagent instead of water at the start of the sample stream at 0.23 ml/minute and the Ascorbic Acid was pumped into the stream between the two mixing coils at 0.32 ml/minute. b. Sampling Procedure and Data Processing Technique Duplicate nutrient subsamples were drawn into 30 ml HDPE (Nalge) wide mouth sample bottles from 8 litre Niskins. The bottles were 10% HCl washed, rinsed once with tap water, three times with Super-Q and oven dried at >100 Degrees F. A sample run included six Working Standards run at the beginning and end. Duplicate Check Standards were run every 16 samples followed by blanks as a Baseline Check. These Standards were made up in 33 ppt NaCl (VWR, Analar grade) as was the wash water. The Standards were tested against CSK Solution Standards (Sagami Chemical Center, Japan). Analog data was converted to digital, processed and statistics calculated by a Pascal 6.0 in house program (Logger) on a PC. Chart recordings, hard copy and disk copies of the data were kept for reference. c. Replicate Analysis A total of 3158 seawater samples were analyzed for silicate, phosphate and NO2+NO3. Included in these samples were a total of 1579 duplicate samples. Duplicate samples were drawn from each rosette bottle on every cast for the determination of silicate, phosphate and nitrate concentrations. Statistics relating to the precision of the sample values follow. All values are given in moles/kg. All sample values are listed in Table C.3. Precision is a measure of the variability of individual measurements and in the following analysis two categories of precision were determined; field and analytical precision. Analytical precision is based on the pooled estimate of the standard deviation of the check standards over the course of a complete autoanalyzer run and is a measure of the greatest precision possible for a particular analysis. Field precision is based on the analysis of two or more water samples taken from a single Niskin sampling bottle and has an added component of variance due to subsampling, storage and natural sample variability. Both categories of precision were determined by computing the variance, , of each replicate set, where "i" is the index of the replicate set. In the case of analytical (field) precision, a replicate set consisted of all the check standards (duplicate samples). Given p replicate sets and n samples within any replicate set, the mean standard deviation, , was determined from See equation in PDF file. The precision expressed in percent was based on the mean concentration, M, of the check standards (analytical precision) or water samples (field precision) and was given by See equation in PDF file. The following table indicates the analytical and field precision obtained for this cruise. Silicate Phosphate NO2+NO3 Number of Samples 3159 3159 3159 Number of Duplicates 1579 1579 1579 Mean concentration (moles/kg) 13.24 1.05 15.71 Field Precision (moles/kg) 0.23 0.03 0.24 Field Precision (%) 1.8 3.2 1.5 Analytical Precision 0.57 0.05 0.27 (moles/kg) Analytical Precision (%) 2.1 4.52 1.71 Detection Limit (moles/kg) 0.24 0.02 0.25 The laboratory temperature during all analyses was between 21 and 23 C. The conversion to mass units for the analytical precision and detection limits used a standard density of 1.02443 kg/L corresponding to 33 ppt and 15C. The conversion of individual sample values from volume to mass units used a potential density with a fixed temperature of 15C. The nutrient detection limits noted in the above table were applied to the dataset. All values at or below the detection limits were set to zero. The following duplicate measurements were used to compute the values given in the SEA file. All values that follow are in moles/kg Table C.3 Nutrient replicate water sample values in moles/kg. ID SiO4 PO4 NO2+NO3 WOCE QF ID SiO4 PO4 NO2+NO3 WOCE QF 150601 12.07 1.17 17.80 5 5 5 151390 6.58 0.92 12.66 2 2 2 150601 12.06 1.14 18.16 5 5 5 151390 6.57 0.90 12.66 2 2 2 150602 11.97 1.35 18.28 5 5 5 151391 1.56 0.34 0.50 2 2 2 150602 11.98 1.18 18.16 5 5 5 151391 1.57 0.34 0.72 2 2 2 150603 11.79 1.21 18.35 5 5 5 151392 12.22 1.07 15.91 2 2 2 150603 11.91 1.17 18.27 5 5 5 151392 12.30 1.06 16.14 2 2 2 150604 12.02 1.23 17.98 5 5 5 151393 10.09 1.05 16.17 2 2 2 150604 12.23 1.19 18.14 5 5 5 151393 10.20 1.04 16.26 2 2 2 150605 12.02 1.22 18.01 5 5 5 151394 9.57 1.04 16.20 2 2 2 150605 11.97 1.16 17.71 5 5 5 151394 9.65 1.04 16.33 2 2 2 150606 11.92 1.29 18.22 5 5 5 151395 9.54 1.05 17.74 2 2 2 150606 11.95 1.22 18.36 5 5 5 151395 9.85 1.07 18.31 2 2 2 150607 11.85 1.20 18.23 5 5 5 151396 9.44 1.07 16.39 2 2 2 150607 11.99 1.28 18.32 5 5 5 151396 9.50 1.06 15.86 2 2 2 150608 11.79 1.23 17.98 5 5 5 151397 9.73 1.09 16.00 2 2 2 150608 11.98 1.22 17.92 5 5 5 151397 9.45 1.06 15.81 2 2 2 150609 5 5 5 151398 8.33 1.00 14.62 2 2 2 150609 5 5 5 151398 8.45 0.99 15.00 2 2 2 150610 5 5 5 151399 1.03 0.23 0.00 2 2 2 150610 5 5 5 151399 1.11 0.22 0.25 2 2 2 150611 5 5 5 151400 10.41 1.05 16.26 2 2 2 150611 5 5 5 151400 10.52 1.07 16.09 2 2 2 150612 5 5 5 151401 10.29 1.07 16.12 2 2 2 150612 5 5 5 151401 10.33 1.06 16.08 2 2 2 150613 5 5 5 151402 10.15 1.06 16.38 2 2 2 150613 5 5 5 151402 10.30 1.15 16.48 2 2 2 150614 5 5 5 151403 5 5 5 150614 5 5 5 151403 5 5 5 150615 5 5 5 151404 10.83 1.14 17.41 2 2 2 150615 5 5 5 151404 10.85 1.15 17.61 2 2 2 150616 5 5 5 151405 11.19 1.15 17.75 2 2 2 150616 5 5 5 151405 10.89 1.16 17.62 2 2 2 150617 5 5 5 151406 11.92 1.20 17.76 2 2 2 150617 5 5 5 151406 12.05 1.21 18.12 2 2 2 150618 5 5 5 151407 10.98 1.13 16.75 3 3 3 150618 5 5 5 151407 11.01 1.10 17.19 3 3 3 150619 5 5 5 151408 11.16 1.16 18.14 2 2 2 150619 5 5 5 151408 11.23 1.15 18.18 2 2 2 150620 5 5 5 151409 11.26 1.19 17.69 2 2 2 150620 5 5 5 151409 11.11 1.18 17.71 2 2 2 150621 9.57 1.00 10.46 3 2 2 151410 0.94 0.27 0.26 2 2 2 150621 9.70 0.98 10.65 3 2 2 151410 0.77 0.28 0.00 2 2 2 150622 7.60 0.88 7.95 3 2 2 151411 9.85 1.05 15.54 2 2 2 150622 7.63 0.85 7.89 3 2 2 151411 10.00 1.04 15.79 2 2 2 150623 0.91 0.28 0.60 3 2 2 151412 10.06 1.05 15.95 2 2 2 150623 0.77 0.30 0.57 3 2 2 151412 10.21 1.07 16.38 2 2 2 150624 10.42 1.07 17.34 3 2 2 151413 10.70 1.08 17.24 2 2 2 150624 10.58 1.06 17.41 3 2 2 151413 10.72 1.09 17.26 2 2 2 150625 10.37 1.06 17.54 3 2 2 151414 10.83 1.12 17.60 2 2 2 150625 10.72 1.07 17.53 3 2 2 151414 11.01 1.11 17.33 2 2 2 150626 10.38 1.09 17.63 3 2 2 151415 9.98 1.06 16.22 2 2 2 150626 10.39 1.08 17.80 3 2 2 151415 9.82 1.05 16.30 2 2 2 150627 10.76 1.08 17.32 3 2 2 151416 10.97 1.16 17.56 2 2 2 150627 10.79 1.08 17.21 3 2 2 151416 11.03 1.14 17.53 2 2 2 150628 10.62 1.09 17.50 3 2 2 151417 9.97 1.11 14.83 2 2 2 150628 10.71 1.07 17.03 3 2 2 151417 9.88 1.10 15.03 2 2 2 150629 10.87 1.04 15.88 3 2 2 151418 7.37 0.93 10.94 2 2 2 150629 10.97 1.06 15.79 3 2 2 151418 7.28 0.92 10.95 2 2 2 150630 11.02 1.01 12.24 3 2 2 151419 11.87 1.06 16.31 2 2 2 150630 10.98 1.01 12.33 3 2 2 151419 11.92 1.08 16.24 2 2 2 150631 1.20 0.32 0.71 3 2 2 151420 11.27 1.06 15.90 2 2 2 150631 1.38 0.31 0.84 3 2 2 151420 11.47 1.06 16.01 2 2 2 150632 13.76 1.11 17.91 3 2 2 151421 10.64 1.07 15.79 2 2 2 150632 13.81 1.10 18.03 3 2 2 151421 10.70 1.06 16.01 2 2 2 150633 5 5 5 151422 10.35 1.08 15.83 2 2 2 150633 5 5 5 151422 10.43 1.07 15.66 2 2 2 150634 10.95 1.06 17.59 3 2 2 151423 10.34 1.07 15.95 2 2 2 150634 11.00 1.09 17.46 3 2 2 151423 10.32 1.05 16.13 2 2 2 150635 11.15 1.07 17.30 3 2 2 151424 10.45 1.08 15.95 2 2 2 150635 11.40 1.08 17.46 3 2 2 151424 10.58 1.10 16.16 2 2 2 150636 11.11 1.09 17.38 3 2 2 151425 10.45 1.10 16.46 2 2 2 150636 11.35 1.11 17.76 3 2 2 151425 10.63 1.11 16.16 2 2 2 150637 11.00 1.08 17.83 3 2 2 151426 10.26 1.12 16.34 2 2 2 150637 11.06 1.09 17.64 3 2 2 151426 10.44 1.10 16.62 2 2 2 150638 11.32 1.10 17.31 3 2 2 151427 10.68 1.10 17.03 2 2 2 150638 11.24 1.08 17.48 3 2 2 151427 10.71 1.11 17.31 2 2 2 150639 10.68 1.08 17.34 3 2 2 151428 10.49 1.12 17.07 2 2 2 150639 10.72 1.10 17.48 3 2 2 151428 10.54 1.11 17.15 2 2 2 150640 10.77 1.10 17.79 3 2 2 151429 10.68 1.15 17.31 2 2 2 150640 10.77 1.10 17.60 3 2 2 151429 10.73 1.16 17.20 2 2 2 150641 11.25 1.14 17.97 3 2 2 151430 9.94 1.13 16.34 2 2 2 150641 11.54 1.14 18.17 3 2 2 151430 9.88 1.12 16.32 2 2 2 150642 10.91 1.12 17.76 3 2 2 151431 10.29 1.10 16.26 2 2 2 150642 10.86 1.13 17.68 3 2 2 151431 10.31 1.13 16.12 2 2 2 150643 10.39 1.12 17.55 3 2 2 151432 10.60 1.16 16.73 2 2 2 150643 10.29 1.11 17.25 3 2 2 151432 10.66 1.19 16.57 2 2 2 150644 12.01 1.24 18.94 3 2 2 151433 16.26 1.07 15.50 2 2 2 150644 12.08 1.22 19.41 3 2 2 151433 16.41 1.07 15.37 2 2 2 150645 5 5 5 151434 15.39 1.06 15.45 2 2 2 150645 5 5 5 151434 15.42 1.06 15.20 2 2 2 150646 1.09 0.28 0.00 3 2 2 151435 14.14 1.17 15.20 2 2 2 150646 1.27 0.25 0.00 3 2 2 151435 14.34 1.04 15.55 2 2 2 150647 17.57 1.07 16.45 3 2 2 151436 14.71 1.06 15.90 2 2 2 150647 17.75 1.08 16.61 3 2 2 151436 14.85 1.07 15.90 2 2 2 150648 16.20 1.12 16.62 3 2 2 151437 13.65 1.07 15.65 2 2 2 150648 16.10 1.12 16.77 3 2 2 151437 13.75 1.08 15.88 2 2 2 150649 16.04 1.10 16.55 3 2 2 151438 13.00 1.07 15.88 2 2 2 150649 16.12 1.10 16.67 3 2 2 151438 12.98 1.07 15.77 2 2 2 150650 16.73 1.16 17.43 3 2 2 151439 12.57 1.08 16.02 2 2 2 150650 16.65 1.16 17.57 3 2 2 151439 12.68 1.09 15.88 2 2 2 150651 15.60 1.16 17.57 3 2 2 151440 11.56 1.09 16.04 2 2 2 150651 15.33 1.15 17.30 3 2 2 151440 11.61 1.08 15.94 2 2 2 150652 15.35 1.19 17.99 3 2 2 151441 10.91 1.08 15.72 2 2 2 150652 15.38 1.18 18.02 3 2 2 151441 10.94 1.09 15.97 2 2 2 150653 14.55 1.17 17.94 3 2 2 151442 10.49 1.08 15.66 2 2 2 150653 14.83 1.17 17.94 3 2 2 151442 10.40 1.08 15.82 2 2 2 150654 13.44 1.20 17.56 3 2 2 151443 10.35 1.08 15.68 2 2 2 150654 13.57 1.18 17.68 3 2 2 151443 10.47 1.09 15.96 2 2 2 150655 12.60 1.16 16.93 3 2 2 151444 10.16 1.11 16.18 2 2 2 150655 12.76 1.20 16.83 3 2 2 151444 10.23 1.08 15.95 2 2 2 150656 12.29 1.19 17.12 3 2 2 151445 10.27 1.09 16.04 2 2 2 150656 12.17 1.19 17.10 3 2 2 151445 10.35 1.11 16.28 2 2 2 150657 12.06 1.20 17.51 3 2 2 151446 10.63 1.10 16.09 2 2 2 150657 12.28 1.20 17.30 3 2 2 151446 10.63 1.11 16.16 2 2 2 150658 12.08 1.21 17.25 3 2 2 151447 10.37 1.11 16.16 2 2 2 150658 12.23 1.22 17.36 3 2 2 151447 10.57 1.11 16.30 2 2 2 150659 12.07 1.24 17.46 3 2 2 151448 10.72 1.14 16.66 2 2 2 150659 12.08 1.24 17.71 3 2 2 151448 10.93 1.16 16.65 2 2 2 150660 10.91 1.18 16.12 3 2 2 151449 9.99 1.14 15.97 2 2 2 150660 10.87 1.17 16.32 3 2 2 151449 10.09 1.15 15.96 2 2 2 150661 12.52 1.32 18.65 3 2 2 151450 11.24 1.23 16.76 2 2 2 150661 12.64 1.32 18.70 3 2 2 151450 11.25 1.22 16.47 2 2 2 150662 12.30 1.29 18.02 3 2 2 151451 8.39 1.07 13.05 2 2 2 150662 12.43 1.29 18.16 3 2 2 151451 8.55 1.08 13.20 2 2 2 150663 10.54 1.10 14.77 3 2 2 151452 0.67 0.30 0.00 2 2 2 150663 10.60 1.11 14.60 3 2 2 151452 0.73 0.30 0.00 2 2 2 150664 10.08 1.07 13.00 3 2 2 151453 18.43 1.11 15.29 2 2 2 150664 10.11 1.06 12.86 3 2 2 151453 18.54 1.11 15.30 2 2 2 150665 8.00 1.02 8.89 3 2 2 151454 15.25 1.07 14.65 2 2 2 150665 8.11 1.02 9.05 3 2 2 151454 15.28 1.07 14.81 2 2 2 150666 1.20 0.24 0.29 3 2 2 151455 14.44 1.07 14.98 2 2 2 150666 1.07 0.26 0.00 3 2 2 151455 14.47 1.08 14.87 2 2 2 150667 18.80 1.04 16.81 3 2 2 151456 13.48 1.10 15.14 2 2 2 150667 18.38 1.19 16.78 3 2 2 151456 13.47 1.09 14.98 2 2 2 150668 18.85 1.05 16.99 3 2 2 151457 13.24 1.11 14.86 2 2 2 150668 19.00 1.05 17.11 3 2 2 151457 13.29 1.11 15.21 2 2 2 150669 18.56 1.06 17.06 3 2 2 151458 12.86 1.11 15.34 2 2 2 150669 18.66 1.06 17.02 3 2 2 151458 13.02 1.10 15.43 2 2 2 150670 5 5 5 151459 12.61 1.11 15.51 2 2 2 150670 17.73 1.06 17.56 3 2 2 151459 12.62 1.12 15.43 2 2 2 150671 16.84 1.07 17.73 3 2 2 151460 11.62 1.11 15.47 2 2 2 150671 16.77 1.06 17.67 3 2 2 151460 11.62 1.11 15.60 2 2 2 150672 16.01 1.08 17.73 3 2 2 151461 11.40 1.12 15.89 2 2 2 150672 16.08 1.09 17.83 3 2 2 151461 11.45 1.11 15.78 2 2 2 150673 14.93 1.07 17.68 3 2 2 151462 10.31 1.12 15.60 2 2 2 150673 14.93 1.07 17.74 3 2 2 151462 10.44 1.12 15.52 2 2 2 150674 17.07 1.11 18.43 3 2 2 151463 10.49 1.12 15.67 2 2 2 150674 17.44 1.12 18.43 3 2 2 151463 10.41 1.11 15.54 2 2 2 150675 16.37 1.12 18.90 3 2 2 151464 10.92 1.15 16.05 2 2 2 150675 15.90 1.25 18.43 3 2 2 151464 11.02 1.15 15.99 2 2 2 150676 14.77 1.10 18.53 3 2 2 151465 10.27 1.14 15.93 2 2 2 150676 14.68 1.11 18.59 3 2 2 151465 10.31 1.15 16.07 2 2 2 150677 13.51 1.11 19.01 3 2 2 151466 10.47 1.16 16.12 2 2 2 150677 13.69 1.10 18.61 3 2 2 151466 10.47 1.16 16.13 2 2 2 150678 11.88 1.05 18.38 3 2 2 151467 10.46 1.16 16.17 2 2 2 150678 12.05 1.10 18.74 3 2 2 151467 10.47 1.16 16.37 2 2 2 150679 11.42 1.07 18.44 3 2 2 151468 10.84 1.20 17.17 2 2 2 150679 11.63 1.08 18.32 3 2 2 151468 10.95 1.20 17.21 2 2 2 150680 11.93 1.09 18.63 3 2 2 151469 11.08 1.21 17.72 2 2 2 150680 12.11 1.10 18.77 3 2 2 151469 11.23 1.25 17.86 2 2 2 150681 11.71 1.10 18.70 3 2 2 151470 11.87 1.28 17.95 2 2 2 150681 11.66 1.11 19.03 3 2 2 151470 11.93 1.29 18.19 2 2 2 150682 11.09 1.12 19.25 3 2 2 151471 10.67 1.22 16.58 2 2 2 150682 11.19 1.13 19.35 3 2 2 151471 10.52 1.21 16.26 2 2 2 150683 11.34 1.14 19.48 3 2 2 151472 0.82 0.27 0.00 2 2 2 150683 11.25 1.27 18.81 3 2 2 151472 0.85 0.26 0.00 2 2 2 150684 10.67 1.09 18.11 3 2 2 151473 15.52 1.06 14.59 2 2 2 150684 10.42 1.06 18.41 3 2 2 151473 15.62 1.06 14.77 2 2 2 150685 11.67 1.07 17.19 3 2 2 151474 15.30 1.07 14.63 2 2 2 150685 11.79 1.10 17.47 3 2 2 151474 15.59 1.08 14.86 2 2 2 150686 0.72 0.25 0.00 3 2 2 151475 15.04 1.08 14.93 2 2 2 150686 0.87 0.13 0.31 3 2 2 151475 14.98 1.08 14.85 2 2 2 150687 5 5 5 151476 19.21 1.16 15.89 2 2 2 150687 21.25 1.22 18.53 3 2 2 151476 19.29 1.15 15.84 2 2 2 150688 5 5 5 151477 16.14 1.15 15.92 2 2 2 150688 20.47 1.09 18.48 3 2 2 151477 16.18 1.14 15.62 2 2 2 150689 19.98 1.08 18.44 3 2 2 151478 15.62 1.16 16.03 2 2 2 150689 5 5 5 151478 15.72 1.14 16.14 2 2 2 150690 5 5 5 151479 13.65 1.12 16.16 2 2 2 150690 19.41 1.09 18.22 3 2 2 151479 13.85 1.14 16.07 2 2 2 150691 5 5 5 151480 12.82 1.15 16.15 2 2 2 150691 17.62 1.08 18.20 3 2 2 151480 12.95 1.16 16.03 2 2 2 150692 5 5 5 151481 12.21 1.15 15.93 2 2 2 150692 15.72 1.08 18.14 3 2 2 151481 12.21 1.16 16.10 2 2 2 150693 16.58 1.14 19.08 3 2 2 151482 11.26 1.15 15.88 2 2 2 150693 5 5 5 151482 11.42 1.16 15.93 2 2 2 150694 15.49 1.13 19.46 3 2 2 151483 11.34 1.16 16.13 2 2 2 150694 15.67 1.13 19.40 3 2 2 151483 11.34 1.16 16.13 2 2 2 150695 14.56 1.10 18.73 3 2 2 151484 11.12 1.16 16.46 2 2 2 150695 14.76 1.21 18.45 3 2 2 151484 11.13 1.16 16.07 2 2 2 150696 13.25 1.10 19.15 3 2 2 151485 11.38 1.17 16.66 2 2 2 150696 13.47 1.10 18.88 3 2 2 151485 11.46 1.17 16.74 2 2 2 150697 11.26 1.10 18.70 3 2 2 151486 11.58 1.20 17.03 2 2 2 150697 11.31 1.08 18.61 3 2 2 151486 11.70 1.20 17.06 2 2 2 150698 11.06 1.10 19.01 3 2 2 151487 11.59 1.21 17.42 2 2 2 150698 11.23 1.09 18.92 3 2 2 151487 11.58 1.20 17.35 2 2 2 150699 12.14 1.16 19.34 3 2 2 151488 11.96 1.24 17.76 2 2 2 150699 11.98 1.10 19.25 3 2 2 151488 11.96 1.26 17.72 2 2 2 150700 11.73 1.12 19.25 3 2 2 151489 12.13 1.31 17.78 2 2 2 150700 11.57 1.12 19.41 3 2 2 151489 12.23 1.31 17.92 2 2 2 150701 11.07 1.13 18.90 3 2 2 151490 11.91 1.34 18.24 2 2 2 150701 11.26 1.11 19.05 3 2 2 151490 12.01 1.33 18.34 2 2 2 150702 10.60 1.12 18.82 3 2 2 151491 4.89 0.85 9.07 2 2 2 150702 10.86 1.12 18.97 3 2 2 151491 4.81 0.85 9.23 2 2 2 150703 10.07 1.08 16.92 3 2 2 151492 0.79 0.18 0.00 2 2 2 150703 10.56 1.17 16.68 3 2 2 151492 0.72 0.18 0.00 2 2 2 150704 7.27 0.87 8.80 3 2 2 151493 20.76 1.14 15.70 2 2 2 150704 7.32 0.86 8.86 3 2 2 151493 20.78 1.14 15.45 2 2 2 150705 1.86 0.33 0.76 3 2 2 151494 22.50 1.18 15.81 2 2 2 150705 1.72 0.39 0.72 3 2 2 151494 22.57 1.18 15.71 2 2 2 150706 0.78 0.27 0.00 3 2 2 151495 21.98 1.18 16.13 2 2 2 150706 0.83 0.27 0.00 3 2 2 151495 22.01 1.16 15.90 2 2 2 150707 5 5 5 151496 21.19 1.17 16.06 2 2 2 150707 5 5 5 151496 21.42 1.18 16.16 2 2 2 150708 10.60 1.13 17.98 3 2 2 151497 12.01 1.18 16.22 2 2 2 150708 10.93 1.06 18.17 3 2 2 151497 11.98 1.16 16.10 2 2 2 150709 11.25 1.05 18.53 3 2 2 151498 16.48 1.17 15.66 2 2 2 150709 11.30 1.09 18.46 3 2 2 151498 16.53 1.19 15.57 2 2 2 150710 10.63 1.08 18.11 3 2 2 151499 14.00 1.16 15.59 2 2 2 150710 10.87 1.06 18.31 3 2 2 151499 13.72 1.15 15.63 2 2 2 150711 10.32 1.07 17.95 3 2 2 151500 14.24 1.18 16.05 2 2 2 150711 10.35 1.08 18.19 3 2 2 151500 13.98 1.19 16.16 2 2 2 150712 10.96 1.21 18.36 3 2 2 151501 12.43 1.16 15.88 2 2 2 150712 10.73 1.09 18.41 3 2 2 151501 12.74 1.18 16.26 2 2 2 150713 12.36 1.21 20.61 3 2 2 151502 12.77 1.16 16.30 2 2 2 150713 12.38 1.23 20.68 3 2 2 151502 12.95 1.18 16.37 2 2 2 150714 12.52 1.21 20.07 3 2 2 151503 12.09 1.16 15.86 2 2 2 150714 13.07 1.23 20.22 3 2 2 151503 12.16 1.16 15.68 2 2 2 150715 13.54 1.39 24.23 3 2 2 151504 10.85 1.15 15.53 2 2 2 150715 13.78 1.38 24.19 3 2 2 151504 10.95 1.15 15.62 2 2 2 150716 4.15 0.60 10.78 3 2 2 151505 11.48 1.19 15.86 2 2 2 150716 4.33 0.51 10.99 3 2 2 151505 11.32 1.16 15.73 2 2 2 150717 17.67 1.09 18.33 3 3 3 151506 11.50 1.25 16.81 2 2 2 150717 17.74 1.16 18.09 3 3 3 151506 11.56 1.24 16.72 2 2 2 150718 16.96 1.11 18.67 3 3 3 151507 12.14 1.23 17.54 2 2 2 150718 17.03 1.11 18.57 3 3 3 151507 11.92 1.23 17.45 2 2 2 150719 15.86 1.12 18.39 3 2 2 151508 12.29 1.25 17.64 2 2 2 150719 16.03 1.12 18.58 3 2 2 151508 12.31 1.23 17.72 2 2 2 150720 17.04 1.27 18.71 3 2 2 151509 13.83 1.42 19.37 2 2 2 150720 16.62 1.16 18.56 3 2 2 151509 13.99 1.41 19.09 2 2 2 150721 16.76 1.15 18.87 3 2 2 151510 12.13 1.35 17.99 2 2 2 150721 17.02 1.15 19.21 3 2 2 151510 12.28 1.37 18.37 2 2 2 150722 14.42 1.13 18.88 3 2 2 151511 5.58 0.86 11.09 2 2 2 150722 14.55 1.12 18.69 3 2 2 151511 5.63 0.87 10.99 2 2 2 150723 13.72 1.12 18.52 3 2 2 151512 0.68 0.17 0.00 2 2 2 150723 13.74 1.11 18.83 3 2 2 151512 0.73 0.17 0.00 2 2 2 150724 11.34 1.12 18.12 3 2 2 151513 21.09 1.18 15.43 2 2 2 150724 11.42 1.07 18.11 3 2 2 151513 21.46 1.19 15.90 2 2 2 150725 11.14 1.11 18.48 3 2 2 151514 22.58 1.21 16.08 2 2 2 150725 11.14 1.08 18.39 3 2 2 151514 23.06 1.21 16.44 2 2 2 150726 10.62 1.06 17.54 3 2 2 151515 21.87 1.21 16.31 2 2 2 150726 10.64 1.07 17.68 3 2 2 151515 22.05 1.20 16.19 2 2 2 150727 11.40 1.13 19.20 3 2 2 151516 16.87 1.15 15.35 2 2 2 150727 11.60 1.12 18.83 3 2 2 151516 17.08 1.16 15.54 2 2 2 150728 11.10 1.10 17.56 3 2 2 151517 16.50 1.17 15.85 2 2 2 150728 11.25 1.21 17.26 3 2 2 151517 16.65 1.21 15.76 2 2 2 150729 12.15 1.21 19.28 3 2 2 151518 15.93 1.18 15.38 2 2 2 150729 12.17 1.21 19.15 3 2 2 151518 15.98 1.20 15.38 2 2 2 150730 13.84 1.43 24.01 3 2 2 151519 13.78 1.10 17.07 2 2 2 150730 14.26 1.48 24.06 3 2 2 151519 13.81 1.11 17.13 2 2 2 150731 9.58 1.10 20.04 3 2 2 151520 13.29 1.12 17.34 2 2 2 150731 9.48 1.13 20.11 3 2 2 151520 13.35 1.12 17.40 2 2 2 150732 5.20 0.66 12.91 3 2 2 151521 12.57 1.13 17.41 2 2 2 150732 5.11 0.71 12.87 3 2 2 151521 12.40 1.12 17.45 2 2 2 150733 2.64 0.36 6.43 3 2 2 151522 11.69 1.13 17.38 2 2 2 150733 2.71 0.35 6.54 3 2 2 151522 11.72 1.11 17.49 2 2 2 150734 2.29 0.28 4.37 3 2 2 151523 11.27 1.15 17.64 2 2 2 150734 2.46 0.27 4.37 3 2 2 151523 11.28 1.14 17.62 2 2 2 150735 1.56 0.11 0.00 3 2 2 151524 11.20 1.16 17.78 2 2 2 150735 1.60 0.09 0.25 3 2 2 151524 11.35 1.17 17.97 2 2 2 150736 1.95 0.15 0.00 3 2 2 151525 11.47 1.19 18.79 2 2 2 150736 1.75 0.12 0.00 3 2 2 151525 11.55 1.20 18.82 2 2 2 150737 20.46 1.19 17.64 3 2 2 151526 11.88 1.23 19.49 2 2 2 150737 21.06 1.05 17.84 3 2 2 151526 11.91 1.25 19.64 2 2 2 150738 15.16 1.11 18.04 3 2 2 151527 12.59 1.26 20.09 2 2 2 150738 15.28 1.08 17.92 3 2 2 151527 12.63 1.30 20.37 2 2 2 150739 20.33 1.11 17.63 3 2 2 151528 12.78 1.38 21.92 2 2 2 150739 20.41 1.10 17.44 3 2 2 151528 12.75 1.37 21.78 2 2 2 150740 18.98 1.10 17.80 3 2 2 151529 10.00 1.20 17.90 2 2 2 150740 18.93 1.10 17.86 3 2 2 151529 10.17 1.20 17.96 2 2 2 150741 17.73 1.10 17.95 3 2 2 151530 7.41 1.02 14.94 2 2 2 150741 17.50 1.10 17.89 3 2 2 151530 7.48 1.02 15.09 2 2 2 150742 16.58 1.13 17.86 3 2 2 151531 5.36 0.83 12.32 2 2 2 150742 16.65 1.09 17.72 3 2 2 151531 5.45 0.83 12.45 2 2 2 150743 14.86 1.11 17.62 3 2 2 151532 0.53 0.23 0.40 2 2 2 150743 15.12 1.12 17.87 3 2 2 151532 0.56 0.23 0.62 2 2 2 150744 13.57 1.16 17.18 3 2 2 151533 26.45 1.19 18.82 2 2 2 150744 13.69 1.15 17.41 3 2 2 151533 26.62 1.21 18.89 2 2 2 150745 13.28 1.16 17.70 3 2 2 151534 25.55 1.20 18.58 2 2 2 150745 13.37 1.15 18.35 3 2 2 151534 26.05 1.21 18.74 2 2 2 150746 12.03 1.16 18.14 3 2 2 151535 25.50 1.17 18.27 2 2 2 150746 11.93 1.16 18.28 3 2 2 151535 25.51 1.20 18.51 2 2 2 150747 11.62 1.17 18.29 3 2 2 151536 23.66 1.19 18.37 2 2 2 150747 11.77 1.19 18.14 3 2 2 151536 23.52 1.18 17.98 2 2 2 150748 10.37 1.13 17.14 3 2 2 151537 13.71 1.16 18.77 2 2 2 150748 10.19 1.13 17.33 3 2 2 151537 13.82 1.17 18.61 2 2 2 150749 11.54 1.21 18.58 3 2 2 151538 21.67 1.17 18.35 2 2 2 150749 11.30 1.21 18.68 3 2 2 151538 21.87 1.17 18.38 2 2 2 150750 12.68 1.31 20.63 3 2 2 151539 19.32 1.16 18.12 2 2 2 150750 13.43 1.31 21.04 3 2 2 151539 19.49 1.17 18.12 2 2 2 150751 13.37 1.46 23.40 3 2 2 151540 17.43 1.16 18.09 2 2 2 150751 13.73 1.46 23.80 3 2 2 151540 17.29 1.17 17.98 2 2 2 150752 8.53 1.13 19.00 3 2 2 151541 15.83 1.15 17.87 2 2 2 150752 8.93 1.16 18.99 3 2 2 151541 15.99 1.16 18.01 2 2 2 150753 2.79 0.61 10.59 3 2 2 151542 14.23 1.16 17.72 2 2 2 150753 3.49 0.60 10.60 3 2 2 151542 14.86 1.15 17.90 2 2 2 150754 0.65 0.16 3.48 3 2 2 151543 13.40 1.11 18.28 2 2 2 150754 0.50 0.17 3.40 3 2 2 151543 13.47 1.13 18.16 2 2 2 150755 -0.13 0.11 2.07 4 2 2 151544 11.92 1.14 18.14 2 2 2 150755 0.00 0.11 2.11 3 2 2 151544 12.14 1.15 18.17 2 2 2 150756 -0.29 0.03 0.28 4 2 2 151545 11.46 1.15 18.20 2 2 2 150756 0.56 0.05 0.39 3 2 2 151545 11.58 1.15 18.14 2 2 2 150757 36.80 1.35 20.77 3 2 2 151546 11.24 1.15 18.15 2 2 2 150757 37.45 1.34 20.99 3 2 2 151546 11.26 1.16 18.41 2 2 2 150758 28.75 1.24 19.52 3 2 2 151547 11.07 1.15 18.61 2 2 2 150758 28.50 1.26 19.88 3 2 2 151547 11.20 1.16 18.46 2 2 2 150759 34.59 1.37 20.97 3 2 2 151548 11.32 1.16 19.98 2 2 2 150759 35.04 1.34 20.50 3 2 2 151548 11.35 1.19 19.26 2 2 2 150760 31.13 1.26 19.54 3 2 2 151549 11.47 1.25 19.98 2 2 2 150760 31.28 1.27 19.47 3 2 2 151549 11.66 1.26 20.03 2 2 2 150761 28.73 1.25 19.18 3 2 2 151550 12.89 1.39 21.86 2 2 2 150761 28.90 1.25 19.33 3 2 2 151550 13.02 1.39 22.06 2 2 2 150762 21.92 1.22 19.00 3 2 2 151551 5.79 0.88 14.72 2 2 2 150762 22.18 1.20 18.66 3 2 2 151551 5.80 0.88 14.72 2 2 2 150763 21.18 1.18 18.90 3 2 2 151552 0.65 0.22 0.00 2 2 2 150763 21.26 1.20 18.90 3 2 2 151552 0.58 0.22 0.00 2 2 2 150764 16.95 1.10 17.40 3 2 2 151553 23.35 1.17 18.31 2 2 2 150764 16.89 1.10 17.33 3 2 2 151553 23.36 1.17 18.53 2 2 2 150765 17.76 1.19 18.75 3 2 2 151554 18.79 1.15 17.81 2 2 2 150765 17.64 1.18 18.50 3 2 2 151554 18.96 1.17 17.76 2 2 2 150766 13.68 1.13 18.20 3 2 2 151555 22.25 1.20 18.21 2 2 2 150766 13.75 1.14 18.36 3 2 2 151555 22.34 1.21 18.31 2 2 2 150767 14.28 1.17 18.50 3 2 2 151556 19.55 1.17 17.73 2 2 2 150767 14.48 1.16 18.73 3 2 2 151556 19.53 1.16 17.61 2 2 2 150768 12.00 1.12 18.05 3 2 2 151557 12.02 1.16 18.04 2 2 2 150768 12.21 1.12 17.73 3 2 2 151557 11.85 1.18 18.24 2 2 2 150769 11.05 1.13 17.97 3 2 2 151558 17.53 1.18 17.88 2 2 2 150769 11.34 1.12 17.99 3 2 2 151558 17.75 1.18 18.19 2 2 2 150770 10.27 1.10 17.95 3 2 2 151559 15.65 1.13 17.66 2 2 2 150770 10.05 1.12 17.94 3 2 2 151559 15.80 1.15 17.97 2 2 2 150771 10.93 1.22 19.99 3 2 2 151560 12.71 1.11 17.19 2 2 2 150771 11.32 1.23 19.89 3 2 2 151560 12.78 1.12 17.29 2 2 2 150772 11.17 1.27 20.01 3 2 2 151561 12.93 1.15 17.82 2 2 2 150772 11.31 1.28 20.13 3 2 2 151561 13.01 1.15 17.85 2 2 2 150773 10.05 1.34 22.69 3 2 2 151562 12.25 1.15 18.14 2 2 2 150773 10.29 1.33 22.89 3 2 2 151562 11.99 1.15 17.65 2 2 2 150774 1.00 0.39 7.03 3 2 2 151563 11.57 1.17 18.39 2 2 2 150774 1.19 0.36 7.12 3 2 2 151563 11.65 1.16 18.17 2 2 2 150775 0.95 0.14 1.95 3 2 2 151564 11.22 1.18 18.33 2 2 2 150775 1.18 0.15 1.88 3 2 2 151564 11.21 1.17 18.45 2 2 2 150776 1.72 0.11 0.30 3 2 2 151565 11.10 1.18 18.46 2 2 2 150776 2.24 0.08 0.31 3 2 2 151565 11.06 1.18 18.41 2 2 2 150777 42.49 1.34 21.35 3 2 2 151566 11.35 1.23 19.14 2 2 2 150777 41.01 1.32 21.72 3 2 2 151566 11.43 1.21 19.01 2 2 2 150778 10.74 1.09 19.04 3 2 2 151567 11.33 1.24 19.39 2 2 2 150778 11.21 1.06 19.43 3 2 2 151567 11.38 1.24 19.52 2 2 2 150779 34.97 1.28 20.70 3 2 2 151568 12.18 1.31 20.63 2 2 2 150779 35.68 1.28 20.62 3 2 2 151568 12.59 1.31 20.69 2 2 2 150780 32.37 1.25 20.05 3 2 2 151569 13.95 1.44 22.84 2 2 2 150780 32.60 1.25 20.76 3 2 2 151569 13.99 1.45 22.87 2 2 2 150781 29.32 1.24 19.71 3 2 2 151570 6.65 0.97 15.59 2 2 2 150781 29.45 1.24 20.27 3 2 2 151570 6.50 0.96 15.35 2 2 2 150782 23.50 1.19 19.11 3 2 2 151571 4.42 0.74 11.92 2 2 2 150782 23.71 1.20 19.37 3 2 2 151571 4.52 0.75 11.99 2 2 2 150783 23.14 1.18 19.02 3 2 2 151572 0.82 0.09 0.00 2 2 2 150783 23.32 1.17 18.95 3 2 2 151572 0.85 0.09 0.00 2 2 2 150784 19.47 1.14 18.56 3 2 2 151573 30.37 1.29 19.48 2 2 2 150784 19.55 1.15 18.19 3 2 2 151573 31.11 1.29 19.50 2 2 2 150785 17.61 1.15 18.64 3 2 2 151574 25.48 1.21 18.55 2 2 2 150785 17.53 1.14 18.61 3 2 2 151574 25.12 1.22 18.55 2 2 2 150786 14.76 1.15 18.56 3 2 2 151575 23.33 1.20 17.86 2 2 2 150786 14.80 1.14 18.48 3 2 2 151575 23.43 1.19 17.76 2 2 2 150787 13.25 1.14 18.31 3 2 2 151576 22.38 1.20 17.92 2 2 2 150787 13.31 1.12 18.55 3 2 2 151576 22.43 1.20 17.77 2 2 2 150788 12.00 1.14 29.53 3 2 4 151577 20.23 1.22 17.99 2 2 2 150788 12.02 1.14 18.82 3 2 2 151577 20.47 1.21 18.01 2 2 2 150789 11.43 1.16 19.04 3 2 2 151578 18.59 1.20 18.07 2 2 2 150789 11.43 1.15 18.78 3 2 2 151578 18.92 1.21 17.97 2 2 2 150790 11.93 1.22 21.24 3 2 2 151579 16.29 1.19 17.73 2 2 2 150790 12.17 1.21 20.21 3 2 2 151579 16.34 1.18 17.67 2 2 2 150791 13.73 1.41 23.50 3 2 2 151580 13.76 1.16 17.13 2 2 2 150791 13.90 1.40 23.14 3 2 2 151580 13.69 1.14 16.96 2 2 2 150792 9.80 1.18 19.96 3 2 2 151581 13.77 1.21 17.73 2 2 2 150792 10.16 1.18 19.74 3 2 2 151581 13.68 1.18 17.87 2 2 2 150793 5.18 0.78 13.05 3 2 2 151582 12.08 1.17 17.36 2 2 2 150793 5.32 0.74 12.89 3 2 2 151582 12.17 1.18 17.35 2 2 2 150794 3.42 2.04 9.18 3 4 2 151583 11.49 1.17 17.95 2 2 2 150794 3.50 0.51 9.40 3 2 2 151583 11.49 1.15 17.58 2 2 2 150795 1.71 0.21 2.45 3 2 2 151584 11.67 1.18 18.09 2 2 2 150795 1.76 0.22 2.50 3 2 2 151584 11.73 1.19 17.90 2 2 2 150796 0.84 0.08 0.00 3 2 2 151585 11.74 1.21 18.34 2 2 2 150796 0.90 0.09 0.00 3 2 2 151585 11.68 1.21 18.23 2 2 2 150797 37.47 1.35 21.08 3 2 2 151586 11.27 1.22 18.61 2 2 2 150797 38.23 1.35 21.20 3 2 2 151586 11.29 1.21 18.64 2 2 2 150798 20.56 1.21 19.66 3 2 2 151587 10.90 1.26 19.17 2 2 2 150798 20.69 1.21 20.41 3 2 2 151587 11.01 1.27 19.71 2 2 2 150799 34.62 1.32 21.05 3 2 2 151588 11.92 1.39 21.56 2 2 2 150799 35.84 1.31 20.78 3 2 2 151588 12.13 1.38 21.75 2 2 2 150800 32.28 1.29 20.30 3 2 2 151589 5.94 0.89 13.73 2 2 2 150800 32.65 1.28 19.93 3 2 2 151589 5.91 0.92 13.85 2 2 2 150801 29.94 1.27 19.88 3 2 2 151590 2.46 0.42 6.17 2 2 2 150801 29.92 1.27 19.96 3 2 2 151590 2.45 0.42 6.28 2 2 2 150802 25.63 1.23 19.12 3 2 2 151591 1.85 0.30 4.82 2 2 2 150802 25.82 1.21 18.95 3 2 2 151591 1.87 0.32 4.84 2 2 2 150803 23.08 1.19 18.68 3 2 2 151592 0.73 0.07 0.00 2 2 2 150803 23.52 1.19 18.92 3 2 2 151592 0.76 0.06 0.00 2 2 2 150804 19.69 1.21 18.64 3 2 2 151593 28.66 1.24 18.50 2 2 2 150804 19.73 1.17 18.24 3 2 2 151593 29.12 1.26 18.52 2 2 2 150805 17.68 1.18 18.82 3 2 2 151594 30.48 1.27 18.77 2 2 2 150805 17.67 1.18 18.63 3 2 2 151594 30.56 1.26 18.70 2 2 2 150806 15.73 1.17 18.62 3 2 2 151595 25.04 1.23 17.86 2 2 2 150806 15.48 1.16 18.33 3 2 2 151595 24.85 1.21 17.87 2 2 2 150807 13.79 1.15 18.34 3 2 2 151596 22.56 1.20 17.80 2 2 2 150807 14.10 1.31 18.33 3 2 2 151596 23.06 1.20 18.00 2 2 2 150808 12.27 1.15 17.73 3 2 2 151597 18.38 1.18 17.76 2 2 2 150808 12.43 1.12 17.95 3 2 2 151597 18.26 1.18 17.69 2 2 2 150809 11.84 1.14 18.06 3 2 2 151598 17.18 1.18 17.76 2 2 2 150809 12.20 1.12 17.92 3 2 2 151598 16.82 1.18 17.57 2 2 2 150810 11.52 1.16 18.86 3 2 2 151599 15.15 1.16 17.47 2 2 2 150810 11.70 1.15 18.31 3 2 2 151599 15.44 1.16 17.40 2 2 2 150811 11.83 1.18 18.88 3 2 2 151600 14.29 1.19 17.73 2 2 2 150811 11.69 1.20 19.16 3 2 2 151600 14.64 1.18 17.79 2 2 2 150812 12.20 1.29 20.63 3 2 2 151601 12.24 1.15 17.32 2 2 2 150812 12.25 1.26 20.54 3 2 2 151601 12.49 1.14 17.47 2 2 2 150813 11.47 1.31 21.20 3 2 2 151602 11.68 1.16 17.55 2 2 2 150813 11.36 1.33 21.37 3 2 2 151602 11.87 1.16 17.74 2 2 2 150814 5.51 0.78 13.18 3 2 2 151603 11.57 1.16 17.65 2 2 2 150814 5.45 0.79 13.16 3 2 2 151603 11.57 1.16 17.62 2 2 2 150815 3.58 0.54 9.00 3 2 2 151604 11.06 1.18 17.93 2 2 2 150815 3.84 0.54 9.02 3 2 2 151604 11.24 1.17 17.90 2 2 2 150816 0.60 0.10 0.00 3 2 2 151605 11.19 1.20 18.51 2 2 2 150816 1.11 0.13 0.00 3 2 2 151605 11.28 1.21 18.55 2 2 2 150817 36.31 1.40 20.90 3 2 2 151606 12.05 1.27 19.31 2 2 2 150817 36.46 1.36 20.91 3 2 2 151606 12.21 1.28 19.30 2 2 2 150818 17.45 1.19 18.65 3 2 2 151607 11.80 1.27 20.08 2 2 2 150818 18.31 1.18 18.75 3 2 2 151607 11.68 1.27 19.66 2 2 2 150819 33.42 1.35 20.45 3 2 2 151608 12.32 1.36 21.46 2 2 2 150819 32.81 1.34 20.34 3 2 2 151608 12.34 1.36 21.80 2 2 2 150820 29.52 1.37 19.95 3 2 2 151609 2.19 0.36 5.38 2 2 2 150820 38.80 1.31 19.85 3 2 2 151609 2.21 0.37 5.31 2 2 2 150821 33.70 1.28 19.38 3 2 2 151610 2.16 0.35 5.33 2 2 2 150821 33.85 1.28 19.33 3 2 2 151610 2.17 0.34 5.30 2 2 2 150822 28.67 1.25 19.18 3 2 2 151611 1.62 0.22 3.42 2 2 2 150822 29.19 1.25 19.34 3 2 2 151611 1.64 0.22 3.46 2 2 2 150823 24.52 1.21 18.73 3 2 2 151612 0.81 0.07 0.00 2 2 2 150823 23.96 1.19 18.52 3 2 2 151612 0.88 0.08 0.00 2 2 2 150824 19.74 1.19 17.98 3 2 2 151613 30.18 1.24 19.09 2 2 2 150824 20.15 1.17 18.15 3 2 2 151613 30.07 1.28 19.47 2 2 2 150825 17.63 1.18 18.12 3 2 2 151614 30.54 1.28 19.39 2 2 2 150825 18.78 1.20 18.10 3 2 2 151614 30.00 1.29 19.58 2 2 2 150826 16.12 1.21 18.47 3 2 2 151615 28.00 1.25 18.91 2 2 2 150826 16.16 1.20 18.36 3 2 2 151615 28.09 1.27 18.82 2 2 2 150827 14.01 1.18 18.35 3 2 2 151616 27.69 1.27 18.79 2 2 2 150827 14.05 1.16 18.30 3 2 2 151616 27.75 1.26 18.77 2 2 2 150828 12.56 1.16 18.16 3 2 2 151617 23.39 17.72 2 4 2 150828 12.63 1.17 18.18 3 2 2 151617 23.58 18.17 2 4 2 150829 11.95 1.16 18.09 3 2 2 151618 22.21 18.24 2 4 2 150829 11.77 1.17 18.18 3 2 2 151618 22.39 18.34 2 4 2 150830 11.82 1.18 18.40 3 2 2 151619 18.63 18.04 2 4 2 150830 11.59 1.17 18.52 3 2 2 151619 18.23 18.03 2 4 2 150831 11.88 1.22 18.87 3 2 2 151620 15.71 17.97 2 4 2 150831 11.97 1.22 19.01 3 2 2 151620 15.83 17.81 2 4 2 150832 12.13 1.25 19.98 3 2 2 151621 11.57 1.21 17.11 2 2 2 150832 12.20 1.26 19.52 3 2 2 151621 11.84 1.20 17.07 2 2 2 150833 13.27 1.43 22.76 3 2 2 151622 11.32 1.19 17.26 2 2 2 150833 13.66 1.44 23.02 3 2 2 151622 11.44 1.19 17.15 2 2 2 150834 10.55 1.25 19.95 3 2 2 151623 11.38 1.19 17.41 2 2 2 150834 10.76 1.24 20.32 3 2 2 151623 11.58 1.18 17.26 2 2 2 150835 4.36 0.61 10.06 3 2 2 151624 11.51 1.21 17.63 2 2 2 150835 4.17 0.62 9.96 3 2 2 151624 11.72 1.22 17.83 2 2 2 150836 1.11 0.15 0.00 3 2 2 151625 11.42 1.21 17.90 2 2 2 150836 1.19 0.16 0.00 3 2 2 151625 11.44 1.19 17.79 2 2 2 150837 27.06 1.34 18.15 2 2 2 151626 11.63 1.23 18.28 2 2 2 150837 27.07 1.18 18.49 2 2 2 151626 11.38 1.23 18.23 2 2 2 150838 5 5 5 151627 11.52 1.27 19.05 2 2 2 150838 5 5 5 151627 11.62 1.28 18.98 2 2 2 150839 21.60 1.18 17.97 2 2 2 151628 12.70 1.36 20.40 2 2 2 150839 21.78 1.16 18.31 2 2 2 151628 12.72 1.36 20.49 2 2 2 150840 19.90 1.17 18.23 2 2 2 151629 11.71 1.35 20.90 2 2 2 150840 19.97 1.16 18.57 2 2 2 151629 11.82 1.35 20.93 2 2 2 150841 17.75 1.13 18.10 2 2 2 151630 4.40 0.72 10.56 2 2 2 150841 17.83 1.14 18.33 2 2 2 151630 4.46 0.73 10.64 2 2 2 150842 15.97 1.13 18.18 2 2 2 151631 2.05 0.33 4.76 2 2 2 150842 15.77 1.15 17.86 2 2 2 151631 2.07 0.34 4.82 2 2 2 150843 13.98 1.14 17.58 2 2 2 151632 1.03 0.08 0.00 2 2 2 150843 14.07 1.09 17.66 2 2 2 151632 1.10 0.09 0.00 2 2 2 150844 12.43 1.10 17.66 2 2 2 151633 30.22 1.25 18.34 2 2 2 150844 12.72 1.10 18.08 2 2 2 151633 30.42 1.27 18.65 2 2 2 150845 11.88 1.11 17.85 2 2 2 151634 24.82 1.20 17.63 2 2 2 150845 11.95 1.07 17.89 2 2 2 151634 24.55 1.21 17.73 2 2 2 150846 11.43 1.25 17.53 2 2 2 151635 22.74 1.23 17.72 2 2 2 150846 11.52 1.10 17.94 2 2 2 151635 23.06 1.23 17.72 2 2 2 150847 11.18 1.12 17.92 2 2 2 151636 22.65 1.22 17.68 2 2 2 150847 11.53 1.11 18.34 2 2 2 151636 22.67 1.23 17.84 2 2 2 150848 11.28 1.12 18.71 2 2 2 151637 19.83 1.21 17.55 2 2 2 150848 11.30 1.13 18.71 2 2 2 151637 20.22 1.21 17.54 2 2 2 150849 11.46 1.17 18.89 2 2 2 151638 19.12 1.20 17.32 2 2 2 150849 11.50 1.15 19.12 2 2 2 151638 19.49 1.20 17.43 2 2 2 150850 12.46 1.24 20.15 2 2 2 151639 18.00 1.21 17.23 2 2 2 150850 12.17 1.24 20.03 2 2 2 151639 17.79 1.20 17.25 2 2 2 150851 10.84 1.13 16.49 2 2 2 151640 15.36 1.22 17.09 2 2 2 150851 10.95 1.11 16.97 2 2 2 151640 15.67 1.20 17.01 2 2 2 150852 7.28 0.99 16.45 2 2 2 151641 14.79 1.16 17.22 2 2 2 150852 7.41 0.96 16.45 2 2 2 151641 14.84 1.18 17.32 2 2 2 150853 2.78 0.47 8.17 2 2 2 151642 13.13 1.18 17.17 2 2 2 150853 2.86 0.40 8.23 2 2 2 151642 13.45 1.17 17.28 2 2 2 150854 1.26 0.22 2.97 2 2 2 151643 11.60 1.17 17.03 2 2 2 150854 1.41 0.27 2.95 2 2 2 151643 11.67 1.18 17.16 2 2 2 150855 1.74 0.31 4.72 2 2 2 151644 11.46 1.18 17.05 2 2 2 150855 1.70 0.29 4.69 2 2 2 151644 11.60 1.20 17.14 2 2 2 150856 0.83 0.11 0.00 2 2 2 151645 11.39 1.19 17.46 2 2 2 150856 0.86 0.10 0.00 2 2 2 151645 11.26 1.19 17.34 2 2 2 150857 41.65 1.50 21.18 2 2 2 151646 11.41 1.24 18.40 2 2 2 150857 42.93 1.35 21.29 2 2 2 151646 11.27 1.24 18.68 2 2 2 150858 22.29 1.14 18.08 2 2 2 151647 11.58 1.24 18.54 2 2 2 150858 22.95 1.08 18.36 2 2 2 151647 11.76 1.23 18.66 2 2 2 150859 34.01 1.26 19.88 2 2 2 151648 12.02 1.30 19.35 2 2 2 150859 34.13 1.26 19.99 2 2 2 151648 12.25 1.31 19.41 2 2 2 150860 30.91 1.25 19.35 2 2 2 151649 10.36 1.29 19.85 2 2 2 150860 31.21 1.22 19.47 2 2 2 151649 10.57 1.26 20.00 2 2 2 150861 28.85 1.20 18.88 2 2 2 151650 6.82 1.01 15.60 2 2 2 150861 28.94 1.21 18.92 2 2 2 151650 6.74 1.01 15.35 2 2 2 150862 27.24 1.22 18.71 2 2 2 151651 2.24 0.37 4.94 2 2 2 150862 27.21 1.37 18.73 2 2 2 151651 2.32 0.38 5.05 2 2 2 150863 23.72 1.20 18.42 2 2 2 151652 0.92 0.06 0.00 2 2 2 150863 24.00 1.18 18.50 2 2 2 151652 0.95 0.08 0.00 2 2 2 150864 21.07 1.19 18.41 2 2 2 151653 29.63 1.24 18.04 2 2 2 150864 21.14 1.19 18.39 2 2 2 151653 29.65 1.22 18.36 2 2 2 150865 19.41 1.16 18.06 2 2 2 151654 29.32 1.22 18.30 2 2 2 150865 19.46 1.18 18.10 2 2 2 151654 29.30 1.22 18.19 2 2 2 150866 16.30 1.13 17.94 2 2 2 151655 23.05 1.15 17.14 2 2 2 150866 16.28 1.12 17.47 2 2 2 151655 22.87 1.14 17.23 2 2 2 150867 13.67 1.13 17.70 2 2 2 151656 22.47 1.15 17.45 2 2 2 150867 13.94 1.11 17.34 2 2 2 151656 22.59 1.16 17.87 2 2 2 150868 12.66 1.14 17.57 2 2 2 151657 15.79 1.13 17.57 2 2 2 150868 12.87 1.12 17.52 2 2 2 151657 15.82 1.13 17.61 2 2 2 150869 12.44 1.12 17.67 2 2 2 151658 16.71 1.11 17.17 2 2 2 150869 12.84 1.15 17.44 2 2 2 151658 16.81 1.11 17.18 2 2 2 150870 12.36 1.32 17.71 2 2 2 151659 14.94 1.11 17.11 2 2 2 150870 12.19 1.17 18.30 2 2 2 151659 15.03 1.09 16.95 2 2 2 150871 12.71 1.22 19.31 2 2 2 151660 13.43 1.12 17.23 2 2 2 150871 12.67 1.23 19.15 2 2 2 151660 13.39 1.11 17.31 2 2 2 150872 14.12 1.35 21.37 2 2 2 151661 12.11 1.11 17.15 2 2 2 150872 14.23 1.36 21.25 2 2 2 151661 12.20 1.11 17.34 2 2 2 150873 12.73 1.35 22.29 2 2 2 151662 12.04 1.12 17.56 2 2 2 150873 12.75 1.36 22.25 2 2 2 151662 11.99 1.12 17.72 2 2 2 150874 4.17 0.61 9.65 2 2 2 151663 5 5 5 150874 4.31 0.49 9.68 2 2 2 151663 5 5 5 150875 1.79 0.22 2.32 2 2 2 151664 11.89 1.16 18.57 2 2 2 150875 1.88 0.17 2.41 2 2 2 151664 12.11 1.16 18.53 2 2 2 150876 1.71 0.14 0.00 2 2 2 151665 12.09 1.19 19.01 2 2 2 150876 1.70 0.15 0.00 2 2 2 151665 12.10 1.19 19.03 2 2 2 150877 41.68 1.40 20.95 2 2 2 151666 11.55 1.18 19.17 2 2 2 150877 42.08 1.40 20.77 2 2 2 151666 11.60 1.17 19.04 2 2 2 150878 38.45 1.38 20.27 2 2 2 151667 10.05 1.17 18.68 2 2 2 150878 38.34 1.38 20.30 2 2 2 151667 10.08 1.14 18.83 2 2 2 150879 5 5 5 151668 7.29 0.95 15.33 2 2 2 150879 5 5 5 151668 7.21 0.94 15.36 2 2 2 150880 31.85 1.33 19.29 2 2 2 151669 3.56 0.53 8.60 2 2 2 150880 32.04 1.32 19.07 2 2 2 151669 3.62 0.53 8.76 2 2 2 150881 28.83 1.29 18.87 2 2 2 151670 2.44 0.37 6.24 2 2 2 150881 29.20 1.30 18.53 2 2 2 151670 2.49 0.40 6.25 2 2 2 150882 25.03 1.25 18.57 2 2 2 151671 1.88 0.27 4.52 2 2 2 150882 25.11 1.26 18.61 2 2 2 151671 1.88 0.27 4.56 2 2 2 150883 20.55 1.25 17.84 2 2 2 151672 0.87 0.06 0.00 2 2 2 150883 20.62 1.22 18.01 2 2 2 151672 0.89 0.06 0.00 2 2 2 150884 17.88 1.22 17.61 2 2 2 151673 26.92 1.18 17.87 2 2 2 150884 17.59 1.22 17.68 2 2 2 151673 27.24 1.17 17.85 2 2 2 150885 15.66 1.18 17.33 2 2 2 151674 25.90 1.17 18.07 2 2 2 150885 15.82 1.18 17.62 2 2 2 151674 26.30 1.17 18.20 2 2 2 150886 14.60 1.18 17.33 2 2 2 151675 24.25 1.16 17.92 2 2 2 150886 14.66 1.20 17.53 2 2 2 151675 24.15 1.16 17.65 2 2 2 150887 13.91 1.21 18.05 2 2 2 151676 24.53 1.17 17.85 2 2 2 150887 13.94 1.21 17.72 2 2 2 151676 24.53 1.17 17.99 2 2 2 150888 11.63 1.19 17.50 2 2 3 151677 20.45 1.16 17.46 2 2 2 150888 11.69 1.19 16.79 2 2 3 151677 20.55 1.16 17.55 2 2 2 150889 11.42 1.19 17.80 2 2 2 151678 19.75 1.14 16.76 2 2 2 150889 11.45 1.19 17.94 2 2 2 151678 19.81 1.14 16.85 2 2 2 150890 5 5 5 151679 16.85 1.11 16.50 2 2 2 150890 5 5 5 151679 16.96 1.13 16.79 2 2 2 150891 12.24 1.30 19.49 2 2 2 151680 14.87 1.11 16.81 2 2 2 150891 12.20 1.31 19.29 2 2 2 151680 14.89 1.11 16.82 2 2 2 150892 10.81 1.36 20.67 2 2 2 151681 13.82 1.11 17.08 2 2 2 150892 10.94 1.35 20.70 2 2 2 151681 13.87 1.12 17.14 2 2 2 150893 1.64 0.30 3.96 2 2 2 151682 14.07 1.13 17.27 2 2 2 150893 1.88 0.29 3.85 2 2 2 151682 14.11 1.13 17.36 2 2 2 150894 1.42 0.27 3.85 2 2 2 151683 12.64 1.12 17.12 2 2 2 150894 1.48 0.28 3.91 2 2 2 151683 12.60 1.12 17.26 2 2 2 150895 1.45 0.26 3.18 2 2 2 151684 11.86 1.16 17.28 2 2 2 150895 1.55 0.27 3.08 2 2 2 151684 11.96 1.14 17.46 2 2 2 150896 0.72 0.08 0.00 3 2 2 151685 11.53 1.15 17.48 2 2 2 150896 0.80 0.10 0.00 3 2 2 151685 11.57 1.14 17.37 2 2 2 150897 35.29 1.34 19.89 2 2 2 151686 11.34 1.15 17.39 2 2 2 150897 36.31 1.36 20.10 2 2 2 151686 11.35 1.16 17.37 2 2 2 150898 33.45 1.37 20.04 2 2 2 151687 11.58 1.19 17.82 2 2 2 150898 36.19 1.38 20.08 2 2 2 151687 11.56 1.19 17.89 2 2 2 150899 34.57 1.36 19.59 2 2 2 151688 12.41 1.25 18.96 2 2 2 150899 34.51 1.36 19.58 2 2 2 151688 12.26 1.26 18.93 2 2 2 150900 33.29 1.35 19.85 2 2 2 151689 13.98 1.46 22.52 2 2 2 150900 33.38 1.34 20.01 2 2 2 151689 14.10 1.47 22.89 2 2 2 150901 30.34 1.34 19.13 2 2 2 151690 12.11 1.36 20.76 2 2 2 150901 30.35 1.32 19.34 2 2 2 151690 12.19 1.35 20.95 2 2 2 150902 13.08 1.26 18.68 2 2 2 151691 3.03 0.47 7.23 2 2 2 150902 13.34 1.27 18.72 2 2 2 151691 3.05 0.46 7.25 2 2 2 150903 22.58 1.24 18.34 2 2 2 151692 1.79 0.24 3.92 2 2 2 150903 21.97 1.22 18.09 2 2 2 151692 1.83 0.24 3.91 2 2 2 150904 20.25 1.27 18.37 2 2 2 151693 23.39 1.18 17.21 2 2 2 150904 20.02 1.27 18.39 2 2 2 151693 23.28 1.20 17.19 2 2 2 150905 17.89 1.26 18.09 2 2 2 151694 21.64 1.14 16.89 2 2 2 150905 18.17 1.26 18.40 2 2 2 151694 21.65 1.14 16.83 2 2 2 150906 16.64 1.25 18.49 2 2 2 151695 22.26 1.16 17.35 2 2 2 150906 16.77 1.26 18.22 2 2 2 151695 22.22 1.17 17.31 2 2 2 150907 14.34 1.23 18.45 2 2 2 151696 21.83 1.17 17.32 2 2 2 150907 14.64 1.23 18.39 2 2 2 151696 21.82 1.16 17.31 2 2 2 150908 12.80 1.25 18.09 2 2 2 151697 18.92 1.15 17.09 2 2 2 150908 12.93 1.24 18.40 2 2 2 151697 18.95 1.17 17.14 2 2 2 150909 12.35 1.26 18.71 2 2 2 151698 16.30 1.15 16.87 2 2 2 150909 11.13 1.26 18.62 2 2 2 151698 16.31 1.14 16.78 2 2 2 150910 11.90 1.27 18.59 2 2 2 151699 15.73 1.14 17.15 2 2 2 150910 12.06 1.29 18.50 2 2 2 151699 15.75 1.17 17.15 2 2 2 150911 12.33 1.29 19.31 2 2 2 151700 13.77 1.17 17.10 2 2 2 150911 12.26 1.27 18.90 2 2 2 151700 13.84 1.18 17.07 2 2 2 150912 12.75 1.39 21.01 2 2 2 151701 12.04 1.15 17.02 2 2 2 150912 12.74 1.39 21.04 2 2 2 151701 12.03 1.15 17.10 2 2 2 150913 6.29 0.97 14.37 2 2 2 151702 11.42 1.16 16.93 2 2 2 150913 6.39 0.98 14.17 2 2 2 151702 11.50 1.17 17.03 2 2 2 150914 2.50 0.45 6.45 2 2 2 151703 11.53 1.18 17.38 2 2 2 150914 2.58 0.47 6.54 2 2 2 151703 11.63 1.19 17.52 2 2 2 150915 1.53 0.24 3.33 2 2 2 151704 10.95 1.19 17.27 2 2 2 150915 1.56 0.25 3.41 2 2 2 151704 11.12 1.19 17.40 2 2 2 150916 1.01 0.07 0.00 2 2 2 151705 11.85 1.23 18.34 2 2 2 150916 1.07 0.09 0.00 2 2 2 151705 11.67 1.23 18.26 2 2 2 150917 35.54 1.34 19.71 2 2 2 151706 12.23 1.27 18.71 2 2 2 150917 35.41 1.33 19.52 2 2 2 151706 12.38 1.25 18.94 2 2 2 150918 36.06 1.37 20.13 2 2 2 151707 13.54 1.37 20.64 2 2 2 150918 36.24 1.38 19.88 2 2 2 151707 13.59 1.37 20.43 2 2 2 150919 32.14 1.34 19.01 2 2 2 151708 10.66 1.26 19.07 2 2 2 150919 32.28 1.33 19.06 2 2 2 151708 10.70 1.26 19.24 2 2 2 150920 31.76 1.34 18.90 2 2 2 151709 8.71 1.15 17.39 2 2 2 150920 32.51 1.35 19.08 2 2 2 151709 8.72 1.13 17.29 2 2 2 150921 25.06 1.31 18.62 2 2 2 151710 4.43 0.71 10.49 2 2 2 150921 24.93 1.31 18.64 2 2 2 151710 4.44 0.70 10.62 2 2 2 150922 26.06 1.30 18.39 2 2 2 151711 2.37 0.36 4.50 2 2 2 150922 26.07 1.31 18.68 2 2 2 151711 2.20 0.36 4.43 2 2 2 150923 21.86 1.27 17.85 2 2 2 151712 0.99 0.06 0.00 2 2 2 150923 21.90 1.27 17.81 2 2 2 151712 0.98 0.06 0.00 2 2 2 150924 19.75 1.29 18.20 2 2 2 151713 20.89 1.15 16.61 2 2 2 150924 20.18 1.30 18.23 2 2 2 151713 21.09 1.15 16.95 2 2 2 150925 17.68 1.25 17.81 2 2 2 151714 21.19 1.16 16.96 2 2 2 150925 17.84 1.25 17.70 2 2 2 151714 21.28 1.17 17.22 2 2 2 150926 14.48 1.21 17.24 2 2 2 151715 20.29 1.21 17.17 2 2 2 150926 14.50 1.20 17.29 2 2 2 151715 20.31 1.17 17.21 2 2 2 150927 16.86 1.27 17.96 2 2 2 151716 20.58 1.20 17.48 2 2 2 150927 16.80 1.24 17.72 2 2 2 151716 20.43 1.19 17.32 2 2 2 150928 14.43 1.25 17.62 2 2 2 151717 18.62 1.18 17.11 2 2 2 150928 14.06 1.25 17.62 2 2 2 151717 18.71 1.19 17.20 2 2 2 150929 12.82 1.24 17.63 2 2 2 151718 16.39 1.12 16.71 2 2 2 150929 12.84 1.25 17.94 2 2 2 151718 16.56 1.14 16.64 2 2 2 150930 12.04 1.29 18.68 2 2 2 151719 14.89 1.12 16.91 2 2 2 150930 12.10 1.30 18.91 2 2 2 151719 15.02 1.15 17.33 2 2 2 150931 12.73 1.34 19.27 2 2 2 151720 13.55 1.12 17.13 2 2 2 150931 12.76 1.34 19.50 2 2 2 151720 13.48 1.12 17.06 2 2 2 150932 13.51 1.48 22.31 2 2 2 151721 12.62 1.11 17.11 2 2 2 150932 13.46 1.48 22.07 2 2 2 151721 12.46 1.12 17.32 2 2 2 150933 2.85 0.51 6.68 2 2 2 151723 11.24 1.12 17.40 2 2 2 150933 3.00 0.50 6.84 2 2 2 151723 11.37 1.13 17.52 2 2 2 150934 1.95 0.29 4.03 2 2 2 151724 11.18 1.13 17.85 2 2 2 150934 1.96 0.30 4.01 2 2 2 151724 11.27 1.15 17.98 2 2 2 150935 1.97 0.27 3.56 2 2 2 151725 11.71 1.16 18.63 2 2 2 150935 2.13 0.29 3.53 2 2 2 151725 11.72 1.17 18.62 2 2 2 150936 1.46 0.07 0.00 2 2 2 151726 11.90 1.23 19.50 2 2 2 150936 1.36 0.08 0.00 2 2 2 151726 12.02 1.25 19.32 2 2 2 150937 37.76 1.36 19.89 2 2 2 151727 12.65 1.24 19.99 2 2 2 150937 37.40 1.37 19.86 2 2 2 151727 12.22 1.24 19.83 2 2 2 150938 35.49 1.37 19.70 2 2 2 151728 13.45 1.38 22.92 2 2 2 150938 36.18 1.37 19.81 2 2 2 151728 13.53 1.38 23.26 2 2 2 150939 34.84 1.35 19.36 2 2 2 151729 7.94 1.00 17.06 2 2 2 150939 34.95 1.34 19.63 2 2 2 151729 7.80 1.00 16.86 2 2 2 150940 31.12 1.32 19.18 2 2 2 151730 5.04 0.73 12.05 2 2 2 150940 31.45 1.31 19.28 2 2 2 151730 4.97 0.72 12.17 2 2 2 150941 27.50 1.29 18.75 2 2 2 151731 0.99 0.07 0.00 2 2 2 150941 28.02 1.27 18.80 2 2 2 151731 1.07 0.06 0.28 2 2 2 150942 24.51 1.26 18.16 2 2 2 151732 0.05 0.00 4 2 2 150942 24.46 1.27 18.06 2 2 2 151732 1.09 0.04 0.00 2 2 2 150943 22.84 1.25 17.98 2 2 2 151733 24.79 1.14 17.99 2 2 2 150943 23.21 1.24 18.44 2 2 2 151733 24.87 1.12 18.02 2 2 2 150944 19.15 1.23 17.98 2 2 2 151734 24.63 1.16 18.22 2 2 2 150944 18.80 1.25 18.18 2 2 2 151734 24.83 1.15 17.99 2 2 2 150945 17.86 1.23 17.87 2 2 2 151735 21.62 1.14 17.60 2 2 2 150945 17.79 1.21 17.68 2 2 2 151735 21.42 1.12 17.05 2 2 2 150946 5 5 5 151736 22.45 1.15 18.21 2 2 2 150946 5 5 5 151736 22.79 1.14 17.94 2 2 2 150947 14.12 1.21 17.65 2 2 2 151737 16.20 1.12 17.71 2 2 2 150947 14.26 1.22 17.98 2 2 2 151737 16.31 1.14 17.62 2 2 2 150948 13.63 1.20 17.60 2 2 2 151738 18.76 1.13 17.33 2 2 2 150948 13.70 1.22 18.05 2 2 2 151738 19.08 1.14 17.28 2 2 2 150949 12.01 1.21 18.10 2 2 2 151739 15.79 1.11 16.98 2 2 2 150949 12.10 1.20 18.13 2 2 2 151739 15.58 1.11 16.69 2 2 2 150950 12.37 1.22 18.14 2 2 2 151740 14.41 1.11 16.97 2 2 2 150950 11.79 1.23 18.27 2 2 2 151740 14.61 1.15 17.47 2 2 2 150951 12.43 1.24 18.49 2 2 2 151741 13.23 1.10 17.41 2 2 2 150951 12.53 1.25 18.44 2 2 2 151741 13.28 1.12 17.78 2 2 2 150952 11.81 1.29 19.22 2 2 2 151742 11.69 1.11 17.20 2 2 2 150952 11.87 1.30 19.22 2 2 2 151742 11.85 1.11 17.31 2 2 2 150953 5.64 0.93 13.95 2 2 2 151743 11.08 1.11 17.42 2 2 2 150953 5.78 0.93 14.40 2 2 2 151743 11.19 1.10 17.46 2 2 2 150954 2.59 0.48 6.60 2 2 2 151744 11.30 1.13 17.56 2 2 2 150954 2.50 0.46 6.66 2 2 2 151744 11.31 1.13 17.70 2 2 2 150955 1.20 0.21 2.85 2 2 2 151745 11.87 1.22 18.97 2 2 2 150955 1.24 0.22 2.91 2 2 2 151745 11.80 1.22 18.92 2 2 2 150956 0.78 0.08 0.00 2 2 2 151746 12.45 1.27 20.20 2 2 2 150956 0.86 0.09 0.00 2 2 2 151746 12.38 1.25 19.79 2 2 2 150957 37.67 1.33 20.18 2 2 2 151747 12.38 1.32 21.56 2 2 2 150957 38.42 1.34 20.25 2 2 2 151747 12.54 1.32 21.30 2 2 2 150958 36.32 1.34 19.92 2 2 2 151748 11.40 1.31 21.21 2 2 2 150958 36.98 1.36 20.30 2 2 2 151748 11.62 1.32 20.90 2 2 2 150959 33.51 1.36 20.13 2 2 2 151749 5.64 0.83 13.61 2 2 2 150959 33.81 1.36 20.19 2 2 2 151749 5.82 0.84 13.69 2 2 2 150960 34.36 1.33 19.40 2 2 2 151750 2.52 0.44 7.17 2 2 2 150960 34.10 1.33 19.57 2 2 2 151750 2.55 0.44 7.03 2 2 2 150961 23.26 1.26 18.61 2 2 2 151751 0.73 0.15 1.42 2 2 2 150961 22.86 1.28 18.50 2 2 2 151751 0.72 0.11 1.41 2 2 2 150962 23.58 1.20 16.94 2 2 2 151752 0.04 0.00 4 2 2 150962 23.62 1.23 17.78 2 2 2 151752 0.87 0.00 0.00 2 2 2 150963 19.64 1.24 18.11 2 2 2 151753 23.19 1.14 17.18 2 2 2 150963 19.66 1.24 18.04 2 2 2 151753 23.69 1.15 17.20 2 2 2 150964 17.71 1.24 17.84 2 2 2 151754 23.04 1.14 17.29 2 2 2 150964 17.74 1.22 17.79 2 2 2 151754 23.38 1.19 17.75 2 2 2 150965 14.42 1.22 17.54 2 2 2 151755 21.96 1.16 17.44 2 2 2 150965 14.64 1.21 17.56 2 2 2 151755 22.38 1.17 17.76 2 2 2 150966 12.96 1.21 17.57 2 2 2 151756 21.31 1.16 17.47 2 2 2 150966 12.87 1.21 17.62 2 2 2 151756 21.32 1.16 17.53 2 2 2 150967 12.14 1.27 18.29 2 2 2 151757 11.80 1.20 18.43 2 2 2 150967 12.20 1.26 18.10 2 2 2 151757 12.21 1.21 18.71 2 2 2 150968 11.57 1.27 18.55 2 2 2 151758 18.13 1.16 17.08 2 2 2 150968 11.67 1.24 18.44 2 2 2 151758 18.05 1.16 17.13 2 2 2 150969 11.66 1.28 19.29 2 2 2 151759 17.95 1.16 17.34 2 2 2 150969 11.95 1.31 19.25 2 2 2 151759 18.02 1.16 17.50 2 2 2 150970 12.76 1.32 20.55 2 2 2 151760 14.89 1.15 17.36 2 2 2 150970 12.80 1.36 20.92 2 2 2 151760 14.91 1.13 17.23 2 2 2 150971 10.42 1.31 19.77 2 2 2 151761 14.19 1.14 17.27 2 2 2 150971 10.50 1.30 20.03 2 2 2 151761 14.43 1.17 17.50 2 2 2 150972 5.40 0.85 13.08 2 2 2 151762 13.19 1.16 17.73 2 2 2 150972 5.47 0.87 13.08 2 2 2 151762 13.23 1.16 17.42 2 2 2 150973 2.59 0.43 6.68 2 2 2 151763 11.33 1.15 17.39 2 2 2 150973 2.58 0.45 6.67 2 2 2 151763 11.67 1.15 17.53 2 2 2 150974 1.62 0.22 3.40 2 2 2 151764 10.90 1.16 17.60 2 2 2 150974 1.62 0.24 3.44 2 2 2 151764 11.01 1.16 17.50 2 2 2 150975 1.36 0.15 2.34 2 2 2 151765 11.12 1.16 17.72 2 2 2 150975 1.36 0.15 2.37 2 2 2 151765 11.23 1.18 17.79 2 2 2 150976 1.06 0.06 0.00 2 2 2 151766 11.41 1.20 18.21 2 2 2 150976 1.07 0.08 0.00 2 2 2 151766 11.31 1.19 17.97 2 2 2 150977 34.96 1.31 20.05 2 2 2 151767 11.32 1.20 18.58 2 2 2 150977 35.88 1.36 19.80 2 2 2 151767 11.72 1.21 18.70 2 2 2 150978 35.37 1.33 19.92 2 2 2 151768 11.74 1.28 19.72 2 2 2 150978 35.38 1.34 19.67 2 2 2 151768 11.75 1.27 19.81 2 2 2 150979 33.04 1.34 19.55 2 2 2 151769 12.62 1.39 21.21 2 2 2 150979 33.22 1.34 19.45 2 2 2 151769 13.16 1.40 21.50 2 2 2 150980 30.80 1.33 19.11 2 2 2 151770 7.07 0.98 15.35 2 2 2 150980 30.97 1.31 18.98 2 2 2 151770 7.10 0.98 15.44 2 2 2 150981 27.34 1.30 18.71 2 2 2 151771 3.00 0.51 8.29 2 2 2 150981 27.15 1.30 18.57 2 2 2 151771 2.94 0.50 8.14 2 2 2 150982 25.04 1.28 18.37 2 2 2 151772 0.63 0.05 0.00 2 2 2 150982 25.23 1.27 18.75 2 2 2 151772 0.68 0.04 0.00 2 2 2 150983 21.99 1.27 18.28 2 2 2 151773 19.81 1.16 16.90 2 2 2 150983 21.99 1.26 18.46 2 2 2 151773 20.24 1.13 16.76 2 2 2 150984 21.44 1.28 19.04 2 2 2 151774 23.05 1.17 17.41 2 2 2 150984 21.53 1.28 18.84 2 2 2 151774 23.26 1.17 17.48 2 2 2 150985 19.68 1.29 18.77 2 2 2 151775 22.36 1.16 17.29 2 2 2 150985 19.78 1.27 18.49 2 2 2 151775 23.06 1.18 17.38 2 2 2 150986 15.66 1.22 17.76 2 2 2 151776 20.83 1.16 17.41 2 2 2 150986 15.55 1.23 18.07 2 2 2 151776 21.52 1.19 17.43 2 2 2 150987 13.80 1.23 17.86 2 2 2 151777 11.62 1.18 17.53 2 2 2 150987 13.88 1.24 18.03 2 2 2 151777 11.58 1.17 17.53 2 2 2 150988 12.63 1.23 17.90 2 2 2 151778 17.89 1.16 17.48 2 2 2 150988 12.66 1.25 17.90 2 2 2 151778 17.68 1.16 17.41 2 2 2 150989 11.99 1.26 17.94 2 2 2 151779 15.85 1.16 17.17 2 2 2 150989 12.09 1.24 18.20 2 2 2 151779 16.04 1.16 17.48 2 2 2 150990 12.11 1.30 18.80 2 2 2 151780 14.19 1.15 17.28 2 2 2 150990 12.11 1.30 18.91 2 2 2 151780 14.19 1.16 17.47 2 2 2 150991 12.45 1.34 19.44 2 2 2 151781 13.96 1.18 17.54 2 2 2 150991 12.65 1.34 19.80 2 2 2 151781 14.13 1.17 17.26 2 2 2 150992 12.70 1.37 20.47 2 2 2 151782 12.72 1.16 17.20 2 2 2 150992 12.67 1.39 20.53 2 2 2 151782 12.50 1.16 17.16 2 2 2 150993 1.92 0.26 3.13 2 2 2 151783 11.21 1.14 17.20 2 2 2 150993 1.69 0.24 3.00 2 2 2 151783 11.38 1.12 17.01 2 2 2 150994 4.71 0.73 10.56 2 2 2 151784 10.96 1.15 17.40 2 2 2 150994 4.94 0.71 10.40 2 2 2 151784 11.16 1.17 17.29 2 2 2 150995 1.77 0.22 2.86 2 2 2 151785 11.57 1.19 17.69 2 2 2 150995 1.90 0.24 2.96 2 2 2 151785 11.59 1.19 17.61 2 2 2 150996 1.38 0.07 0.00 2 2 2 151786 11.22 1.18 17.31 2 2 2 150996 1.43 0.08 0.00 2 2 2 151786 10.91 1.18 17.45 2 2 2 150997 35.58 1.35 20.19 2 2 2 151787 11.58 1.22 18.83 2 2 2 150997 35.57 1.41 19.76 2 2 2 151787 11.37 1.23 18.64 2 2 2 150998 34.92 1.33 19.78 2 2 2 151788 13.19 1.38 21.45 2 2 2 150998 34.93 1.36 19.74 2 2 2 151788 13.31 1.39 21.73 2 2 2 150999 32.76 1.30 19.83 2 2 2 151789 11.10 1.36 20.98 2 2 2 150999 33.60 1.31 19.92 2 2 2 151789 11.39 1.37 21.22 2 2 2 151000 31.64 1.27 19.50 2 2 2 151790 7.38 1.03 16.06 2 2 2 151000 31.85 1.28 19.63 2 2 2 151790 7.39 1.03 15.85 2 2 2 151001 23.64 1.24 18.91 2 2 2 151791 2.71 0.46 7.19 2 2 2 151001 23.09 1.24 18.82 2 2 2 151791 2.78 0.48 7.20 2 2 2 151002 22.55 1.22 18.40 2 2 2 151792 0.86 0.09 0.00 2 2 2 151002 22.32 1.22 18.54 2 2 2 151792 0.85 0.09 0.00 2 2 2 151003 21.46 1.26 18.80 2 2 2 151793 19.96 1.16 16.67 2 2 2 151003 21.58 1.26 18.52 2 2 2 151793 20.13 1.12 16.72 2 2 2 151004 18.07 1.23 18.35 2 2 2 151794 22.36 1.17 17.44 2 2 2 151004 18.32 1.23 18.38 2 2 2 151794 22.02 1.17 17.30 2 2 2 151005 16.84 1.25 18.31 2 2 2 151795 20.99 1.16 17.06 2 2 2 151005 16.87 1.19 18.39 2 2 2 151795 20.96 1.16 17.14 2 2 2 151006 13.57 1.18 18.14 2 2 2 151796 20.56 1.16 17.10 2 2 2 151006 13.78 1.16 18.57 2 2 2 151796 20.71 1.17 17.06 2 2 2 151007 12.33 1.17 18.25 2 2 2 151797 12.35 1.15 17.23 2 2 2 151007 12.16 1.24 18.23 2 2 2 151797 12.57 1.18 17.29 2 2 2 151008 11.72 1.17 18.49 2 2 2 151798 16.65 1.15 16.82 2 2 2 151008 11.85 1.17 18.48 2 2 2 151798 16.83 1.16 17.11 2 2 2 151009 10.51 1.13 17.79 2 2 2 151799 14.26 1.14 16.57 2 2 2 151009 10.46 1.15 17.70 2 2 2 151799 14.49 1.13 16.98 2 2 2 151010 11.31 1.21 19.02 2 2 2 151800 13.00 1.15 16.92 2 2 2 151010 11.14 1.21 19.09 2 2 2 151800 12.91 1.23 17.11 2 2 2 151011 12.37 1.31 20.75 2 2 2 151801 11.80 1.15 17.36 2 2 2 151011 12.69 1.29 21.04 2 2 2 151801 11.86 1.15 17.36 2 2 2 151012 10.05 1.21 20.14 2 2 2 151802 11.13 1.16 17.55 2 2 2 151012 10.16 1.23 20.27 2 2 2 151802 11.29 1.17 17.45 2 2 2 151013 3.55 0.57 9.27 2 2 2 151803 10.94 1.17 17.98 2 2 2 151013 3.64 0.63 9.39 2 2 2 151803 11.15 1.20 17.91 2 2 2 151014 2.12 0.35 6.03 2 2 2 151804 11.28 1.21 18.16 2 2 2 151014 2.12 0.34 6.03 2 2 2 151804 11.27 1.18 18.21 2 2 2 151015 1.45 0.18 3.01 2 2 2 151805 11.29 1.21 18.51 2 2 2 151015 1.37 0.17 3.00 2 2 2 151805 11.34 1.20 18.39 2 2 2 151016 1.20 0.07 0.00 2 2 2 151806 5 5 5 151016 1.22 0.07 0.00 2 2 2 151806 5 5 5 151017 37.47 1.36 20.95 2 2 2 151807 12.35 1.35 20.68 2 2 2 151017 38.05 1.32 20.98 2 2 2 151807 12.44 1.37 20.59 2 2 2 151018 35.71 1.34 20.59 2 2 2 151808 11.04 1.30 19.33 2 2 2 151018 35.96 1.33 20.74 2 2 2 151808 11.19 1.30 19.27 2 2 2 151019 31.51 1.29 20.02 2 2 2 151809 7.40 1.04 14.95 2 2 2 151019 31.49 1.28 20.05 2 2 2 151809 7.50 1.06 14.99 2 2 2 151020 27.18 1.24 19.32 2 2 2 151810 5.00 0.79 11.81 2 2 2 151020 27.27 1.26 19.81 2 2 2 151810 4.90 0.77 11.75 2 2 2 151021 21.33 1.21 19.08 2 2 2 151811 3.43 0.60 8.34 2 2 2 151021 21.33 1.24 19.15 2 2 2 151811 3.36 0.57 8.22 2 2 2 151022 21.15 1.21 19.80 2 2 2 151812 0.78 0.17 0.00 2 2 2 151022 21.27 1.25 20.19 2 2 2 151812 0.82 0.17 0.00 2 2 2 151023 18.30 1.19 19.57 2 2 2 151813 20.86 1.19 16.45 2 2 2 151023 18.39 1.21 19.60 2 2 2 151813 21.24 1.23 16.91 2 2 2 151024 15.47 1.19 18.89 2 2 2 151814 22.26 1.19 17.15 2 2 2 151024 15.96 1.19 19.33 2 2 2 151814 22.27 1.18 17.23 2 2 2 151025 13.36 1.17 18.82 2 2 2 151815 19.90 1.19 17.55 2 2 2 151025 13.19 1.18 18.81 2 2 2 151815 20.23 1.20 17.31 2 2 2 151026 12.74 1.16 18.72 2 2 2 151816 21.47 1.17 17.41 2 2 2 151026 12.34 1.17 18.72 2 2 2 151816 21.37 1.20 17.30 2 2 2 151027 11.97 1.18 18.96 2 2 2 151817 19.10 1.23 17.37 2 2 2 151027 12.17 1.19 19.09 2 2 2 151817 19.44 1.16 17.29 2 2 2 151028 11.99 1.17 19.12 2 2 2 151818 17.63 1.18 17.14 2 2 2 151028 12.30 1.19 18.99 2 2 2 151818 17.65 1.16 17.13 2 2 2 151029 11.40 1.18 19.80 2 2 2 151819 15.57 1.15 17.10 2 2 2 151029 11.57 1.24 19.43 2 2 2 151819 15.79 1.15 17.00 2 2 2 151030 11.25 1.22 20.19 2 2 2 151820 13.57 1.13 16.96 2 2 2 151030 11.62 1.21 19.91 2 2 2 151820 13.64 1.15 16.96 2 2 2 151031 12.81 1.31 21.79 2 2 2 151821 13.21 1.16 16.78 2 2 2 151031 12.59 1.33 21.81 2 2 2 151821 13.40 1.15 16.89 2 2 2 151032 13.82 1.42 23.50 2 2 2 151822 11.92 1.15 16.77 2 2 2 151032 13.93 1.43 23.68 2 2 2 151822 11.97 1.16 16.91 2 2 2 151033 2.89 0.48 7.87 2 2 2 151823 11.41 1.16 17.04 2 2 2 151033 3.00 0.43 8.06 2 2 2 151823 11.22 1.15 17.06 2 2 2 151034 1.69 0.25 4.22 2 2 2 151824 11.46 1.16 16.89 2 2 2 151034 1.72 0.27 4.28 2 2 2 151824 11.56 1.16 16.67 2 2 2 151035 1.40 0.19 2.53 2 2 2 151825 11.50 1.18 17.11 2 2 2 151035 1.42 0.19 2.50 2 2 2 151825 11.60 1.20 17.28 2 2 2 151036 1.17 0.08 0.00 2 2 2 151826 11.51 1.20 17.66 2 2 2 151036 1.22 0.08 0.00 2 2 2 151826 11.60 1.19 17.62 2 2 2 151037 38.45 1.39 21.95 2 2 2 151827 11.69 1.20 17.81 2 2 2 151037 39.02 1.46 21.72 2 2 2 151827 11.76 1.21 18.10 2 2 2 151038 37.28 1.37 21.46 2 2 2 151828 11.83 1.22 18.52 2 2 2 151038 37.01 1.39 21.91 2 2 2 151828 11.95 1.23 18.58 2 2 2 151039 35.65 1.33 21.23 2 2 2 151829 12.08 1.29 19.46 2 2 2 151039 35.85 1.33 21.34 2 2 2 151829 12.25 1.28 19.35 2 2 2 151040 29.07 1.27 20.17 2 2 2 151830 12.62 1.31 19.88 2 2 2 151040 29.43 1.27 20.54 2 2 2 151830 12.73 1.34 20.36 2 2 2 151041 26.74 1.27 20.60 2 2 2 151831 9.81 1.21 17.44 2 2 2 151041 26.90 1.25 20.10 2 2 2 151831 9.80 1.23 17.31 2 2 2 151042 23.82 1.26 19.68 2 2 2 151832 0.79 0.19 0.00 2 2 2 151042 24.18 1.21 19.70 2 2 2 151832 0.81 0.17 0.00 2 2 2 151043 21.29 1.23 19.92 2 2 2 151833 23.10 1.18 17.06 2 2 2 151043 21.35 1.23 20.04 2 2 2 151833 23.49 1.17 17.13 2 2 2 151044 16.45 1.16 19.19 2 2 2 151834 21.76 1.18 17.04 2 2 2 151044 16.60 1.16 19.00 2 2 2 151834 21.85 1.20 17.18 2 2 2 151045 14.55 1.18 18.67 2 2 2 151835 22.95 1.20 17.10 2 2 2 151045 14.58 1.14 19.12 2 2 2 151835 22.84 1.19 16.94 2 2 2 151046 12.04 1.12 18.42 2 2 2 151836 22.34 1.25 17.07 2 2 2 151046 11.76 1.11 18.37 2 2 2 151836 22.41 1.20 17.23 2 2 2 151047 10.93 1.14 18.80 2 2 2 151837 16.21 1.18 16.98 2 2 2 151047 11.14 1.13 18.46 2 2 2 151837 16.42 1.16 16.89 2 2 2 151048 11.60 1.17 19.51 2 2 2 151838 18.26 1.18 16.85 2 2 2 151048 11.81 1.16 19.44 2 2 2 151838 18.28 1.16 16.66 2 2 2 151049 11.28 1.18 19.94 2 2 2 151839 16.11 1.17 16.74 2 2 2 151049 11.43 1.21 20.00 2 2 2 151839 16.21 1.16 16.66 2 2 2 151050 12.33 1.27 21.45 2 2 2 151840 14.24 1.13 16.88 2 2 2 151050 12.07 1.26 21.28 2 2 2 151840 14.42 1.14 16.67 2 2 2 151051 14.48 1.46 24.96 2 2 2 151841 13.66 1.15 16.78 2 2 2 151051 14.57 1.49 25.40 2 2 2 151841 13.89 1.15 17.14 2 2 2 151052 8.90 1.16 20.54 2 2 2 151842 11.80 1.14 16.98 2 2 2 151052 9.11 1.14 20.72 2 2 2 151842 11.85 1.13 16.87 2 2 2 151053 1.41 0.21 3.24 2 2 2 151843 11.52 1.15 17.24 2 2 2 151053 1.46 0.25 3.23 2 2 2 151843 11.58 1.15 17.08 2 2 2 151054 1.45 0.20 3.33 2 2 2 151844 11.02 1.15 17.21 2 2 2 151054 1.47 0.21 3.34 2 2 2 151844 11.07 1.15 17.02 2 2 2 151055 1.62 0.20 3.22 2 2 2 151845 10.96 1.18 17.29 2 2 2 151055 1.64 0.20 3.30 2 2 2 151845 11.14 1.18 17.44 2 2 2 151056 1.09 0.07 0.00 2 2 2 151846 11.35 1.20 17.71 2 2 2 151056 1.12 0.08 0.00 2 2 2 151846 11.37 1.20 17.78 2 2 2 151057 40.34 1.38 22.20 2 2 2 151847 11.93 1.24 18.68 2 2 2 151057 41.58 1.35 22.66 2 2 2 151847 11.87 1.24 18.55 2 2 2 151058 33.15 1.28 20.80 2 2 2 151848 12.14 1.27 18.67 2 2 2 151058 34.12 1.27 21.37 2 2 2 151848 12.19 1.27 18.81 2 2 2 151059 23.74 1.18 19.05 2 2 2 151849 12.44 1.34 19.73 2 2 2 151059 23.75 1.17 19.24 2 2 2 151849 12.53 1.34 19.77 2 2 2 151060 22.37 1.18 19.63 2 2 2 151850 10.72 1.26 18.38 2 2 2 151060 22.46 1.17 19.15 2 2 2 151850 10.73 1.27 18.26 2 2 2 151061 20.69 1.15 19.16 2 2 2 151851 6.40 0.94 11.97 2 2 2 151061 20.79 1.24 18.87 2 2 2 151851 6.23 0.94 11.80 2 2 2 151062 20.19 1.16 19.12 2 2 2 151852 0.86 0.21 0.00 2 2 2 151062 20.85 1.16 19.49 2 2 2 151852 0.84 0.21 0.00 2 2 2 151063 14.61 1.09 18.26 2 2 2 151853 16.49 1.11 15.67 2 2 2 151063 14.68 1.09 18.09 2 2 2 151853 16.66 1.10 15.92 2 2 2 151064 14.51 1.11 18.34 2 2 2 151854 20.54 1.17 16.62 2 2 2 151064 14.21 1.13 18.54 2 2 2 151854 20.59 1.16 16.38 2 2 2 151065 13.94 1.14 18.84 2 2 2 151855 21.44 1.20 16.72 2 2 2 151065 14.18 1.14 19.13 2 2 2 151855 21.54 1.21 17.04 2 2 2 151066 13.83 1.18 19.29 2 2 2 151856 21.90 1.17 17.06 2 2 2 151066 13.90 1.15 19.44 2 2 2 151856 22.03 1.22 17.21 2 2 2 151067 12.89 1.15 19.20 2 2 2 151857 14.78 1.14 16.18 2 2 2 151067 13.13 1.16 19.37 2 2 2 151857 14.46 1.13 16.08 2 2 2 151068 12.24 1.14 18.85 2 2 2 151858 14.36 1.12 16.09 2 2 2 151068 12.56 1.15 19.40 2 2 2 151858 14.38 1.12 16.11 2 2 2 151069 11.06 1.13 19.00 2 2 2 151859 15.38 1.17 16.66 2 2 2 151069 11.27 1.16 18.50 2 2 2 151859 15.19 1.16 16.42 2 2 2 151070 11.13 1.16 19.39 2 2 2 151860 13.12 1.15 16.58 2 2 2 151070 11.28 1.16 19.38 2 2 2 151860 13.04 1.15 16.48 2 2 2 151071 11.20 1.17 19.66 2 2 2 151861 11.63 1.18 16.25 2 2 2 151071 11.16 1.17 19.50 2 2 2 151861 11.66 1.16 16.31 2 2 2 151072 11.54 1.20 20.33 2 2 2 151862 12.31 1.14 16.58 2 2 2 151072 11.55 1.22 20.34 2 2 2 151862 12.37 1.15 16.63 2 2 2 151073 13.22 1.46 22.64 3 2 2 151863 11.61 1.16 16.54 2 2 2 151073 13.40 1.58 22.69 3 2 2 151863 11.71 1.16 16.66 2 2 2 151074 12.90 1.47 22.57 3 2 2 151864 10.77 1.04 16.85 2 2 2 151074 12.98 1.47 22.94 3 2 2 151864 10.82 1.05 16.83 2 2 2 151075 2.60 0.50 7.08 3 2 2 151865 10.37 1.05 16.89 2 2 2 151075 2.75 0.40 7.25 3 2 2 151865 10.26 1.07 16.95 2 2 2 151076 1.00 0.12 0.00 3 2 2 151866 9.94 1.04 16.90 2 2 2 151076 1.06 0.10 0.00 3 2 2 151866 9.99 1.05 16.76 2 2 2 151077 29.67 1.39 17.87 3 2 2 151867 9.94 1.04 16.65 2 2 2 151077 29.85 1.29 18.19 3 2 2 151867 9.99 1.04 16.68 2 2 2 151078 27.70 1.28 18.34 3 2 2 151868 9.70 1.06 16.79 2 2 2 151078 28.29 1.27 18.45 3 2 2 151868 9.71 1.06 16.64 2 2 2 151079 24.68 1.22 17.97 3 2 2 151869 9.80 1.06 16.96 2 2 2 151079 24.22 1.24 17.39 3 2 2 151869 9.77 1.07 16.85 2 2 2 151080 22.33 1.22 17.19 3 2 2 151870 9.77 1.06 17.17 2 2 2 151080 22.44 1.22 17.25 3 2 2 151870 9.85 1.04 17.21 2 2 2 151081 15.71 1.20 17.02 3 2 2 151871 8.85 1.04 16.26 2 2 2 151081 15.81 1.29 16.90 3 2 2 151871 8.91 1.03 16.17 2 2 2 151082 16.10 1.20 17.57 3 2 2 151872 1.02 0.19 0.00 2 2 2 151082 16.39 1.20 17.52 3 2 2 151872 1.07 0.21 0.00 2 2 2 151083 19.51 1.22 17.75 3 2 2 151873 15.49 1.00 16.19 2 2 2 151083 19.21 1.20 17.51 3 2 2 151873 15.57 1.00 16.08 2 2 2 151084 16.37 1.20 17.39 3 2 2 151874 19.02 1.05 16.97 2 2 2 151084 16.53 1.21 17.49 3 2 2 151874 19.27 1.07 17.04 2 2 2 151085 14.64 1.20 17.47 3 2 2 151875 20.08 1.11 17.22 2 2 2 151085 14.97 1.19 17.60 3 2 2 151875 20.04 1.09 17.04 2 2 2 151086 12.92 1.19 17.03 3 2 2 151876 19.16 1.08 16.81 2 2 2 151086 13.05 1.18 17.33 3 2 2 151876 18.63 1.09 16.80 2 2 2 151087 11.85 1.21 17.01 3 2 2 151877 15.23 1.07 16.59 2 2 2 151087 11.98 1.21 17.14 3 2 2 151877 15.66 1.06 16.77 2 2 2 151088 11.51 1.20 17.26 3 2 2 151878 17.29 1.10 17.29 2 2 2 151088 11.68 1.19 17.39 3 2 2 151878 17.36 1.10 17.48 2 2 2 151089 11.21 1.22 18.04 3 2 2 151879 12.11 1.03 16.50 2 2 2 151089 11.31 1.30 17.33 3 2 2 151879 12.34 1.03 16.51 2 2 2 151090 11.70 1.26 18.91 3 2 2 151880 11.35 1.02 16.08 2 2 2 151090 12.01 1.29 18.67 3 2 2 151880 11.53 1.03 16.36 2 2 2 151091 11.33 1.26 19.06 3 2 2 151881 11.34 1.02 16.80 2 2 2 151091 11.36 1.27 18.99 3 2 2 151881 11.31 1.03 16.67 2 2 2 151092 8.00 1.15 16.72 3 2 2 151882 10.52 1.02 16.64 2 2 2 151092 8.20 1.13 16.95 3 2 2 151882 10.68 1.05 16.75 2 2 2 151093 3.88 0.70 10.41 3 2 2 151883 9.73 1.06 16.64 2 2 2 151093 3.88 0.67 10.26 3 2 2 151883 9.93 1.06 16.73 2 2 2 151094 1.56 0.28 3.78 3 2 2 151884 9.94 1.04 16.48 2 2 2 151094 1.56 0.25 3.79 3 2 2 151884 10.11 1.04 16.31 2 2 2 151095 1.15 0.20 2.23 3 2 2 151885 9.91 1.03 16.59 2 2 2 151095 1.09 0.19 2.22 3 2 2 151885 10.11 1.05 16.54 2 2 2 151096 0.94 0.11 0.00 3 2 2 151886 9.92 1.05 16.89 2 2 2 151096 0.94 0.07 0.00 3 2 2 151886 9.97 1.06 17.01 2 2 2 151097 20.99 1.26 16.63 3 2 2 151887 10.09 1.06 17.23 2 2 2 151097 21.40 1.18 16.95 3 2 2 151887 10.10 1.05 17.04 2 2 2 151098 23.62 1.22 17.64 3 2 2 151888 10.39 1.03 16.95 2 2 2 151098 23.67 1.22 17.67 3 2 2 151888 10.16 1.04 17.10 2 2 2 151099 21.08 1.20 17.01 3 2 2 151889 9.70 1.06 17.06 2 2 2 151099 20.91 1.21 17.17 3 2 2 151889 9.87 1.06 17.00 2 2 2 151100 21.45 1.21 17.38 3 2 2 151890 9.98 1.08 17.22 2 2 2 151100 21.04 1.22 17.43 3 2 2 151890 9.98 1.09 17.28 2 2 2 151101 15.94 1.18 17.20 3 2 2 151891 9.79 1.09 16.92 2 2 2 151101 16.45 1.19 17.26 3 2 2 151891 9.82 1.09 16.79 2 2 2 151102 14.26 1.20 16.75 3 2 2 151892 1.34 0.23 0.49 2 2 2 151102 14.48 1.19 16.58 3 2 2 151892 1.41 0.23 0.67 2 2 2 151103 12.91 1.18 16.51 3 2 2 151893 12.94 1.00 15.66 2 2 2 151103 13.30 1.17 16.93 3 2 2 151893 13.24 1.00 16.12 2 2 2 151104 12.83 1.17 17.14 3 2 2 151894 12.67 1.02 16.14 2 2 2 151104 13.10 1.17 16.99 3 2 2 151894 12.94 1.03 16.19 2 2 2 151105 13.12 1.26 16.77 3 2 2 151895 12.49 1.02 16.27 2 2 2 151105 12.89 1.19 17.03 3 2 2 151895 12.77 1.01 16.08 2 2 2 151106 11.69 1.22 16.83 3 2 2 151896 12.93 1.00 15.79 2 2 2 151106 12.02 1.20 17.04 3 2 2 151896 12.78 1.00 15.57 2 2 2 151107 11.25 1.19 17.59 3 2 2 151897 12.66 1.03 16.14 2 2 2 151107 11.15 1.20 17.22 3 2 2 151897 12.74 1.01 16.11 2 2 2 151108 11.65 1.23 18.02 3 2 2 151898 11.76 1.05 16.55 2 2 2 151108 11.42 1.23 17.89 3 2 2 151898 11.84 1.05 16.57 2 2 2 151109 11.68 1.27 18.69 3 2 2 151899 11.21 1.04 16.37 2 2 2 151109 11.82 1.28 18.71 3 2 2 151899 11.32 1.04 16.58 2 2 2 151110 12.41 1.34 20.55 3 2 2 151900 10.78 1.04 16.43 2 2 2 151110 12.50 1.34 20.20 3 2 2 151900 11.00 1.04 16.44 2 2 2 151111 10.15 1.26 18.95 3 2 2 151901 10.98 1.03 16.26 2 2 2 151111 10.27 1.25 19.17 3 2 2 151901 10.61 1.03 16.40 2 2 2 151112 8.44 1.18 17.53 3 2 2 151902 10.32 1.04 16.41 2 2 2 151112 8.62 1.19 17.69 3 2 2 151902 10.44 1.05 16.40 2 2 2 151113 7.22 1.07 16.29 3 2 2 151903 9.92 1.04 16.57 2 2 2 151113 7.14 1.16 15.70 3 2 2 151903 10.16 1.04 16.74 2 2 2 151114 1.75 0.33 4.62 3 2 2 151904 10.13 1.03 16.32 2 2 2 151114 1.87 0.27 4.89 3 2 2 151904 10.16 1.02 16.35 2 2 2 151115 1.38 0.22 3.12 3 2 2 151905 9.94 1.05 16.57 2 2 2 151115 1.34 0.22 3.08 3 2 2 151905 9.96 1.04 16.67 2 2 2 151116 0.97 0.08 0.00 3 2 2 151906 9.97 1.07 17.18 2 2 2 151116 1.00 0.07 0.00 3 2 2 151906 10.01 1.06 16.97 2 2 2 151117 34.74 1.34 19.32 3 2 2 151907 9.70 1.07 16.83 2 2 2 151117 34.96 1.39 19.33 3 2 2 151907 9.79 1.07 16.84 2 2 2 151118 29.37 1.27 18.63 3 2 2 151908 7.28 0.91 13.37 2 2 2 151118 29.86 1.29 18.58 3 2 2 151908 7.20 0.90 13.51 2 2 2 151119 27.91 1.27 18.23 3 2 2 151909 1.56 0.25 0.90 2 2 2 151119 28.05 1.30 18.49 3 2 2 151909 1.59 0.25 1.02 2 2 2 151120 26.61 1.28 17.85 3 2 2 151910 9.98 1.07 16.28 2 2 2 151120 26.64 1.29 17.82 3 2 2 151910 10.01 1.05 16.70 2 2 2 151121 23.30 1.36 17.15 3 2 2 151911 9.82 1.06 16.92 2 2 2 151121 23.54 1.27 17.75 3 2 2 151911 9.84 1.05 16.86 2 2 2 151122 22.36 1.27 17.89 3 2 2 151912 10.97 1.07 16.70 2 2 2 151122 22.55 1.28 18.01 3 2 2 151912 10.94 1.10 17.10 2 2 2 151123 19.50 1.27 17.32 3 2 2 151913 8.98 1.03 15.97 2 2 2 151123 20.42 1.26 18.09 3 2 2 151913 9.00 1.04 15.92 2 2 2 151124 16.32 1.25 17.18 3 2 2 151914 1.07 0.27 0.00 2 2 2 151124 16.90 1.24 17.64 3 2 2 151914 1.11 0.20 0.00 2 2 2 151125 14.89 1.23 17.75 3 2 2 151915 12.27 1.15 16.97 2 2 2 151125 14.91 1.23 17.69 3 2 2 151915 12.56 1.15 17.28 2 2 2 151126 12.79 1.22 17.20 3 2 2 151916 6.18 0.95 12.90 2 2 2 151126 12.92 1.21 17.25 3 2 2 151916 6.12 0.95 12.64 2 2 2 151127 11.76 1.21 17.43 3 2 2 151917 0.98 0.21 0.00 2 2 2 151127 12.11 1.22 17.32 3 2 2 151917 0.83 0.21 0.00 2 2 2 151128 11.75 1.24 17.94 3 2 2 151918 9.28 1.08 15.39 2 2 2 151128 11.84 1.21 17.89 3 2 2 151918 9.36 1.08 15.43 2 2 2 151129 11.80 1.32 17.99 3 2 2 151919 0.74 0.18 0.00 2 2 2 151129 11.62 1.24 18.10 3 2 2 151919 0.77 0.20 0.00 2 2 2 151130 11.62 1.27 18.81 3 2 2 151920 14.65 1.26 18.66 2 2 2 151130 11.65 1.31 18.54 3 2 2 151920 14.76 1.24 18.62 2 2 2 151131 11.66 1.34 19.59 3 2 2 151921 2.64 0.81 9.30 2 2 2 151131 11.81 1.34 19.56 3 2 2 151921 2.72 0.81 9.52 2 2 2 151132 9.79 1.27 18.55 3 2 2 151922 0.71 0.28 0.00 2 2 2 151132 10.03 1.27 18.62 3 2 2 151922 0.69 0.21 0.00 2 2 2 151133 6.14 0.95 14.07 3 2 2 151923 12.47 1.10 17.07 2 2 2 151133 6.21 0.98 14.11 3 2 2 151923 12.49 1.09 17.18 2 2 2 151134 3.32 0.58 8.73 3 2 2 151924 9.44 1.03 15.83 2 2 2 151134 3.35 0.59 8.75 3 2 2 151924 9.39 1.06 15.82 2 2 2 151135 1.48 0.24 3.60 3 2 2 151925 3.85 0.74 7.57 2 2 2 151135 1.53 0.27 3.48 3 2 2 151925 3.75 0.76 7.61 2 2 2 151136 0.65 0.07 0.00 3 2 2 151926 1.43 0.23 0.44 2 2 2 151136 0.62 0.07 0.00 3 2 2 151926 1.48 0.24 0.52 2 2 2 151137 31.26 1.40 18.19 3 2 2 151927 9.66 1.05 16.36 2 2 2 151137 31.94 1.34 18.86 3 2 2 151927 9.83 1.04 16.24 2 2 2 151138 29.02 1.28 18.09 3 2 2 151928 9.68 1.13 16.41 2 2 2 151138 29.27 1.29 18.43 3 2 2 151928 9.86 1.04 16.71 2 2 2 151139 27.08 1.29 17.95 3 2 2 151929 9.74 1.06 16.75 2 2 2 151139 27.21 1.28 17.88 3 2 2 151929 9.82 1.07 16.62 2 2 2 151140 25.02 1.26 17.61 3 2 2 151930 9.34 1.05 16.35 2 2 2 151140 25.24 1.27 17.61 3 2 2 151930 9.23 1.08 16.46 2 2 2 151141 21.73 1.26 17.04 3 2 2 151931 1.51 0.28 0.98 2 2 2 151141 21.90 1.26 17.55 3 2 2 151931 1.56 0.27 1.21 2 2 2 151142 18.36 1.22 16.89 3 2 2 151932 9.56 1.04 16.10 2 2 2 151142 18.50 1.23 17.08 3 2 2 151932 9.63 1.04 16.38 2 2 2 151143 16.00 1.22 16.69 3 2 2 151933 9.88 1.04 16.47 2 2 2 151143 16.11 1.22 16.77 3 2 2 151933 9.91 1.05 16.61 2 2 2 151144 15.36 1.24 17.02 3 2 2 151934 9.66 1.05 16.46 2 2 2 151144 15.22 1.23 16.61 3 2 2 151934 9.72 1.06 16.44 2 2 2 151145 12.08 1.10 16.75 3 2 2 151935 9.84 1.05 16.52 2 2 2 151145 12.21 1.16 16.81 3 2 2 151935 9.87 1.06 16.54 2 2 2 151146 10.21 1.09 16.07 3 2 2 151936 9.97 1.05 16.68 2 2 2 151146 10.56 1.09 16.09 3 2 2 151936 10.05 1.06 16.85 2 2 2 151147 10.50 1.11 16.52 3 2 2 151937 9.48 1.06 16.68 2 2 2 151147 10.75 1.11 16.83 3 2 2 151937 9.31 1.05 16.68 2 2 2 151148 11.48 1.15 17.26 3 2 2 151938 9.45 1.05 16.66 3 3 3 151148 11.22 1.14 16.82 3 2 2 151938 9.46 1.05 16.43 3 3 3 151149 10.83 1.15 17.05 3 2 2 151939 8.70 1.04 15.54 3 3 3 151149 10.68 1.15 16.98 3 2 2 151939 8.70 1.02 15.55 3 3 3 151150 10.80 1.17 17.30 3 2 2 151940 0.90 0.21 0.18 3 3 3 151150 10.81 1.19 17.56 3 2 2 151940 0.93 0.20 0.07 3 3 3 151151 11.73 1.22 18.44 3 2 2 151941 12.99 1.02 15.60 2 2 2 151151 11.93 1.22 18.61 3 2 2 151941 13.09 1.01 15.73 2 2 2 151152 12.38 1.33 19.55 3 2 2 151942 12.57 1.01 15.97 2 2 2 151152 12.72 1.32 19.90 3 2 2 151942 12.58 1.03 15.95 2 2 2 151153 12.70 1.36 21.43 3 2 2 151943 12.36 1.03 15.70 2 2 2 151153 12.99 1.41 21.51 3 2 2 151943 12.42 1.04 15.90 2 2 2 151154 7.98 1.07 16.54 3 2 2 151944 12.33 1.06 16.02 2 2 2 151154 7.93 1.07 16.62 3 2 2 151944 12.41 1.03 15.92 2 2 2 151155 2.17 0.35 4.95 3 2 2 151945 12.14 1.04 16.08 2 2 2 151155 2.20 0.40 4.81 3 2 2 151945 12.02 1.04 16.16 2 2 2 151156 1.04 0.11 0.00 3 2 2 151946 12.05 1.05 16.06 2 2 2 151156 0.95 0.11 0.00 3 2 2 151946 12.12 1.04 16.04 2 2 2 151157 24.15 1.21 16.96 3 2 2 151947 11.78 1.04 15.95 2 2 2 151157 23.77 1.17 17.18 3 2 2 151947 11.82 1.04 16.20 2 2 2 151158 21.81 1.16 16.89 3 2 2 151948 11.03 1.05 16.03 2 2 2 151158 22.13 1.16 16.77 3 2 2 151948 11.13 1.08 16.24 2 2 2 151159 21.11 1.16 16.84 3 2 2 151949 10.67 1.07 16.38 2 2 2 151159 21.22 1.16 16.94 3 2 2 151949 10.66 1.08 16.77 2 2 2 151160 22.64 1.23 17.10 3 2 2 151950 9.82 1.05 16.62 2 2 2 151160 23.23 1.20 17.65 3 2 2 151950 9.66 1.05 16.41 2 2 2 151161 11.78 1.22 17.56 3 2 2 151951 9.58 1.07 16.45 2 2 2 151161 12.07 1.18 17.79 3 2 2 151951 9.68 1.06 16.45 2 2 2 151162 18.10 1.17 16.78 3 2 2 151952 9.67 1.07 16.62 2 2 2 151162 18.07 1.17 17.04 3 2 2 151952 9.77 1.07 16.64 2 2 2 151163 14.35 1.14 16.37 3 2 2 151953 9.74 1.08 16.74 2 2 2 151163 14.40 1.13 16.13 3 2 2 151953 9.94 1.09 16.89 2 2 2 151164 12.29 1.13 16.09 3 2 2 151954 9.74 1.07 16.71 2 2 2 151164 12.29 1.12 16.07 3 2 2 151954 9.82 1.07 16.95 2 2 2 151165 12.75 1.15 16.66 3 2 2 151955 9.64 1.08 16.87 2 2 2 151165 13.03 1.14 17.07 3 2 2 151955 9.56 1.07 16.74 2 2 2 151166 11.67 1.16 16.66 3 2 2 151956 9.26 1.07 16.48 2 2 2 151166 12.00 1.15 16.77 3 2 2 151956 9.29 1.09 16.47 2 2 2 151167 11.05 1.16 17.02 3 2 2 151957 10.88 1.15 17.79 2 2 2 151167 11.05 1.18 17.20 3 2 2 151957 10.75 1.16 17.59 2 2 2 151168 10.41 1.17 17.55 3 2 2 151958 12.66 1.24 18.44 2 2 2 151168 10.48 1.19 17.36 3 2 2 151958 11.93 1.19 18.44 2 2 2 151169 11.42 1.26 17.70 3 2 2 151959 11.85 1.25 18.91 2 2 2 151169 11.27 1.28 17.82 3 2 2 151959 11.86 1.21 19.02 2 2 2 151170 11.43 1.07 18.06 3 2 2 151960 4.09 0.90 11.27 2 2 2 151170 11.50 18.11 3 4 2 151960 4.15 0.99 11.23 2 2 2 151171 11.90 1.34 18.95 3 2 2 151961 14.43 1.00 15.18 2 2 2 151171 12.10 1.34 19.12 3 2 2 151961 14.53 0.99 15.56 2 2 2 151172 11.54 1.44 19.07 3 2 2 151962 15.93 1.02 15.80 2 2 2 151172 11.61 1.36 19.74 3 2 2 151962 16.18 1.01 15.91 2 2 2 151173 12.13 1.42 20.84 3 2 2 151963 17.30 1.03 16.66 2 2 2 151173 12.54 1.36 20.30 3 2 2 151963 17.21 1.02 16.57 2 2 2 151174 4.31 0.72 10.51 3 2 2 151964 13.99 1.00 16.29 2 2 2 151174 4.38 0.72 11.06 3 2 2 151964 14.06 1.00 16.03 2 2 2 151175 2.15 0.38 5.54 3 2 2 151965 16.75 1.06 16.93 2 2 2 151175 2.28 0.40 5.60 3 2 2 151965 16.81 1.11 17.09 2 2 2 151176 0.96 0.15 0.00 3 2 2 151966 15.13 1.06 16.84 2 2 2 151176 0.97 0.12 0.00 3 2 2 151966 15.27 1.06 16.83 2 2 2 151177 31.87 1.30 18.41 3 2 2 151967 14.68 1.04 16.71 2 2 2 151177 31.84 1.35 18.31 3 2 2 151967 14.64 1.04 17.04 2 2 2 151178 27.50 1.24 18.08 3 2 2 151968 13.29 1.05 17.12 2 2 2 151178 28.70 1.27 18.00 3 2 2 151968 13.74 1.05 17.30 2 2 2 151179 24.77 1.22 18.07 3 2 2 151969 12.58 1.02 16.39 2 2 2 151179 24.84 1.25 18.10 3 2 2 151969 12.70 1.02 16.74 2 2 2 151180 23.00 1.20 17.22 3 2 2 151970 11.28 1.01 16.80 2 2 2 151180 23.47 1.20 17.48 3 2 2 151970 11.52 1.00 16.65 2 2 2 151181 16.55 1.20 17.44 3 2 2 151971 10.77 1.00 16.91 2 2 2 151181 16.17 1.18 17.14 3 2 2 151971 10.85 0.99 16.87 2 2 2 151182 15.87 1.20 17.66 3 2 2 151972 11.47 1.01 17.15 2 2 2 151182 16.15 1.20 17.32 3 2 2 151972 11.52 1.03 17.04 2 2 2 151183 13.62 1.17 16.93 3 2 2 151973 10.39 1.01 16.72 2 2 2 151183 13.93 1.17 17.16 3 2 2 151973 10.31 1.01 16.69 2 2 2 151184 11.72 1.16 16.76 3 2 2 151974 10.47 1.01 16.78 2 2 2 151184 11.83 1.16 16.88 3 2 2 151974 10.41 1.01 16.75 2 2 2 151185 12.01 1.16 16.78 3 2 2 151975 10.70 1.02 17.38 2 2 2 151185 12.14 1.22 16.97 3 2 2 151975 10.86 1.03 17.49 2 2 2 151186 11.37 1.19 17.05 3 2 2 151976 10.43 1.01 17.42 2 2 2 151186 11.66 1.20 17.33 3 2 2 151976 10.53 1.01 17.00 2 2 2 151187 11.35 1.19 17.46 3 2 2 151977 10.92 1.06 17.71 2 2 2 151187 11.37 1.19 17.68 3 2 2 151977 10.99 1.07 17.76 2 2 2 151188 11.33 1.23 17.68 3 2 2 151978 12.47 1.12 18.84 2 2 2 151188 11.43 1.22 17.78 3 2 2 151978 12.15 1.12 18.87 2 2 2 151189 12.02 1.30 18.78 3 2 2 151979 10.04 1.04 16.73 2 2 2 151189 12.23 1.29 18.81 3 2 2 151979 10.13 1.05 16.92 2 2 2 151190 12.28 1.38 20.70 3 2 2 151980 0.98 0.18 0.00 2 2 2 151190 12.67 1.38 20.86 3 2 2 151980 1.41 0.16 0.00 2 2 2 151191 4.29 0.69 9.86 3 2 2 151981 13.98 0.92 15.39 2 2 2 151191 4.42 0.65 9.97 3 2 2 151981 14.34 0.92 15.54 2 2 2 151192 2.01 0.33 4.72 3 2 2 151982 17.72 0.98 16.25 2 2 2 151192 2.08 0.34 4.71 3 2 2 151982 17.56 0.97 16.20 2 2 2 151193 2.05 0.33 4.55 3 2 2 151983 15.72 0.96 15.88 2 2 2 151193 2.12 0.39 4.61 3 2 2 151983 15.65 0.98 15.92 2 2 2 151194 2.04 0.33 4.80 3 2 2 151984 13.71 0.98 16.39 2 2 2 151194 2.08 0.33 4.77 3 2 2 151984 13.72 1.00 16.50 2 2 2 151195 2.10 0.34 5.07 3 2 2 151985 13.90 1.00 16.78 2 2 2 151195 2.03 0.35 4.99 3 2 2 151985 13.94 0.99 16.84 2 2 2 151196 0.71 0.07 0.00 3 2 2 151986 13.72 1.00 16.50 2 2 2 151196 0.76 0.08 0.00 3 2 2 151986 13.75 1.00 16.68 2 2 2 151197 30.38 1.30 17.62 3 2 2 151987 13.25 1.01 16.55 2 2 2 151197 30.64 1.28 17.80 3 2 2 151987 13.35 1.01 16.63 2 2 2 151198 24.71 1.22 16.82 3 2 2 151988 11.88 1.00 16.69 2 2 2 151198 25.65 1.22 17.12 3 2 2 151988 11.87 1.01 16.75 2 2 2 151199 24.21 1.22 17.36 3 2 2 151989 11.98 1.02 16.89 2 2 2 151199 24.51 1.22 17.41 3 2 2 151989 12.31 1.02 17.25 2 2 2 151200 23.06 1.23 17.18 3 2 2 151990 11.81 1.04 17.56 2 2 2 151200 23.57 1.23 17.32 3 2 2 151990 11.72 1.04 17.39 2 2 2 151201 19.62 1.20 16.77 3 2 2 151991 11.59 1.04 17.48 2 2 2 151201 20.10 1.24 16.68 3 2 2 151991 11.57 1.04 17.42 2 2 2 151202 20.18 1.22 16.97 3 2 2 151992 11.30 1.05 17.72 2 2 2 151202 20.06 1.22 16.81 3 2 2 151992 11.42 1.05 17.63 2 2 2 151203 17.87 1.20 16.73 3 2 2 151993 11.52 1.06 17.91 2 2 2 151203 18.18 1.19 16.73 3 2 2 151993 11.64 1.06 17.78 2 2 2 151204 15.47 1.18 16.49 3 2 2 151994 11.45 1.06 17.78 2 2 2 151204 15.98 1.18 16.64 3 2 2 151994 11.53 1.07 17.70 2 2 2 151205 13.85 1.21 16.69 3 2 2 151995 11.86 1.12 18.88 2 2 2 151205 13.93 1.19 16.35 3 2 2 151995 12.32 1.13 19.02 2 2 2 151206 12.53 1.20 16.87 3 2 2 151996 12.53 1.20 20.03 2 2 2 151206 12.58 1.18 16.82 3 2 2 151996 12.49 1.19 19.97 2 2 2 151207 11.62 1.20 16.78 3 2 2 151997 11.83 1.22 20.05 2 2 2 151207 12.03 1.20 17.06 3 2 2 151997 11.89 1.22 20.29 2 2 2 151208 11.01 1.21 16.75 3 2 2 151998 10.20 1.15 19.49 2 2 2 151208 11.02 1.20 16.83 3 2 2 151998 10.41 1.15 19.48 2 2 2 151209 11.81 1.30 17.23 3 2 2 151999 3.97 0.57 10.10 2 2 2 151209 11.94 1.22 17.35 3 2 2 151999 4.08 0.57 10.04 2 2 2 151210 12.60 1.33 19.14 3 2 2 152000 0.94 0.14 0.60 2 2 2 151210 12.49 1.30 18.85 3 2 2 152000 0.84 0.15 0.49 2 2 2 151211 8.13 1.11 15.88 3 2 2 152001 15.16 1.00 15.81 2 2 2 151211 8.43 1.09 16.15 3 2 2 152001 15.38 0.99 15.84 2 2 2 151212 2.41 0.43 5.47 3 2 2 152002 18.94 1.03 16.41 2 2 2 151212 2.43 0.38 5.53 3 2 2 152002 19.54 1.04 16.59 2 2 2 151213 2.20 0.37 4.93 3 2 2 152003 19.62 1.06 16.76 2 2 2 151213 2.29 0.36 4.81 3 2 2 152003 19.79 1.07 17.06 2 2 2 151214 2.21 0.36 4.98 3 2 2 152004 15.27 1.03 16.07 2 2 2 151214 2.14 0.34 4.95 3 2 2 152004 15.28 1.02 16.18 2 2 2 151215 1.98 0.35 5.10 3 2 2 152005 12.70 1.02 16.30 2 2 2 151215 2.00 0.37 5.04 3 2 2 152005 12.75 1.03 16.33 2 2 2 151216 0.74 0.09 0.00 3 2 2 152006 14.48 1.05 16.68 2 2 2 151216 0.74 0.07 0.00 3 2 2 152006 14.32 1.05 16.72 2 2 2 151217 30.93 1.23 17.97 3 2 2 152007 13.69 1.06 16.94 2 2 2 151217 31.26 1.28 17.59 3 2 2 152007 13.59 1.05 16.89 2 2 2 151218 24.31 1.15 16.91 3 2 2 152008 12.31 1.08 16.96 2 2 2 151218 24.32 1.16 16.75 3 2 2 152008 12.45 1.07 17.05 2 2 2 151219 22.13 1.12 16.85 3 2 2 152009 11.40 1.08 17.02 2 2 2 151219 22.26 1.13 16.79 3 2 2 152009 11.42 1.07 17.26 2 2 2 151220 23.51 1.16 17.10 3 2 2 152010 11.46 1.06 17.17 2 2 2 151220 23.97 1.14 17.19 3 2 2 152010 11.49 1.07 17.34 2 2 2 151221 14.08 1.09 16.83 3 2 2 152011 10.75 1.08 17.17 2 2 2 151221 14.32 1.10 16.81 3 2 2 152011 10.79 1.07 17.01 2 2 2 151222 16.02 1.10 17.00 3 2 2 152012 11.09 1.10 17.71 2 2 2 151222 16.20 1.10 17.05 3 2 2 152012 11.02 1.10 17.52 2 2 2 151223 14.14 1.10 16.82 3 2 2 152013 10.88 1.10 17.94 2 2 2 151223 14.24 1.08 16.54 3 2 2 152013 10.92 1.10 17.80 2 2 2 151224 10.86 0.99 15.49 3 2 2 152014 10.58 1.11 17.98 2 2 2 151224 11.10 1.02 15.60 3 2 2 152014 10.59 1.15 17.85 2 2 2 151225 11.49 1.05 16.55 3 2 2 152015 11.28 1.16 18.59 2 2 2 151225 11.50 1.12 16.50 3 2 2 152015 11.29 1.18 18.64 2 2 2 151226 12.27 1.08 17.13 3 2 2 152016 11.72 1.23 19.46 2 2 2 151226 12.04 1.09 16.84 3 2 2 152016 11.75 1.24 19.61 2 2 2 151227 12.01 1.10 17.52 3 2 2 152017 10.54 1.21 19.34 2 2 2 151227 12.11 1.10 17.51 3 2 2 152017 10.57 1.21 19.40 2 2 2 151228 11.64 1.13 17.54 3 2 2 152018 7.30 0.96 15.09 2 2 2 151228 11.66 1.11 17.62 3 2 2 152018 7.34 0.95 15.24 2 2 2 151229 11.36 1.12 17.73 3 2 2 152019 2.48 0.42 6.84 2 2 2 151229 11.40 1.13 17.70 3 2 2 152019 2.45 0.43 6.72 2 2 2 151230 11.51 1.15 17.80 3 2 2 152020 1.06 0.19 1.43 2 2 2 151230 11.29 1.14 17.98 3 2 2 152020 1.15 0.19 1.49 2 2 2 151231 11.78 1.16 18.97 3 2 2 152021 13.09 1.00 15.33 2 2 2 151231 11.58 1.17 18.79 3 2 2 152021 13.16 0.98 15.35 2 2 2 151232 10.46 1.21 19.32 3 2 2 152022 15.08 1.05 16.08 2 2 2 151232 10.60 1.18 19.45 3 2 2 152022 15.09 1.03 16.06 2 2 2 151233 3.64 0.57 9.04 3 2 2 152023 15.56 1.04 16.23 2 2 2 151233 3.65 0.53 9.10 3 2 2 152023 15.68 1.05 16.28 2 2 2 151234 2.28 0.34 6.15 3 2 2 152024 17.41 1.09 16.92 2 2 2 151234 2.32 0.33 6.12 3 2 2 152024 17.52 1.07 16.90 2 2 2 151235 1.76 0.27 4.87 3 2 2 152025 16.00 1.06 16.85 2 2 2 151235 1.81 0.26 4.99 3 2 2 152025 16.04 1.07 16.86 2 2 2 151236 0.56 0.04 0.00 3 2 2 152026 14.53 1.06 16.64 2 2 2 151236 0.47 0.04 0.00 3 2 2 152026 14.71 1.06 16.53 2 2 2 151237 20.27 1.08 15.91 3 2 2 152027 12.51 1.06 16.71 2 2 2 151237 20.45 1.05 16.68 3 2 2 152027 12.49 1.06 16.78 2 2 2 151238 20.36 1.09 17.05 3 2 2 152028 11.30 1.05 16.81 2 2 2 151238 19.89 1.04 16.52 3 2 2 152028 11.35 1.06 16.69 2 2 2 151239 20.73 1.08 17.06 3 2 2 152029 10.29 1.06 16.76 2 2 2 151239 20.45 1.09 17.01 3 2 2 152029 10.31 1.06 16.96 2 2 2 151240 19.58 1.09 16.46 3 2 2 152030 9.99 1.07 16.95 2 2 2 151240 19.91 1.07 16.56 3 2 2 152030 10.12 1.07 16.87 2 2 2 151241 13.67 1.16 17.10 3 2 2 152031 10.04 1.08 17.09 2 2 2 151241 14.53 1.10 17.22 3 2 2 152031 10.05 1.08 17.11 2 2 2 151242 17.07 1.09 17.00 3 2 2 152032 10.38 1.08 17.18 2 2 2 151242 17.33 1.09 16.83 3 2 2 152032 10.09 1.08 17.27 2 2 2 151243 14.54 1.08 16.28 3 2 2 152033 10.44 1.11 17.69 2 2 2 151243 14.69 1.07 16.49 3 2 2 152033 10.45 1.10 17.59 2 2 2 151244 12.57 1.06 16.38 3 2 2 152034 10.09 1.12 17.50 2 2 2 151244 12.45 1.09 16.48 3 2 2 152034 10.39 1.11 17.76 2 2 2 151245 11.55 1.08 16.30 3 2 2 152035 10.66 1.15 18.32 2 2 2 151245 11.68 1.08 16.55 3 2 2 152035 10.71 1.15 18.18 2 2 2 151246 12.29 1.10 16.58 3 2 2 152036 11.30 1.23 19.50 2 2 2 151246 12.28 1.10 16.63 3 2 2 152036 11.62 1.23 19.57 2 2 2 151247 10.88 1.12 16.65 3 2 2 152037 8.37 1.04 16.67 2 2 2 151247 11.25 1.10 17.42 3 2 2 152037 8.46 1.04 16.74 2 2 2 151248 11.23 1.11 17.52 3 2 2 152038 3.71 0.58 9.64 2 2 2 151248 11.38 1.13 17.34 3 2 2 152038 3.69 0.60 9.52 2 2 2 151249 12.11 1.27 18.14 3 2 2 152039 1.10 0.19 1.49 2 2 2 151249 12.17 1.22 18.59 3 2 2 152039 0.95 0.19 1.38 2 2 2 151250 13.63 1.38 21.72 3 2 2 152040 1.04 0.19 1.18 2 2 2 151250 13.76 1.37 21.67 3 2 2 152040 1.07 0.19 1.19 2 2 2 151251 13.79 1.40 22.35 3 2 2 152041 13.72 1.00 15.37 2 2 2 151251 13.83 1.41 22.58 3 2 2 152041 13.84 0.99 15.65 2 2 2 151252 9.26 1.13 17.76 3 2 2 152042 13.79 0.99 15.65 2 2 2 151252 9.36 1.11 18.21 3 2 2 152042 13.86 1.02 15.40 2 2 2 151253 3.42 0.55 8.66 3 2 2 152043 17.28 1.08 16.59 2 2 2 151253 3.54 0.55 8.91 3 2 2 152043 17.16 1.07 16.57 2 2 2 151254 2.15 0.35 6.09 3 2 2 152044 14.99 1.05 16.64 2 2 2 151254 2.17 0.35 5.98 3 2 2 152044 15.05 1.06 16.63 2 2 2 151255 2.41 0.37 6.47 3 2 2 152045 14.31 1.08 16.80 2 2 2 151255 2.52 0.37 6.54 3 2 2 152045 14.34 1.07 16.76 2 2 2 151256 0.89 0.18 0.00 3 3 2 152046 12.97 1.08 16.85 2 2 2 151256 1.09 0.07 0.00 3 2 2 152046 13.03 1.08 16.79 2 2 2 151257 18.70 1.10 15.67 3 2 2 152047 11.74 1.10 16.91 2 2 2 151257 19.27 1.05 16.05 3 2 2 152047 11.56 1.06 16.92 2 2 2 151258 20.73 1.11 16.41 3 2 2 152048 10.16 1.07 16.60 2 2 2 151258 21.09 1.08 16.57 3 2 2 152048 10.10 1.17 16.68 2 2 2 151259 17.52 1.09 16.07 3 2 2 152049 10.75 1.09 16.91 2 2 2 151259 17.81 1.09 16.41 3 2 2 152049 10.89 1.33 16.88 2 2 2 151260 17.34 1.07 16.10 3 2 2 152050 10.41 1.05 16.36 2 2 2 151260 17.30 1.08 15.84 3 2 2 152050 10.44 1.03 16.43 2 2 2 151261 15.35 1.06 16.20 3 2 2 152051 10.63 1.04 16.93 2 2 2 151261 15.49 1.08 16.27 3 2 2 152051 10.82 1.04 17.13 2 2 2 151262 15.47 1.11 16.72 3 2 2 152052 10.58 1.04 17.03 2 2 2 151262 15.74 1.09 16.83 3 2 2 152052 11.29 1.04 17.08 2 2 2 151263 14.37 1.09 16.26 3 2 2 152053 10.14 1.04 16.81 2 2 2 151263 14.40 1.09 16.32 3 2 2 152053 10.11 1.03 16.95 2 2 2 151264 12.58 1.07 16.11 3 2 2 152054 11.18 1.10 17.73 2 2 2 151264 12.77 1.09 16.57 3 2 2 152054 11.42 1.10 17.70 2 2 2 151265 12.44 1.08 16.27 3 2 2 152055 11.45 1.11 18.60 2 2 2 151265 12.66 1.15 16.49 3 2 2 152055 11.32 1.12 18.12 2 2 2 151266 11.43 1.08 16.12 3 2 2 152056 12.35 1.18 19.61 2 2 2 151266 11.72 1.09 16.26 3 2 2 152056 12.15 1.18 19.41 2 2 2 151267 11.22 1.08 16.53 3 2 2 152057 12.31 1.27 20.25 2 2 2 151267 11.13 1.08 16.74 3 2 2 152057 12.40 1.26 20.06 2 2 2 151268 11.27 1.11 16.72 3 2 2 152058 5.91 0.75 13.50 2 2 2 151268 11.66 1.10 17.11 3 2 2 152058 6.02 0.75 13.72 2 2 2 151269 11.12 1.13 16.89 3 2 2 152059 3.69 0.53 9.77 2 2 2 151269 11.15 1.13 17.16 3 2 2 152059 3.73 0.52 9.75 2 2 2 151270 11.35 1.15 17.39 3 2 2 152060 0.93 0.10 0.00 2 2 2 151270 11.76 1.17 17.56 3 2 2 152060 0.96 0.10 0.00 2 2 2 151271 11.90 1.18 18.62 3 2 2 152061 18.28 1.00 16.32 2 2 2 151271 11.93 1.19 18.09 3 2 2 152061 18.11 1.01 18.08 2 2 3 151272 12.58 1.29 19.87 3 2 2 152062 18.25 1.01 16.50 2 2 2 151272 12.86 1.30 19.87 3 2 2 152062 18.47 1.02 16.74 2 2 2 151273 12.85 1.37 21.25 3 2 2 152063 5 5 5 151273 13.08 1.43 21.40 3 2 2 152063 19.40 1.05 17.00 2 2 2 151274 5.95 0.86 13.51 3 2 2 152064 17.94 1.04 16.73 2 2 2 151274 6.02 0.83 13.74 3 2 2 152064 18.08 1.03 16.89 2 2 2 151275 1.80 0.25 4.66 3 2 2 152065 11.80 1.04 17.36 2 2 2 151275 1.78 0.28 4.59 3 2 2 152065 11.68 1.04 17.31 2 2 2 151276 0.75 0.08 0.00 3 2 2 152066 13.64 1.04 16.72 2 2 2 151276 0.85 0.08 0.00 3 2 2 152066 13.70 1.02 16.98 2 2 2 151277 18.44 1.10 15.57 3 2 2 152067 11.15 1.01 16.48 2 2 2 151277 18.64 1.06 15.75 3 2 2 152067 11.28 1.04 16.37 2 2 2 151278 20.26 1.10 16.15 3 2 2 152068 11.83 1.04 16.88 2 2 2 151278 20.73 1.10 16.24 3 2 2 152068 12.01 1.04 16.79 2 2 2 151279 18.37 1.09 15.91 3 2 2 152069 5 5 5 151279 18.30 1.06 15.88 3 2 2 152069 5 5 5 151280 16.59 1.08 15.31 3 2 2 152070 11.39 1.04 17.15 2 2 2 151280 17.14 1.08 16.02 3 2 2 152070 11.43 1.04 16.97 2 2 2 151281 14.21 1.06 15.76 3 2 2 152071 11.23 1.08 17.69 2 2 2 151281 14.59 1.10 15.73 3 2 2 152071 11.15 1.07 17.63 2 2 2 151282 13.43 1.07 15.90 3 2 2 152072 11.37 1.09 17.86 2 2 2 151282 13.82 1.07 15.68 3 2 2 152072 11.29 1.10 17.92 2 2 2 151283 13.24 1.06 15.90 3 2 2 152073 11.58 1.12 18.20 2 2 2 151283 13.32 1.06 15.74 3 2 2 152073 11.60 1.13 18.24 2 2 2 151284 11.33 1.07 15.77 3 2 2 152074 11.73 1.16 18.73 2 2 2 151284 11.49 1.08 16.30 3 2 2 152074 11.78 1.16 18.59 2 2 2 151285 10.93 1.05 15.60 3 2 2 152075 12.07 1.29 19.55 2 2 2 151285 11.30 1.07 16.20 3 2 2 152075 12.13 1.23 19.79 2 2 2 151286 10.98 1.08 16.18 3 2 2 152076 11.46 1.20 19.47 2 2 2 151286 11.05 1.07 16.16 3 2 2 152076 11.48 1.20 19.57 2 2 2 151287 11.44 1.08 16.36 3 2 2 152077 5.85 0.74 12.42 2 2 2 151287 11.75 1.09 16.61 3 2 2 152077 5.85 0.76 12.36 2 2 2 151288 11.79 1.11 16.73 3 2 2 152078 3.96 0.55 9.58 2 2 2 151288 12.24 1.11 16.41 3 2 2 152078 3.98 0.56 9.61 2 2 2 151289 11.07 1.11 16.38 3 2 2 152079 1.57 0.23 3.60 2 2 2 151289 11.49 1.15 16.59 3 2 2 152079 1.60 0.23 3.73 2 2 2 151290 10.58 1.11 16.59 3 2 2 152080 0.95 0.09 0.00 2 2 2 151290 10.67 1.13 16.55 3 2 2 152080 0.95 0.09 0.00 2 2 2 151291 11.91 1.20 17.83 3 2 2 152081 17.14 0.99 15.88 2 2 2 151291 11.67 1.26 17.50 3 2 2 152081 17.47 1.00 15.64 2 2 2 151292 12.30 1.31 19.14 3 2 2 152082 19.36 1.03 16.76 2 2 2 151292 12.65 1.31 19.06 3 2 2 152082 19.38 1.04 16.51 2 2 2 151293 10.73 1.28 19.14 3 2 2 152083 19.04 1.03 16.39 2 2 2 151293 10.98 1.27 19.33 3 2 2 152083 19.49 1.05 16.44 2 2 2 151294 4.37 0.70 10.48 3 2 2 152084 18.26 1.03 16.41 2 2 2 151294 4.63 0.66 10.68 3 2 2 152084 18.24 1.05 16.54 2 2 2 151295 2.54 0.42 6.77 3 2 2 152085 16.98 1.06 16.98 2 2 2 151295 2.51 0.42 6.66 3 2 2 152085 17.09 1.06 17.05 2 2 2 151296 5 5 5 152086 14.89 1.05 16.93 2 2 2 151296 5 5 5 152086 15.27 1.04 17.10 2 2 2 151297 17.94 1.10 15.13 3 2 2 152087 13.03 1.02 16.52 2 2 2 151297 18.24 1.07 15.57 3 2 2 152087 13.24 1.03 16.47 2 2 2 151298 16.56 1.11 15.24 3 2 2 152088 12.71 1.05 16.65 2 2 2 151298 16.60 1.06 15.25 3 2 2 152088 12.84 1.06 16.93 2 2 2 151299 14.56 1.06 15.40 3 2 2 152089 11.58 1.05 16.66 2 2 2 151299 14.70 1.06 15.41 3 2 2 152089 11.60 1.04 16.96 2 2 2 151300 13.95 1.04 15.72 3 2 2 152090 11.21 1.05 16.86 2 2 2 151300 13.97 1.07 15.56 3 2 2 152090 11.25 1.04 16.93 2 2 2 151301 12.67 1.10 15.98 3 2 2 152091 11.32 1.06 16.88 2 2 2 151301 12.64 1.10 15.79 3 2 2 152091 11.34 1.06 16.54 2 2 2 151302 12.54 1.07 15.80 3 2 2 152092 11.08 1.07 17.41 2 2 2 151302 12.66 1.07 15.71 3 2 2 152092 11.04 1.08 17.51 2 2 2 151303 14.09 1.11 16.34 3 2 2 152093 11.30 1.08 17.64 2 2 2 151303 13.82 1.11 16.32 3 2 2 152093 11.30 1.09 17.79 2 2 2 151304 10.64 1.07 15.80 3 2 2 152094 11.80 1.15 18.75 2 2 2 151304 10.59 1.05 15.75 3 2 2 152094 12.19 1.16 18.76 2 2 2 151305 11.29 1.09 16.06 3 2 2 152095 12.18 1.20 19.29 2 2 2 151305 11.51 1.08 16.02 3 2 2 152095 12.25 1.17 19.24 2 2 2 151306 10.49 1.15 15.69 3 2 2 152096 12.06 1.30 20.72 2 2 2 151306 10.57 1.07 15.84 3 2 2 152096 11.93 1.27 21.03 2 2 2 151307 11.28 1.12 16.48 3 2 2 152097 8.15 0.98 16.16 2 2 2 151307 11.30 1.13 16.61 3 2 2 152097 8.16 0.98 16.14 2 2 2 151308 11.35 1.16 16.63 3 2 2 152098 5.12 0.71 11.84 2 2 2 151308 11.42 1.15 16.60 3 2 2 152098 5.15 0.71 11.97 2 2 2 151309 11.73 1.16 17.32 3 2 2 152099 2.91 0.42 7.23 2 2 2 151309 11.51 1.15 17.33 3 2 2 152099 2.97 0.44 7.18 2 2 2 151310 11.44 1.19 17.49 3 2 2 152100 1.23 0.16 1.86 2 2 2 151310 11.61 1.17 17.64 3 2 2 152100 1.24 0.16 1.80 2 2 2 151311 13.03 1.33 19.45 3 2 2 152101 19.23 1.03 16.43 2 2 2 151311 13.15 1.34 19.46 3 2 2 152101 19.44 1.06 16.76 2 2 2 151312 10.96 1.28 19.12 3 2 2 152102 18.84 1.07 16.68 2 2 2 151312 11.26 1.27 19.17 3 2 2 152102 18.98 1.09 16.81 2 2 2 151313 8.51 1.03 14.43 3 2 2 152103 17.66 1.06 16.88 2 2 2 151313 8.40 1.07 14.92 3 2 2 152103 17.87 1.08 16.97 2 2 2 151314 5.73 0.83 12.80 2 2 2 152104 15.75 1.05 16.83 2 2 2 151314 5.79 0.80 13.18 2 2 2 152104 15.84 1.06 16.86 2 2 2 151315 2.29 0.37 4.79 2 2 2 152105 13.95 1.06 16.81 2 2 2 151315 2.40 0.37 4.99 2 2 2 152105 14.05 1.06 16.66 2 2 2 151316 0.88 0.10 0.00 2 2 2 152106 13.19 1.06 16.69 2 2 2 151316 0.97 0.10 0.00 2 2 2 152106 13.22 1.06 16.84 2 2 2 151317 15.66 1.05 15.38 2 2 2 152107 11.48 1.05 16.63 2 2 2 151317 15.81 1.03 15.29 2 2 2 152107 11.62 1.05 16.72 2 2 2 151318 14.50 1.05 15.80 2 2 2 152108 10.61 1.05 16.49 2 2 2 151318 14.56 1.07 15.83 2 2 2 152108 10.75 1.06 16.63 2 2 2 151319 14.30 1.05 15.93 2 2 2 152109 11.05 1.08 16.97 2 2 2 151319 14.24 1.05 16.05 2 2 2 152109 11.14 1.07 16.76 2 2 2 151320 13.47 1.07 16.26 2 2 2 152110 11.10 1.07 17.25 2 2 2 151320 13.46 1.08 15.97 2 2 2 152110 11.03 1.08 17.33 2 2 2 151321 13.07 1.08 16.17 2 2 2 152111 5 5 5 151321 13.21 1.10 16.34 2 2 2 152111 11.05 1.08 17.59 2 2 2 151322 12.19 1.09 16.07 2 2 2 152112 11.14 1.11 17.71 2 2 2 151322 12.30 1.06 16.49 2 2 2 152112 11.25 1.11 17.69 2 2 2 151323 12.78 1.08 16.56 2 2 2 152113 11.58 1.18 18.02 2 2 2 151323 12.78 1.08 16.60 2 2 2 152113 11.69 1.14 18.18 2 2 2 151324 12.14 1.11 16.42 2 2 2 152114 11.84 1.18 18.53 2 2 2 151324 12.20 1.10 16.39 2 2 2 152114 11.92 1.17 18.84 2 2 2 151325 12.10 1.10 16.65 2 2 2 152115 12.07 1.22 18.69 2 2 2 151325 12.01 1.09 16.39 2 2 2 152115 12.21 1.22 18.95 2 2 2 151326 11.66 1.10 16.30 2 2 2 152116 9.70 1.13 18.06 2 2 2 151326 11.67 1.09 16.68 2 2 2 152116 9.78 1.12 18.06 2 2 2 151327 11.55 1.11 16.95 2 2 2 152117 5.54 0.74 12.03 2 2 2 151327 11.70 1.12 17.11 2 2 2 152117 5.52 0.76 12.11 2 2 2 151328 11.60 1.13 17.31 2 2 2 152118 3.26 0.51 8.30 2 2 2 151328 11.64 1.11 17.14 2 2 2 152118 3.32 0.50 8.32 2 2 2 151329 11.52 1.15 17.25 2 2 2 152119 2.09 0.37 5.59 2 2 2 151329 11.54 1.13 17.09 2 2 2 152119 2.09 0.35 5.70 2 2 2 151330 11.47 1.15 17.31 2 2 2 152120 0.79 0.11 0.00 2 2 2 151330 11.72 1.14 17.55 2 2 2 152120 0.84 0.11 0.00 2 2 2 151331 12.16 1.21 18.78 2 2 2 152121 22.88 1.10 17.03 2 2 2 151331 12.38 1.18 18.31 2 2 2 152121 22.94 1.10 17.43 2 2 2 151332 12.79 1.30 19.89 2 2 2 152122 23.19 1.14 17.73 2 2 2 151332 12.68 1.28 19.58 2 2 2 152122 23.33 1.13 17.58 2 2 2 151333 13.42 1.36 20.25 2 2 2 152123 22.01 1.17 17.27 2 2 2 151333 13.44 1.36 20.00 2 2 2 152123 22.20 1.15 17.54 2 2 2 151334 12.71 1.36 20.61 2 2 2 152124 21.58 1.16 17.82 2 2 2 151334 12.73 1.36 20.96 2 2 2 152124 21.66 1.16 17.91 2 2 2 151335 6.08 0.87 11.08 2 2 2 152125 18.44 1.14 17.74 2 2 2 151335 6.10 0.86 11.03 2 2 2 152125 18.40 1.17 17.62 2 2 2 151336 0.76 0.24 0.00 2 2 2 152126 15.72 1.13 17.45 2 2 2 151336 0.81 0.23 0.00 2 2 2 152126 15.85 1.12 17.41 2 2 2 151337 11.21 1.09 15.94 2 2 2 152127 13.75 1.12 17.38 2 2 2 151337 11.29 1.08 15.98 2 2 2 152127 14.00 1.12 17.26 2 2 2 151338 11.67 1.08 16.21 2 2 2 152128 12.74 1.14 17.30 2 2 2 151338 11.67 1.10 16.02 2 2 2 152128 12.86 1.14 17.34 2 2 2 151339 11.39 1.10 16.51 2 2 2 152129 11.69 1.13 17.32 2 2 2 151339 11.71 1.08 16.16 2 2 2 152129 11.61 1.11 17.29 2 2 2 151340 11.12 1.09 16.38 2 2 2 152130 10.68 1.09 16.89 2 2 2 151340 10.95 1.10 16.37 2 2 2 152130 10.91 1.11 17.19 2 2 2 151341 10.88 1.11 16.61 2 2 2 152131 10.62 1.13 16.82 2 2 2 151341 10.92 1.10 16.69 2 2 2 152131 10.63 1.10 16.95 2 2 2 151342 10.98 1.12 16.98 2 2 2 152132 10.86 1.10 17.35 2 2 2 151342 11.53 1.11 16.79 2 2 2 152132 10.87 1.12 17.31 2 2 2 151343 11.20 1.15 17.46 2 2 2 152133 10.97 1.13 17.84 2 2 2 151343 11.20 1.14 17.05 2 2 2 152133 11.07 1.14 18.11 2 2 2 151344 10.89 1.14 16.87 2 2 2 152134 11.00 1.14 18.18 2 2 2 151344 10.71 1.14 16.85 2 2 2 152134 11.14 1.15 18.60 2 2 2 151345 11.60 1.17 17.95 2 2 2 152135 11.36 1.23 19.32 2 2 2 151345 11.96 1.18 17.62 2 2 2 152135 11.42 1.21 19.31 2 2 2 151346 11.24 1.17 16.79 2 2 2 152136 11.72 1.32 20.45 2 2 2 151346 11.66 1.15 16.80 2 2 2 152136 11.78 1.28 20.39 2 2 2 151347 12.76 1.26 18.55 2 2 2 152137 11.57 1.28 20.58 2 2 2 151347 12.85 1.29 18.85 2 2 2 152137 11.57 1.29 20.70 2 2 2 151348 12.55 1.27 19.17 2 2 2 152138 11.15 1.30 20.71 2 2 2 151348 12.61 1.29 19.26 2 2 2 152138 11.26 1.28 20.65 2 2 2 151349 7.98 0.96 11.08 2 2 2 152139 4.58 0.71 11.15 2 2 2 151349 8.07 0.99 10.85 2 2 2 152139 4.71 0.71 11.35 2 2 2 151350 0.72 0.26 0.00 2 2 2 152140 2.11 0.42 6.45 2 2 2 151350 0.77 0.24 0.00 2 2 2 152140 2.14 0.41 6.44 2 2 2 151351 10.28 1.09 16.00 2 2 2 152141 18.42 1.06 16.27 2 2 2 151351 10.37 1.09 15.86 2 2 2 152141 18.34 1.08 16.36 2 2 2 151352 10.05 1.08 16.03 2 2 2 152142 24.21 1.15 17.61 2 2 2 151352 10.16 1.11 15.74 2 2 2 152142 24.26 1.15 17.58 2 2 2 151353 10.07 1.08 15.58 2 2 2 152143 20.22 1.11 17.33 2 2 2 151353 10.22 1.10 15.63 2 2 2 152143 20.47 1.11 16.92 2 2 2 151354 10.27 1.11 15.83 2 2 2 152144 20.45 1.12 17.14 2 2 2 151354 10.34 1.11 15.70 2 2 2 152144 20.62 1.14 17.57 2 2 2 151355 10.92 1.12 15.28 2 2 2 152145 18.45 1.13 17.53 2 2 2 151355 11.10 1.10 15.47 2 2 2 152145 18.09 1.14 17.23 2 2 2 151356 11.93 1.09 14.63 2 2 2 152146 17.89 1.12 17.37 2 2 2 151356 11.41 1.12 14.92 2 2 2 152146 17.82 1.12 17.58 2 2 2 151357 10.89 1.04 12.95 2 2 2 152147 15.28 1.10 17.07 2 2 2 151357 11.08 1.07 12.89 2 2 2 152147 15.50 1.12 17.45 2 2 2 151358 9.99 1.05 9.07 2 2 2 152148 13.76 1.11 17.44 2 2 2 151358 10.01 1.05 9.20 2 2 2 152148 13.78 1.14 17.51 2 2 2 151359 1.36 0.40 0.00 2 2 2 152149 12.24 1.11 17.38 2 2 2 151359 1.37 0.40 0.00 2 2 2 152149 12.34 1.10 17.30 2 2 2 151360 10.35 1.11 15.38 2 2 2 152150 12.61 1.11 17.46 2 2 2 151360 10.30 1.11 15.88 2 2 2 152150 12.72 1.12 17.48 2 2 2 151361 10.29 1.10 15.90 2 2 2 152151 11.72 1.11 17.38 2 2 2 151361 10.25 1.11 15.93 2 2 2 152151 11.51 1.10 17.29 2 2 2 151362 10.16 1.10 15.68 2 2 2 152152 11.44 1.11 17.52 2 2 2 151362 10.18 1.10 15.28 2 2 2 152152 11.53 1.15 17.64 2 2 2 151363 10.87 1.11 15.48 2 2 2 152153 11.30 1.14 17.78 2 2 2 151363 10.89 1.09 15.70 2 2 2 152153 11.23 1.16 17.88 2 2 2 151364 11.39 1.10 14.88 2 2 2 152154 11.44 1.18 18.70 2 2 2 151364 11.41 1.13 14.92 2 2 2 152154 11.33 1.16 18.23 2 2 2 151365 9.75 1.04 8.98 2 2 2 152155 11.70 1.21 19.06 2 2 2 151365 9.77 1.04 9.03 2 2 2 152155 12.02 1.22 18.77 2 2 2 151366 2.17 0.50 0.75 2 2 2 152156 11.97 1.30 20.47 2 2 2 151366 2.11 0.49 0.64 2 2 2 152156 12.02 1.28 20.22 2 2 2 151367 10.86 1.11 14.62 2 2 2 152157 10.72 1.23 19.43 2 2 2 151367 10.89 1.11 14.91 2 2 2 152157 10.78 1.24 19.52 2 2 2 151368 11.65 1.11 15.07 2 2 2 152158 5.89 0.84 13.35 2 2 2 151368 11.51 1.11 15.02 2 2 2 152158 5.99 0.82 13.40 2 2 2 151369 11.72 1.11 13.89 2 2 2 152159 1.91 0.34 5.67 2 2 2 151369 11.63 1.09 14.28 2 2 2 152159 1.89 0.35 5.58 2 2 2 151370 9.63 1.04 8.35 2 2 2 152160 0.83 0.13 0.48 2 2 2 151370 9.78 1.02 8.40 2 2 2 152160 0.98 0.13 0.42 2 2 2 151371 11.31 1.07 12.88 2 2 2 152161 31.92 1.28 19.15 2 2 2 151371 11.40 1.08 12.99 2 2 2 152161 31.41 1.26 18.99 2 2 2 151372 9.96 1.06 9.71 2 2 2 152162 27.66 1.25 18.36 2 2 2 151372 9.99 1.05 9.86 2 2 2 152162 28.10 1.24 18.46 2 2 2 151373 1.28 0.38 0.00 2 2 2 152163 23.50 1.18 17.55 2 2 2 151373 1.30 0.35 0.00 2 2 2 152163 23.74 1.20 17.69 2 2 2 151374 15.09 1.11 11.50 2 2 2 152164 22.33 1.20 18.02 2 2 2 151374 15.05 1.11 11.48 2 2 2 152164 22.96 1.20 18.05 2 2 2 151375 8.68 1.03 7.99 2 2 2 152165 20.16 1.18 17.79 2 2 2 151375 8.71 1.01 8.09 2 2 2 152165 20.25 1.16 17.74 2 2 2 151376 0.79 0.33 0.00 2 2 2 152166 5 5 5 151376 0.72 0.35 0.00 2 2 2 152166 16.37 1.14 16.87 2 2 2 151377 10.99 1.00 11.66 2 2 2 152167 14.54 1.12 17.08 2 2 2 151377 11.24 1.00 11.97 2 2 2 152167 14.65 1.18 17.50 2 2 2 151378 5.23 0.90 5.96 3 3 3 152168 13.77 1.20 17.77 2 2 2 151378 5.29 0.93 5.74 3 3 3 152168 13.99 1.15 17.78 2 2 2 151379 0.80 0.35 -0.06 3 3 3 152169 11.69 1.12 17.43 2 2 2 151379 0.80 0.34 0.04 3 3 3 152169 11.70 1.08 16.98 2 2 2 151380 10.28 0.98 11.97 2 2 2 152170 11.15 1.13 17.46 2 2 2 151380 10.37 0.98 11.67 2 2 2 152170 11.19 1.13 17.24 2 2 2 151381 10.63 1.01 10.87 2 2 2 152171 10.74 1.13 17.30 2 2 2 151381 10.77 1.01 10.79 2 2 2 152171 10.82 1.13 17.29 2 2 2 151382 10.88 1.05 9.47 2 2 2 152172 11.36 1.17 17.76 2 2 2 151382 11.05 1.07 9.23 2 2 2 152172 11.61 1.18 17.82 2 2 2 151383 13.17 1.08 15.00 2 2 2 152173 11.69 1.21 18.94 2 2 2 151383 13.21 1.10 15.29 2 2 2 152173 11.73 1.28 18.86 2 2 2 151384 12.68 1.05 14.42 2 2 2 152174 12.81 1.34 20.08 2 2 2 151384 12.35 1.06 14.22 2 2 2 152174 12.72 1.31 20.25 2 2 2 151385 7.93 0.94 9.74 2 2 2 152175 14.01 1.45 23.13 2 2 2 151385 8.00 0.94 9.94 2 2 2 152175 13.75 1.49 22.93 2 2 2 151386 1.92 0.42 0.78 2 2 2 152176 8.57 1.11 16.49 2 2 2 151386 2.04 0.40 0.98 2 2 2 152176 8.59 1.09 16.62 2 2 2 151387 9.78 1.06 15.47 2 2 2 152177 4.58 0.70 11.24 2 2 2 151387 9.89 1.06 16.01 2 2 2 152177 4.58 0.70 11.51 2 2 2 151388 9.37 1.05 15.82 2 2 2 152178 1.99 0.31 5.15 2 2 2 151388 9.51 1.05 16.23 2 2 2 152178 2.03 0.32 5.13 2 2 2 151389 8.63 1.04 15.60 2 2 2 152179 1.82 0.27 4.50 2 2 2 151389 8.80 1.03 15.67 2 2 2 152179 1.88 0.27 4.43 2 2 2 152180 0.94 0.09 0.00 2 2 2 152180 0.93 0.15 0.00 2 2 2 5. Dissolved Inorganic Carbon in Seawater Bob Gershey a. Description of Equipment and Technique The total dissolved inorganic carbon content of seawater was defined as the total concentration of carbonate ion, bicarbonate ion and unionized species of carbon dioxide. Before analysis, the sample was treated with acid to convert all ionized species to the unionized form, which was then separated from the liquid phase and subsequently measured by the coulometric titration technique. This involved the reaction of carbon dioxide gas with a dimethysulfoxide solution of ethanoline to produce hydroxyethylcarbamic acid. The acidic solution was titrated with hydroxide ion formed by the electrolytic decomposition of water. The progress of the titration was followed through colorimetric measurement of the absorbance of a Ph indicator dye (thymolphthalein) in the ethanolamine solution. A known volume of seawater was dispensed into a stripping chamber from a pipet of known volume and temperature controlled to within 0.4 C. It was then acidified with ten percent of its volume with an eight percent solution of carbon dioxide-free phosphoric acid. The solution was stripped of carbon dioxide gas by bubbling with a stream of nitrogen gas directed through a glass frit. The carrier gas exiting the stripper passed through a magnesium perchlorate trap which removed water vapour and acidic water droplets. The gas stream was then directed into the coulometric titrator where the total amount of carbon dioxide gas was quantified. The coulometer was calibrated in two ways. Calibration using gas loops was accomplished by filling stainless steel sample loops (1.5, 2.5 ml) with 99.995% carbon dioxide gas and injecting these into the coulometer. The temperature and pressure of the gas within the loops must be known to within 0.05 C and 20 Pa respectively. Standard solutions of sodium carbonate were also used to calibrate the system. These samples were treated in the same manner as a seawater sample. Values were reported in units of mol/kg. The overall precision of the analysis should have been at least 1.5 mol/kg for samples with concentrations in the range of 1800-2300 mol/kg. b. Sampling Procedure and Data Processing Technique Water samples were initially collected using a Niskin bottle or similar sampler. Samples for analysis of total inorganic carbon were taken as soon as possible after recovery of the samples to minimize exchange of carbon dioxide gas with the head space in the sampler which would typically result in a loss of carbon dioxide. It was desirable that the samples be drawn before half the sampler was emptied and within ten minutes of recovery. Clean borosilicate glass bottles were rinsed twice with 30 - 50 ml of the sample. The bottle was then filled from the bottom using a length of vinyl tubing attached to the spigot of the sampler. The sample was overflowed by at least one half of the volume of the bottle (typically 250 ml). A head space of one percent was left to allow for expansion without leakage. If samples were not to be analyzed within four to five hours, the samples were poisoned with 100 l/250 ml of 50% saturated mercuric chloride solution. The bottle was tightly sealed and stored near the temperature of collection. c. Replicate Analysis In total, 105 replicate carbonate measurements were obtained for 99 sample id numbers. Six sample id numbers had two replicates, while the remaining 93 sample id numbers only had one replicate. The replicate for sample id number, 151847 (1 replicate), could not be obtained because of a system malfunction. Thus, only 98 sample id numbers were available to be used in calculating replicate difference statistics. The following is a statistical summary of the absolute value of the differences between replicates. Table C.4 lists all replicate measurements. Number of Replicate Differences = 6 ids had two replicates * 3 possible differences + 92 ids had one replicate * 1 possible difference = 18 + 92 = 110 Statistic Value Number of Replicate Differences 110 Minimum (moles/kg) 0 Maximum (moles/kg) 290.2 Mean (moles/kg) 12.8 Median (moles/kg) 1.1 Standard Deviation (moles/kg) 46.8 Table C.4 Replicate water sample total carbon values in moles/kg. Sample ID Total WOCE Sample ID Total WOCE Number Carbon QF Number Carbon QF 150625 2158.7 2 151382 2130.5 2 150625 2158.6 2 151382 2130.3 2 150659 2165.7 2 151385 2116.5 2 150659 2167.5 2 151385 2117.9 2 150664 2123.6 2 151389 2147.5 2 150664 2130.3 2 151389 2148.0 2 150675 2161.6 2 151393 2151.1 2 150675 2162.4 2 151393 2151.6 2 150710 2156.5 2 151402 2150.9 2 150710 2156.9 2 151402 2152.2 2 150714 2165.2 2 151402 2153.0 2 150714 2166.0 2 151410 1998.4 2 150727 2162.0 2 151410 1998.3 2 150727 2160.7 2 151412 1912.2 2 150731 2138.2 2 151412 2151.7 2 150731 2170.0 2 151422 2149.6 2 150748 2157.2 2 151422 2150.4 2 150748 2157.6 2 151425 2152.7 2 150759 2184.6 2 151425 2153.0 2 150759 2184.7 2 151437 2152.2 2 150762 2166.1 2 151437 2152.5 2 150762 2168.1 2 151456 2150.5 2 150764 2153.1 2 151456 2151.7 2 150764 2155.4 2 151494 2161.3 2 150801 2181.3 2 151494 2161.7 2 150801 2178.2 2 151498 2154.6 2 150803 2170.4 2 151498 2156.2 2 150803 2169.2 2 151501 1939.5 2 150819 2183.9 2 151501 1954.1 2 150819 2185.2 2 151501 2150.4 2 150839 2169.1 2 151516 2155.2 2 150839 2169.4 2 151516 2156.3 2 150862 2162.2 2 151556 2157.6 2 150862 2164.0 2 151556 2159.0 2 150912 2172.8 2 151566 2158.9 2 150912 2174.3 2 151566 2159.7 2 150922 2165.4 2 151574 2162.9 2 150922 2165.5 2 151574 2163.9 2 150932 2177.8 2 151590 2098.5 2 150932 2179.3 2 151590 2099.3 2 150940 2175.2 2 151594 2171.4 2 150940 2174.9 2 151594 2167.1 2 150953 2140.9 2 151628 2171.1 2 150953 2142.0 2 151628 2172.0 2 150963 2160.5 2 151635 2161.0 2 150963 2160.9 2 151635 2162.0 2 150988 2157.3 2 151655 2121.6 2 150988 2158.9 2 151655 2124.2 2 150992 2176.3 2 151667 2078.9 2 150992 2176.5 2 151667 2082.8 2 150999 2179.2 2 151675 1879.5 2 150999 2180.3 2 151675 2169.7 2 151025 2158.2 2 151696 2167.6 2 151025 2158.3 2 151696 2168.3 2 151025 2159.4 2 151717 2161.9 2 151039 2057.7 2 151717 2162.0 2 151039 2178.2 2 151719 2157.8 2 151039 2178.8 2 151719 2159.8 2 151046 2152.4 2 151757 2168.0 2 151046 2153.2 2 151757 2169.9 2 151076 2022.5 2 151783 2151.2 2 151076 2024.6 2 151783 2153.9 2 151082 2158.4 2 151800 2154.5 2 151082 2160.4 2 151800 2156.0 2 151098 2164.9 2 151815 2162.7 2 151098 2166.3 2 151815 2163.9 2 151121 2166.8 2 151840 2158.3 2 151121 2165.7 2 151840 2157.6 2 151122 2136.7 2 151847 5 151122 2157.9 2 151847 2167.3 2 151122 2163.0 2 151856 2164.6 2 151147 2149.3 2 151856 2164.9 2 151147 2150.6 2 151874 2161.5 2 151147 2157.9 2 151874 2162.0 2 151165 2154.5 2 151897 2152.9 2 151165 2154.9 2 151897 2154.8 2 151187 2154.4 2 151933 2151.0 2 151187 2157.8 2 151933 2151.0 2 151217 2174.3 2 151936 2152.7 2 151217 2174.4 2 151936 2153.3 2 151225 2153.0 2 151952 2150.9 2 151225 2154.1 2 151952 2151.0 2 151241 2158.1 2 151981 2156.8 2 151241 2158.7 2 151981 2157.1 2 151252 2161.7 2 152023 2155.5 2 151252 2161.9 2 152023 2156.4 2 151256 2025.7 2 152042 2156.8 2 151256 2027.3 2 152042 2158.9 2 151282 2152.2 2 152065 2158.8 2 151282 2151.5 2 152065 2158.6 2 151322 2149.4 2 152082 2159.0 2 151322 2152.1 2 152082 2160.4 2 151340 2151.6 2 152105 2155.0 2 151340 2152.8 2 152105 2156.0 2 151356 2148.8 2 152116 2160.6 2 151356 2149.3 2 152116 2161.3 2 151367 2149.2 2 152132 2153.6 2 151367 2149.4 2 152132 2154.1 2 151371 2133.7 2 152155 2168.4 2 151371 2134.8 2 152155 2172.5 2 151378 2108.5 2 152164 2168.5 2 151378 2107.2 2 152164 2167.4 2 6. Alkalinity Frank Zemlyak a. Description of Equipment and Technique Total alkalinity was determined using the Marine Chemistry automated titration system. A potentiometric titration of the sea water sample using hydrochloric acid was utilized to determine the total alkalinity. Once the sample was connected to the system, the operation proceeded automatically, from the glass reaction vessel being rinsed and filled with the sea water sample, to the final calculations at the conclusion of the titration. When the reaction vessel was filled, the semi-micro combination Ross electrode senses when the sample had come to equilibrium and the initial relative mvolt reading was logged, at the same time, the cell temperature was also recorded. At this point, a rather large quantity of 0.2N hydrochloric acid, was added to the cell via a Metrohm E-655 Dosimat. The increase in volume was accommodated by the withdrawal, by a stepper motor via an ACME lead screw, of an internal glass piston. This large quantity of acid added titrated the sample beyond the carbonate endpoint. Next, smaller aliquots (0.040mL) of acid were added until the sample had been titrated to and beyond the second inflection point. With each addition of acid the sample was allowed to come to equilibrium and the mvolt reading was logged. Thus, with these relative changes in the voltage in the cell, the endpoint was calculated by using a modified Gran function. Corrections to the final total alkalinity result were made by using the sample salinity, sample temperature and the nutrients, silicate and phosphate. b. Sampling Procedure and Data Processing Technique The 500 ml samples used for alkalinity analysis were collected from eight litre Niskin bottles in much the same fashion as oxygen samples. The samples were stored in a cold water bath whilst awaiting analysis. Note: The alkalinity data is currently under quality review. c. Replicate Analysis No replicate information is currently available. 7. CFC's Mike Hingston a. Description of Equipment and Technique The analyses were carried out on two purge and trap systems developed at the Bedford Institute of Oceanography. The water samples were injected into the systems directly from the syringes. To ensure proper rinsing, at least two volumes of water were passed through the sample pipette before the actual sample volume. The samples were purged for four minutes with ultra high purity nitrogen at a flow rate of 60 ml/min. The components were trapped in Porapak-N trap which was cooled to a temperature of less than 10C. They were then desorbed by heating the trap up to at least 170C. The contents of the trap were then passed through a 75m DB-624 megabore column. b. Sampling Procedure and Data Processing Technique All samples were collected directly from the Niskin bottles using 100 ml syringes. The syringes were rinsed three times before they were filled. To prevent contamination, the CFC samples were the first samples collected from the Niskin bottles. The samples were then stored in a water bath of continuously flowing surface sea water until analysis. Air samples from the winch room were taken periodically to ensure that it had not become contaminated. The analysis of the samples was always completed within 24 hours after they had been drawn. c. Replicate Analysis A total of 81 sample id numbers had replicate CFC water samples drawn. In total, 13 sample id numbers had duplicate samples drawn and 68 sample id numbers had triplicate samples drawn. Replicates were taken at each station, with some of these being run on each system to ensure that the results were comparable. The following is a statistical summary, in pmoles/kg, of the absolute value of the replicate differences. Only acceptable sample values were used when calculating replicate differences. The sample id numbers having replicate measurements are listed in Table C.5. Statistic CFC11 CFC12 CFC113 Carbon Tet. Methyl Chl. Number of Replicate Differences 209 206 205 209 207 Minimum (pmoles/kg) 0.000 0.001 0 0.003 0.004 Maximum (pmoles/kg) 0.603 0.612 0.126 1.089 10.480 Mean (pmoles/kg) 0.076 0.095 0.025 0.161 2.660 Median (pmoles/kg) 0.039 0.077 0.019 0.100 2.170 Standard Deviation (pmoles/kg) 0.099 0.090 0.025 0.186 2.428 Detection Limits (pmoles/kg) 0.022 0.017 0.010 0.040 0.017 Table C.5 Replicate CFC samples in pmoles/kg. Sample Carbon Methyl ID Number Freon 11 Freon 12 Freon 113 Tetrachloride Chloroform WOCE QF 150621 5.017 3.029 0.401 7.131 21.452 2 2 2 2 2 150621 4.912 2.868 0.396 6.972 20.863 2 2 2 2 2 150628 3.092 1.628 0.258 4.190 9.246 2 2 2 2 2 150628 3.257 1.551 0.229 4.350 7.040 2 2 2 2 2 150640 2.144 0.118 3.482 4.366 2 5 2 2 2 150640 2.368 0.994 0.089 3.273 8.964 2 2 2 2 2 150653 0.559 0.628 0.019 1.309 2.203 2 2 2 2 2 150653 0.539 0.747 0.020 1.388 1.766 2 2 2 2 2 150653 0.552 0.721 0.000 1.548 1.212 2 2 2 2 2 150674 0.395 0.354 0.000 0.877 0.668 2 2 2 2 2 150674 0.392 0.373 0.000 1.006 1.238 2 2 2 2 2 150674 0.392 0.447 0.000 1.028 1.568 2 2 2 2 2 150700 1.724 0.949 0.037 2.531 1.807 2 2 2 2 2 150700 1.777 0.967 0.055 2.853 7.215 2 2 2 2 2 150700 1.783 0.939 0.044 2.816 2.489 2 2 2 2 2 150711 3.335 1.737 0.190 5.081 13.760 2 2 2 2 2 150711 3.359 1.786 0.281 5.085 14.490 2 2 2 2 2 150730 0.791 0.472 0.189 0.848 3.034 2 2 2 2 2 150730 0.796 0.650 0.096 0.843 4.409 2 2 2 2 2 150730 0.768 0.524 0.062 0.799 2.132 2 2 2 2 2 150743 0.741 0.663 0.035 1.509 0.993 2 2 2 2 2 150743 0.782 0.417 0.017 1.727 2.924 2 2 2 2 2 150743 0.787 0.428 0.022 1.594 0.205 2 2 2 2 2 150774 1.724 0.972 0.000 0.320 2.861 2 2 2 2 2 150774 1.749 0.976 0.020 0.416 3.402 2 2 2 2 2 150774 1.763 0.803 0.012 0.389 4.241 2 2 2 2 2 150783 0.331 0.231 0.000 0.886 0.000 2 2 2 2 2 150783 0.331 0.232 0.012 0.953 1.714 2 2 2 2 2 150801 0.339 0.288 0.014 0.911 1.508 2 2 2 2 2 150801 0.338 0.217 0.000 0.946 1.653 2 2 2 2 2 150801 0.308 0.197 0.000 0.858 0.000 2 2 2 2 2 150830 1.349 0.791 0.029 2.170 1.279 2 2 2 2 2 150830 1.317 0.710 0.035 2.294 5.234 2 2 2 2 2 150844 0.938 0.458 0.051 2.066 2.881 2 2 2 2 2 150844 0.956 0.560 0.045 1.936 3.259 2 2 2 2 2 150844 0.969 0.654 0.043 1.976 3.187 2 2 2 2 2 150869 1.232 0.701 0.051 2.264 4.899 2 2 2 2 2 150869 1.143 0.624 0.074 2.117 2.256 2 2 2 2 2 150869 1.160 0.641 0.046 2.017 1.164 2 2 2 2 2 150891 1.330 0.643 0.077 2.012 6.851 2 2 2 2 2 150891 1.276 0.573 0.056 1.944 4.829 2 2 2 2 2 150891 1.278 0.690 0.044 1.963 5.319 2 2 2 2 2 150904 0.330 0.219 0.028 1.019 2.764 2 2 2 2 2 150904 0.269 0.227 0.000 0.899 1.636 2 2 2 2 2 150904 0.316 0.109 0.042 0.933 2.147 2 2 2 2 2 150924 0.477 0.223 0.000 0.847 1.072 2 2 2 2 2 150924 0.444 0.251 0.014 0.785 1.701 2 2 2 2 2 150924 0.451 0.226 0.013 0.781 1.698 2 2 2 2 2 150945 0.299 0.169 0.018 0.000 1.157 2 2 2 2 2 150945 0.315 0.284 0.020 0.781 0.143 2 2 2 2 2 150945 0.321 0.158 0.000 0.882 1.308 2 2 2 2 2 150964 0.349 0.231 0.000 0.895 1.288 2 2 2 2 2 150964 0.357 0.278 0.000 0.905 1.530 2 2 2 2 2 150964 0.366 0.356 0.000 0.774 0.000 2 2 2 2 2 150985 5 5 5 5 5 150985 0.204 0.144 0.000 0.697 0.859 2 2 2 2 2 150985 0.213 0.068 0.012 0.842 0.575 2 2 2 2 2 151010 1.123 0.516 0.044 1.792 0.943 2 2 2 2 2 151010 1.177 0.646 0.057 1.890 4.489 2 2 2 2 2 151010 1.214 0.703 0.065 1.877 4.785 2 2 2 2 2 151033 1.784 1.088 0.089 1.143 3.655 2 2 2 2 2 151033 1.808 1.255 0.061 0.898 1.484 2 2 2 2 2 151033 2.049 1.220 0.126 0.946 6.272 2 2 2 2 2 151047 1.869 0.935 0.060 3.322 1.646 2 2 2 2 2 151047 1.881 0.994 0.178 3.221 8.329 2 2 2 2 2 151047 1.895 0.972 0.182 3.280 8.533 2 2 2 2 2 151063 1.042 0.544 0.061 2.019 4.679 2 2 2 2 2 151063 1.056 0.607 0.024 2.349 2.344 2 2 2 2 2 151063 1.065 0.596 0.030 2.243 1.049 2 2 2 2 2 151083 0.379 0.149 0.000 1.076 0.560 2 2 2 2 2 151083 0.418 0.266 0.015 1.056 1.609 2 2 2 2 2 151083 0.426 0.280 0.016 1.069 1.518 2 2 2 2 2 151100 0.726 0.409 0.045 1.578 3.103 2 2 2 2 2 151100 0.689 0.402 0.000 1.981 0.820 2 2 2 2 2 151100 0.623 0.286 0.000 1.392 0.000 2 2 2 2 2 151131 1.010 0.551 0.031 1.070 3.861 2 2 2 2 2 151131 1.016 0.564 0.035 1.072 3.956 2 2 2 2 2 151131 0.886 0.481 0.028 0.820 0.000 2 2 2 2 2 151145 1.447 0.720 0.048 3.095 1.102 2 2 2 2 2 151145 1.502 0.808 0.065 3.649 3.659 2 2 2 2 2 151145 1.636 0.827 0.089 2.958 6.633 2 2 2 2 2 151171 1.218 0.781 0.027 1.766 0.529 2 2 2 2 2 151171 1.259 0.687 0.050 1.595 4.467 2 2 2 2 2 151171 1.277 0.750 0.036 1.600 4.484 2 2 2 2 2 151189 1.323 0.931 0.030 1.759 4.815 2 2 2 2 2 151189 1.265 0.791 0.065 1.774 2.578 2 2 2 2 2 151189 1.267 0.624 0.052 1.631 2.222 2 2 2 2 2 151203 0.609 0.356 0.000 1.366 2.550 2 2 2 2 2 151203 0.599 0.323 0.023 1.334 2.624 2 2 2 2 2 151203 0.547 0.258 0.024 1.243 0.213 2 2 2 2 2 151246 0.843 0.597 0.038 2.188 0.915 2 2 2 2 2 151246 0.904 0.600 0.040 1.988 3.631 2 2 2 2 2 151246 1.176 1.209 0.152 2.725 3.762 2 2 2 2 2 151263 0.728 0.511 0.041 1.618 3.084 2 2 2 2 2 151263 0.739 0.464 0.052 1.680 3.061 2 2 2 2 2 151263 0.746 0.479 0.010 1.698 0.457 2 2 2 2 2 151283 1.083 0.409 0.017 2.060 0.087 2 2 2 2 2 151283 1.106 0.693 0.046 2.040 4.567 2 2 2 2 2 151313 1.972 0.988 0.095 1.930 1.965 2 2 2 2 2 151313 2.152 1.124 0.121 1.976 7.476 2 2 2 2 2 151313 2.165 1.038 0.132 1.966 7.830 2 2 2 2 2 151336 2.512 1.527 0.213 3.753 3.963 2 2 2 2 2 151336 2.711 1.448 0.226 4.307 9.336 2 2 2 2 2 151357 4.660 2.484 0.410 6.422 7.908 2 2 2 2 2 151357 4.705 2.249 0.466 6.369 17.318 2 2 2 2 2 151357 4.568 2.602 0.654 6.339 17.892 2 2 3 2 2 151364 4.145 2.001 0.324 4.726 9.435 2 2 2 2 2 151364 4.147 2.143 0.304 5.811 15.376 2 2 2 2 2 151364 4.157 1.942 0.330 4.722 10.700 2 2 2 2 2 151373 3.877 1.965 0.329 4.713 12.737 2 2 2 2 2 151373 3.953 1.879 0.336 4.775 11.516 2 2 2 2 2 151375 5.356 2.758 0.418 6.105 18.463 2 2 2 2 2 151375 4.765 2.642 0.441 6.681 14.336 2 2 2 2 2 151375 5.368 2.640 0.413 6.131 18.592 2 2 2 2 2 151386 4.264 3.232 0.405 6.294 8.061 2 2 2 2 2 151386 4.644 3.076 0.379 5.762 14.312 2 2 2 2 2 151389 3.629 1.946 0.319 4.965 6.252 2 2 2 2 2 151389 3.707 2.230 0.319 5.244 5.820 2 2 2 2 2 151396 3.275 1.925 0.241 4.494 3.533 2 2 2 2 2 151396 3.454 1.924 0.254 4.754 3.004 2 2 2 2 2 151396 3.724 2.019 0.251 4.767 13.483 2 2 2 2 2 151406 2.811 1.508 0.182 3.336 10.557 2 2 2 2 2 151406 2.839 1.421 0.162 3.289 10.414 2 2 2 2 2 151406 2.537 1.391 0.160 3.230 1.828 2 2 2 2 2 151407 2.605 1.224 0.120 3.472 9.473 2 2 2 2 2 151407 2.285 1.119 0.109 3.729 6.702 2 2 2 2 2 151416 2.194 1.041 0.133 2.970 5.103 2 2 2 2 2 151416 2.235 1.112 0.136 2.950 4.169 2 2 2 2 2 151416 2.521 1.324 0.124 3.063 9.177 2 2 2 2 2 151423 2.483 1.114 0.107 3.850 3.734 2 2 2 2 2 151423 2.530 1.147 0.130 3.953 4.583 2 2 2 2 2 151423 2.706 1.343 0.113 3.881 11.291 2 2 2 2 2 151440 1.612 0.710 0.051 2.750 2.205 2 2 2 2 2 151440 1.720 0.911 0.069 2.765 7.011 2 2 2 2 2 151440 1.723 0.910 0.039 2.719 6.623 2 2 2 2 2 151466 2.329 1.392 0.091 3.593 3.305 2 2 2 2 2 151466 2.344 1.511 0.105 3.982 4.953 2 2 2 2 2 151466 2.546 1.393 0.147 3.535 10.831 2 2 2 2 2 151483 5 5 5 5 5 151483 1.848 0.992 0.118 3.377 7.878 2 2 2 2 2 151483 1.865 1.001 0.119 3.224 7.628 2 2 2 2 2 151496 1.023 0.409 0.094 2.193 3.460 2 2 2 2 2 151496 0.678 0.308 0.019 1.504 2.687 2 2 2 2 2 151496 0.723 0.417 0.029 1.543 2.962 2 2 2 2 2 151522 1.421 0.728 0.102 2.686 6.372 2 2 2 2 2 151522 1.413 0.675 0.046 2.559 1.683 2 2 2 2 2 151522 1.407 0.732 0.113 2.586 6.012 2 2 2 2 2 151552 2.114 1.338 0.134 3.112 1.889 2 2 2 2 2 151552 2.135 1.198 0.187 3.169 8.680 2 2 2 2 2 151552 2.225 1.527 0.175 3.706 4.998 2 2 2 2 2 151563 1.369 0.775 0.042 2.533 1.344 2 2 2 2 2 151563 1.411 0.684 0.070 2.596 6.529 2 2 2 2 2 151563 1.458 0.760 0.064 2.740 6.971 2 2 2 2 2 151585 1.274 0.611 0.157 2.179 6.235 2 2 2 2 2 151585 1.294 0.607 0.059 2.256 3.545 2 2 2 2 2 151585 1.295 0.589 0.040 1.971 0.973 2 2 2 2 2 151606 1.408 0.751 0.053 1.847 0.879 2 2 2 2 2 151606 1.473 0.685 0.126 1.907 5.703 2 2 2 2 2 151606 1.479 0.729 0.107 1.928 5.783 2 2 2 2 2 151629 1.004 0.804 0.026 0.765 0.000 2 2 2 2 2 151629 1.021 0.603 0.066 0.956 0.832 2 2 2 2 2 151629 1.073 0.657 0.083 0.807 3.934 2 2 2 2 2 151640 0.744 0.395 0.011 1.572 2 2 2 2 5 151640 0.776 0.402 0.016 1.725 3.280 2 2 2 2 2 151640 0.777 0.419 0.011 1.673 3.163 2 2 2 2 2 151670 1.854 1.167 0.040 0.785 1.248 2 2 2 2 2 151670 1.905 1.039 0.066 0.833 2.267 2 2 2 2 2 151670 1.982 1.159 0.062 0.876 4.865 2 2 2 2 2 151679 0.776 0.536 0.000 1.810 1.106 2 2 2 2 2 151679 0.780 0.452 0.048 1.625 3.239 2 2 2 2 2 151679 0.789 0.437 0.051 1.699 3.375 2 2 2 2 2 151709 1.222 0.426 0.000 0.660 4.568 2 2 2 2 2 151709 1.278 0.737 0.000 0.717 4.304 2 2 2 2 2 151709 1.168 0.700 0.034 0.785 3.855 2 2 2 2 2 151721 5 5 5 5 5 151721 1.379 0.696 0.048 2.707 5.636 2 2 2 2 2 151721 1.386 0.780 0.045 2.591 5.517 2 2 2 2 2 151748 1.158 0.837 0.031 0.978 0.833 2 2 2 2 2 151748 1.191 0.728 0.070 1.125 2.503 2 2 2 2 2 151748 1.235 0.685 0.093 1.045 4.576 2 2 2 2 2 151758 5 5 5 5 5 151758 0.625 0.319 0.028 1.384 2.351 2 2 2 2 2 151758 0.636 0.404 0.011 1.803 0.976 2 2 2 2 2 151786 1.790 0.857 0.061 3.386 4.361 2 2 2 2 2 151786 1.821 1.048 0.067 3.567 5.551 2 2 2 2 2 151786 1.944 1.007 0.094 3.321 8.157 2 2 2 2 2 151797 1.512 0.815 0.058 2.593 6.252 2 2 2 2 2 151797 1.552 0.757 0.072 2.671 6.350 2 2 2 2 2 151797 1.411 0.653 0.000 2.696 1.810 2 2 2 2 2 151828 1.371 0.674 0.062 2.064 2.894 2 2 2 2 2 151828 1.439 0.752 0.103 2.088 5.500 2 2 2 2 2 151828 1.361 0.101 2.288 4.145 2 5 2 2 2 151838 0.715 0.366 0.060 1.325 0.079 2 2 2 2 2 151838 0.735 0.417 0.024 1.660 3.313 2 2 2 2 2 151838 0.744 0.398 0.027 1.574 3.290 2 2 2 2 2 151865 2.535 1.278 0.102 4.318 3.512 2 2 2 2 2 151865 2.541 1.289 0.121 4.623 7.347 2 2 2 2 2 151865 2.680 1.265 0.058 4.276 11.085 2 2 2 2 2 151892 3.446 1.594 0.213 5.292 4.518 2 2 2 2 2 151892 3.542 1.634 0.267 5.338 13.812 2 2 2 2 2 151892 3.543 1.662 0.270 5.107 13.111 2 2 2 2 2 151899 1.949 0.914 0.127 3.778 5.052 2 2 2 2 2 151899 2.137 0.938 0.124 3.581 8.955 2 2 2 2 2 151899 1.958 0.998 0.112 3.732 4.499 2 2 2 2 2 151954 3.056 1.675 0.199 5.151 9.905 2 2 2 2 2 151954 3.146 1.909 0.162 4.895 3.184 2 2 2 2 2 151954 3.308 1.721 0.212 5.018 12.295 2 2 2 2 2 151984 1.415 0.902 0.127 2.688 0.057 2 2 2 2 2 151984 1.476 0.737 0.106 2.632 5.697 2 2 2 2 2 151984 1.482 0.797 0.078 2.769 5.991 2 2 2 2 2 152008 1.424 0.771 0.069 2.579 3.953 2 2 2 2 2 152008 1.471 0.761 0.042 2.711 5.820 2 2 2 2 2 152008 1.498 0.764 2.652 5.657 2 2 5 2 2 152066 0.935 0.590 0.043 1.931 0.305 2 2 2 2 2 152066 0.973 0.458 0.030 2.113 2.382 2 2 2 2 2 152066 1.009 0.532 0.000 1.994 3.794 2 2 2 2 2 152099 2.073 1.118 0.092 0.969 0.466 2 2 2 2 2 152099 2.165 1.219 0.089 1.222 6.945 2 2 2 2 2 152099 2.186 1.065 0.128 1.073 6.605 2 2 2 2 2 152107 2.097 0.875 0.071 3.111 1.557 2 2 2 2 2 152107 2.109 1.140 0.086 3.454 6.383 2 2 2 2 2 152125 0.637 0.305 0.026 1.469 2.735 2 2 2 2 2 152125 0.660 0.240 0.010 1.510 0.000 2 2 2 2 2 152125 0.662 0.305 0.022 1.485 2.574 2 2 2 2 2 152147 0.754 0.449 0.028 1.636 3.041 2 2 2 2 2 152147 0.767 0.428 0.033 1.661 3.372 2 2 2 2 2 152147 0.787 0.540 0.033 1.779 2.418 2 2 2 2 2 152175 0.915 0.479 0.022 0.915 3.834 2 2 2 2 2 152175 0.903 0.573 0.069 0.871 1.138 2 2 2 2 2 152175 0.913 0.454 0.059 0.851 0.808 2 2 2 2 2 d. Standards Used Standardization was carried out using gas standards made up at Brookhaven National Laboratories. Standard volumes were corrected for lab temperature and pressure. Results were reported in units of pmol/kg of sea water. Clean air samples were also analyzed with each station, as a check on the standardization. 8. Reversing Thermometers Anthony W. Isenor a. Description of Equipment and Technique Sensoren-Instrumente-Systeme digital reversing thermometers model RTM 4002 were used to verify CTD thermistor readings on most deep stations. The thermometers had a depth range of up to 10000 m. The pressure housing was made of a glass tube closed at the ends by metal stoppers. One end contained the platinum sensor and at the other end was the battery compartment. The thermometers were placed on bottles one and three on the rosette, thus, sampling the temperature at the deepest and third deepest bottle trips. The thermometers were placed in standard reversing thermometer racks on the Niskin bottles. Before deployment, a magnet was passed over the thermometers to clear the display and place the thermometer in sample mode. A new temperature was then recorded upon reversal of the thermometer. On the deepest stations, unprotected mercury in glass thermometers were also attached to the deepest and third deepest bottle trips. The following table lists the number of readings from each thermometer. Digital thermometers are indicated with a 'T' in the serial number. Thermometer Ser. No. Number of Readings 000T345 94 000T347 94 000T350 96 000T352 1 000T354 95 0010987 114 0010988 125 b. Sampling Procedure and Data Processing Technique The thermometers indicated the temperature reading either via a digital display or column of mercury. The temperature was read and noted on log sheets. The readings were later digitized and calibrations applied using the water sample database system. c. Calibration Data The digital thermometers were calibrated at BIO in June 1994, while the mercury thermometers were last calibrated in January 1989. d. Replicate Analysis A total of 180 sample id numbers had one digital thermometer temperature replicate. The following is a statistical summary of the absolute value of the replicate differences. Only acceptable values were used in calculating the statistics. Statistic Number of Replicate Differences 120 Minimum (C) 0.002 Maximum (C) 0.011 Mean (C) 0.007 Median (C) 0.007 Standard Deviation (C) 0.002 All of the replicate reversing thermometer temperature values, along with the reversing thermometer pressure values are given in Table C.6. Table C.6 Replicate Reversing Thermometer samples. Temperature is in C and ITS-90 scale. Pressure is in dbars. Sample ID Thermometer Serial Main Thermometer WOCE QF Number Number Corrected Pressure 150601 000T350 3.644 2 9 150601 000T352 3.646 2 9 150601 0010988 9 9 150603 000T345 3.639 2 9 150603 000T347 3.644 2 9 150603 0010987 9 9 150621 000T350 -0.849 3 9 150621 000T354 -0.850 3 9 150621 0010988 9 9 150623 000T345 9.211 3 9 150623 000T347 9.219 3 9 150623 0010987 9 9 150624 000T350 3.276 2 9 150624 000T354 3.283 2 9 150624 0010988 9 9 150626 000T345 3.374 2 9 150626 000T347 3.380 2 9 150626 0010987 9 9 150632 000T350 3.285 3 9 150632 000T354 3.279 3 9 150632 0010988 9 9 150634 000T345 3.103 2 9 150634 000T347 3.110 2 9 150634 0010987 9 9 150647 000T350 2.237 2 9 150647 000T354 2.245 2 9 150649 000T345 2.593 2 9 150649 000T347 2.598 2 9 150667 000T350 2.215 2 9 150667 000T354 2.223 2 9 150667 0010988 3575.7 9 2 150669 000T345 2.318 2 9 150669 000T347 2.324 2 9 150669 0010987 9 9 150687 000T350 2.239 2 9 150687 000T354 2.246 2 9 150687 0010988 3854.4 9 3 150689 000T345 2.272 3 9 150689 000T347 2.279 3 9 150689 0010987 3601.8 9 3 150707 000T350 9 9 150707 000T354 9 9 150707 0010988 9 9 150709 000T345 9 9 150709 000T347 9 9 150709 0010987 9 9 150717 000T350 2.547 2 9 150717 000T354 2.553 2 9 150717 0010988 9 9 150719 000T345 3.401 4 9 150719 000T347 3.406 4 9 150719 0010987 9 9 150737 000T350 2.250 2 9 150737 000T354 2.257 2 9 150737 0010988 4144.2 9 2 150737 0010988 4144.5 9 2 150739 000T345 2.327 3 9 150739 000T347 2.333 3 9 150739 0010987 3749.5 9 3 150739 0010987 3748.2 9 3 150757 000T350 2.269 2 9 150757 000T354 2.276 2 9 150757 0010988 5486.4 9 2 150757 0010988 5506.4 9 2 150759 000T345 2.255 2 9 150759 000T347 2.262 2 9 150759 0010987 5154.3 9 2 150759 0010987 5155.4 9 2 150777 000T350 2.267 2 9 150777 000T354 2.275 2 9 150777 0010988 5500.8 9 2 150779 000T345 2.274 2 9 150779 000T347 2.279 2 9 150779 0010987 5198.7 9 2 150797 000T350 2.266 2 9 150797 000T354 2.274 2 9 150797 0010988 5493.8 9 2 150797 0010988 5481.2 9 2 150799 000T345 2.262 2 9 150799 000T347 2.267 2 9 150799 0010987 5184.2 9 2 150799 0010987 5184.7 9 2 150817 000T350 2.278 2 9 150817 000T354 2.285 2 9 150817 0010988 5508.8 9 2 150817 0010988 5514.7 9 2 150819 000T345 2.259 2 9 150819 000T347 2.265 2 9 150819 0010987 5186.1 9 2 150819 0010987 5186.1 9 2 150837 000T350 2.356 2 9 150837 000T354 2.362 2 9 150837 0010988 4126.5 9 2 150837 0010988 4126.8 9 2 150839 000T345 2.658 2 9 150839 000T347 2.663 2 9 150839 0010987 3520.0 9 2 150839 0010987 3516.1 9 2 150857 000T350 2.229 2 9 150857 000T354 2.237 2 9 150857 0010988 5486.2 9 2 150857 0010988 5498.3 9 2 150859 000T345 2.274 2 9 150859 000T347 2.280 2 9 150859 0010987 4992.8 9 2 150859 0010987 5006.4 9 2 150877 000T350 2.243 2 9 150877 000T354 2.251 2 9 150877 0010988 5437.0 9 2 150877 0010988 5450.1 9 2 150879 000T345 2.269 2 9 150879 000T347 2.274 2 9 150879 0010987 4917.1 9 3 150879 0010987 4917.6 9 3 150897 000T350 2.302 2 9 150897 000T354 2.310 2 9 150897 0010988 5443.5 9 2 150897 0010988 5444.9 9 2 150899 000T345 2.280 2 9 150899 000T347 2.285 2 9 150899 0010987 5134.5 9 2 150899 0010987 5141.5 9 2 150917 000T350 2.302 2 9 150917 000T354 2.308 2 9 150917 0010988 5382.7 9 2 150919 000T345 2.264 2 9 150919 000T347 2.271 2 9 150919 0010987 4751.0 9 3 150937 000T350 2.277 2 9 150937 000T354 2.286 2 9 150937 0010988 5325.6 9 2 150939 000T345 2.259 2 9 150939 000T347 2.264 2 9 150939 0010987 4966.5 9 2 150939 0010987 4991.1 9 2 150957 000T350 2.270 2 9 150957 000T354 2.277 2 9 150957 0010988 5313.3 9 2 150959 000T345 2.263 3 9 150959 000T347 2.190 3 9 150959 0010987 4997.2 9 3 150977 000T350 2.284 2 9 150977 000T354 2.292 2 9 150977 0010988 5241.6 9 2 150977 0010988 5254.7 9 2 150979 000T345 2.258 2 9 150979 000T347 2.264 2 9 150979 0010987 4718.6 9 2 150997 000T350 2.281 2 9 150997 000T354 2.288 2 9 150997 0010988 5225.9 9 2 150997 0010988 5230.4 9 2 150999 000T345 2.258 2 9 150999 000T347 2.263 2 9 150999 0010987 4897.6 9 2 150999 0010987 4885.6 9 2 151017 000T350 9 9 151017 000T354 9 9 151017 0010988 9 9 151019 000T345 2.219 2 9 151019 000T347 2.225 2 9 151019 0010987 4492.2 9 2 151019 0010987 4504.8 9 2 151037 000T350 2.172 2 9 151037 000T354 2.179 2 9 151037 0010988 4679.3 9 2 151039 000T345 2.185 2 9 151039 000T347 2.191 2 9 151039 0010987 4375.4 9 2 151057 000T350 2.157 2 9 151057 000T354 2.165 2 9 151057 0010988 4739.7 9 2 151059 000T345 2.253 2 9 151059 000T347 2.259 2 9 151059 0010987 4401.9 9 2 151059 0010987 4389.3 9 2 151077 000T350 2.263 2 9 151077 000T354 2.270 2 9 151077 0010988 4873.0 9 2 151077 0010988 4874.0 9 2 151079 000T345 2.281 2 9 151079 000T347 2.288 2 9 151079 0010987 4576.4 9 2 151079 0010987 4572.8 9 2 151097 000T350 2.303 2 9 151097 000T354 2.310 2 9 151097 0010988 4898.5 9 3 151097 0010988 4911.1 9 3 151099 000T345 2.322 2 9 151099 000T347 2.328 2 9 151099 0010987 4425.4 9 2 151099 0010987 4432.3 9 2 151117 000T350 9 9 151117 000T354 9 9 151117 0010988 9 9 151119 000T345 2.302 3 9 151119 000T347 2.307 3 9 151119 0010987 4268.6 9 4 151137 000T350 2.287 2 9 151137 000T354 2.296 2 9 151137 0010988 4982.7 9 2 151139 000T345 2.298 2 9 151139 000T347 2.304 2 9 151139 0010987 4408.4 9 2 151139 0010987 4421.0 9 2 151157 000T350 2.300 2 9 151157 000T354 2.307 2 9 151157 0010988 4990.8 9 2 151157 0010988 4992.8 9 2 151159 000T345 3.210 4 9 151159 000T347 3.215 4 9 151159 0010987 9 9 151177 000T350 2.272 2 9 151177 000T354 2.280 2 9 151177 0010988 4854.4 9 3 151177 0010988 4854.9 9 3 151179 000T345 3.998 4 9 151179 000T347 4.004 4 9 151179 0010987 9 9 151197 000T350 2.266 2 9 151197 000T354 2.274 2 9 151197 0010988 4935.5 9 4 151197 0010988 4935.2 9 4 151199 000T345 9 9 151199 000T347 9 9 151199 0010987 9 9 151217 000T350 2.253 2 9 151217 000T354 2.260 2 9 151217 0010988 4361.1 9 3 151217 0010988 4379.5 9 3 151219 000T345 3.993 4 9 151219 000T347 3.995 4 9 151219 0010987 9 9 151237 000T350 2.303 2 9 151237 000T354 2.311 2 9 151237 0010988 4613.0 9 3 151239 000T345 9 9 151239 000T347 9 9 151239 0010987 9 9 151257 000T350 2.223 2 9 151257 000T354 2.231 2 9 151257 0010988 4223.9 9 2 151259 000T345 3.016 4 9 151259 000T347 3.022 4 9 151259 0010987 9 9 151277 000T350 2.209 2 9 151277 000T354 2.216 2 9 151277 0010988 4032.0 9 2 151277 0010988 4032.8 9 2 151279 000T345 2.855 4 9 151279 000T347 2.861 4 9 151279 0010987 9 9 151297 000T350 2.167 2 9 151297 000T354 2.173 3 9 151297 0010988 3703.3 9 3 151297 0010988 3704.5 9 3 151299 000T345 2.952 2 9 151299 000T347 2.959 2 9 151299 0010987 9 9 151317 000T350 15.295 4 9 151317 000T354 15.193 4 9 151317 0010988 9 9 151319 000T345 3.119 4 9 151319 000T347 3.125 4 9 151319 0010987 9 9 151337 000T350 3.104 2 9 151337 000T354 3.112 2 9 151337 0010988 9 9 151339 000T345 3.101 2 9 151339 000T347 3.106 2 9 151339 0010987 9 9 151351 000T350 3.372 2 9 151351 000T354 3.379 2 9 151351 0010988 9 9 151353 000T345 3.489 4 9 151353 000T347 3.492 4 9 151353 0010987 9 9 151360 000T350 3.477 2 9 151360 000T354 3.484 2 9 151360 0010988 9 9 151362 000T345 -0.858 4 9 151362 000T347 -0.856 4 9 151362 0010988 9 9 151367 000T350 3.142 2 9 151367 000T354 3.150 2 9 151367 0010988 9 9 151369 000T345 9 9 151369 000T347 9 9 151369 0010987 9 9 151371 000T350 0.905 3 9 151371 000T354 0.916 3 9 151371 0010988 9 9 151373 000T345 9.579 3 9 151373 000T347 9.503 3 9 151373 0010987 9 9 151374 000T350 -0.858 3 9 151374 000T354 -0.850 3 9 151377 000T350 -0.462 3 9 151377 000T354 -0.453 3 9 151378 000T345 9 9 151378 000T347 9 9 151380 000T350 -0.122 2 9 151380 000T354 -0.113 2 9 151380 0010988 9 9 151382 000T345 9 9 151382 000T347 9 9 151382 0010987 9 9 151383 000T350 2.003 2 9 151383 000T354 2.012 2 9 151383 0010988 9 9 151385 000T345 5.266 4 9 151385 000T347 5.290 4 9 151385 0010987 9 9 151387 000T350 3.101 4 9 151387 000T354 3.109 4 9 151387 0010988 9 9 151389 000T345 2.499 4 9 151389 000T347 2.504 4 9 151389 0010987 9 9 151392 000T350 2.946 4 9 151392 000T354 2.956 4 9 151392 0010988 9 9 151394 000T345 3.461 4 9 151394 000T347 3.468 4 9 151394 0010987 9 9 151400 000T350 3.188 2 9 151400 000T354 3.197 2 9 151402 000T345 4.439 4 9 151402 000T347 4.444 4 9 151407 000T350 3.725 2 9 151407 000T354 3.733 2 9 151409 000T345 9 9 151409 000T347 9 9 151411 000T350 2.986 2 9 151411 000T354 2.995 2 9 151411 0010988 9 9 151413 000T345 3.402 2 9 151413 000T347 3.407 2 9 151413 0010987 9 9 151419 000T350 3.068 2 9 151419 000T354 11.046 4 9 151419 0010988 9 9 151421 000T345 3.032 3 9 151421 000T347 3.037 3 9 151421 0010987 9 9 151433 000T350 2.233 2 9 151433 000T354 10.672 4 9 151433 0010988 3000.2 9 2 151435 000T345 2.246 4 9 151435 000T347 10.722 4 9 151435 0010987 9 9 151453 000T350 2.190 2 9 151453 000T354 2.199 2 9 151453 0010988 3635.0 9 2 151453 0010988 3640.8 9 2 151455 000T345 3.140 4 9 151455 000T347 3.128 4 9 151455 0010987 9 9 151473 000T350 2.192 3 9 151473 000T354 2.181 3 9 151473 0010988 3801.0 9 3 151473 0010988 3801.1 9 3 151475 000T345 2.428 4 9 151475 000T347 2.436 4 9 151475 0010987 3483.8 9 4 151475 0010987 3485.7 9 4 151493 000T350 2.223 2 9 151493 000T354 2.231 2 9 151493 0010988 4303.2 9 2 151495 000T345 3.385 4 9 151495 000T347 3.389 4 9 151495 0010987 9 9 151513 000T350 2.282 2 9 151513 000T354 2.288 2 9 151513 0010988 4498.9 9 2 151515 000T345 2.597 4 9 151515 000T347 2.601 4 9 151515 0010987 9 9 151533 000T350 2.289 2 9 151533 000T354 2.297 2 9 151533 0010988 4881.4 9 2 151533 0010988 4882.7 9 2 151535 000T345 2.318 4 9 151535 000T347 2.322 4 9 151535 0010987 4138.3 9 4 151535 0010987 4138.8 9 4 151553 000T350 2.270 2 9 151553 000T354 2.278 2 9 151553 0010988 4949.3 9 4 151555 000T345 2.401 4 9 151555 000T347 2.405 4 9 151555 0010987 4275.6 9 4 151573 000T350 2.266 4 9 151573 000T354 2.274 2 9 151573 0010988 4953.1 9 2 151573 0010988 4950.0 9 2 151575 000T345 2.307 2 9 151575 000T347 2.311 2 9 151575 0010987 4415.8 9 3 151575 0010987 4416.2 9 3 151593 000T350 2.293 2 9 151593 000T354 2.300 2 9 151593 0010988 4945.8 9 2 151595 000T345 2.359 4 9 151595 000T347 2.363 4 9 151595 0010987 4210.5 9 4 151613 000T350 2.285 3 9 151613 000T354 2.294 3 9 151613 0010988 4908.3 9 3 151613 0010988 4909.6 9 3 151615 000T345 2.289 2 9 151615 000T347 2.293 2 9 151615 0010987 4699.5 9 2 151615 0010987 4700.1 9 2 151633 000T350 2.293 2 9 151633 000T354 2.301 2 9 151633 0010988 5005.3 9 2 151633 0010988 4993.3 9 2 151635 000T345 2.347 2 9 151635 000T347 2.351 2 9 151635 0010987 4243.8 9 2 151635 0010987 4249.2 9 2 151653 000T350 2.289 2 9 151653 000T354 2.298 2 9 151653 0010988 4968.4 9 2 151653 0010988 4964.7 9 2 151655 000T345 2.314 2 9 151655 000T347 2.318 2 9 151655 0010987 4659.5 9 2 151673 000T350 2.300 2 9 151673 000T354 2.309 2 9 151673 0010988 4933.9 9 2 151673 0010988 4935.2 9 2 151675 000T345 2.309 2 9 151675 000T347 2.313 2 9 151675 0010987 4544.3 9 2 151693 000T350 2.305 2 9 151693 000T354 2.315 2 9 151693 0010988 4914.7 9 2 151695 000T345 2.344 2 9 151695 000T347 2.349 2 9 151695 0010987 4654.8 9 2 151713 000T350 2.297 2 9 151713 000T354 2.305 2 9 151713 0010988 4888.8 9 2 151713 0010988 4887.5 9 2 151715 000T345 2.462 4 9 151715 000T347 2.467 4 9 151715 0010987 4179.7 9 4 151715 0010987 4180.4 9 4 151733 000T350 2.294 3 9 151733 000T354 2.300 3 9 151733 0010988 9 9 151735 000T345 3.186 4 9 151735 000T347 3.192 4 9 151735 0010987 9 9 151753 000T350 2.284 2 9 151753 000T354 2.293 2 9 151753 0010988 4832.9 9 2 151753 0010988 4834.2 9 2 151755 000T345 16.140 4 9 151755 000T347 15.815 4 9 151755 0010987 9 9 151773 000T350 2.285 2 9 151773 000T354 2.294 2 9 151773 0010988 4831.5 9 2 151773 0010988 4840.5 9 2 151775 000T345 16.935 9 9 151775 000T347 16.458 9 9 151813 000T350 2.286 2 9 151813 000T354 2.295 2 9 151813 0010988 4748.3 9 2 151815 000T345 2.300 2 9 151815 000T347 2.305 2 9 151815 0010987 4309.6 9 2 151833 000T350 2.277 2 9 151833 000T354 2.284 2 9 151833 0010988 4651.1 9 3 151835 000T345 2.282 2 9 151835 000T347 2.285 2 9 151835 0010987 4415.0 9 2 151853 000T350 2.177 2 9 151853 000T354 2.186 2 9 151853 0010988 4166.0 9 2 151855 000T345 2.200 2 9 151855 000T347 2.206 2 9 151855 0010987 3972.9 9 2 151873 000T350 2.164 2 9 151873 000T354 2.174 2 9 151873 0010988 3952.0 9 2 151875 000T345 2.233 2 9 151875 000T347 2.237 2 9 151875 0010987 3624.5 9 2 151893 000T350 2.590 2 9 151893 000T354 2.599 2 9 151893 0010988 9 9 151895 000T345 9.271 9 9 151895 000T347 9.243 9 9 151895 0010987 9 9 151910 000T350 2.979 2 9 151910 000T354 2.990 2 9 151912 000T345 3.409 2 9 151912 000T347 3.412 2 9 151915 000T350 2.170 2 9 151915 000T354 2.178 2 9 151915 0010988 9 9 151917 000T345 10.065 3 9 151917 000T347 10.066 3 9 151917 0010987 9 9 151918 000T350 1.529 3 9 151918 000T354 1.537 3 9 151918 0010988 9 9 151920 000T350 2.695 2 9 151920 000T354 2.706 2 9 151920 0010988 9 9 151922 000T345 9.393 2 9 151922 000T347 9.397 2 9 151922 0010987 9 9 151923 000T350 3.434 2 9 151923 000T354 3.445 2 9 151923 0010988 9 9 151925 000T345 1.895 3 9 151925 000T347 1.898 3 9 151925 0010987 9 9 151927 000T350 2.836 2 9 151927 000T354 2.843 2 9 151929 000T345 3.336 4 9 151929 000T347 3.338 4 9 151932 000T350 2.830 2 9 151932 000T354 2.840 2 9 151932 0010988 9 9 151934 000T345 2.833 3 9 151934 000T347 2.838 3 9 151934 0010987 9 9 151941 000T350 2.318 2 9 151941 000T354 2.329 2 9 151941 0010988 9 9 151943 000T345 2.613 2 9 151943 000T347 2.618 2 9 151943 0010987 9 9 151961 000T350 2.060 2 9 151961 000T354 2.070 2 9 151961 0010988 3580.7 9 2 151963 000T345 2.289 2 9 151963 000T347 2.294 2 9 151963 0010987 9 9 151981 000T350 2.079 2 9 151981 000T354 2.088 2 9 151981 0010988 3977.7 9 2 151981 0010988 3978.2 9 2 151983 000T345 2.210 3 9 151983 000T347 2.214 3 9 151983 0010987 3701.7 9 3 151983 0010987 3700.6 9 3 152001 000T350 2.186 2 9 152001 000T354 2.196 2 9 152001 0010988 4262.7 9 2 152003 000T345 2.287 2 9 152003 000T347 2.291 2 9 152003 0010987 3781.6 9 2 152021 000T350 2.133 2 9 152021 000T354 2.143 2 9 152021 0010988 4385.3 9 2 152023 000T345 2.297 3 9 152023 000T347 2.302 3 9 152023 0010987 3985.4 9 3 152041 000T350 2.156 2 9 152041 000T354 2.165 2 9 152041 0010988 4611.6 9 2 152043 000T345 2.319 2 9 152043 000T347 2.321 2 9 152043 0010987 4244.5 9 2 152061 000T350 2.286 2 9 152061 000T354 2.296 2 9 152061 0010988 4572.8 9 2 152063 000T345 2.329 2 9 152063 000T347 2.331 2 9 152063 0010987 4280.2 9 2 152081 000T350 2.256 2 9 152081 000T354 2.265 2 9 152081 0010988 4665.4 9 2 152081 0010988 4665.9 9 2 152083 000T345 2.475 4 9 152083 000T347 2.479 4 9 152083 0010987 4009.2 9 4 152083 0010987 4009.5 9 4 152101 000T350 2.399 3 9 152101 000T354 2.400 3 9 152101 0010988 9 9 152103 000T345 2.820 4 9 152103 000T347 2.824 4 9 152103 0010987 9 9 152121 000T350 2.293 2 9 152121 000T354 2.301 2 9 152121 0010988 4193.1 9 2 152121 0010988 4193.8 9 2 152123 000T345 2.336 2 9 152123 000T347 2.340 2 9 152123 0010987 3755.7 9 2 152123 0010987 3754.7 9 2 152141 000T350 2.281 2 9 152141 000T354 2.292 2 9 152141 0010988 4854.2 9 2 152141 0010988 4873.1 9 2 152143 000T345 2.308 2 9 152143 000T347 2.314 2 9 152143 0010987 4493.8 9 2 152143 0010987 4481.7 9 2 152161 000T350 15.277 4 9 152161 000T354 15.057 4 9 152161 0010988 3821.8 9 4 152161 0010988 3822.1 9 4 152163 000T345 15.355 4 9 152163 000T347 15.133 4 9 152163 0010987 3420.2 9 4 152163 0010987 3419.0 9 4 D. ACKNOWLEDGEMENTS E. REFERENCES Carritt, D.E. and J.H. Carpenter. 1966. Comparison and Evaluation of Currently Employed Modifications of the Winkler Method for Determining Dissolved Oxygen in Seawater. A NASCO Report, Jour. Mar. Res., 24, 268-318. Clarke, R. Allyn, Jean-Guy Dessureault and Geoff Lebans. 1995. Upper-ocean Profiling from Vessels Underway, Sea Technology, February 1995. Jones, E.P., F. Zemlyak and P. Stewart. 1992. Operating Manual for the Bedford Institute of Oceanography Automated Dissolved Oxygen Titration System. Can. Tech. Rep. of Hydrography and Ocean Sci. 138: iv+51p. Levy, E.M., C.C. Cunningham, C.D.W. Conrad and J.D. Moffatt. 1977. The Determination of Dissolved Oxygen in Sea Water, Bedford Institute of Oceanography Report Series, BI-R-77-9, August 1977. Appendix 1 94030 Reversed Pump Investigation PRIVATE March 13, 1995 Adam Rostis A.1 INTRODUCTION On cruise 94030, it was found that for stations 1 through 14 inclusive, the pump on the CTD was hooked up in reverse. This caused water to flow past the CTD sensors opposite to the normal flow direction as shown in Figure A1. (See also the document 94030 Reversed Pump Problem, January 16, 1995). pump ^ | | oxygen ^ | | direction of normal flow ^ conductivity | ^ | | | temperature Figure A1: Relative location of sensors on CTD showing normal direction of water flow. A.2 CONDUCTIVITY AND TEMPERATURE ALIGNMENT In either the normal or reversed case, the physical distance between sensors results in a finite time for a parcel of water to move between sensors. In turn, this produces a time delay between the sensor signals that result by exposing the sensors to the particular parcel of water (i.e. in the normal flow case the signal produced by the conductivity sensor refers to a parcel of water which arrived at the temperature sensor delta-t seconds earlier). It is necessary to align the signals in time so that they refer to the same parcel of water. The SEASOFT module ALIGNCTD allows for time alignment of the conductivity and temperature signals by specifying values for delta-t (where delta-t is the time advance of conductivity relative to temperature). The Seabird manual CTD Data Acquisition Software SEASOFT Version 4.201 (pg. 18) states that: "the best diagnostic of proper alignment is the elimination of salinity spikes that coincide with very sharp temperature steps." Graphs of salinity, density and potential temperature were produced using various values of delta-t to determine which delta-t would minimize salinity spiking. A.2.1 Determining an Initial Guess for delta-t The Seabird manual titled The Temperature and Conductivity Duct: Installation, Use and Data Processing Steps to Minimize Salinity Spiking Error gave an indication of the direction to change delta-t based on the observed direction of salinity spikes on a salinity vs. pressure curve. "If salinity spikes are negative, conductivity must be lagged (negative advance). If salinity spikes are positive, conductivity must be advanced." (p.12). Figure A2 was taken from the above manual and illustrates the 2 possible situations *1 The magnitude of the change to delta-t was determined by subjectively evaluating the effect of various delta-t's on the salinity spiking. *1 An analogy can be used to help clarify the meaning of "advance" and "lag" as they apply to conductivity and temperature signals. Think of a meeting occurring on some date. To "advance" the meeting means to move it in time a negative number of days or hours. To postpone or "lag" the meeting would mean to move it in time a positive number of days or hours. Figure A2*: The shift of conductivity data relative to temperature. A.2.2 Procedure to Determine a delta-t Value (stations 1 to 14): - download the .odf, .dat and .con file for a station in the reversed-pump range. Station 6 was chosen. The filenames were d030a006_1dbar.odf, 030a006.dat and 030a006.con. The files are located on the Fundy VAX under the directory digby$dka200:[data.seabird]. - using the SigmaPlot plotting software, plot Salinity, Density and Potential Temperature vs. Pressure from the archived .odf file, and select a region of pressure where there is a large temperature gradient. - make an initial guess for delta-t in ALIGNCTD and run station 6 using the process.bat file (see Appendix B for processing sequence). - import the resulting .cnv file into SigmaPlot and plot Salinity, Density and Potential Temperature vs. Pressure - based on the direction of salinity spiking (see under Introduction, Determining an Initial Guess for delta-t) repeat the above 2 steps until salinity spiking is minimized. - for 2 other stations in the reversed-pump range, create .cnv files using the delta-t value determined above. This is to ensure that the delta-t value chosen will apply to other stations. A.2.3 Results of delta-t Investigation As expected, large salinity spikes were noted for the reversed-pump stations with a standard delta-t value. For station 6, it was found that the coefficient that produced salinity curves with the least amount of spiking was delta-t = -0.270. For the 2 other stations (10 and 14), delta-t = -0.270 also produced salinity curves with minimal spiking. Figure A3* is a plot created from station 6 data after processing with ALIGNCTD using -0.270 for delta-t. A.3 PRESSURE SPIKING PROBLEM In addition to the reversed-pump problem, it was found that large pressure spikes were occurring on the first 10 stations. At the time of data collection, the problem was thought to be related to electronic interference from the deck unit. It was later determined to be a pressure sensor problem. A pressure spike removal program was created which marked bad any points included in these spikes. During processing using SEASOFT, these bad points were excluded from processing. See Appendix A for additional information on the pressure spike removal program. A.4 HEATING EFFECT The reversed pump situation appeared to introduce a thermal signal in the water passing through the duct system. Comparison of CTD and thermometer data from stations 1-14 with stations 15 onward indicate an increase in CTD temperature of 0.015C (see report by C.K. Ross) for the reversed pump situation. Thus, the 0.015C signal is removed from the temperature data for stations 1-14. Figure A3*. Station 6, Cruise 94030, 24 Hz .cnv data, Zoomed Pressure and delta-t = -0.27 A.5 PRESSURE OFFSET A diagram of the CTD (Figure A4) shows that water in the reversed-flow case travels a large distance (92 inches) before reaching the sensors at point A. The time lag associated with travelling this distance resulted in the pressure associated with the conductivity and temperature measurements being offset. This lag is important for associating the conductivity and temperature signals with the correct pressure from which the water parcel originated. This time lag was estimated using two methods. Method 1: Approximate the diameter of the tube over the entire circuit and then using the pump specification of 30 ml/s compute the time required to complete the circuit. The distance-weighted tube diameter was: (0.6 cm) * 12/92 + (1.12 cm) * 35/92 + (0.97 cm) * 45/92 1.0 cm (1) and so the time required for the water to flow through the entire circuit was Volume/Flowrate = ((92")(2.54 cm/in)pi(0.5cm)^2)/(30 ml/s) 6.1 seconds (2) Using the data shown in Figure A5*, we estimated dp/dt at Station 4 using the scan number and the 24 Hz sampling rate. Station 4 was chosen because of the large salinity gradient near the bottom of the cast. The large gradient provides the signal required to estimate the pressure offset, while the proximity to the bottom implies minimal time between the up and down cast. The following estimate of dp/dt was obtained from station 4 data. Direction Scan Range dp/dt (dbar/s) Down 63244-68184 0.97 Up 83467-78912 1.05 Applying these vertical CTD velocities, we obtained the delta-p associated with this estimate of the flow. Table 2 summarizes these results for both the up and down motion of the CTD. Figure A4*: Exhaust Path of Temperature/Conductivity Duct Water Figure A5*: Upcast and Downcast for station 4 Table 2A: delta-p associated with method 1 calculation. CTD Motion delta-p down cast 5.9 dbars up cast 6.4 dbars Total 12.3 dbars Method 2: This method is based on the delta-t value used for ALIGNCTD. We know that it takes ~ 0.2 s for water to travel between the temperature and conductivity sensors, a distance of ~18 cm. (Note: a 0.07 s offset was applied in the deck unit. To correct this, a value of -0.07 s must be applied in ALIGNCTD. Thus, 0.27 - 0.07 = 0.2. A value of 0.2 actually indicates the lag between the two sensors.) So the velocity in this section was: 18cm/0.2s = 90 cm/s (3) To estimate the velocity in the larger tubing, scale the velocity in eqn. (3) by the tube area: ((0.3)^2)/((0.5)^2) * 90 cm/s = 32 cm/s (4) This gave a travel time in the larger tubing of: ((92")(2.54 cm/in) - 18cm)/(32cm/s) = 6.7 s (5) for a total travel time of: 6.7 + 0.2 7 s (6) Again, using the above estimates of vertical CTD velocity we obtained Table A3 which estimated these results for both the up and down motion of the CTD. Table A3: delta-p associated with method 2 calculation. CTD Motion delta-p down cast 6.8 dbars up cast 7.4 dbars Total 14.2 dbars So, an overall estimate based on the results of these two calculations gave a total pressure offset between 12.3 and 14.2 dbars. Station 4 was then analyzed to determine whether this estimate agreed with an observed pressure offset. This station was chosen because of a salinity jump near the end of the cast which would allow the pressure offset to be detected (see Figure A5*). The 24 Hz salinity data for the up and down casts was used to produce a 0.5 dbar dataset. Pressure, downcast salinity and upcast salinity were imported into Quattro Pro for Windows. The upcast salinity was adjusted or "lagged" relative to the downcast salinity using pressures between 10 to 20 dbars. For each lag used, a correlation coefficient (r-value) was computed between the upcast and downcast salinity. High correlation coefficients would indicate that the downcast and upcast data were correlated for that region. The overall goal here was to determine by how much the upcast and downcast pressures were offset and to see if this offset agreed with the estimated offset. It was found that the best r-value (r = 0.971) for the correlation was obtained when the upcast salinity was lagged by 14.5 dbars over the pressure range 2050 - 2250 dbars. The entire range of correlation coefficients calculated are given in Table A4. The are also displayed in Figure A6*. Figure A6*: Results of the correlation between upcast and downcast salinity for various offsets in upcast salinity. Table A4: Results of the correlation between upcast and downcast salinity for various offsets in upcast salinity. Lag value r-value (dbars) 10 0.949664 11 0.958635 12 0.964828 13 0.968735 14 0.970667 14.5 0.970952 15 0.970732 15.5 0.970011 16 0.968781 17 0.964893 18 0.959119 19 0.951483 20 0.942292 CONCLUSION To correct the reversed pump situation for stations 1-14 the following procedure was followed to produce the 1 dbar and 2 dbar datasets from the raw 24 Hz data: - Conductivity was shifted by -0.27 s relative to temperature. Consider a parcel of water, W1, at the exit of the tubing (what would normally be the entrance). Suppose this parcel has conductivity and temperature of C(1+delta-t), and T1 respectively (C(1+delta-t) represents the time shifted conductivity). - Salinity is computed based on P1, C(1+delta-t), and T1, where P1 represents the pressure at the time W1 is at the temperature sensor. - remove the 0.015C heating effect from the temperature signal _ offset the pressure and scan number channels from all other parameter channels by lagging scan number and pressure by 7 seconds, or 168 scans. - compute the 1 and 2 dbar averages - compute theta and sigma parameters The following procedure was followed for the discrete CTD data found in the SEA file: - salinity was computed within the DATCNV module and 10 seconds of data was output to the ROS file. - remove the 0.015C heating effect from the temperature signal - offset the pressure and scan number channels from all other parameter channels by lagging scan number and pressure by 7 seconds, or 168 scans. - compute a 72 scan average for the discrete CTD values INCONSISTENCIES 1. The 72 scan average for the discrete CTD values should have been a 73 scan average to be consistent the shipboard processing. 2. The 168 scan offset represents a shift of 6.9583 seconds, not truly 7 seconds. 3. The produced QAT files for stations 1-14 will not contain a conductivity channel because of the different processing method 4. The CTD oxygen calculated for stations 1-14 during the reversed pump correction will be incorrect. The problem results from the in-situ temperature and pressure in the expression for oxygen. The in-situ temperature would have been high by 0.015 while the pressure would not have been offset by the required 7 seconds. We expect these problems would have been rectified during subsequent oxygen calibration steps. -------------------------------------------------------------------------------- Appendix A Description of the spike removal program ctd_prsp.exe (Program was created by Igor Yashayaev) The spike removal program takes an ASCII input data file (which is the .cnv file produced by the SEASOFT module DATCNV, running in ASCII-output mode) and marks as "bad" any regions where there are large pressure spikes. It does this by putting a small value (-9.99e-29) across all columns of the dat file where the pressure is spiking. It also writes out the values in this spiked pressure region to the file called "garbage". ctd_prsp also places a comment '* Pressure Spikes Removal Date